ライフサイエンスコーパス: nitrobenzene

1 ce of a major contaminant (4-methylphenol or nitrobenzene).

2 loroethane, dichloromethane, chloroform, and nitrobenzene).

3 ates, as well as the intersystem crossing of nitrobenzene.

4 f the ion trap and has been demonstrated for nitrobenzene.

5 ion in four steps and 24% overall yield from nitrobenzene.

6 ane, the long elusive phosphorus analogue of nitrobenzene.

7 lambda >= 340 nm) photoexcitation of aqueous nitrobenzene.

8 nitro compounds also such as Picric acid and Nitrobenzene.

9 r ortho (if para is substituted) position of nitrobenzene.

10 he activation of the remote meta-C-H bond of nitrobenzene.

11 nm), the nitroso oxide rapidly rearranges to nitrobenzene.

12 bearing clay minerals on the bioreduction of nitrobenzene.

13 are excellent catalysts in the reduction of nitrobenzene.

14 ,4,6-trichlorophenol, pentafluorophenol, and nitrobenzene.

15 ion by microbial and/or abiotic reduction of nitrobenzene.

16 from 15 to 1.7% for the 1347 cm(-1) mode of nitrobenzene.

17 ethoxy-2-nitroaniline and 1-iodo-4-methoxy-2-nitrobenzene.

18 s synthesized in three steps from 1-fluoro-2-nitrobenzene.

19 of several cytotoxic antitumor quinones and nitrobenzenes.

20 in large positive shifts in potential of the nitrobenzene(0/)(-) cyclic voltammetry wave with little

21 explosives and explosives-related compounds nitrobenzene, 1,3-dinitrobenzene, o-nitrotoluene, 2,4-di

22 , 3-nitroaniline, 4-nitroaniline, 1-chloro-2-nitrobenzene, 1-chloro-3-nitrobenzene, and 1-chloro-4-ni

23 Reductive hydrodynamic voltammograms of nitrobenzene, 2,4,6-trinitrotoluene, and hexahydro-1,3,5

24 cluding an array of nitroaromatic compounds (nitrobenzene, 2-, 3-, and 4-nitrotoluene, 2,4- and 2,6-d

25 dimethoxy-5,5'-binaphthoquinone in refluxing nitrobenzene (210 degrees C) gives, in a single syntheti

26 imulant methyl salicylate (1.24 ppb) and for nitrobenzene (629 pptr) are achieved.

27 acy of 86-92% for nitromethane and 1-ethyl-2-nitrobenzene, 71% for different mixtures of nitromethane

28 1,3-diphenylpropane (6), benzyl alcohol (7), nitrobenzene (8), and cyanobenzene (9).

29 Allylic esters of nitrobenzene acetic acids undergo facile palladium-catal

30 s synthesized from 1,3,5-tris(bromomethyl)-2-nitrobenzene acting as the self-immolative trigger respo

31 The three-component reaction between a nitrobenzene, an aldehyde, and a dienophile in the prese

32 tinum disk electrode in a solution of 0.06 M nitrobenzene and 0.5 M tetra-n-butylammonium hexafluorop

33 66% p-nitrophenol and 34% m-nitrophenol from nitrobenzene and 100% p-methoxyphenol from methoxybenzen

34 The limits of detection for nitrobenzene and 2,4-dinitrotoluene using SPI were also

35 stem is tested using the explosive simulants nitrobenzene and 2,4-dinitrotoluene, and with the nitram

36 stable intermediate in the biodegradation of nitrobenzene and 2-aminophenol by Pseudomonas pseudoalca

37 ame enzyme that initiates the degradation of nitrobenzene and 2-nitrotoluene also oxidizes 4-nitrotol

38 responding catechols by two enzymes, namely, nitrobenzene and 2-nitrotoluene dioxygenase (NBDO and 2N

39 sponding (13)C-KIEs for the dioxygenation of nitrobenzene and 2-nitrotoluene were 1.025 +/- 0.001 and

40 ioxygenation of two nitroaromatic compounds (nitrobenzene and 2-nitrotoluene) by nitrobenzene dioxyge

41 . strain JS42, which is capable of growth on nitrobenzene and 2-nitrotoluene, in experiments to exami

42 Detection limits are 25 ng for nitrobenzene and 50 ng for 2,4-dinitrotoluene.

43 cals like ethylbenzene, cumene, cyclohexane, nitrobenzene and alkylbenzene.

44 odeling and spin trapping in the presence of nitrobenzene and atrazine probes showed that SO(4)(*-) p

45 ar lack of positional selectivity is seen in nitrobenzene and benzonitrile.

46 In this work, electrochemical behavior of nitrobenzene and benzyl alcohol derivatives was studied

47 nd energies of attraction in acetonitrile of nitrobenzene and its anion radical and dianion with a se

48 ractionation revealed a common mechanism for nitrobenzene and nitrotoluenes.

49 known Pd catalysts for the hydrogenation of nitrobenzene and styrene and the Suzuki coupling reactio

50 We also find that hydrogen bonding between nitrobenzene and surrounding water molecules slows the S

51 ion cascade reaction between 2-amino/hydroxy nitrobenzenes and activated methyl groups.

52 aniline, 1-chloro-2-nitrobenzene, 1-chloro-3-nitrobenzene, and 1-chloro-4-nitrobenzene, could not onl

53 ides into solutions of DC18C6 in chloroform, nitrobenzene, and 1-octanol was undetectable.

54 sociated with the transformation of toluene, nitrobenzene, and four substituted nitrotoluenes by perm

55 The classic nitrobenzene anion-radical (NB(-*) or nitrobenzenide) is

56 on/ion reactions between peptide cations and nitrobenzene anions have been examined at both room temp

57 yl ether, tetrahydrofuran, benzophenone, and nitrobenzene are involved, the coordination number of th

58 s and alkyl-/arylthioanilides using 1-iodo-4-nitrobenzene as catalyst and oxone as an inexpensive and

59 hione S-conjugate precursor, 1-chloro-2,4-di-nitrobenzene, as well as cadmium.

60 thoxy-substituted giant biaryl (e.g., 21) in nitrobenzene at 260 degrees C does not yield the corresp

61 with 6,6'-dimethoxy-5,5'-binaphthoquinone in nitrobenzene at higher temperatures (250-260 degrees C),

62 rp(70) and Ser(45) were the key residues for nitrobenzene binding.

63 illonite SWy-2 and nontronite NAu-2 enhanced nitrobenzene bioreduction.

64 rnover of large substrates such as furan and nitrobenzene but caused no similar increase for the phys

65 tion from the O-demethylation of 1-methoxy-4-nitrobenzene by P450 1A2 isolated from rabbit liver prod

66 lso an intermediate in the biodegradation of nitrobenzene by Pseudomonas pseudoalcaligenes JS45.

67 reaction between hydroxyl radical (*OH) and nitrobenzene (C(6)H(5)NO(2)) were measured in subcritica

68 ectivity of the electrophilic bromination of nitrobenzene can be fundamentally changed by strongly co

69 d to test the relative reactivity, including nitrobenzene, carbamazepine, and fluconazole, whereby fe

70 DNT), 2,6-dinitrotoluene (2,6-DNT), 1-chloro-nitrobenzene (CNB), and nitrobenzene (NB), by their effe

71 ene, 1-chloro-3-nitrobenzene, and 1-chloro-4-nitrobenzene, could not only be detected but the electro

72 tive salt binding experiments carried out in nitrobenzene-d(5) and acetonitrile-d(3), these hosts cap

73 3) and CsCl from an aqueous D(2)O layer into nitrobenzene-d(5) as inferred from (1)H NMR spectroscopi

74 mination occurred upon themolysis of 1a,b in nitrobenzene-d(5).

75 d to 2-aminomuconic acid semialdehyde in the nitrobenzene-degrading strain Pseudomonas pseudoalcalige

76 4.6 for aqueous pyridine or 2.2-3.7 for neat nitrobenzene, depending on the analyzed vibrational mode

77 ablished but yet complex system (a thiolated nitrobenzene derivative 4-NBM) whose reduction mechanism

78 4,5-dialkoxy-2-nitroaniline with a 1-bromo-2-nitrobenzene derivative featuring additional tert-butyl,

79 hydrogen bonding was studied for a series of nitrobenzene derivative radical anions, working as large

80 Highly fluorinated nitrobenzene derivatives are suitable substrates for pal

81 Reduction of nitrobenzene derivatives in the presence of arylureas in

82 ination reactions, starting from halogenated nitrobenzene derivatives.

83 yl-1-piperidine N-oxyl (4-amino-TEMPO) and 4-nitrobenzene diazonium (4-NBD) in real time.

84 via electrochemical reduction of 4-fluoro-3-nitrobenzene diazonium ion has been developed and utiliz

85 Molecular grafting of p-nitrobenzene diazonium salt at the surface of (Li)FePO4-

86 orts a genetic analysis of the expression of nitrobenzene dioxygenase (NBDO) in Comamonas sp. strain

87 mpounds (nitrobenzene and 2-nitrotoluene) by nitrobenzene dioxygenase (NBDO) to obtain insights into

88 cts from 3-nitrotoluene than those made from nitrobenzene dioxygenase.

89 di- and polyarylureas possessing pyrene and nitrobenzene end groups separated by a variable number o

90 all three redox active ferrocene, C(60), and nitrobenzene entities.

91 roM GS-Succ-BP is provided by dinitrophenol, nitrobenzene, ethacrynic acid, and S-hexylglutathione, a

92 found that chemically reduced NAu-2 reduced nitrobenzene faster as compared to chemically reduced SW

93 (14) and ethyl 2-chloropropionate (16) with nitrobenzene followed by subsequent addition of an alkyl

94 oxygen atom transfer from electron-deficient nitrobenzenes, followed by trapping of the resultant acy

95 nitrate analysis was developed by producing nitrobenzene from the nitrate in the samples and benzene

96 Attaching a 4-nitrobenzene group to the open end of the spiropyran uni

97 X-ray data (100 K) allowed the resolution of nitrobenzene guest molecules at the internal walls of th

98 ease occurs in two steps with the disordered nitrobenzene guests released in the first step (lower te

99 are observed during the 1-e(-) reduction of nitrobenzene in acetonitrile solutions.

100 s of the ultrafast photochemical dynamics of nitrobenzene in aqueous solution.

101 allows the tandem reduction/N-alkylation of nitrobenzenes in good yields (up to 80%).

102 the quantification of 1,2-dichloroethane and nitrobenzene into water, yielding diffusion coefficients

103 These results are unexpected since nitrobenzene is a polar solvent that generally leads to

104 Arylation of nitrobenzene is also reported.

105 tions then show that thermal dissociation of nitrobenzene is dominated by 'roaming-mediated isomeriza

106 een 2,4-dinitrotoluene, ammonium nitrate and nitrobenzene is on a par with other state-of-the-art exp

107 Nitrobenzene is the smallest nitroaromatic molecule and

108 Nitrobenzene is treated with the same computational prot

109 Additional exposure of the nitrobenzene layer to chloroform and water gives 3 in it

110 tion of the resulting ketone tethered to the nitrobenzene moiety gives access to the hexahydro-2,6-me

111 r from the pyrene donors in gel 2 to trapped nitrobenzene molecules.

112 thionite) iron-bearing clay minerals reduced nitrobenzene more rapidly than biologically reduced iron

113 this study are to demonstrate degradation of nitrobenzene (NB) as a probe compound for sequential ele

114 llected from several sites contaminated with nitrobenzene (NB) or chlorobenzene (CB) were tested for

115 generated electrons to catalyze reduction of nitrobenzene (NB) to aniline with a yield of 97.8% durin

116 cis-syn-cis-dicyclohexano-18-crown-6 (1) in nitrobenzene (NB) was correlated with the standard Gibbs

117 n aqueous solutions and benzonitrile (BN) or nitrobenzene (NB) was measured and used to evaluate the

118 etection of nitroaromatic molecules, such as nitrobenzene (NB), 2,4-dinitrotoluene (DNT), 2,4,6-trini

119 This was observed with nitrobenzene (NB), 7,7,8,8-tetracyanoquinodimethane (TCN

120 (2,6-DNT), 1-chloro-nitrobenzene (CNB), and nitrobenzene (NB), by their effective quenching of the n

121 for the rapid and sensitive determination of nitrobenzene (NB).

122 unds [m-nitroaniline and p-nitroaniline] and nitrobenzenes [nitrobenzene, p-nitrotoluene, 2,4-dinitro

123 t (13)C- and (2)H-kinetic isotope effects of nitrobenzene, nitrotoluene isomers, 2,6-dinitrotoluene,

124 reaction was explored with eight substituted nitrobenzenes, obtaining yields of up to 87%.

125 rmediate while ruling out the possibility of nitrobenzene or nitroso-benzene formation during this tr

126 bination with energy-rich but non-hypergolic nitrobenzene or pyrazine yielded hypergolic co-crystals

127 ly 5 ps to form QD(*-); electron transfer to nitrobenzene or the intermediates nitrosobenzene and phe

128 ificantly better aryl radical acceptors than nitrobenzenes or phenyl ethers.

129 pecificity for 4-nitroaniline and 1-chloro-2-nitrobenzene over other nitroaniline isomers and nitroch

130 could extract KF from an aqueous phase into nitrobenzene, overcoming the high hydration energies of

131 d by application of thioacidolysis, alkaline nitrobenzene oxidation and acetyl bromide analyses.

132 ramatically slowed, the regiospecificity for nitrobenzene oxidation is altered, and 10-fold more T111

133 te constant for p-nitrophenol resulting from nitrobenzene oxidation.

134 iline and p-nitroaniline] and nitrobenzenes [nitrobenzene, p-nitrotoluene, 2,4-dinitrotoluene, and 2,

135 (+) cation of the CsNO(3) extracted into the nitrobenzene phase by receptor 3 may be released into th

136 extracted from the water phase into the bulk nitrobenzene phase containing highly lipophilic ionophor

137 o the aqueous phase by contacting the loaded nitrobenzene phase with an aqueous KClO(4) solution.

138 witterionic aminophosphinates derived from a nitrobenzene precursor accomplished the cyclization in g

139 The nitrobenzene produced was measured on a gas chromatograp

140 irectional transport of the electrogenerated nitrobenzene radical anion over macroscopic distances wi

141 ative of reversible hydrogen bonding between nitrobenzene radical anions and arylureas.

142 ucture-activity relationships when comparing nitrobenzene radical anions.

143 ologically driven, but at later time points, nitrobenzene reduction by biologically formed structural

144 ship (LFER) proposed in a previous study for nitrobenzene reduction by iron oxide-Fe(2+) couples, i.e

145 nd thermodynamic properties were considered, nitrobenzene reduction kinetics for all particle sizes w

146 Further, Cu(II) stimulates the nitrobenzene reduction of NfoR, indicating that Cu(II) p

147 y examining the effect that carbonate has on nitrobenzene reduction rates by Fe(2+) bound to goethite

148 Carbonate slowed nitrobenzene reduction rates by inducing goethite partic

149 Nitrobenzene reduction rates were lower for smaller part

150 On short time scales (<50 h), nitrobenzene reduction was primarily biologically driven

151 2+) reduction potentials or the mechanism of nitrobenzene reduction.

152 sulfenyl)phthalimide, and 4-azido-1-fluoro-2-nitrobenzene, respectively, and characterized as reversi

153 p-cresol and p-nitrophenol from toluene and nitrobenzene, respectively, as well as produced 2-naphth

154 The behavior of both the pyrene and nitrobenzene singlet states has been investigated by mea

155 or for cesium chloride and cesium bromide in nitrobenzene solution.

156 The cations form weak complexes with neutral nitrobenzene, stronger ion pairs with the monoanion, and

157 ER), similar to that reported previously for nitrobenzene, successfully captures all MC reduction rat

158 ure-dependent release of a model compound, 3-nitrobenzene sulfonate (3-NBS), from individual opticall

159 sol from toluene and 100% m-nitrophenol from nitrobenzene; thus, for the first time a true meta-hydro

160 d during initial steps in the degradation of nitrobenzene to a novel ring-fission lower pathway in Ps

161 interfacial redox reaction: the reduction of nitrobenzene to aniline by iron-oxide-bound Fe(2+).

162 le-light photocatalysts for the reduction of nitrobenzene to aniline through six sequential photoindu

163 as a source of hydrogen for the reduction of nitrobenzene to aniline.

164 Dioxygenation of nitrobenzene to catechol and 2-nitrotoluene to 3-methylc

165 The application of the photoreduction of nitrobenzene to the synthesis of paracetamol was achieve

166 elect) for the liquid-phase hydrogenation of nitrobenzene under standard operating conditions.

167 l conversion process for both the pyrene and nitrobenzene upper singlet states, as well as the inters

168 synthesis of derivatives of Indoprofen from nitrobenzene using readily available inexpensive startin

169 g the probe compounds tert-butyl alcohol and nitrobenzene verified the bubble-water interface as the

170 d 4,5-dialkoxy-2-nitroanilines and 1-bromo-2-nitrobenzenes via Buchwald-Hartwig amination, followed b

171 rent reactivity of SWy-2 versus NAu-2 toward nitrobenzene was caused by different forms of structural

172 on under extraction conditions from water to nitrobenzene was determined from plots of the cesium dis

173 When approximately 5% nitrobenzene was gelated together with benzene, fluoresc

174 hetero)arylhydroxylamines were obtained when nitrobenzene was substituted by electron-withdrawing gro

175 of a synthetic heparin mimetic, Arixtra, at nitrobenzene/water microinterfaces was investigated to o

176 r molecules in the photochemical dynamics of nitrobenzene, we compare the results of these investigat

177 1-nitronaphthalene in the presence of excess nitrobenzene, where it was shown that the resulting SOA

178 roxylation with all substrates tested except nitrobenzene, which gives only m-nitrophenol.

179 ry also agreed well for the dioxygenation of nitrobenzene, which was associated with (2)H- and (13)C-

180 ion of diaryl amide by aminocarbonylation of nitrobenzene with boronic acids.

181 ical behavior of cyclooctatetraene (COT) and nitrobenzene with Density Functional Theory and the cond

182 The cyclocondensation reactions of nitrobenzene with hydrogen-terminated Si(100) and Si(111

183 larger substrates such as ethane, furan, and nitrobenzene with Q while decreasing the rate constant f

184 an imaging study of the photodissociation of nitrobenzene with state-specific detection of the result

185 ical anions from para- and ortho-substituted nitrobenzenes with 1,3-diethylurea in acetonitrile was p