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2 -dihydro-4,4,5,5-tetramethyl-1H-imidazolyl-1-oxy-3-oxide (carboxy-PTIO, an NO scavenger), 1H-[1,2,4]-
3 nging; (ii) 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) scavenging; (iii) ferric ions (Fe(3+)) reduc
4 ak area reproducibility were obtained for 14 oxy-compounds present in trace amount in the complex bio
5 -tert-butyl-1,2-quinone-(3,5-di-tert-butyl-2-oxy-1-phenyl)imine) to give five-coordinate (X)(Y)Si(ON[
9 ther, these results indicate that both the 3-oxy and 4'-benzylamide positions in (R)-1 can accommodat
10 ied introduction of larger moieties at the 3-oxy site in (R)-1 was offset, in part, by including unsa
11 all nonpolar, nonbulky substituents at the 3-oxy site provided compounds with pronounced seizure prot
12 roups tethered by a 1,4-phenylenebis(butyl-4-oxy) unit (the strap) and carrying a methylbenzoic ester
13 s shown that the polarizing agent 1-(TEMPO-4-oxy)-3-(TEMPO-4-amino)propan-2-ol (TOTAPOL) has a strong
15 lylations to afford the desired 1,3-dienyl-6-oxy motif and enable complex polyketide synthesis in a r
17 acetoxybenzyl-based, 4-(5-(((4-acetoxybenzyl)oxy)amino)-2-carboxy-5-oxopentyl)benzoic acid, 12, provi
18 itrate and ferric ammonium citrate), against oxy- and met-hemoglobin erythrocytes used as controls.
21 ular anionic cyclization of (2-alkynylbenzyl)oxy nitriles has been developed for the preparation of s
22 (20 mol %) to a solution of (2-alkynylbenzyl)oxy nitriles in tetrahydrofuran at room temperature in a
23 ed base (BB) catalysis and the use of alpha'-oxy enones as enabling Michael acceptors with ambivalent
25 ones, thiazolones, and azlactones) to alpha'-oxy enones can afford the corresponding tetrasubstituted
26 ubstituted aliphatic, alpha-amino, and alpha-oxy acids as well as a variety of electron-deficient alk
27 ectively functionalize alpha-amino and alpha-oxy sp(3) C-H bonds in both cyclic and acyclic systems.
28 n successfully applied to a variety of alpha-oxy and alpha-amino acids, as well as simple hydrocarbon
30 ds, including hydrocarbon-substituted, alpha-oxy, and alpha-amino acids, provides a versatile CO2-ext
31 nd the chlorine radical source for the alpha-oxy C(sp(3))-H arylation of cyclic and acyclic ethers.
32 way is the cleavage of peroxide to the alpha-oxy radical (likely catalyzed by Cu), which is computati
35 ated by thermal transformation of aluminium (oxy)hydroxides, structural differences between them aris
36 he aqueous AlAl12(7+) ion to solid aluminum (oxy)-hydroxide phases, we found that this ion lies close
37 cotinamide core structure, 5-((3-amidobenzyl)oxy)nicotinamides offered excellent activity against SIR
42 tituted pyrimidine derivatives armed with an oxy-functionalized acetate chain at the ring is describe
43 imaging of a targeted fluorescent agent and oxy- and deoxyhemoglobin gave functional information abo
44 of the Fe-O(2) center in oxy-hemoglobin and oxy-myoglobin is a long-standing issue in the field of b
45 odocyclohexenone followed by methylation and oxy-Cope rearrangement delivered enantiomerically enrich
46 s (PAHs), PAH derivatives (nitro- (NPAH) and oxy-(OPAH)), organic carbon (OC), and particulate matter
50 amura's chiral allylzinc reagent, an anionic oxy-Cope rearrangement, and the Lewis acid-promoted cycl
51 lation of a cyclic enone followed by anionic oxy-Cope rearrangement delivered the ketone as a mixture
52 that relies on a diastereoselective anionic oxy-Cope rearrangement to set the relative configuration
58 iple functional groups, the chemistry of BCP-oxy and other alkoxy radicals in the system is diverse.
60 (6S)-2-nitro-6-{[4-(trifluoromethoxy)benzyl]oxy}-6,7-dihydro-5H-imidazo[2,1-b][1, 3]oxazine (PA-824)
61 -[(Guanine-9H-yl)methyl]propane-1,3-diyl)bis(oxy)]bis(methylene)}diphosphonic acid (compound 17) exhi
62 hyrinato zinc(II) 1 and 5-(2,5-phenylene-bis(oxy)diacetamide)-10,15,20-tris(triphenylamino)porphyrina
63 on prompts reaction with H2 to give a borane-oxy-borate derivative, the product of C-O bond cleavage.
64 ut on an alert macaque demonstrate that both oxy- and deoxyhemoglobin concentrations in the frontal l
65 eoxy), CO-inhibited (carboxy), and O2-bound (oxy) hemes in myoglobin (MB) and hemoglobin (HB) solutio
66 ethyl 6-bromo-8-(4-((tert-butyldimethylsilyl)oxy)benzamido)-4-oxo-4H-chromene-2-carboxy late (19) wit
67 pyl)-4-(((4-methoxyphenyl)(methyl) carbamoyl)oxy)indolin-1-ium hydrochloride) with IC50s of 0.4 and 1
68 d analog of [4-[[N-(3-chlorophenyl)carbamoyl]oxy]-2-butynyl]trimethylammonium chloride (McN-A-343).
69 erivatives: (3beta)-3-((thiophene-2-carbonyl)oxy)-olean-12-en-28-oic acid (1a) (IZ=22mm) and (2alpha,
73 icient strategy involving a copper-catalyzed oxy-alkynylation of diazo compounds with ethynylbenziodo
74 ein, we report the first palladium-catalyzed oxy- and aminoalkynylation using aliphatic bromoalkynes,
75 Hg(2+) is similar regardless of whether CO2 (oxy-fuel combustion) or N2 (air combustion) are the main
78 the absence of TCP, H(2)O(2) alone converts oxy-DHP to an inactive state (compound RH) instead of ox
81 ort EPR spectroscopic studies of cryoreduced oxy-F33Y-CuBMb, a functional model of HCOs engineered in
82 o EPR signal, in contrast to the cryoreduced oxy-wild-type (WT) Mb, which is unable to deliver a prot
83 pectroscopy data on solution and crystalline oxy-Hb indicate both geometric and electronic structure
84 concentrations of deoxy-hemoglobin (ctHHb), oxy-hemoglobin (ctHbO2), water (ctH2O), lipid, and TOI (
85 f the synthesis include a diastereoselective oxy-Cope rearrangement/oxidation sequence to install the
87 onitrile (5a) and (Z)-6-((2,6-dichlorobenzyl)oxy)-2-(pyridin-4-ylmethylene)benzofuran-3(2H)-one (5b)
88 wart rearrangement of (dimethylcarbamothioyl)oxy (oxa)helicenes in a flow reactor or nucleophilic sub
89 including (2S,2'S)-1,1'-(butane-1,4-diylbis(oxy))bis(N-isopropylpropan-2-amine) 7, (2S,2'S)-1,1'-(pe
90 lithiated (2S,2'S)-1,1'-(pentane-1,5-diylbis(oxy))bis(N-isopropyl-3-methylbutan-2-amine) 10 is a mono
91 amine) 7, (2S,2'S)-1,1'-(pentane-1,5-diylbis(oxy))bis(N-isopropylpropan-2-amine) 8, and (2S,2'S)-1,1'
92 e) 8, and (2S,2'S)-1,1'-(heptane-1,7-diylbis(oxy))bis(N-isopropyl-3-methylbutan-2-amine) 9 are dimers
93 ies, Hf(OTf)4 was used to convert the double oxy-Michael product 28 into C1-C19 building block 10.
94 SO(2) and SO(3), is considerably high during oxy-fuel combustion even though the sulfur content in Mo
95 erefore, for Morwell coal utilization during oxy-fuel combustion, additional sulfur removal, or polis
96 tonation step to form an enantiodiscriminant oxy-allyl cation prior to the stereodefining nucleophili
97 bis{[(E)-3-(3,4-dihydroxyphenyl)prop-2-enoyl]oxy}-1,5-dihydroxycyclohexane-1-carboxylic methyl ester
99 electron-donating (4-methoxy-1-(2-ethylhexyl)oxy)benzene (MEH) and electron-accepting benzothiadiazol
100 SHSAMs: ITO/IFL/poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][ 2-[[(2-eth
101 conducting PTB7 (poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluor o-2
102 ar-cell material poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro -2
103 -b']dithiophene-2,6-diyl][ 2-[[(2-ethylhexyl)oxy]carbonyl]-3-fluorothieno[3,4-b]thiophenediyl]]:pheny
104 pecies, ZnS, Zn3(PO4)2, and Zn associated Fe oxy/hydroxides, also regardless of the form of Zn added.
105 adsorption capacity for As(V) of a single Fe oxy-hydroxide combined with enhanced As(III) removal bas
106 t the ratio of ZnS and Zn associated with Fe oxy/hydroxide depended on the redox state and water cont
107 organically complexed Fe, and colloidal Fe (oxy)hydroxides, stabilized by surface interactions with
108 critical component of record-activity Ni/Fe (oxy)hydroxide (Ni(Fe)OxHy) oxygen evolution reaction (OE
109 Moreover, we found selective removal of Fe (oxy)hydroxides by aggregation at increasing salinity, wh
112 inct steps: 1) initial oxidation of ferrous (oxy) to ferryl Hb; 2) autoreduction of the ferryl interm
114 ize the active-site structure of the ferrous-oxy complexes of human (hIDO) and Shewanella oneidensis
116 T. cruzi and N-(3-chloro-4-((3-fluorobenzyl)oxy)phenyl)-7-(4-((4-methyl-1,4-diazepan-1-yl)sulf onyl)
117 gen, such as 4-((3-chloro-4-((3-fluorobenzyl)oxy)phenyl)amino)-6-(4-((4-methyl-1,4-diazepan-1- yl)sul
118 rophenyl) piperazin-1-yl)-2-((4-fluorobenzyl)oxy)-ethanone, or DPFE, demonstrates improved solubility
120 eal that: (i) the lipid binding affinity for oxy-Mb increases as the chain length increases (i.e. C12
124 ab-scale in a relevant environment) and full oxy-fuel combustion (TRL 4 being the component and syste
126 ational spectroscopy reveals that a furfuryl-oxy intermediate forms on TiO(2) as a result of a charge
127 rface activate the formation of the furfuryl-oxy intermediate via an electron transfer to furfuraldeh
129 rities--typical of flue gas from natural gas oxy-fuel combustion processes--the measured dew point pr
130 DA by VMAT2 increase levels of DA-generated oxy radicals ultimately resulting in degeneration of DAe
131 -beta-d-glucopyranosyl-beta-d-glucopyranosyl)oxy]-20-[(6-O-beta-d-xylopyra nosyl-beta-d-glucopyranosy
132 -beta-d-xylopyra nosyl-beta-d-glucopyranosyl)oxy]-dammar-24-en-19-al; (3beta)-28-oxo-28-(phenylmethox
133 -beta-d-glucopyranosyl-beta-d-glucopyranosyl)oxy]-ent-kaur-16-en-19-oic acid beta-d-glucopyranosyl es
134 eta-d-glucopy ranosyl)-beta-d-glucopyranosyl]oxy]-(3beta)-lanost-9(11)-en-24-one; 4-(2Z)-2-decen-1-yl
137 hydroxybenzoate (1), 2-2-[(4-hydroxybenzoyl)-oxy]-ethyl-4-methoxy-4-2-[(4-methylpentyl)oxy]-3,4-dihyd
138 s TCE by Fe(II) associated with the Fe(III) (oxy)hydroxide coating is substantially slower than that
139 also lead to transformation of the Fe(III) (oxy)hydroxide coating to more crystalline phases, the ra
140 to the abundance of precipitated iron(III) (oxy)hydroxides, are hot spots for the removal and rediss
141 and reactivity of floc amorphous Fe((III))-(oxy)hydroxide (FeOOH) phases under ice ([FeOOH](summer)
142 ental ligands on the dissolution of Cr(III)-(oxy)hydroxide solids and associated Cr isotope fractiona
143 vestigated the stability of Cr(III)-Fe(III)-(oxy)hydroxides, common Cr(VI) remediation products, with
146 lectronic structure of the Fe-O(2) center in oxy-hemoglobin and oxy-myoglobin is a long-standing issu
147 Patients with MDD had smaller changes in oxy-haemoglobin in the frontal and temporal cortices tha
148 ed using a 52-channel system, and changes in oxy-haemoglobin in the frontal and temporal regions were
151 lude an acid-catalyzed tandem intermolecular oxy-Michael/intramolecular trans-ketalization reaction a
154 tion was carried out on the N1-(p-iodobenzyl)oxy]methyl derivative of compound 5 using propagyl alcoh
155 d is employed to fabricate well-defined iron oxy-hydroxides and transitional metal doped iron oxy-hyd
157 hydroxides and transitional metal doped iron oxy-hydroxides nanomaterials, which show good catalytic
158 r performance in comparison to the pure iron oxy-hydroxide (FeOOH) catalysts, originate from the bran
160 rce of orthophosphate to WEOM-adsorbed iron (oxy)hydroxide AFM tips suggesting that the molecular mas
161 he phase transformation from amorphous iron (oxy)hydroxide to goethite, resulting in pyrite surface p
163 nding force between orthophosphate and iron (oxy)hydroxide that was coated onto atomic force microsco
168 rganic matter (WEOM) for adsorption to iron (oxy)hydroxide mineral surfaces is an important factor in
170 f calcium phosphate, calcium carbonate, iron(oxy)(hydr)oxide, silica, and also amino acids as an exam
171 xes and precipitated as nanoparticulate iron(oxy)hydroxides which aggregated as the pH increased, wit
172 thus became more coupled to that of the iron(oxy)hydroxides downstream in the circumneutral streams.
173 M but at pH >4.5 became associated with iron(oxy)hydroxides, and its transport thus became more coupl
177 biosolids with iron, aluminum, and manganese oxy/hydroxides has been advocated as a key mechanism lim
179 of dissolved organic matter (DOM) to metal (oxy)hydroxide mineral surfaces is a critical step for C
181 (3), BiVO(4), Si) paired with various metal-(oxy)hydroxide overlayers (e.g., Ni(Fe)O (x)H (y) and CoO
182 oxocyclohexa-1,4-dien-1-yl)methylene]-N-meth oxy-undecanamide (E3330-amide), a novel uncharged deriva
183 l)-oxy]-ethyl-4-methoxy-4-2-[(4-methylpentyl)oxy]-3,4-dihydr o-2H-6-pyranylbutanoic acid (2) and 3-((
184 d (3S)-(15-methyl-3-((13-methyltetradecanoyl)oxy)hexadecanoyl)glycyl-l-serine, abbreviated as l-serin
186 indicated the contribution of reductive Mn (oxy)hydoxide dissolution with Mn eventually becoming a t
188 ypes of regio- and enantioselective multiple oxy- and amino-functionalizations of terminal alkenes vi
189 s are important as Fe-containing Co- and Ni-(oxy)hydroxides are the fastest OER catalysts known.
190 vior of the anodic peak for amorphous nickel oxy/hydroxide (a-NiOx) films in basic media was investig
191 cluding 97 different parent, alkyl-, nitro-, oxy-, thio-, chloro-, bromo-, and high molecular weight
193 (eta(1)-ONO(2)) demonstrating the ability of oxy coboglobin models to promote the nitric oxide dioxyg
195 urther, although the rate of autoxidation of oxy-DHP is somewhat enhanced by the presence of TCP, the
196 tion that the cryoreduced ternary complex of oxy-P450scc-CH is catalytically competent and hydroxylat
198 ioselective, with preferential deposition of oxy-Zn(II) species within the small pores of NU-1000.
199 ies, the electronic structure description of oxy-Hb remains elusive, with at least three different de
202 , and oxalic acids confirms the potential of oxy aromatics to produce light-absorbing aqueous seconda
204 scribed in detail the magnetic properties of oxy- and deoxyhemoglobin, as well as those of closely re
206 henol (TCP) brings about facile switching of oxy-DHP to the enzymatically active ferric state via a p
207 n of spectral features identical to those of oxy-tyrosinase indicates that oxy-NspF contains a Cu(2)O
209 ature survey showed surface complexation of (oxy)anions (As, B, and PO4) is consistently exothermic,
210 s desulfurization (WFGD) plants, focusing on oxy-coal combustion processes and differences when compa
212 oxygenation reactions: anthracene oxidation, oxy-functionalization of citronellol through the Schenck
213 ed performance when coated with metal-oxide/(oxy)hydroxide overlayers that are catalytic for the wate
214 9i (LMK235) (N-((6-(hydroxyamino)-6-oxohexyl)oxy)-3,5-dimethylbenzamide) showed similar effects compa
216 e included in such a study, oxygenated-PAHs (oxy-PAHs) and nitrogen containing heterocyclic PACs (N-P
217 reveals that the distal pocket of the parent oxy-P450scc-cholesterol complex exhibits an efficient pr
218 For application at cement plants, partial oxy-fuel combustion, amine scrubbing, and calcium loopin
219 4- methyl-1-oxo-2-[(1-oxopropyl)amino]pentyl]oxy]-L-leucyl-N,O-dimethyl-,(7-->1)-lac tone (9CI)}, a n
221 potent P2Y4R-selective N(4)-(3-phenylpropyl)oxy agonist was phenyl ring-substituted or replaced with
222 The potent N(4)-(3-(4-methoxyphenyl)-propyl)oxy analogue 19 (EC50: P2Y2R, 47 nM; P2Y4R, 23 nM) was f
223 AZ12799734 [4-({4-[(2,6-dimethyl-3-pyridinyl)oxy]-2-pyridinyl}amino)benzenesulfonamide] (IC(50) = 18
224 nder three different atmospheres: pyrolysis, oxy-fuel combustion, and carbon dioxide gasification con
226 formation, [2,3]-sigmatropic rearrangement, oxy-Cope rearrangement, enol-keto tautomerization and fi
229 the catalytically inactive oxyferrous state (oxy-DHP), we find that the combination of H(2)O(2) and t
230 ort the use of bis(((difluoromethyl)sulfinyl)oxy)zinc (DFMS) as a source of CF2H radical for a rapid
235 al to those of oxy-tyrosinase indicates that oxy-NspF contains a Cu(2)O(2) core where peroxide is coo
244 ing the same oxidation state as found in the oxy-bridged MOF, the triply oxidized HITP(3-) found in C
248 otonation and hence further reduction of the oxy complex to the hydroperoxy intermediate resulting in
249 nd applied it to study the properties of the oxy-ferrous complex of a human membrane bound P450, CYP1
253 FM-300(V(IV)) shows CO2 bound side-on to the oxy group and sandwiched between two phenyl groups invol
257 f a three-step sequence comprising a thermal oxy-Cope rearrangement, an iridium-catalyzed hydrogenati
259 te these results with measurements of tissue oxy- and deoxyhemoglobin concentration during oxygen dep
262 30, provide direct and sustainable routes to oxy-functionalized derivatives of these building block m
264 S)-N-isobutyl-3-methyl-1-((triisopropylsilyl)oxy)butan-2-amide forms both a 2:2 mixed aggregate and a
265 S)-N-isobutyl-3-methyl-1-((triisopropylsilyl)oxy)butan-2-amine and n-butyllithium are characterized b
266 ithium (S)-N-isopropyl-1-((triisopropylsilyl)oxy)propan-2-amide forms mostly a 2:2 ladder-type mixed
267 d from (S)-N-isopropyl-1-((triisopropylsilyl)oxy)propan-2-amine, (R)-N-(1-phenyl-2-((triisopropylsily
269 amine, (R)-N-(1-phenyl-2-((triisopropylsilyl)oxy)ethyl)propan-2-amine, or (S)-N-isobutyl-3-methyl-1-(
270 iyama-Michael reaction of 2-[(trimethylsilyl)oxy]furan with diverse alpha,beta-unsaturated ketones is
271 the effect of the gases present in a typical oxy-coal combustion atmosphere on mercury speciation and
272 fur was found to be converted to SO(3) under oxy-fuel combustion, whereas SO(3) was undetectable duri
274 oncentrations were considerably higher under oxy-fuel combustion compared to that in the air combusti
276 gether, our results support a model in which oxy-Mb is a novel regulator of long-chain acylcarnitine
277 of both fatty acids and acylcarnitines with oxy-Mb using molecular dynamic simulations and isotherma
282 ble 2',2''-(10-(2-((2,5-dioxopyrrolidin-1-yl)oxy)-2-oxoethyl)-1,4,7,10-tetraazacyclod odecane-1,4,7-t
285 aminomethyl)-6-(trifluoromethyl)pyridin-2-yl)oxy)phenyl)(3- fluoro-4-hydroxypyrrolidin-1-yl)methanone
286 N-{trans-3-[(5-Cyano-6-methylpyridin-2-yl)oxy]-2,2,4,4-tetramethylcyclobutyl}imid azo[1,2-a]pyrimi
287 (2-(5-bromofuran-2-yl)-4-oxo-4H-chromen-3-yl)oxy)acetamide (CB7993113), was further tested for its ab
288 dimethyl-1-(3-((2,4,5-trimethylthiophen-3-yl)oxy)propyl)piperazin-1-ium bromide] conjugated polyelect
289 inhibitor, N-(4-((6,7-dimethoxyquinolin-4-yl)oxy)-3-fluorophenyl)-1,5-dimethyl-3-oxo-2-pheny l-2,3-di
290 omatic)-N'-{4-[(6,7-dimethoxyquinazolin-4-yl)oxy]phenyl}urea were identified as potent and selective
291 nol, 2, 4-[(4-fluoro-2-methyl-1 H-indol-5-yl)oxy]-6-methoxyquinazolin-7-ol, by chloropyrrolidine, 3,
292 )methylene)-3-oxo-2,3-dihydrobenzofuran-6-yl)oxy)acetonitrile (5a) and (Z)-6-((2,6-dichlorobenzyl)oxy
294 nthren-3-yl]o xy]-6-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol], an alkaloid iso
295 l-N-phenyl-2-{[2-(pyridin-2-yl)quinolin-4-yl]oxy}propanamide (22a; rat Ki=0.10 nM; human TSPO genotyp
296 6,7-dihydro-5H-pyrrolo[2,3-d]pyrimidin- 4-yl}oxy)-1-piperidinecarboxylate (GSK1104252A) (3), a potent
297 xy-pyridin-3-yl)-benzyl]-5-(pyridin-2-ylmeth oxy)-1H-indol-2-yl]-2,2-dimethyl-propionic acid (11j) is
298 Zr(25) is a pentagonal assembly of 25 Zr-oxy/peroxo/hydroxyl polyhedra and is the largest Zr/Hf c
299 -4-(trifluoromethyl-3H-diazirin-3-yl)ben zyl]oxy]carbonyl]nonanoyl]-sn-glycero-3-phosphocholine to th
300 -4-(trifluoromethyl-3H-diazirin-3-yl)ben zyl]oxy]carbonyl]nonanoyl]-sn-glycero-3-phosphocholine, the