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1 ogen absorption capacity and HER activity of palladium.
3 side-chain, Boc-Arg(Nap)-OH, was prepared by palladium(0)-catalyzed coupling of Boc-Arg-OH with a 4-b
9 ridone-assisted dissociation of the trimeric palladium acetate [Pd(3)(OAc)(6)] is found to be crucial
10 cludes a formal dehydrative step followed by palladium AcOH-induced CH(sp(3))-CH(sp(2)) oxidative cro
15 ution reaction catalyzed by a combination of palladium and a chiral phosphoric acid was investigated
16 we report a 2-pyridone ligand that binds to palladium and accelerates non-directed C-H functionaliza
17 athode through electrochemical deposition of palladium and chemical oxidation to carry out the sulfit
18 ylation of 1,1-disubstituted olefins by dual palladium and copper hydride catalysis as a convenient a
19 etal reagents or by transition metal (mainly palladium and copper) catalyzed alkynylations, carbon mo
20 y inhomogeneous surfaces comprising of gold, palladium and nickel were generated on copper substrates
22 sition are prepared from the co-reduction of palladium and silver precursors in aqueous solution usin
23 ng reactions, particularly those mediated by palladium, are some of the most broadly used chemical tr
25 urface area (138.7 square metres per gram of palladium) as well as high atomic utilization, resulting
26 ds the ORR of 16.37 amperes per milligram of palladium at 0.9 volts versus the reversible hydrogen el
27 the population of weakly bound states on the palladium at high hydrogen atom coverages which are near
30 trast, in the CrFeCoNiPd alloy, in which the palladium atoms have a markedly different atomic size an
32 single synthetic protocol to obtain uniform palladium-based bimetallic nanocrystals (PdM, M = V, Mn,
34 ed oxygen biosensor employs the quenching of palladium-benzoporphyrin by molecular oxygen to transduc
35 readily accessible starting materials using palladium binaphthyl nanoparticles (Pd-BNPs) has been de
36 combined with bulky monophospine ligands on palladium, can direct the arylation of tri- and tetrasub
37 report a new class of initiators, (pai-allyl)palladium carboxylate dimers, which polymerize ethyl dia
38 n principles proposed in this work extend to palladium-catalysed benzylic substitution, demonstrating
46 monophosphine ligand, GPhos, that supports a palladium catalyst capable of promoting carbon-nitrogen
47 -) were investigated using CHMs with varying palladium catalyst densities, and mass transport of reac
48 quentially in the same flask, preventing the palladium catalyst from being inhibited by the high conc
50 eaction mixture: generation of more reactive palladium catalyst versus deactivation of a substrate by
51 sily accessible and low-cost equipment and a palladium catalyst were successfully used for the synthe
55 that the rate of oxidative addition between palladium catalysts and alkyl/aryl electrophiles can be
57 etathesis reactions (Nobel Prize in 2005) or palladium catalysts for C-C bond forming reactions such
58 to afford highly active and enantioselective palladium catalysts for the arylation of methylene C(sp(
61 is study provided insightful information for palladium catalytic system design to generate heteroaryl
62 (p)) and (S(c),R(p)) Phosferrox (PPh(2)), to palladium catalyzed allylic alkylation of trans-1,3-diph
63 ferent dioxiranes, as well as chemodivergent palladium catalyzed cross-coupling reactions using boron
66 talline lactone intermediate via a selective palladium-catalyzed 4-methylimidazole N(1)-arylation usi
72 n an arene and an arenophile, and subsequent palladium-catalyzed allylic substitution of the resultin
73 he long-standing challenge of conducting the palladium-catalyzed alpha-arylation of carboxylic aids a
74 ngs to a wide range of aromatic compounds by palladium-catalyzed alpha-arylation of cyclopropyl, cycl
76 al-group compatibility is highlighted in the palladium-catalyzed aminocarbonylation, alkoxycarbonylat
79 This system is not only the first reported palladium-catalyzed arylation of NHC-bound homoenolates
80 cess these alkaloids by use of a challenging palladium-catalyzed asymmetric allylic alkylation of an
83 yl-beta-amino acids has been developed via a palladium-catalyzed auxiliary-directed regioselective Cs
84 lhydrazones and bromophenols, proceeds via a palladium-catalyzed Barluenga-Valdes cross-coupling, fol
85 um ylides are efficient directing groups for palladium-catalyzed beta-arylation and alkylation of sp(
87 hypervalent iodine(III) aryl substrates in a palladium-catalyzed C-H activation/beta-arylation reacti
89 simple workflow for easier design of popular palladium-catalyzed C-H functionalization reactions, whe
98 e synthesis of functionalized isoxazoles via palladium-catalyzed cascade annulation/allylation of alk
99 nthetic strategy relied on an intramolecular palladium-catalyzed coupling reaction to complete the te
104 f potassium acyltrifluoroborates (KATs) by a palladium-catalyzed cross-coupling of boronic acids and
107 effective nucleophilic coupling partners in palladium-catalyzed cross-coupling reactions with (heter
111 rmediate that participates in the subsequent palladium-catalyzed cross-coupling, which furnishes benz
114 xadienyl ketoesters which are subjected to a palladium-catalyzed DcA reaction, providing a variety of
117 ation of the bridged diazadecalin core and a palladium-catalyzed decarboxylative allylation to instal
118 lectron-withdrawing groups in substrates for palladium-catalyzed decarboxylative allylation was explo
119 roxymethyl handle enhances the yields of the palladium-catalyzed decarboxylative cross-coupling react
125 mployed as the starting substrate to undergo palladium-catalyzed intramolecular C-H/C-Br bond cross-c
126 es a dihydrobenzothienooxepine formation via palladium-catalyzed intramolecular direct C-H arylation
127 ienooxepines in good to excellent yields via palladium-catalyzed intramolecular direct C-H arylation,
129 t herein synthetic and DFT investigations of palladium-catalyzed ligand-controlled regiodivergent hyd
130 thylcyclohexane-1,4-dicarboxylate (+)-1, via palladium-catalyzed methoxycarbonylation of an enol trif
131 ibes the development of a remarkably general palladium-catalyzed monoacylation of carbazoles using to
136 ral limitations of previously reported allyl-palladium-catalyzed oxidation, and is further leveraged
142 a bidentate diamidophosphite ligand class in palladium-catalyzed reactions that allow a challenging t
145 An appropriate and efficient Q-tube-assisted palladium-catalyzed strategy for the synthesis of novel,
148 ugh indole- and benzo[b]thiophene synthesis, palladium-catalyzed Suzuki coupling, oxidative cyclizati
151 ron complex can be effectively modified by a palladium-catalyzed Suzuki-Miyaura cross-coupling reacti
152 ed by functionalization of bromine through a palladium-catalyzed Suzuki-Miyaura cross-coupling reacti
154 Compounds such as 20 were prepared using a palladium-catalyzed Ullmann cross-coupling reaction betw
157 show that a modular, practical, and general palladium-catalyzed, radical three-component coupling ca
159 nation of the remote protecting group to the palladium center is determinant for the control of the r
160 om an optically pure Cu complex to a gold or palladium center reveals, for the first time, a full ste
163 scope to be prepared from either an isolated palladium-CF(3) complex, or from Pd(PPh(3))(4) and other
166 of a fluorescent semiconducting polymer and palladium complex, for quantitative longitudinal imaging
167 ne) dipalladium (Tris DBA), a small-molecule palladium complex, has been shown to inhibit cell growth
169 resentative subset of monomeric, monoligated palladium complexes allowed us to draw a unique parallel
170 s illustrate that the chain-walking of alkyl-palladium complexes can be controlled through the altera
171 ng to the formation of catalytically dormant palladium complexes that reactivate only upon heating.
173 33 was developed, promoted by electron-rich palladium complexes, including the novel phosphine ligan
174 Due to the electronic bias of the pai-alkene-palladium complexes, nucleopalladations with terminal al
175 reaction promotes the formation of dinuclear palladium complexes, wherein only a single metal center
176 utations of noble and base metals (platinum, palladium, copper, nickel, and cobalt) were synthesized
178 we report a platinum-trimer decorated cobalt-palladium core-shell nanocatalyst with a low platinum lo
180 he amount of hydrogen that absorbed into the palladium decreased, and HER electrocatalytic activity i
181 ition between nucleophilic and electrophilic palladium difluorocarbene ([Pd]=CF(2)) is the key factor
182 m-catalysed strategy that confers the formed palladium difluorocarbene (Pd=CF(2)) species with both n
187 to improve the electrocatalytic activity of palladium electrodes for reduction of carbon dioxide or
192 ion-metal-catalyzed approaches championed by palladium have allowed the installation of a fluorine su
193 ase transition, crystals of (phenylazophenyl)palladium hexafluoroacetylacetonate of submillimeter to
195 zi- and N-methyltropiporphyrins reacted with palladium(II) acetate to give stable palladium(II) compl
199 hylcarbaporphyrin-2-carbaldehyde also gave a palladium(II) complex, but this gradually rearranged at
200 , anionic trifluoromethyl and difluorobenzyl palladium(II) complexes undergo fluoride abstraction fol
201 ed with palladium(II) acetate to give stable palladium(II) complexes, demonstrating that N-alkylation
202 onate complex to enable addition of the aryl palladium(II) species and an organoboronic ester substit
204 nce of a preformed biarylphosphine-supported palladium(II)-aryl complex and a weak base, lysine amino
205 ce transferred onto a protein substrate, the palladium(II)-aryl group facilitates conjugation by unde
213 ienyne complexes were readily synthesized by palladium(II)-catalyzed oxidative macrocyclizations of b
217 ure of the molecular electronic junction for palladium ions complexed and reduced on 4-mercaptopyridi
218 the chain ends, small molecule ligands, and palladium ions; polyMOCs are formed via metal-ligand coo
220 tereospecific pathway of transmetallation to palladium is required to effect efficient chirality tran
221 ladium-silver interface length, with smaller palladium islands more efficiently supplying hydrogen at
222 e that, following dihydrogen dissociation on palladium islands, hydrogen atoms migrate from palladium
223 perties, and structural modifications to the palladium lattice of an industrial type interstitial bor
226 edication Naproxen and Flurbiprofen with low palladium loading further highlights the practical value
229 ate was used to generate the highly reactive palladium-mediated dipoles for the first time, and a div
231 emendous efforts have focused on copper- and palladium-mediated/catalyzed trifluoromethylation of ary
232 experiments showing how hydrogenation in the palladium membrane reactor proceeds at faster reaction r
238 ial engineering of orthogonal Lewis acid and palladium nanoparticle (NP) catalysts in a metal-organic
239 tigated 1,1,1-TCA and TCE co-reduction using palladium nanoparticle (PdNP) catalysts spontaneously de
240 an industrial type interstitial boron doped palladium nanoparticle catalyst system (Pd-(int)B/C NPs)
241 ules combined with catalytic bimetallic gold-palladium nanoparticles (Au-Pd NPs) in solution for an i
242 ctuation of graphene quantum dots (GQDs) and palladium nanoparticles (Pd NPs) for the rapid and label
247 nabled by a unique class of electrophiles in palladium-norbornene cooperative catalysis, which are su
251 al difunctionalization of thiophenes via the palladium/norbornene (Pd/NBE) cooperative catalysis.
252 lation method is reported through a directed palladium/norbornene (Pd/NBE) cooperative catalysis.
253 zed via alkenyl halide- or triflate-mediated palladium/norbornene catalysis, which is enabled by a mo
257 the field of the metal-based nanocatalysis, palladium occupies a privileged position mainly due to i
258 rogenolysis of tertiary benzylic alcohols on palladium on carbon (Pd/C) generally proceeds with inver
262 approach using stoichiometric quantities of palladium oxidative addition complexes (OACs) derived fr
263 of a silver surface oxide in the presence of palladium oxide compared to pure silver oxide resulting
264 ng from the transfer of atomic hydrogen from palladium oxide islands onto the surrounding surface for
267 ) )(2) As)(8) ] (Pd(16) ) comprises a cyclic palladium-oxo unit capped by eight dimethylarsinate grou
269 demonstrate the NHC being coordinated to the palladium particles and affecting their electronic prope
270 istic interaction between partially oxidized palladium (Pd(delta+)) and oxygen-functionalized carbon
271 zed and quantified the following: (1) Pt and palladium (Pd) abundance, (2) geochemistry of 58 element
273 en contain residual metal impurities such as palladium (Pd) clusters that are formed during the polym
274 exhibit poor catalyst performance with high palladium (Pd) loading (e.g., 10 mole %) and a need for
275 existing colloidal synthesis for corrugated palladium (Pd) nanoparticles to electrochemical growth o
277 nulated donor and acceptor moieties based on palladium (Pd)-catalyzed [3+2] annulation reaction betwe
278 is selective cathode with a carbon-supported palladium (Pd/C) anode to establish a membrane-free, roo
279 port commercially available carbon-supported-palladium (Pd/C)-catalyzed N-methylation of nitroarenes
280 ements (HSEs; namely, gold, iridium, osmium, palladium, platinum, rhenium, rhodium and ruthenium) in
283 ed to the several reaction pathways that the palladium-propargyl intermediate can proceed by, and the
284 The method involves the synthesis of stable palladium-protein oxidative addition complexes (Pd-prote
285 uinoline as an N-ligand, and evidence of the palladium-quinoline interaction is provided by (1)H-(15)
287 ~500 nanometers) composed of platinum (Pt), palladium, rhodium, nickel, and cobalt, as well as a lib
288 d supported growth of ruthenium (bio-Ru) and palladium/ruthenium (bio-Pd@Ru) core@shell nanoparticles
289 nsity functional theory studies suggest that palladium's ligation state during oxidative addition is
290 rns of compression strengthening in gold and palladium samples down to the smallest grain sizes.
294 te of hydrogen atom migration depends on the palladium-silver interface length, with smaller palladiu
299 lladium islands, hydrogen atoms migrate from palladium to silver, to which they are generally less st