ライフサイエンスコーパス: pentane

1 d(13)C propane > d(13)C n-butane > d(13)C n-pentane).

2 pentane ligand was observed in (HEB)W(CO)(2)(pentane).

3 on the odd-chain-length alkanes, propane and pentane.

4 1-tert-butyl-3-(trimethylsilyl)bicyclo[1.1.1]pentane.

5 - 3.3 kcal/mol for 1-tert-butylbicyclo[1.1.1]pentane.

6 .1.1]pentyl)sulfamide and azoxybicyclo[1.1.1]pentane.

7 and to the long-range (6)J(HH) couplings in pentane.

8 2] cycloaddition product to be bicyclo[2.1.0]pentane.

9 rat feces exude large amounts of ethane and pentane.

10 osphine ligand (2S,4S)-bis(diphenylphosphino)pentane.

11 normal isomers, for example, n-butane and n-pentane.

12 pe complexes with 1,3,5-trimethoxybenzene in pentane.

13 f n-BuLi to pivaldehyde at -116 degrees C in pentane.

14 ng inversion in this and other bicyclo[2.1.0]pentanes.

15 he productive formation of the bicyclo[1.1.1]pentanes.

16 was applied using a mixture of diethyl ether-pentane (1:1,w/w) as solvent.

17 (compound 1) and 5-(4-phenoxyphenylsulfonyl)pentane-1,2-dithiol (compound 2), that are potent and se

18 irect fluorination of dimethyl bicyclo[1.1.1]pentane-1,3-dicarboxylate, obtained from [1.1.1]propella

19 with the mGluR agonist ISR,3RS-1-aminocyclo-pentane-1,3-dicarboxylic acid (tACPD) limited the anatom

20 tural framework to MIL-53 with bicyclo[1.1.1]pentane-1,3-dicarboxylic acid as the organic linker comp

21 med diketone in batch afforded bicyclo[1.1.1]pentane-1,3-dicarboxylic acid in a multigram amount.

22 Radical chlorination of bicyclo[1.1.1]pentane-1,3-dicarboxylic acid is highly selective, and u

23 al chlorination of 2,2-difluorobicyclo[1.1.1]pentane-1,3-dicarboxylic acid.

24 15 possible bridge-fluorinated bicyclo[1.1.1]pentane-1,3-dicarboxylic acids, isolated by preparative

25 for primaquine (4-N-(6-methoxyquinolin-8-yl)pentane-1,4-diamine), the only drug that can block Plasm

26 1'-peroxybis (1-hydroperoxycycloalkanes) and pentane-1,5-dial catalyzed by Sm(NO(3))(3).6H(2)O.

27 3-carboxypropyl)(hydroxy)(phosphinyl)-methyl]pentane-1,5-dioic acid) in 1 step with >95% yield and no

28 dase inhibitors, ZJ43 and 2-(phosphonomethyl)pentane-1,5-dioic acid, would elevate levels of synaptic

29 action between 3-phenyl-1,5-bis(pyridin-2-yl)pentane-1,5-dione dioxime (pdpdH(2)) and triangular [Mn(

30 ase induced reaction of 1,3,5-trisubstituted pentane-1,5-diones and substituted pyrazoles afforded go

31 e dimers, whereas dilithiated (2S,2'S)-1,1'-(pentane-1,5-diylbis(oxy))bis(N-isopropyl-3-methylbutan-2

32 N-isopropylpropan-2-amine) 7, (2S,2'S)-1,1'-(pentane-1,5-diylbis(oxy))bis(N-isopropylpropan-2-amine)

33 acidities of the 3-substituted bicyclo[1.1.1]pentane-1-carboxylic acids are linearly related to the C

34 oxylic acids and 3-substituted bicyclo[1.1.1]pentane-1-carboxylic acids have been calculated at the M

35 aethylbenzene; alkane = cyclopentane (16) or pentane (17-19); OR(f) = perfluoro-tert-butoxy) via phot

36 pentane-2,3-dione) and off-flavors (2-furanyl)methanol,

37 a; BDI(Dip) = N,N'-bis(2,6-diisopropylphenyl)pentane-2,4-diiminate) in toluene afforded the complexes

38 } (BDI(Mes) = N,N'-bis(2,4,6-trimethylphenyl)pentane-2,4-diiminate) with the low-valent group 13 meta

39 es 1 and 3-(3-oxo-2-benzofuran-1(3H)-ylidene)pentane-2,4-dione (2).

40 in the ultraviolet-induced photochemistry of pentane-2,4-dione (acetylacetone, AcAc).

41 sostructural analogues of the hydrocarbons n-pentane, 3-ethylpentane, and n-heptane, respectively.

42 n disulfide, dimethyl sulfide, nitromethane, pentane, 3-methylfuran, 2-ethylfuran, and dimethyl disul

43 S complexes, [Mg((Et)NON(TCHP))(kappa(2)-H,H-pentane)] 4, [Mg((Et)NON(TCHP))(kappa(2)-H,H-hexane)] 5

44 and the acidity of 1-tert-butylbicyclo[1.1.1]pentane (408.5 +/- 0.9) was determined by the DePuy kine

45 utane (798 cm(-1)), n-butane (830 cm(-1)), n-pentane (840 cm(-1)), propane (869 cm(-1)), ethane (993

46 r Me; R'(2)N = pyrrolidino or Me(2)N) in THF/pentane afford a (n-BuLi)(3)(ROLi) (3:1) mixed tetramer

47 lithium hexamethyldisilazide (LiHMDS) in THF/pentane afford a (RCCLi)(3)(ROLi) mixed tetramer, a C(2)

48 alkoxide derived from camphor (R*OLi) in THF/pentane afford an asymmetric (RCCLi)(3)(R*OLi) mixed tet

49 riphenylsilane to [(iPr2) TpCu]2 (mu-OH)2 in pentane allows isolation of a key intermediate [(iPr2) T

50 The release of pentane and 2-ethylfuran was related to the degree of ti

51 n fractions in the wood sawdust into hexane, pentane and alkylcyclohexanes, respectively.

52 the analogous experimental data obtained in pentane and computational studies help to elucidate the

53 d, strained frameworks such as bicyclo[1.1.1]pentane and cubane are particularly well suited as the r

54 ions persist in hydrocarbon solvents such as pentane and cyclohexane-d(12).

55 inglet's bent :CH-group favors bicyclo[2.1.0]pentane and cyclopentene formation.

56 the channel with a dilute solution in 1:1 n-pentane and dichloromethane and pumping away the solvent

57 rofuran, dioxane, tert-butyl methyl ether, n-pentane and dichloromethane.

58 c solvent extraction applying the mixture of pentane and diethyl ether 1:2v/v (solvent A) as well as

59 ed on a packed silica gel column eluted with pentane and diethyl ether to separate minor compounds.

60 tallized readily from toluene or mixtures of pentane and ether and are sensitive to air and moisture.

61 Pentane and hexane used as carrier solvent showed good r

62 cipitated from solution upon the addition of pentane and isolated.

63 one, ethanol, and trichloroethylene (TCE) in pentane and methanol and acetonitrile in pentane are fir

64 of the alkane is not rate-determining since pentane and pentane-d12 can be dehydrogenated to 4 and 4

65 Reverse micelles composed of AOT and pentane and solutions with varying concentrations of NaC

66 LDAO performs well in both the low viscosity pentane and ultralow viscosity liquid ethane and therefo

67 synthesis of boron-substituted bicyclo[1.1.1]pentanes and (hetero)bicyclo[2.1.1]hexanes by an iridium

68 isomers of bridge-halogenated bicyclo[1.1.1]pentanes and to obtain relative strain energies for all

69 atural refrigerants (water, ethanol, hexane, pentane) and synthetic low-global-warming-potential refr

70 Conformational free energies of butane, pentane, and hexane in water are calculated from molecul

71 lbutane, 2-methylpentane, 3-methylpentane, n-pentane, and n-hexane produce methane in situ.

72 %, 347%, 636%, and 688% for ethanol, hexane, pentane, and R1233zd(E), respectively, compared to filmw

73 e most were diisopropylamine, triethylamine, pentane, and xylenes.

74 hanism--in 16 micros, a terminal hydrogen on pentane appears to migrate to the Bpin ligand to form a

75 in pentane and methanol and acetonitrile in pentane are first separated using a standard gas chromat

76 The obtained difluoro-bicyclo[1.1.1]pentanes are suggested to be used as saturated bioisoste

77 n-alkane gases (ethane, propane, butane, and pentane) are initially produced by irreversible cracking

78 n-propylamine, n-butylamine, and 1,5-diamino pentane as mimics for the side chain of lysine (Lys).

79 zirine distilled into a cold trap containing pentane at -70 degrees C over 6-7 h.

80 LFP of 2,4,6-tri-tert-butyl phenyl azide in pentane at ambient temperature again produces a singlet

81 antyldiazirine with phenylchlorodiazirine in pentane at room temperature generates adamantylethylenes

82 dichlorocarbene or phenylchlorodiazirine in pentane at room temperature produces noradamantylethylen

83 Choosing n-pentane at very low concentrations as a model for highly

84 strained bioisosteres such as bicyclo[1.1.1]pentane, azetidine, and cyclobutane to modify their lead

85 troducing substituents such as bicyclo[1.1.1]pentanes, azetidines, or cyclobutanes often outweighs th

86 Since the first synthesis of bicyclo[1.1.1]pentane (BCP) analogues in the 1960s, both the academic

87 ctivities of matching pairs of bicyclo[1.1.1]pentane (BCP) and BCP-F(2) analogues, we discovered that

88 f gem-diboromethyl-substituted bicyclo[1.1.1]pentane (BCP) and other related C(sp(3))-rich carbocycli

89 decade, the successful use of bicyclo[1.1.1]pentane (BCP) as a para-disubstituted benzene replacemen

90 yl allowed construction of the bicyclo[1.1.1]pentane (BCP) core in a 1 kg scale within 1 day.

91 ns through the introduction of bicyclo[1.1.1]pentane (BCP) core motifs.

92 ioisosteres such as cubane and bicyclo[1.1.1]pentane (BCP) have been used as highly effective phenyl

93 Bicyclo[1.1.1]pentane (BCP) is a rigid aliphatic hydrocarbon with a th

94 Recently, the bicyclo[1.1.1]pentane (BCP) motif has increasingly received attention

95 The bicyclo[1.1.1]pentane (BCP) motif is an emerging scaffold in medicinal

96 Bicyclo[1.1.1]pentane (BCP) motifs as para-disubstituted aryl bioisost

97 Recently, bicyclo[1.1.1]pentane (BCP) motifs have become valuable as pharmaceuti

98 Over the past decade, bicyclo[1.1.1]pentane (BCP) motifs have come to the fore as valuable p

99 acokinetics, by exploiting the bicyclo[1.1.1]pentane (BCP) ring system.

100 The bicyclo[1.1.1]pentane (BCP) unit is under scrutiny as a bioisostere in

101 nes and tert-butyl groups with bicyclo[1.1.1]pentane (BCP) units.

102 ing reactions with 2,2-difluorobicyclo[1.1.1]pentane (BCP-F(2)) building blocks.

103 he synthesis of functionalised bicyclo[1.1.1]pentanes (BCP) rely on the reaction of [1.1.1]propellane

104 1-Aryl-substituted bicyclo[1.1.1]pentanes (BCPs) are an important class of BCP derivative

105 1,2,3-Trisubstituted bicyclo[1.1.1]pentanes (BCPs) are emerging saturated hydrocarbon biois

106 Bicyclo[1.1.1]pentanes (BCPs) are important motifs in contemporary dru

107 1,3-Disubstituted bicyclo[1.1.1]pentanes (BCPs) are important motifs in drug design as s

108 1,3-Disubstituted bicyclo[1.1.1]pentanes (BCPs) are valuable bioisosteres of para-substi

109 les; however, the potential of bicyclo[1.1.1]pentanes (BCPs) as versatile scaffolds in glycoscience r

110 rticular, 1,3-difunctionalized bicyclo[1.1.1]pentanes (BCPs) have been widely adopted as bioisosteres

111 o[2.1.1]hexanes (aza-BCHs) and bicyclo[1.1.1]pentanes (BCPs) have emerged as attractive classes of sp

112 Over the past decade, bicyclo[1.1.1]pentanes (BCPs) have emerged as valuable bioisosteres of

113 In particular, substituted bicyclo[1.1.1]pentanes (BCPs) have risen to prominence as bioisosteres

114 Bicyclo[1.1.1]pentanes (BCPs) have sparked the interest of medicinal c

115 Bicyclic hydrocarbons, and bicyclo[1.1.1]pentanes (BCPs) in particular, are playing an emerging r

116 install highly functionalized bicyclo[1.1.1]pentanes (BCPs) using tricyclo[1.1.1.0(1,3)]pentane (TCP

117 developed for the synthesis of bicyclo[1.1.1]pentanes (BCPs), bridge-substituted BCPs, and bicyclo[2.

118 insertion into BCBs to afford bicyclo[1.1.1]pentanes (BCPs).

119 ed C(2)-H functionalization of bicyclo[1.1.1]pentanes (BCPs).

120 Complexes 1-6-d1 in toluene and pentane between 296 and 213 K exhibit coupling constants

121 along with G3 predictions for bicyclo[1.1.1]pentane, bicyclo[2.1.1]hexane, bicyclo[3.1.1]heptane, an

122 conformational changes was examined and the pentane-bridged complex, AH78P, was optimal for condensi

123 m one precursor, 1-azido-3-iodobicyclo[1.1.1]pentane, by "click" reactions and integrated cycloadditi

124 rading mid-chain petroleum n-alkanes between pentane (C(5)) and tetradecane (C(14)) at 70 degrees C u

125 strain is introduced into the bicyclo[1.1.1]pentane cage by polyfluorination; it is calculated to be

126 ination by TMS(3)SiH, four new bicyclo[1.1.1]pentane cages carrying two fluorine and one to three chl

127 thod show that the apparent diffusivity of n-pentane can be more than doubled after SiO(2) deposition

128 2-Substituted bicyclo[1.1.1]pentane carboxylates have been synthesized using two seq

129 Isomerization of n-pentane, catalyzed by Pt/Beta, is taken as a model react

130 ombining spiro[3.3]heptane and bicyclo[1.1.1]pentane centerpieces with imidazolium and ammonium termi

131 nes, benzene, toluene, ethylbenzene, hexane, pentane, chloroform, and carbon tetrachloride.

132 physical organic curiosities, bicyclo[2.1.0]pentanes (colloquially termed housanes) are useful strai

133 kyl-, CHF(2)-, CF(3)- and even bicyclo[1.1.1]pentane-containing derivatives.

134 fers to molecules possessing a bicyclo[2.1.0]pentane core.

135 When the solvent is pentane, Cp'2Ce(OCH2)CeCp'2 forms, in which the oxomethy

136 ge tanks as the primary source of VOCs, with pentane, cyclopentane, and cyclohexane being the dominan

137 -methoxy-2-methylpropane, 2-butyne, acetone, pentane, cyclopentane, trifluoroethane, fluoromethane, d

138 m singlet cyclobutylcarbene to bicyclo[2.1.0]pentane, cyclopentene, and methylenecyclobutane were com

139 ne is not rate-determining since pentane and pentane-d12 can be dehydrogenated to 4 and 4-d12 with co

140 The resultant 1,4-diazaspiro[2.2]pentane (DASP) scaffolds contain two electronically diff

141 nversion of 1,4,5,5-tetrafluorobicyclo[2.1.0]pentane (deltaG(double dagger) = 6.8 +/- 0.2 kcal/mol),

142 structure of this 1,5-bridged bicyclo[2.1.0]pentane derivative was established by NMR and an X-ray c

143 ntral inverted bond to provide bicyclo[1.1.1]pentane derivatives.

144 It was shown that the bicyclo[2.1.0]pentane did not significantly affect pK(a) of the corres

145 -fluoro-4-biphenylyl)ethyl]-4(S)-n-butyl-1,5-pentane dioic acid 1-(alpha(S)-tert-butylglycine methyla

146 Pentane evolution rates displayed more inter-rat and day

147 ough breath, whereas a significant amount of pentane evolves from sources other than breath.

148 arious indexes of lipid peroxidation (breath pentane excretion and susceptibility of LDL to copper-me

149 resulted in a significant decrease in breath-pentane excretion as well as a significant improvement i

150 Repeated extractions of rat heart SMPs with pentane exponentially depleted both CoQ homologues while

151 known of such hydrocarbons is bicyclo[1.1.1]pentane, for which the angle between the exit vectors of

152 te, and measure breath ethane and total-body pentane from rats.

153 ith very low surface tension liquids such as pentane (gamma(lv) = 15.7 mN/m).

154 The bisimidazolio bicyclo[1.1.1]pentane guest forms a highly stable complex only with CB

155 -dichloronorbornane to 1-chloronorbornane in pentane has been elucidated; the reaction, which also yi

156 variety of novel 2-substituted bicyclo[1.1.1]pentanes have been synthesized in good to moderate yield

157 The alkane sigma-complex (HEB)W(CO)(2)(pentane) (HEB = eta(6)-hexaethylbenzene) is produced fro

158 synthetic oil mixtures of known composition (pentane, hexadecane) are tested and MMP values are compa

159 to the formation of 1-sulfonylbicyclo[2.1.0]pentane (housane) analogues when 4-chloro-1,2-epoxybutan

160 n approach to 1,3-disubstitued bicyclo[2.1.0]pentane (housane) derivatives was developed.

161 progress in this general area, bicyclo[2.1.0]pentanes (housanes) are an understudied class of molecul

162 The measurement of ethane and pentane in breath offers a sensitive and noninvasive mea

163 ased amounts of malondialdehyde in blood and pentane in breath; both serve as indirect indicators of

164 n-Pentane in exhaled gas in vivo, an index of lipid peroxi

165 shift signature appeared to be due to a syn pentane interaction between the gem-dimethyl groups on t

166 ismatching is attributed to a developing syn-pentane interaction in the transition state.

167 the S-gamma-methyl peptide minimizes the syn-pentane interactions between the alpha- and gamma-methyl

168 ternary carbons and is marked by several syn-pentane interactions which force a six-membered ring int

169 ly substituted hydrocarbons, by avoiding syn-pentane interactions, adopt well-defined conformations t

170 s, result in significant and unavoidable syn-pentane interactions, suggesting substantially reduced c

171 effects of internal hydrogen bonding and syn-pentane interactions.

172 hrough the introduction of destabilizing syn-pentane interactions.

173 ons with the main chain, thus minimizing syn-pentane interactions.

174 s is controlled through the avoidance of syn-pentane interactions: alternating syn-anti isomers adopt

175 disubstituted BCPs from 1-iodo-bicyclo[1.1.1]pentanes (iodo-BCPs) by direct iron-catalyzed cross-coup

176 -pyridine-3-carbonyl)-amino]-pentyl}-ureido)-pentaned ioic acid (DCFPyL), PSMA-617, PSMA-1007, and ot

177 When the chloroform concentration in pentane is >/=5 ppm, the color change of the EC sensor i

178 on energy for the decay of benzoylnitrene in pentane is -3.20 +/- 0.02 kcal/mol.

179 2,5-hexatriene, and 2-methylenebicyclo[2.1.0]pentane is carried out employing density functional theo

180 ale synthesis for 1,3-diethynylbicyclo[1.1.1]pentane is described.

181 ion of 1,4-dicyano-5,5-difluorobicyclo[2.1.0]pentane is predicted to raise the barrier height by 6.1

182 teria (methanotrophs, propanotrophs, octane, pentane, isobutane, toluene, and ammonia oxidizers), kno

183 They were analyzed for n-pentane isomerization activity and selectivity as a func

184 ed for more acid-demanding reactions, like n-pentane isomerization, with regard to surface density de

185 Cracking transition states for n-pentane lead to a metastable intermediate (a local minim

186 y binding of the methyl functionality of the pentane ligand was observed in (HEB)W(CO)(2)(pentane).

187 syn-Pentane-like interactions between this substituent and t

188 t minimization of allylic 1,3-strain and syn-pentane-like interactions work together in establishing

189 meso-2,4-Bis(diphenylphosphino)pentane (mBDPP) has proved to be an effective regiocontr

190 e early-eluting compounds acetone, isoprene, pentane, methyl alcohol, and ethyl alcohol, which are al

191 the remaining salts by addition of a dioxane/pentane mixture.

192 This trend was accentuated in methanol-pentane mixtures, where ionic fragmentation was further

193 he intrinsic advantages of the bicyclo[1.1.1]pentane moiety over conventional phenyl ring replacement

194 le CO ligand and solvation of the metal by a pentane molecule from the bath within 2 ps.

195 bitor 1 (BMS-708,163) with the bicyclo[1.1.1]pentane motif led to the discovery of compound 3, an equ

196 A prime example is the bicyclo[1.1.1]pentane motif, which is mainly synthesized by ring-openi

197 -phase material, and the analytes included n-pentane, n-hexane, n-heptane, 1 -butanol, and 1-pentanol

198 stigate interfacial adsorption effects for n-pentane, n-hexane, n-heptane, 1-butanol, and benzene sol

199 Treating 1 with n-pentane, n-hexane, or tetramethylsilane (TMS) gave the f

200 tantial in this area, as inferred from the i-pentane/n-pentane ratio (1.17).

201 ntation of nortricyclyloxychlorocarbene 5 in pentane occurs by an S(N)i-like process which yields nor

202 either n-BuLi or t-BuLi) and/or the solvent (pentane or diethyl ether); the 3-deuterated substrate, 3

203 on and washing the crude product with either pentane or ethanol (column-chromatography-free protocol)

204 For small hydrocarbons such as n-pentane or n-hexane, two guests enter the host, and they

205 fragmentation and coupling of bicyclo[2.1.0]pentane, or housane, ketones show promise but are curren

206 antiprotozoal drug 1,5-bis(4-amidinophenoxy)pentane (pentamidine) has been synthesized and tested fo

207 fter ultrasound stimulation, the perfluoro-n-pentane (PFP) liquid core of the nanodroplets vaporized,

208 n scaffolds, as exemplified by bicyclo[1.1.1]pentanes, play an increasingly high-profile role as satu

209 also established that grafting reactions in pentane provide a preponderance of =SiO-La{C(SiHMe(2))(3

210 this area, as inferred from the i-pentane/n-pentane ratio (1.17).

211 crystal lattice and a temperature-dependent pentane rearrangement implicated by the SSNMR data.

212 The pentane sigma-complex [Rh{Cy2 P(CH2 CH2 )PCy2 }(eta(2) :

213 reported method to convert the bicyclo[1.1.1]pentane skeleton to the bicyclo[3.1.1]heptane skeleton.

214 om 1 by selective precipitation using cold n-pentane; solid-state structures for both 1 and 2 are pre

215 (3) (2) was synthesized by the addition of a pentane solution of LiCH(2)CMe(3) to Cp*(2)ScCl at low t

216 )(5); pin = 1,2-O(2)C(2)-(CH(3))(4)) in neat pentane solution primarily results in dissociation of a

217 In pentane solution, 2 equiv of the icosahedral CB(11)Me(12

218 of quinazolinones and phenylacetylene in THF/pentane solutions with lithium hexamethyldisilazide affo

219 ]pentanes (BCPs) using tricyclo[1.1.1.0(1,3)]pentane (TCP) as a radical linchpin, as well as other di

220 exane, and bicyclo[2.1.0]- and bicyclo[1.1.1]pentane, thereby presenting challenging structures for s

221 stigated, and the steric requirement for the pentane to adopt an unfavorable gauche conformation when

222 rallel with activation enthalpies going from pentane to decane solvent, suggesting that enthalpy-entr

223 ){Co(CO)3(PCy3)}2(THF)3 disproportionates in pentane to form Sm(III){Co(CO)3(PCy3)}3(THF)3 containing

224 Successful modulation from n-pentane to pyrene (boiling points = 36/394 degrees C) is

225 asts with the previously reported binding of pentane to rhenium fragments, wherein both methylene and

226 d magnesium bromide (MgBr(2)) on addition of pentane to the reaction mixture.

227 bly is observed with methane through butane, pentane triggers assembly, and hexane through octane aga

228 the resulting complex, cis-Cp*W(CO)(2)(Bpin)(pentane), undergoes C-H bond activation by a sigma-bond

229 structure formed in reactions carried out in pentane (up to 2.0 M TME) is shown to be the cyclic hexa

230 o-propane, bromocyclo-butane, and bromocyclo-pentane upon Br(3d) and C(1s) inner-shell ionization usi

231 ] and decomposes at ambient temperature in n-pentane via multiple C-H bond activations to the mixed m

232 tetrahedrane (tetracyclo[2.1.0.0(1,3).0(2,4)]pentane) via four different carbene reactions is compute

233 of the termini of 1,3-diethynylbicyclo[1.1.1]pentane was coupled with a brominated aza heterocycle, a

234 ch to the difluoro-substituted bicyclo[1.1.1]pentanes was developed.

235 t in the case in which an immiscible solute (pentane) was mixed with H(2)O.

236 olayer thickness by growing films at a sharp pentane/water interface, which allows the fabrication of

237 nce was developed in which the bicyclo[1.1.1]pentanes were afforded starting from two distinct diazo

238 lization of the secondary sites of hexane or pentane, whereas acceptor ethyl diazoacetate leads to an

239 data for the hydroxylation of bicyclo[2.1.0]pentane, which also suggested a 50 ps radical lifetime,

240 nt VOC was the gasoline evaporation tracer i-pentane, which exceeded 1200 ppbv in the tunnels.

241 37 Gg d(-1)) of natural gas (methane through pentanes), yielding a total hydrocarbon release rate of

242 N-oxide/hexanol reverse micelles prepared in pentane yields NMR spectra essentially identical to the