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1 iral arm was introduced as a pendant in poly(phenylacetylene).
2 dine N-oxyl reactions, and reactions without phenylacetylene.
3 ation or rhodium-catalysed polymerization of phenylacetylene.
4 aries, as was indeed observed in the case of phenylacetylene.
5 Ph)] (4), which was also obtained from 1 and phenylacetylene.
6 n of Cu(OAc) with Ph2SiH2 in the presence of phenylacetylene.
7 se were observed in the pyrolytic studies of phenylacetylene.
8 three key intermediates and silane-protected phenylacetylenes.
9 i-Markovnikov addition of benzylthiolates to phenylacetylenes.
10 lex 1 also reacts with weak acids A-H (A-H = phenylacetylene, 1,2-propadiene, phenylacetonitrile, 4-(
11  will undergo a benzannulation reaction with phenylacetylene, 1-pentyne, 3-hexyne, and trimethylsilyl
12 s-coupling reactions of five arylacetylenes (phenylacetylene; 1-ethynyl-2-ethylbenzene; 1-ethynyl-2,4
13 ping of the aryl radical with the support of phenylacetylene 19.
14                        A solution containing phenylacetylene (50 muM) and 4-methoxyphenylboronic acid
15 rdinate cationic intermediate, which forms a phenylacetylene adduct that is then deprotonated to give
16 thanol and with carbon dioxide; insertion of phenylacetylene affords a gem-dicopper vinyl complex.
17                         Facile reaction with phenylacetylene affords the sigma,pi-activated phenylace
18 tization of naphthyl, biphenyl, styrene, and phenylacetylene analogues also leads to rearrangement, p
19 sed to study the adsorption and reactions of phenylacetylene and chlorobenzene on Ag(100).
20  carbene undergoes a facile rearrangement to phenylacetylene and could not be trapped by olefins.
21 imidazolium ion (IPhEt) from p-toluidine and phenylacetylene and its conversion to the hydrosilylatio
22    Oxidative addition of the C(sp)-H bond of phenylacetylene and methyl propiolate along the Cl-Os-CP
23 al polybenzene lattice, and the resulting 3D phenylacetylene and phenyldiacetylene nets comprise a 12
24 unsaturated Ga(-) framework is necessary for phenylacetylene and styrene adsorption.
25                                          For phenylacetylene and styrene, stabilization of the interm
26 n of an electron donor acceptor pair between phenylacetylene and thiophenol as the light-absorbing sy
27  regiodiscrimination in their reactions with phenylacetylene and xylyl isocyanide, affording in the c
28                            Using p-lithiated phenylacetylenes and a range of boronic esters coupling
29 termolecular oxidation of selected terminal (phenylacetylene) and internal alkynes (2-butyne, 1-pheny
30 ctions with methyl trifluoromethansulfonate, phenylacetylene, and CO2.
31 2-iodophenyl)-N-methyl-3-phenylpropiolamide, phenylacetylene, and secondary amine using binaphthyl st
32  lithium acetylides prepared from 1-pentyne, phenylacetylene, and trimethylsilylacetylene to diverse
33 biphenolate ligand used is the presence of a phenylacetylene antenna for optimal chirality recognitio
34                                              Phenylacetylenes are key structural motifs in organic ch
35            By employing the hydrogenation of phenylacetylene as a model transformation, we demonstrat
36 ignal at delta = 19.64 ppm, was reacted with phenylacetylene at 60 degrees C in toluene to yield [(2,
37 g monodendrons with unsymmetrical conjugated phenylacetylene branches and perylene cores, one with pi
38  phenylacetylene (PhCCH) to give cyclic poly(phenylacetylene) (c-PPA), whereas its precursor, complex
39 adical (C2H) to the ortho-carbon atom of the phenylacetylene (C6H5C2H) molecule, the reactive interme
40                         Here, by probing the phenylacetylene (C8 H6 ) intermediate together with naph
41 pot multicomponent coupling reaction between phenylacetylene, carbon dioxide, and 3-bromo-1-phenyl-1-
42  modeled the hydrophosphination of Me2PH and phenylacetylene catalyzed by 1.
43 ily available building blocks [2-(methylthio)phenylacetylenes, CO, an alcohol, and O(2) (from air)],
44 h three DNA strands attached to a rigid tris(phenylacetylene) core.
45 Diels-Alder reaction, [Co(I)(dppe)(isoprene)(phenylacetylene)](+), could be generated via IMR and exa
46                     In the cases where A-H = phenylacetylene, cyclobutanone, aniline, phenol, and p-c
47 atalyzed hydrogenation reactions of styrene, phenylacetylene, cyclohexene, and hex-5-en-2-one in a mi
48 ction of nido-1,2-(CpRuH)(2)B(3)H(7), 1, and phenylacetylene demonstrate the ways in which cluster me
49  The optical and photophysical properties of phenylacetylene dendritic macromolecules based on unsymm
50 benzene configurational switch was linked to phenylacetylene dendrons through acetylenic linkages to
51 ira cross-coupling between the CP-PAHs and a phenylacetylene derivative.
52 th in the quinoline/pyridine N-oxides and in phenylacetylene derivatives, has been observed, affordin
53 ithC-Y) predicts a similar reactivity of the phenylacetylenes: F > OCH3 > Cl > H.
54 a couplings with appropriate iodobenzenes or phenylacetylene followed by reduction and deprotection t
55 itrogen complexes in the presence of H(2) or phenylacetylene furnished isocyanato metallocene complex
56                     A set of chiral discotic phenylacetylenes have been synthesized by 3-fold Sonogas
57 nprecedented direct conversion of styrene to phenylacetylene in one pot.
58  for the gas-phase reaction of isoprene with phenylacetylene in the coordination sphere of the cobalt
59 olines from N-benzyl-1-phenylmethanimine and phenylacetylene in the superbasic medium KO(t)Bu/dimethy
60 how that deprotonation of quinazolinones and phenylacetylene in THF/pentane solutions with lithium he
61 ng a (13)C label at the beta-carbon produced phenylacetylene in which the label was found exclusively
62 , effectively catalyzes the hydrogenation of phenylacetylene into styrene and ethylbenzene under mode
63   Electronic band calculations indicate that phenylacetylene is metallic, while phenyldiacetylene is
64                                    Similarly phenylacetylene is mono-hydroborated by pyrrolylborane,
65                  Treating [LNi2(D)2](-) with phenylacetylene led to D2 and dinickel(II) complex 3(-)
66 where BODIPY moieties are attached through a phenylacetylene linker at the 13- or 3,13-positions of c
67 -3a,4a-diaza-s-in dacene (iodo-BODIPY) via a phenylacetylene linker.
68 u(OTf)] (2-OTf), with the conjugated base of phenylacetylene, lithium phenylacetylide (LiCCPh), yield
69  Soluble organic nanorods were prepared from phenylacetylene macrocycles using the topochemical polym
70 ds characterized by the presence of a common phenylacetylene moiety at the 5-position of the thiophen
71  bond to iridium, (ii) insertion of a second phenylacetylene molecule into the resulting Ir-H bond, a
72 ough the concerted cycloaddition of the next phenylacetylene molecule to 2-aza-1,4-pentadiene, while
73 ccessible for the nucleophilic attack by the phenylacetylene molecule.
74 trical monodendrons are compared to those of phenylacetylene monodendrons with symmetrical branching,
75 tern (i.e., ortho, meta, para) of the parent phenylacetylene monomer undergo modification are analyze
76 rization of oligo[(p-phenyleneethynylene)(n)]phenylacetylene monomers (n = 1, 2) bearing L-decyl alan
77  are active for the cyclic polymerization of phenylacetylene, namely, [(BDI)M{kappa(2) -C,C-(Me(3) Si
78 or the three least electrophilic substrates: phenylacetylene, naphthalene, and 1-chloro-4-ethylbenzen
79 nylacetylene, benzonitrile, methyl benzoate, phenylacetylene, naphthalene, and 1-chloro-4-ethylbenzen
80 he reaction of C-vinylation of aldimine with phenylacetylene occurs with a similar activation energy
81 reactions of 3 with terminal alkynes such as phenylacetylene or 3,3-dimethyl-1-butyne show that the i
82 eactions with various N-donor-functionalized phenylacetylenes or corresponding arylvinylboronic acids
83 rowth mechanism and binding configuration of phenylacetylene (PA) one-dimensional nanostructures on t
84  or Pd/t-Bu(2)PCy for sterically undemanding phenylacetylene, Pd/t-BuPCy(2) for 2- and 2,6-substitute
85 hat cleanly results in release of 1 equiv of phenylacetylene per Cu20 cluster.
86 ion of the model calculations to substituted phenylacetylenes (Ph-C identical withC-Y) predicts a sim
87 ) is a precatalyst for the polymerization of phenylacetylene (PhCCH) to give cyclic poly(phenylacetyl
88 e reactivity of individual carbon centers in phenylacetylene, phenylbutadiyne, and phenylhexatriyne.
89 g E-H bonds (primary amines, ammonia, water, phenylacetylene, phenylphosphine, and phenylsilane) is r
90 alent metals (i.e., Ca(2+), Ba(2+)) and poly(phenylacetylene) polymers bearing alpha-methoxyphenylace
91                  Reactions with ethylene and phenylacetylene proceeded smoothly under mild conditions
92 y transformed, in situ, to the corresponding phenylacetylene product.
93 s), and aggregation observed in helical poly(phenylacetylene)s (PPAs) when either the type of linkage
94 ronic and vibrational properties of the poly(phenylacetylene)s chains.
95 ented for benzene, toluene, aniline, phenol, phenylacetylene, styrene, ethylbenzene, and phenylhydraz
96 ethynylbenzonitrile substituted BODIPY 3 and phenylacetylene substituted BODIPY 4.
97     We have demonstrated that 4-(tert-butyl)-phenylacetylene (tBPA) is a potent mechanism-based inact
98  With the monoalkynes 1-hexyne or 4-(t)butyl-phenylacetylene, the complexes [{(((Ad)ArO)(3)N)U(IV)}(2
99 titutional and structural differences of the phenylacetylenes, the optical absorption and emission pr
100 PtBu2)2) is found to promote dimerization of phenylacetylene to give the enyne complex (PCP)Ir(trans-
101  in THF at room temperature, the addition of phenylacetylene to linear or branched aliphatic aldehyde
102 lyze the addition of the alkynyl C-H bond of phenylacetylene to the pincer complex (PCP)Ir(CO).
103 fects the heterolytic cleavage of the C-H of phenylacetylene to yield the imide acetylide [{((Me(3)Si
104         The obtained diiodide was coupled to phenylacetylene under Sonogashira conditions with (Ph(3)
105 kbone through the pyridine 4-position with a phenylacetylene unit increases the two-photon absorption
106 yl and alkyl ketones from simple phenols and phenylacetylene via C identical withC triple bond cleava
107 nation of ammonia borane and the addition of phenylacetylene via heterolytic C-H bond cleavage, furth
108            The ultraviolet photochemistry of phenylacetylene was studied in a molecular beam at 193 n
109                                 Isoprene and phenylacetylene were introduced into the mass spectromet
110 ward the Diels-Alder substrates isoprene and phenylacetylene were probed in gas-phase ion/molecule re
111  polymers that are catalytically formed from phenylacetylene were verified to have a cyclic topology
112 B4 by the acetylenic inhibitor 4-(tert-butyl)phenylacetylene, whose activated form is known to attach
113 propiolates with 88-99% ee; the reactions of phenylacetylene with 81-87% ee; the reactions of 4-pheny
114 m radical addition onto alkyl propiolates or phenylacetylene with aromatic substitution of the result
115             On the example of interaction of phenylacetylene with benzonitrile in the KOBu(t)/DMSO me
116 lecular interactions, involving acetylene or phenylacetylene with various onium ions, revealed the hi

 
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