ライフサイエンスコーパス: photolytic

1 NH(2)C(O)P, which was generated through the photolytic (193 nm) dehydrogenation of phosphinecarboxam

2 ion to the N-acylhydrazones under thermal or photolytic (300 nm) conditions.

3 terface of the recording chamber after their photolytic activation in a diffraction-limited volume.

4 On the other hand, under photolytic activation, the reaction with 1,5-cyclooctadi

5 ium sulfate with methylglyoxal changes under photolytic aging by UVA radiation in the aqueous phase.

6 Photolytic aging induced significant changes in the ligh

7 Photolytic and biological events were distinguished by c

8 (i)Pr)]}(2)(mu-eta(1):eta(1)-N(2)) (9) under photolytic and dark conditions, respectively, to produce

9 Exploiting this synergy and orthogonality of photolytic and hydrolytic degradation, we designed conce

10 system interacting with the c-helix enabled photolytic and metabolic stability improvements.

11 f dediazoniation in the IL (both thermal and photolytic) and the evolution of the products were direc

12 n IP3 receptor antagonist, and reproduced by photolytic application of IP3.

13 the Marcus inverted region for a variety of photolytic applications.

14 e explored further for the identification of photolytic aromatic dechlorination reactions.

15 Interestingly, photolytic back-transformation to SMX was observed for 4

16 By reducing the size of the photolytic beam, glutamate was released at several diffe

17 We describe the synthesis and photolytic behavior of cobalamin conjugates comprised of

18 for photolysis, DECM-caged glutamate and its photolytic byproducts were found to be biologically iner

19 a convenient cyclobutadiene precursor and a photolytic C-H carboxylation reaction, respectively.

20 Neurons undergoing targeted photolytic cell death degenerate by apoptosis.

21 the O3 + hnu --> O((3)P) + O2(X(3)Sigmag(-)) photolytic channel at the interface, leads to an enhance

22 The pulsed photolytic chlorine-initiated oxidation of methyl-tert-b

23 uent polysulfur abundances comparable to the photolytic cis-OSSO mechanism through a more plausible p

24 e extent of isotope fractionation during SMX photolytic cleavage is pH-dependent.

25 This easy photolytic cleavage makes the NHC-boryl sulfides good ty

26 n advanced oxidation process which relies on photolytic cleavage of free available chlorine (i.e., hy

27 In photolytic cleavage those forces act through control of

28 lytic cycle with thiophenol (PhSH) by way of photolytic cleaveage of the disulfide bond.

29 borylene that can be liberated by selective photolytic CO extrusion and that, although highly reacti

30 d structurally stable across all hydrous and photolytic conditions investigated in this study.

31 ue decomposed to inactive products under the photolytic conditions of the catalysis.

32 ith C60 in toluene solution under thermal or photolytic conditions produces C60{eta(1)-Ru(CO)2(eta(5)

33 Third, under photolytic conditions with hexamethylditin, primary radi

34 Under similar photolytic conditions, H/D exchange reactions between D2

35 xygen trapping products did not change under photolytic conditions, where dediazoniation occurs at ro

36 alogen atom transfer agents under thermal or photolytic conditions.

37 ion was achieved under both the tin-free and photolytic conditions; in this case, the adduct bears al

38 e-dependent paired-pulse facilitation of the photolytic currents, indicating that a change in the sub

39 Acetylenes undergo thermal and photolytic cycloaddition/1,5-sigmatropic rearrangement r

40 ally mimicking the effect of locomotion, and photolytic damage of VIP neurons abolished the enhanceme

41 Photolytic decarbonylation of 1 results in the incorpora

42 In this work, we investigated the photolytic dechlorination of 2-Cl- and 3-Cl-aniline to a

43 r current and previous work illustrates that photolytic dechlorinations of 2-Cl-, 3-Cl-, and 4-Cl-ani

44 h a yield of ca. 30-35% after correction for photolytic decomposition of 3b.

45 In addition, product studies confirmed clean photolytic decomposition to the expected alcohol, 2-hydr

46 oduct ArF is also formed in both thermal and photolytic dediazoniation, depending on the substituent(

47 These syntheses also feature stereospecific photolytic deformylation of beta,gamma-unsaturated aldeh

48 Because photolytic degeneration simulates some mechanisms underl

49 Photolytic degradation half-lives of TDBDPB ranged from

50 cabromodiphenyl ether (BDE-209), that formed photolytic degradation products in tetrahydrofuran (THF)

51 , which may be linked to a TDBDPB source via photolytic degradation to more bioavailable and persiste

52 osing iPPO to UVA light (365 nm) resulted in photolytic degradation.

53 o wind-assisted transport and fracturing via photolytic degradation.

54 tive depolymerization of gels produced under photolytic deliganding of CO hemoglobin S.

55 Photolytic delivery of nitric oxide and nitroxide has su

56 ch utilized a microphotochemical reactor for photolytic denitrosation.

57 '-OH group by a thioacetyl unit, followed by photolytic deoxygenation or radical-based 2'-deoxygenati

58 the methane abundance was maintained against photolytic depletion throughout Titan's history, either

59 in the form of cyanuric acid, preventing the photolytic destruction of residual chlorine by sunlight.

60 n isotopic fractionation mechanism, based on photolytic destruction, to explain the 15N/14N and 18O/1

61 involve vinylcarbene intermediates formed by photolytic dinitrogen extrusion.

62 Here, we show that the selective photolytic disruption of auditory cortical commissural c

63 bles a single Cr catalyst to facilitate both photolytic dissociation and aldehyde addition.

64 After photolytic dissociation of CO, the majority, but not all

65 ficance of HOON as a key intermediate in the photolytic dissociation-association cycle of HONO at low

66 denine dinucleotide phosphate induced by the photolytic event.

67 e) have been investigated by thermolytic and photolytic experiments to investigate the chemical react

68 The same ratios were reproduced via photolytic experiments, which suggested that the condens

69 d to solutions with SRN, indicating that the photolytic fate of select antibiotics varies for agricul

70 This study examined the photolytic fate of the chlortetracycline (CTC), ciproflo

71 Finally, the ability to analyze the photolytic fate of trace chemicals at natural abundance

72 ng carbons on the PAH framework, followed by photolytic formation and ejection of H(2).

73 ansition-metal-carbene chemistry, catalysis, photolytic formation of carbohydrates, and possibly even

74 nance (EPR) spectroscopy to characterize the photolytic formation of ROS in aqueous extracts of SOA f

75 we propose an alternative SMB proxy based on photolytic fractionation of nitrogen isotopes in nitrate

76 Under MALDI conditions, partial photolytic fragmentation of the MBB-peptide bound occurr

77 haracterized as the radical 5b, based on its photolytic generation in the less polar CH(3)CN and on i

78 The principle of the strategy is photolytic generation of nitrogen ylides from N-heteroar

79 the appearance of vinylcyclopropyl following photolytic generation of pentadienyl is more likely the

80 Photolytic H(+) uncaging from 2-nitrobenzaldehyde also r

81 le protocols are far behind the conventional photolytic halogenation process which uses hazardous hal

82 with a turnover number (TON) of 266 300, and photolytic HER for two days with a TON of 15 000 in pH 7

83 th a tetrapyridylamine ligand that catalyzes photolytic HER with turnover number up to 218 000 in pur

84 Neither N2 fixation nor direct photolytic hydrogenogenesis was significant to this H2 e

85 adiance, enhancing both oxidative and direct photolytic inhibition mechanisms.

86 dary C(sp(3) )-H bonds, by either thermal or photolytic initiation, is supported by NMR and UV/Vis da

87 3- completely suppresses the yield of 3b The photolytic intermediate is identified as the aryloxenium

88 Prior photolytic labeling with agonist analogues of the neighb

89 -metal carbonyl complexes is demonstrated by photolytic liberation of CO and subsequent intramolecula

90 The photolytic lifetime of IMD at a solar zenith angle of 35

91 Photolytic ligand displacement and salt metathesis route

92 This strategy, using a photolytic ligation auxiliary and a desulphurization rea

93 The photolytic link between O3 and N2O is identified as the

94 ned experimental and modeling approach, that photolytic loss of SOA mass significantly alters SOA bud

95 nts of SOA photolysis, which limits how well photolytic losses can be modeled.

96 vity of predicted SOA mass concentrations to photolytic losses.

97 The photolytic mechanism described here is based on electron

98 5]- and [5.6.6.5]tetracyclic systems via the photolytic method of Livinghouse.

99 We have developed a photolytic method to determine the concentration of reac

100 ubility of the assembly was measured using a photolytic micromethod over a temperature range of 17-31

101 gth single photon method for a wide array of photolytic molecules via triplet-triplet annihilation ph

102 light partners (the photosensitizers and the photolytic molecules) can be energetically matched to ad

103 shes this strategy as the foundation for the photolytic multicomponent reaction.

104 and the trans,trans-isomer is also inert to photolytic N(2) cleavage.

105 uctive formation of a bridging N(2) complex, photolytic N(2) splitting, and proton-coupled electron t

106 Key steps include a 'one-pot' photolytic N-N bond cleavage of a Group 6 dinuclear dini

107 r environments, thus, limiting the extent of photolytic OH sources.

108 transporter currents (GTCs) were induced by photolytic or synaptic glutamate release and isolated ph

109 d cis-fused gamma-lactones efficiently under photolytic or thermolytic conditions.

110 ibuted significantly to improve electro- and photolytic organic transformations in terms of energy ef

111 ent, the possibility of OH formation through photolytic pathways indoors has been ignored up to now.

112 Thermo-oxidative and photolytic pathways represent the most relevant degradat

113 ed BPs can be used as markers to distinguish photolytic PBDE transformation products from naturally p

114 However, under comparable conditions, no photolytic pH(2)/oH(2) interconversion was observed for

115 ne of the reasons why the quantum yields for photolytic polymer degradation (and long-chain molecules

116 spectrometry measurements confirmed that the photolytic process did not produce dye radicals.

117 trum and calculate the rate constant for the photolytic process HNO(3) + hnu -> NO(2) + OH, leading t

118 trum and calculate the rate constant for the photolytic process HNO(3) + hv NO(2) + OH, leading to 2

119 The C10-C11 trans-alkene was isomerized by a photolytic process; control experiments suggest that thi

120 most suitable model to explore environmental photolytic processes in situ.

121 However, these photolytic processes remain poorly constrained.

122 (2)O(2) presence indicates active radiolytic/photolytic processing of the water ice-rich surface by s

123 material escaping from Pluto, as well as the photolytic processing of this material into more complex

124 at it is possible to adjust and modulate the photolytic product distribution by varying the parameter

125 concentrations, with desulfinyl fipronil (a photolytic product) contributing about 25%.

126 can therefore serve as a stable reactant for photolytic production of [5,6]-C(60)O.

127 Ca2+ release triggered by photolytic production of cADPr was initially slow, with

128 ccelerating growth may result from increased photolytic production of condensable organic species in

129 that Fe(III)-binding ligands can enhance the photolytic production of reactive iron species in the eu

130 lausible mechanism of formation of different photolytic products is suggested.

131 ng gulls are exposed (e.g., via the diet) to photolytic products of TeDB-DiPhOBz, OH-PB-DiPhOBz and o

132 Pairs of short 2P photolytic pulses (1 ms, 810 nm) were applied with diffe

133 external stimuli such as chemical, thermal, photolytic, radiolytic, electronic, and mechanical facto

134 d visible light spectroscopic signatures and photolytic rate constant in the troposphere.

135 kcal/mol) and, as a result, the (laser flash photolytic) rate constants for fragmentation were essent

136 ds and the formation of the O-O bond in this photolytic reaction involve low-energy triplet states an

137 e major component (approximately 86%) of the photolytic reaction is 45 microseconds, while that of th

138 Legrand et al. reported on the photolytic reaction of an alpha-pyrone confined in a cry

139 ions, cloud formation, and heterogeneous and photolytic reaction rates, with potentially important im

140 Product analysis of the photolytic reaction showed clean conversion of NPE-caged

141 by 71% within 50 ms of the initiation of the photolytic reaction when the concentration of released D

142 Preparation and varied thermal and photolytic reactions of 2-diazo-5,6-(disubstituted)acena

143 Over the past two decades, the photolytic reactions of dibenzyl ketones sorbed on zeoli

144 -bi-1,2,3-triazolyl) undergoes unprecedented photolytic reactivity to liberate free btz (Phi363 appro

145 Recently, photolytic reductive elimination (re) of the E(4)(4H) hy

146 age and release based on a unique example of photolytic reductive elimination of the tetrahedral P(4)

147 photolysis of Plutonian methane generates a photolytic refractory distribution on Charon that increa

148 In cerebellar slices rapid photolytic release (t (1/2) < 0.7 ms) of 7--70 microM L-

149 of the probe angle change and tension after photolytic release [Ca2+] by laser photolysis of NP-EGTA

150 In control experiments, photolytic release from photolabile precursors of carbam

151 The response to photolytic release of ADP showed that the rate of NADH d

152 ned at 0.09 ML s-1 immediately following the photolytic release of ATP and at 0.04 ML s-1 prior to th

153 ontractions were elicited at 12 degrees C by photolytic release of ATP from the P3 -1-(2-nitrophenyl)

154 rse of isometric force development following photolytic release of ATP in the presence of Ca(2+) was

155 bserved during brief activations elicited by photolytic release of ATP.

156 ured on activation from the relaxed state by photolytic release of Ca2+ from a caged Ca2+ compound, n

157 ulture, including puffer pipet spritzing and photolytic release of caged effectors, each is limited i

158 We used electrophysiological recording, photolytic release of caged glutamate and a newly develo

159 and Cl(-) currents following the controlled photolytic release of caged-InsP(3) or caged-Ca(2+).

160 Photolytic release of free alanine results in the genera

161 The photolytic release of free kainate from the caged kainat

162 ors of glutamate clearance after synaptic or photolytic release of glutamate in striatal slices.

163 current evoked by uncaging Ca(2+) or by the photolytic release of higher concentrations of InsP(3).

164 Photolytic release of InsP(3) elicited a transient outwa

165 the role of InsP3 in the induction of LTD by photolytic release of InsP3 from its biologically inacti

166 Photolytic release of IP(3) elicited a transient Ca(2+)

167 trypanosomes or isolated acidocalcisomes and photolytic release of IP(3) in intact trypanosomes loade

168 rlying the sEPSP was investigated with rapid photolytic release of L-glutamate from nitroindolinyl (N

169 ooth muscle, but rigor force decreased after photolytic release of Mg(2+) in the presence of ADP.

170 Photolytic release of MgADP (25-300 microM) from caged A

171 s, in the microsecond time scale through the photolytic release of substrates from caged compounds.

172 The photolytic release of substrates from caged substrates h

173 Current decay initiated by photolytic release of the D2 antagonist sulpiride from C

174 was invariably induced, even with low-level photolytic release of threshold amounts of InsP(3).

175 mixed-valence CO complex with (18)O(2) after photolytic removal of CO.

176 etic toolkit of MOFs, we report a controlled photolytic removal of linkers to create mesopores within

177 Potentiation of photolytic responses developed rapidly in a stepwise man

178 The photolytic ROS formation serves as the driving force for

179 Also, neither this caged urea nor its photolytic side products inhibit hydrolysis of free urea

180 The catalyst, operating through a photolytic single-electron transfer, was utilized for ph

181 on resonance mass spectrometry of N(2)/CH(4) photolytic solid products at 60 and 82.5 nm indicates th

182 s acid (HONO), a species known to be a major photolytic source of the highly reactive hydroxyl radica

183 of unexpected acyl intermediates of variable photolytic stability.

184 cordingly, the rate limitation in the second photolytic step originates from a slow calcium-induced d

185 2 Mn atoms are involved in the rate-limiting photolytic step under steady-state conditions.

186 (4) Prior to the next photolytic step, one Ca2+ ion must bind at its effector

187 Responses to strong synaptic and photolytic stimulation were selectively prolonged by sma

188 Time-resolved infrared (TRIR) flash photolytic techniques have been employed to initiate and

189 Steady-state and time-resolved photolytic techniques show that an efficient transductio

190 The photolytic transformation of decabromodiphenyl ethane-a

191 oil biodegradation, but in the photic zone, photolytic transformation of PACs may play an important

192 Applying LC/MS/MS, multiple photolytic transformation products of IPAs were observed

193 Photolytic uncaging and release of free glutamate occur

194 , we addressed this question by applying the photolytic uncaging approach to induce focal increases i

195 Localized photolytic uncaging of Ca(2+) from o-nitrophenyl-EGTA in

196 Photolytic uncaging of p-hydroxyphenacyl (pHP) GABA demo

197 -activation of presynaptic GABA receptors by photolytic uncaging of RuBi-GABA has a biphasic effect o

198 ination of patch clamp electrophysiology and photolytic uncaging of RuBi-GABA we show that GABA(B) re

199 m using whole-cell patch-clamp recording and photolytic uncaging of RuBi-GABA.

200 2)) and ozone (O(3)) suggest that unmeasured photolytic VOCs were emitted during cooking events.