ライフサイエンスコーパス: pincer

1 ](2-) ligand coordinates as a kappa(3)-O,P,O pincer.

2 is the first enzyme known to possess a metal pincer active site.

3 ymerization results for the first trianionic pincer alkylidyne complex, [(t)BuOCO]W identical withCC(

4 PNP (PNP- = N[2-P(CHMe2)2-4-methylphenyl]2) pincer ancillary bound to nickel.

5 ) metal phosphors bearing both the dicarbene pincer ancillary such as 2,6-diimidazolylidene benzene a

6 nteresting applications employing trianionic pincer and pincer-type complexes include: (1) catalyzed

7 Trianionic pincer and pincer-type ligands are the focus of this rev

8 The type of donor atoms within trianionic pincer and pincer-type ligands to be discussed include:

9 Since this is the first review of trianionic pincer and pincer-type ligands, an emphasis is placed on

10 ure, consisting of a central "body", with a "pincer" and a "tail" at the respective ends.

11 frontal lobe EZ; cup, politician's fist, and pincer are strongly predictive of temporal lobe EZ.

12 s validate that both of the RNAP crab claw's pincers are mobile, as both beta and beta' have substant

13 yl and iron alkoxide complexes bearing boxmi pincers as stereodirecting ligands have been employed as

14 results demonstrate the strong influence of pincer backbone and hydrosilane sterics on the different

15 ithin the secondary coordination sphere of a pincer-based Fe(II) complex provides Lewis acidic sites

16 tion of alpha,beta-unsaturated nitriles to a pincer-based Ru-H complex affords structurally character

17 strates that Co and Cu nanopores exhibit the pincer behavior as well, suggesting that this mechanism

18 I)-(N2) precursor supported by a monoanionic pincer bis(carbene) ligand, (Mes)CCC ((Mes)CCC = bis(mes

19 l % of Rh catalyst supported by a new chiral pincer carbodicarbene ligand that delivers allylic subst

20 ommercially available ruthenium(II) PNP-type pincer catalyst (Ru-Macho) promotes the formation of alp

21 ydrogenation, in the presence of a ruthenium pincer catalyst at 150 degrees C and 70 bar H(2), we rep

22 A manganese pincer catalyst catalyzes the reactions, which provides

23 single homogeneous acridine-based ruthenium pincer catalyst.

24 fect of molecular structure of the ruthenium pincer catalysts and the amines that are critical for a

25 context we have examined the use of iridium pincer catalysts for the hydrosilylative reduction of su

26 droproducts (e.g., Ir and Rh diphosphine and pincer catalysts).

27 A highly efficient ruthenium pincer-catalyzed Guerbet-type process for the production

28 to the area of platinum(ii) cyclometallated pincer chemistry and shows the advantage of having an al

29 An appropriately tuned cationic pincer cobalt(I) complex, featuring a central silylene d

30 orm the organic component of the (SCS)Ni(II) pincer cofactor of LarA.

31 e was no prior evidence for the existence of pincer cofactors in enzymes.

32 Employing a nickel(II) pincer complex ([(N(2)N)Ni-Cl]) in combination with carb

33 coupling catalyzed by a preformed nickel(II) pincer complex ([(N2N)Ni-Cl]).

34 e alkynyl C-H bond of phenylacetylene to the pincer complex (PCP)Ir(CO).

35 Rhodium-hydride PNP pincer complex 1 is shown to add CO2 in two disparate pa

36 ng water as the only reagent is catalyzed by pincer complex 2.

37 The cationic iridium pincer complex [(POCOP)Ir(H)(acetone)](+)[B(C(6)F(5))(4)

38 The nonclassical ruthenium hydride pincer complex [Ru(PNP)(H)(2)(H(2))] 1 (PNP = 1,3-bis(di

39 (C6H2(t)Bu2-3,5-O-4)(2-), in the Bi(3+) NCN pincer complex Ar'Bi(C6H2(t)Bu2-3,5-O-4), 1, [Ar' = 2,6-

40 The Bi(3+) (N,C,N)-pincer complex Ar'BiCl(2) (1) [Ar' = 2,6-(Me(2)NCH(2))(2

41 esence of a commercially available ruthenium pincer complex as a catalyst.

42 The first Pd-pincer complex bearing a halogen (fluorine) arm has been

43 amates, and heterocycles via ruthenium-based pincer complex catalyzed acceptorless dehydrogenative co

44 actobacillus plantarum harbors a (SCS)Ni(II) pincer complex derived from nicotinic acid.

45 nt, this pathway could be used to generate a pincer complex in other enzymes.

46 ydrosilylation catalyzed by the iridium(III) pincer complex introduced by Brookhart.

47 ed at 20 degrees C using Brookhart's Ir(III) pincer complex IrH(2)POCOP (5) (POCOP = [mu(3)-1,3-(OPtB

48 The reaction is catalyzed by a pincer complex of an earth-abundant metal (manganese), i

49 The reaction is catalyzed by a pincer complex of earth-abundant manganese in the presen

50 in, we report on the catalytic activity of a pincer complex of the abundant earth metal manganese for

51 The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms

52 A new de-aromatized pyridine-based PNP pincer complex of the Earth-abundant, first-row transiti

53 -density polyethylene with either an iridium-pincer complex or platinum/zinc supported on silica as c

54 A hydride Mn(I) PNP pincer complex recently developed in our laboratory cata

55 tethered to Lys(184) and forms a tridentate pincer complex that coordinates nickel through one metal

56 d by a well-defined acridine-based ruthenium pincer complex was investigated in detail by both experi

57 In a preliminary study, a related Fe(II) PNP pincer complex was shown to catalyze the methylation of

58 An air- and moisture-stable SeCSe-Pd(II) pincer complex was synthesized and found to catalyze the

59 elimination of methane and formation of the pincer complex, [kappa(3)-Ar(Tol'(2))]Ta(PMe(3))(2)MeCl

60 n or added oxidant, catalyzed by a ruthenium pincer complex, is developed.

61 A well-defined hydride Mn(I) PNP pincer complex, recently developed in our laboratory, ca

62 -derived compounds, catalyzed by a manganese pincer complex, yields methanol in addition to amine and

63 An Earth-abundant Mn-PNP pincer complex-catalyzed terpenylation of cyclic and acy

64 ter as the oxidant, catalyzed by a ruthenium pincer complex.

65 mentary recognition unit, a p-methoxy SCS-Pd pincer complex.

66 New carbazolide-based iridium pincer complexes ((carb)PNP)Ir(C2H4), 3a, and ((carb)PNP

67 ) has been constructed from Pd diphosphinite pincer complexes ([L-PdX](4-) = [(2,6-(OPAr2)2C6H3)PdX](

68 A series of new bis(phosphinite) p-XPCPIrHCl pincer complexes ([PCP = eta(3)-5-X-C(6)H(2)[OP(tBu)(2)]

69 Reaction of bis(phosphinite) PCP iridium pincer complexes (p-XPCP)IrHCl (5a-f) [X = MeO (5a), Me

70 of the phenylhydrosilanes PhnSiH4-n with the pincer complexes (POCsp(2)OP)Ni(OSiMe3), 1-OSiMe3, and (

71 Ir pincer complexes [((t)BuPNP)Ir(R)] (R = C6H5 (1), CH2COC

72 y, despite the high reactivity of several Ru pincer complexes [RuHClPNP (R)(CO)] (R = Ph/ i-Pr/Cy/ t-

73 Random copolymers possessing both palladated-pincer complexes and diaminopyridine moieties (hydrogen-

74 s serves as the first example of boron-metal pincer complexes and possesses several interesting elect

75 tion of secondary alcohols and diols on iron pincer complexes and reversible oxidative dehydrogenatio

76 hly luminescent platinum(ii) cyclometallated pincer complexes are outlined and the strategy to improv

77 n (ADA) of alcohols utilizing new Ni(II)-NNO pincer complexes as catalysts.

78 Ruthenium-pincer complexes bearing CNN- and PNN-pincer ligands wit

79 The activation of carbodicarbene (CDC)-Rh(I) pincer complexes by secondary binding of metal salts is

80 A series of PNP zinc pincer complexes capable of bond activation via aromatiz

81 the synthesis of several unique, boron-rich pincer complexes derived from m-carborane.

82 The new Pt(II) pincer complexes display very high luminescence quantum

83 efforts, the synthesis of iron PC(carbene)P pincer complexes has so far remained elusive.

84 Earth-abundant metal pincer complexes have played an important role in homoge

85 Recent applications of these cyclometallated pincer complexes in the area of opto-electronics is desc

86 th HBpin (pin = pinacolate) using POCOP-type pincer complexes of Ir has been demonstrated, with turno

87 We report the synthesis of PAlP and PBP pincer complexes of Rh with a central bis(N-pyrrolyl)alu

88 Pincer complexes of the type ((R)PCP)IrH(2), where ((R)P

89 rticle, we describe a series of iridium(III) pincer complexes of the type [(PEP)IrCl(CO)(H)] (q) enab

90 ons in transition-metal chemistry to furnish pincer complexes or "pogo stick" type compounds.

91 Six amide-based NNN palladium(II) pincer complexes Pd(L)(CH3CN) were synthesized, characte

92 However, most of the studies are based on pincer complexes with a central nitrogen donor.

93 The first [ECE]Ni(II) pincer complexes with E = Si(II) and E = Ge(II) metallyl

94 ghtest binding ligands toward the palladated pincer complexes with the alanyl derivative being the st

95 A series of iron bis(phosphinite) pincer complexes with the formula of [2,6-((i)Pr2PO)2C6H

96 chelate yielding the corresponding modified pincer complexes, ((tBu)mPNP)CoX (X = H, CH3, Cl, CCPh).

97 nd reactivity of unusual T-shaped (LXL)Au(I)-pincer complexes, based on a carbazole framework flanked

98 development of cyclometallated platinum(ii) pincer complexes, in which the tridentate ligand forms o

99 PN5P-Ir-pincer complexes, recently developed in our laboratory,

100 complexes have been known for 150 years and pincer complexes, supported by a tridentate chelating li

101 ration of the possibility of MLC by PCP-type pincer complexes, we report herein the synthesis, charac

102 ents between appropriate intact and modified pincer complexes.

103 activation by ligand cooperativity in nickel pincer complexes.

104 oxylation of unactivated olefins by iridium "pincer" complexes.

105 ist-led information technology intervention (PINCER), composed of feedback, educational outreach, and

106 ioxyselenuranes and diminished activity when pincer compounds were produced.

107 A V-shaped pincer connects HEL2 and the CTD by gripping an alpha-he

108 In this way, the pincer coordinates functions of all the domains and coup

109 A recent study showed that a Mn-pincer could catalyze the acceptorless dehydrogenative c

110 The pincer-crown ether ligand exhibits tridentate, tetradent

111 ion ligated in a pentadentate fashion by the pincer-crown ether ligand.

112 ali metal cation binding with a macrocyclic "pincer-crown ether" ligand.

113 Our approach was to use molecular pincer design in which a pair of antibodies recognizing

114 An iridium pincer dihydride catalyst was immobilized on carbon nano

115 ral studies of RIG-I have identified a novel Pincer domain composed of two alpha helices that physica

116 ophysical analysis, we further show that the Pincer domain controls coupled enzymatic activity of the

117 pathic helix (the basic amino acid PI(4,5)P2 pincer domain) was required for PI(4,5)P2 binding and re

118 evolved to potentiate interactions with the Pincer domain, resulting in an adapted ATPase cleft that

119 eview is structured according to the type of pincer donor atoms that bind to the metal ion.

120 ingers ("fist," "cup," "politician's fist," "pincer," "extended hand," "pointing").

121 ring Rh and the chelating aryl carbon of the pincer framework.

122 activation within the strained m-carboranyl pincer framework.

123 We present the ProteIN ConsERvation (PINCER) genome-wide CRISPR library, which for the first

124 ilestones was similar, whereas attainment of pincer grasp and early vocalisation were mildly delayed.

125 h which they use chopsticks, handedness, and pincer grip activities.

126 her activities and subjects who denied other pincer grip activities.

127 and subjects who did not engage in any other pincer grip activities.

128 This suggests that RNA polymerase II's pincer grip is important as it slides on DNA in search o

129 At 6 months' follow-up, patients in the PINCER group were significantly less likely to have been

130 PINCER has a 95% probability of being cost effective if

131 led that borylation of the 4-position of the pincer in the cobalt catalyst was faster than arene bory

132 INTERPRETATION: The PINCER intervention is an effective method for reducing

133 This analysis suggests that the PINCER intervention is strongly effective in reducing th

134 ium centre in molecular single crystals of a pincer Ir(I) complex.

135 not the thermodynamics) of C-H addition to (pincer)Ir are favored by sigma-withdrawal from the phosp

136 e to unsubstituted PCP) addition to the 14e (pincer)Ir fragments but disfavor addition to the 16e com

137 y proceeds via alpha-olefin C-H addition to (pincer)Ir to give an allyl intermediate as was previousl

138 ave analogous resting states: square planar (pincer)Ir(alkene).

139 tion to the 16e complexes (pincer)IrH(2) or (pincer)Ir(CO).

140 Instead, (pincer)Ir(eta(2)-olefin) species undergo isomerization v

141 undergo isomerization via the formation of (pincer)Ir(eta(3)-allyl)(H) intermediates; one example of

142 on, which limits yields of alpha-olefin from pincer-Ir catalyzed alkane dehydrogenation, proceeds via

143 but disfavor addition to the 16e complexes (pincer)IrH(2) or (pincer)Ir(CO).

144 The corresponding dihydrides, (pincer)IrH(2), are known to hydrogenate olefins via init

145 ydroaryloxylation of aryl alkyl ethers using pincer iridium catalysts.

146 mation within a nonporous molecular crystal: pincer iridium single crystals ligated with nitrogen, et

147 The pincer-iridium fragment ((iPr)PCP)Ir ((R)PCP = kappa(3)-

148 PINCER is available for individual gene knockout and gen

149 epresenting the N- and C-termini of TSC1; a "pincer" is formed by the highly flexible N-terminal TSC1

150 alyst (1a) bearing a redox-active tridentate pincer (L(1a)).

151 , we demonstrate superior performance of the PINCER library compared to alternative genome-wide CRISP

152 A SeNSe pincer ligand (L1) and its palladium(II) complex (C1) we

153 feature a rare nickel-carbene linkage as the pincer ligand anchor point.

154 ing a tridentate 2,6-pyridinedicarboxamidate pincer ligand and a terminal hydroxide ligand.

155 By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demon

156 ence further by chemical manipulation of the pincer ligand and of the auxiliary ligand in the fourth

157 s supported by a naphthyridine-diimine (NDI) pincer ligand as functional surrogates of Co2 (CO)8 .

158 coupled electron transfer from the saturated pincer ligand backbone.

159 -)) that are deprotonated at nitrogen in the pincer ligand backbone.

160 y(NMes)) was prepared as a rigid, tridentate pincer ligand containing pendent anilines as hydrogen bo

161 e incorporation of the metal center into the pincer ligand decreases the NICS(1)zz values.

162 mplex (3) supported by a bis(phosphino)amine pincer ligand efficiently catalyzes both acceptorless de

163 nt the up to now strongest chelating neutral pincer ligand for the simplest electrophile of chemistry

164 A new class of [CCC] X(3)-donor pincer ligand for transition metals has been constructed

165 Nickel complexes of a PC(carbene)P pincer ligand framework are described.

166 A new bifunctional pincer ligand framework bearing pendent proton-responsiv

167 emase, which features a pyridinium-based SCS pincer ligand framework bound to nickel.

168 A tetra(carboxylated) PCP pincer ligand has been synthesized as a building block f

169 idinedicarboxamidate(2-)) derived from a NNN pincer ligand have been prepared including L = OH(-) (1)

170 [ReCl3(PPh3)2(NCMe)] reacts with pincer ligand HN(CH2CH2PtBu2)2 (HPNP) to five coordinate

171 possible involvement of the N-H group on the pincer ligand in the catalysis via a metal-ligand cooper

172 (3))(2)(CD(3))(3)Cl(2) demonstrates that the pincer ligand is created by a pair of Ar-H/Ta-Me sigma-b

173 e (tBu) PCP (kappa(3)-2,6-((t)Bu2PCH2)2C6H3) pincer ligand is possible.

174 nstrained phosphine bearing a tridentate NNS pincer ligand is reported.

175 strongly trans directing silyl group at the pincer ligand of these complexes are discussed on the ba

176 A carbodicarbene (CDC)-based pincer ligand scaffold is reported, along with its appli

177 ungsten catalyst supported by a tetraanionic pincer ligand that can rapidly polymerize alkynes to for

178 atalyst appears to be the new ancillary SiNN pincer ligand that combines amido, quinoline, and silyl

179 upling with one of the phosphine arms of the pincer ligand to produce a phosphanylidene phosphorane c

180 Application of a tridentate NHC containing pincer ligand to Pt catalyzed cascade cyclization reacti

181 The basicity of the ipso-carbon atom of the pincer ligand was investigated in a related complex.

182 A new PC(carbene)P pincer ligand with 2,3-benzo[b]thiophene linkers connect

183 e (PCP)Ir(I) fragment containing an aromatic pincer ligand with methyl-substituted hydrazines form a

184 -innocent pyrrole-based trianionic (ONO)(3-) pincer ligand within [(pyr-ONO)TiCl(thf)2 ] (2) can acce

185 ((tBu) mPNP)Co=NMes ((tBu) mPNP=modified PNP pincer ligand) has been synthesized from addition of 2,4

186 The complex containing an aromatic pincer ligand, (PCP)Ir(H)(NHNC(5)H(10)), slowly undergoe

187 New iridium complexes of a tridentate pincer ligand, 2,6-bis(di-tert-butylphosphinito)pyridine

188 I)(OH)(n)(H(2)O)(m), 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to cata

189 = CCH3(CF3)2) 1, featuring a stabilizing ONO pincer ligand, initiates the controlled living polymeriz

190 ormational flexibility of the acridine-based pincer ligand.

191 ed by an iridium complex supported by a SiNN pincer ligand.

192 ploying an iron-based catalyst bearing a PNP-pincer ligand.

193 bonds in remote positions of the supporting pincer ligand.

194 catalyzed by a nickel(II) hydride bearing a pincer ligand.

195 highly reversible C-C coupling with the PNP pincer ligand.

196 y cooperative 2 H(+) /2 e(-) transfer of the pincer ligand.

197 ered alkylidene (4) featuring a tetraanionic pincer ligand.

198 investigated manganese catalysts possessing pincer ligands (particularly phosphine-based ligands).

199 reacting silver(I) oxide with N-substituted pincer ligands 3 (a = 2,6-bis(ethanolimidazoliummethyl)p

200 The concept of aromaticity in pincer ligands and complexes was discussed in order to p

201 aromatic PN(x)(P) and dearomatized PN(x)(P)* pincer ligands and the corresponding transition metal co

202 Palladium complexes with chiral pincer ligands are demonstrated to have utility in deter

203 ligand cooperative reactivity, PC(carbene) P pincer ligands are rarely reported for first-row transit

204 s of the process when different dearomatized pincer ligands are used.

205 (1H-1,2,4-triazol-5-yl)pyridine luminophoric pincer ligands bearing either CF(3) or (t)Bu moieties on

206 The SeBSe and SBS pincer ligands can be synthesized via two independent sy

207 ert-butyl substituted bis(phosphino)pyridine pincer ligands has been synthesized and structurally cha

208 eric and electronic properties of trianionic pincer ligands has occurred rapidly over the past ten ye

209 able tridentate directing groups inspired by pincer ligands have been designed to stabilize otherwise

210 Cobalt(II) alkyl complexes of aliphatic PNP pincer ligands have been synthesized and characterized.

211 ive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenati

212 The increase in use of pincer ligands in forming stable, isolable complexes is

213 um dihydride complexes supported by PCP-type pincer ligands rapidly insert CO(2) to yield kappa(2)-fo

214 Iridium complexes of sterically unhindered pincer ligands such as (iPr4)PCP, in the solid phase, ar

215 The introduction of functional pincer ligands that can store protons and/or electrons a

216 he rare earths, are combined with trianionic pincer ligands to produce some of the most interesting c

217 es of aromatic (PCP) and aliphatic (D(t)BPP) pincer ligands undergo single cleavage of the N-H bonds

218 henium-pincer complexes bearing CNN- and PNN-pincer ligands with diethyl- or diisopropylamino side gr

219 nd relevance of cooperating and redox-active pincer ligands within the mechanistic scenarios.

220 is is put on the common appearance in AAD of pincer ligands, of noninnocent ligands, and of outer sph

221 Cobalt complexes stabilized with pincer ligands, recently developed in our laboratory, ca

222 hilic traps with electrophilic trisphosphine pincer ligated Pt(II) complexes results in the formation

223 system comprises one molecular catalyst (a "pincer"-ligated iridium complex) that effects alkane deh

224 eneous or molecular catalysts--specifically 'pincer'-ligated iridium complexes--and olefinic hydrogen

225 R)POCOP = kappa(3)-C(6)H(3)-2,6-(OPR(2))(2)) pincer-ligated catalysts, which also show catalytic acti

226 A family of pincer-ligated cobalt complexes has been synthesized and

227 Di-isopropylphosphino-substituted pincer-ligated iridium catalysts are found to be signifi

228 alkanes catalyzed by solid-phase, molecular, pincer-ligated iridium catalysts, using ethylene or prop

229 process involves alkane dehydrogenation by a pincer-ligated iridium complex and alkene dimerization b

230 A pincer-ligated iridium complex, (PCP)Ir (PCP = kappa(3)-

231 le (H(2), arene, alkane, and CO) addition to pincer-ligated iridium complexes of several different co

232 The p-methoxy-substituted pincer-ligated iridium complexes, (MeO-(tBu)PCP)IrH(4) (

233 isomerization of olefins by complexes of the pincer-ligated iridium species ((tBu)PCP)Ir ((tBu)PCP =

234 thermochemical and kinetic analyses of a new pincer-ligated rhenium complex ((tBu)POCOP)Re(CO)(2) ((t

235 Reported herein is a pincer-ligated rhenium system that reduces N(2) to NH(3)

236 The pincer-ligated species (PCP)Ir (PCP = kappa3-C6H3-2,6-(C

237 to date in this area has been achieved with pincer-ligated transition-metal-based catalysts; this an

238 The pincer-like 1,3-alternate conformation of the oxacalix[4

239 ich the carboxy-terminal tail domain is held pincer-like by the vinculin head, and ligand binding is

240 m152 interacts in a pincer-like manner with two sites on the alpha1 and alph

241 releasing" motions between vinculin tail and pincer-like structure formed by first three domains of v

242 suggest that a wide family of pyridine-based pincers may also be redox-active.

243 Resultantly, the pincer mechanism endows P-Zn with a high Faradic efficie

244 anion receptor functions via a novel dynamic pincer mechanism where upon nitrate anion binding, both

245 es, and catalytic applications of trianionic pincer metal complexes.

246 s tandem [4 + 2]/[4 + 2] cycloadditions in a pincer mode.

247 u)PNP)CoH, at 110 degrees C also resulted in pincer modification by H atom loss while the chloride an

248 es of mutations that additively decouple the Pincer motif from the ATPase core and show that this dec

249 and a nickel-containing cofactor, the nickel-pincer nucleotide (NPN).

250 igher binding ability offered by two pendant pincers of the former.

251 , a C51 H24 hydrocarbon with two corannulene pincers on a dibenzonorbornadiene tether, exhibits an af

252 ionally fixed aromatic residues, hydrophobic pincer pair that locks the different drug structures on

253 ppendages approximately perpendicular to the pincer plane, with increasingly better alignment progres

254 s presented upon reduction of a rhenium(III) pincer platform.

255 We find that the Pincer plays an important role in mediating the enzymati

256 ys a well-defined and bench-stable Mn(I) PNP pincer precatalyst, allowing benzylic and simple primary

257 ssociation constants are comparable to other pincer-pyridine systems in DMSO suggesting that the cont

258 the controlled coordination of the metalated pincer/pyridine interaction is an interesting biological

259 imary alcohols, alkyl chains, and palladated pincer receptors, synthesized by ring-opening metathesis

260 inant spherocytosis and with the presence of pincered red cells in the peripheral blood smears of uns

261 2 featuring one and two pendant amide side "pincers", respectively, and three triphenylamine substit

262 This article describes a well-defined pincer-Rh catalyst for C-S cross-coupling reactions.

263 f Milstein's well-defined acridine-based PNP-pincer Ru complex has been investigated both experimenta

264 The reaction is catalyzed by a PNP pincer ruthenium complex, generating efficiently only di

265 A new PNN-pincer ruthenium(0)-imine complex is a highly active cat

266 ligand combining a rigid, strongly donating pincer scaffold with a flexible, weakly donating aza-cro

267 In contrast, several selenides that afford pincer selenuranes (e.g., 20 and 21) instead of spirosel

268 red which specifically binds Ni(II) at a NNN pincer site and five-coordinate Fe(II) at a triamine sit

269 B/Al metathesis with the preservation of the pincer structure in the product (PBP)Rh(CO)(2).

270 The PINCER study, a cluster randomised controlled trial, is

271 ort the synthesis of stable and isolable OCO pincer-supported alkyl-Pd(IV) complexes containing cyclo

272 Utilizing this zinc pincer system, base-free catalytic hydrogenation of imin

273 analogous diarylamido/bis(phosphine) (PNP)Rh pincer system.

274 havior of isoelectronic Mn(I) and Fe(II) PNP pincer systems.

275 ibody-based protein sensor design (molecular pincers) that allows rapid and sensitive detection of a

276 he concave surface of nanopores works like a pincer to capture and clamp CO(2) and H(2) O precursors

277 rization of the new CF(3)-ONO(3-) trianionic pincer tungsten-alkylidene [CF(3)-ONO]W horizontal lineC

278 ated amines using Ni(II)-N(Lambda)N(Lambda)O pincer type complexes through the borrowing hydrogen met

279 esign of highly basic nonionic superbases of pincer type.

280 The square planar pincer-type carbene effects quantitative oxygen-atom tra

281 primary alcohols by newly synthesized nickel pincer-type complexes (1-3) has been described.

282 arenes and alcohols by new palladium(II)-NNO pincer-type complexes has been described.

283 applications employing trianionic pincer and pincer-type complexes include: (1) catalyzed aerobic oxi

284 Patients with pincer-type FAI had a significantly larger femoral antet

285 on was significantly higher in patients with pincer-type FAI than in those with cam-type FAI for read

286 [C(CF3)2O])2N(3-)} supported by a trianionic pincer-type ligand demonstrates enhanced nucleophilicity

287 rization of a novel CF(3)-ONO(3-) trianionic pincer-type ligand, rationally designed to mimic enamine

288 Pincer-type ligands are believed to be very robust scaff

289 Trianionic pincer and pincer-type ligands are the focus of this review.

290 yhydride complexes containing tridentate PNP pincer-type ligands is described.

291 of donor atoms within trianionic pincer and pincer-type ligands to be discussed include: NCN(3-), OC

292 is the first review of trianionic pincer and pincer-type ligands, an emphasis is placed on providing

293 Here we design a Pt(II) pincer-type material with selective absorptive and emiss

294 was observed in the analogous complex with a pincer-type mer-C,N,S ligation, emphasizing the importan

295 d the problem of high prevalence of cam- and pincer-type morphology in asymptomatic persons.

296 of arylboronic acids catalyzed by a new ONO pincer-type Pd(II) complex under mild reaction condition

297 Theoretically designed pincer-type phosphorus compound is found to be active fo

298 Ni(II) complexes (C1-C3) encapsulated in NNS pincer-type thiosemicarbazone ligands have been synthesi

299 (nacnac) chelate arms (L(-) ), providing two pincer-type {N(3) } binding pockets, has been reported t

300 uring a redox-noninnocent tridentate arylazo pincer under comparatively mild aerobic conditions via d