ライフサイエンスコーパス: polyoxometalate

1 blackberry formation for a non-Mo-containing polyoxometalate.

2 ization of disulfide bond-based polymer with polyoxometalate.

3 ns, flexibility and dynamic is possible with polyoxometalates.

4 now facilitate efforts to design functional polyoxometalates.

5 ular metal-oxide nanoclusters, also known as polyoxometalates.

6 ner of the shell, evocative of mono-lacunary polyoxometalates.

7 s in selectivity in the self-assembly of the polyoxometalates.

8 of molecular oxygen in reactions mediated by polyoxometalates.

9 sport studies of magnetically functionalized polyoxometalates.

10 {P2 W18 } (3), and {Mo12 O36 (HPO3 )2 } (4) polyoxometalates.

11 Finally, inhibition of CD39 activity by polyoxometalate-1, a pharmacologic inhibitor of nucleosi

12 (31)P NMR shows that the Cu-NO2-substituted polyoxometalates act as oxygen donors to the C-C double

13 irst, we reveal that the Anderson-Evans type polyoxometalate [AlMo(6)O(18)(OH)(6)](3-) represents an

14 hesized gold nanoparticles (AuNPs) and alpha-polyoxometalate (alpha-POM) (K7PMO2W9O39 .

15 sembled monolayer to enhance the doping with polyoxometalate, an impressive efficiency of 20.1 % is a

16 brid of silica aerogel with a Preyssler-type polyoxometalate and MIL-101(Cr) metal-organic framework

17 but less common than other Keggin isomers in polyoxometalate and polyoxocation chemistry.

18 synthesised a pyridyl-capped Anderson-Evans polyoxometalate and used it to fabricate single-molecule

19 of nearly spherical shape and thus includes polyoxometalates and boron clusters.

20 r the screening and scale up of syntheses of polyoxometalates and manganese-based single-molecule mag

21 the process of the self-assembly of gigantic polyoxometalates and their subsequent molecular growth,

22 l and biological sciences, are a subclass of polyoxometalates and usually self-assemble in aqueous-ph

23 rt through different oxidation states of the polyoxometalate, and we report here an efficient three-s

24 table redox states (e.g., metalloporphyrins, polyoxometalates, and C60) is more particularly discusse

25 clude aluminum polycations, transition-metal polyoxometalates, and the actinyl peroxide clusters have

26 terials, including organometallic complexes, polyoxometalates, and the primary focus of this Perspect

27 2)Mo(18)O(62)](4-), and [S(2)W(18)O(62)](4-) polyoxometalate anions (POMs) and oxidation of water occ

28 including but not limited to combinations of polyoxometalate anions and redox-active cations, was con

29 Unlike metallo-organic catalysts, polyoxometalate anions are oxidatively stable and are re

30 show that equilibration reactions typical of polyoxometalate anions keep the pH of the system near 7

31 used to characterize triply charged tungsten-polyoxometalate anions, PW(12)O(40)(3-) (WPOM).

32 Polyoxometalates are anionic metal oxide clusters of a v

33 Polyoxometalates are clusters of metal-oxide units, comp

34 These complex polyoxometalates are known to be highly sensitive to rea

35 onto metallic 1T-MoS(2), using Anderson-type polyoxometalates as precursors.

36 The fuel cell uses polyoxometalates as the photocatalyst and charge carrier

37 to describe the synthesis of the core-shell polyoxometalates based on the monitoring results.

38 etical and experimental investigation of two polyoxometalate-based metal-organic frameworks (MOFs), [

39 Two MOF-like but all-inorganic polyoxometalate-based networks, [Na7X2W18Sn9Cl5O68.(H2O)

40 Polyoxometalate-based open frameworks (POM-OFs) are exte

41 Meanwhile, polyoxometalates-based organic-inorganic hybrid material

42 Here we develop a covalently modified polyoxometalate/beta-cyclodextrin (POM/beta-CD) organic-

43 Ru4-polyoxometalate bridges the gap between homogeneous and

44 o(2)O(2)S(2)}(2+) and {Mo(3)S(4)}(4+) toward polyoxometalate building blocks.

45 porating phosphorus(III)-based anions into a polyoxometalate cage, a new type of tungsten-based uncon

46 The reduced polyoxometalate can be reoxidized in fuel cells that con

47 A typical type of core-shell polyoxometalates can be obtained through the Keggin-type

48 we describe how building block libraries of polyoxometalates can be used to construct systems with i

49 In a similar vein, polyoxometalates can stabilize metal nanoparticles, lead

50 ) in the presence of a bio-inspired Ru-based polyoxometalate catalyst to produce synzyme protocells (

51 chemical warfare nerve agent simulant over a polyoxometalate catalyst.

52 munication describes a new method for the Pd/polyoxometalate-catalyzed aerobic olefination of unactiv

53 The detection is triggered by polyoxometalate-catalyzed oxidative doping of polypyrrol

54 The review article goes beyond the realms of polyoxometalate chemistry and encompasses emerging resea

55 Polyoxometalate cluster anions (POMs) control formation

56 In this work, we show how a polyoxometalate cluster with an integrated pore, based o

57 4,4'-azipentanoate (NHS-diazirine), and the polyoxometalate cluster {P(8)W(48)}.

58 elope of both events and employ it for a new polyoxometalate cluster, Na6 [Mo120 Ce6 O366 H12 (H2 O)7

59 2+) ) around a rigid, spherical, 2.9-nm size polyoxometalate cluster, {Mo(132) }(42-) , is determined

60 xygen-atom abstraction from the surface of a polyoxometalate cluster.

61 amolecular assembly of a series of nanoscale polyoxometalate clusters (from the same one-pot reaction

62 is achieved by incorporating Anderson-Evans polyoxometalate clusters (POMs, MMo(6)O(24), M = Rh/Pt)

63 Uranyl polyoxometalate clusters are both fundamentally fascinat

64 nd have many common building blocks; in fact polyoxometalate clusters are perhaps the largest non-bio

65 Polyoxometalate clusters are soluble in water, but more

66 ese results demonstrate the promise of using polyoxometalate clusters as building blocks for tunable

67 hods for the grafting of peptide chains onto polyoxometalate clusters by the use of general activated

68 the ability to add delocalized electrons to polyoxometalate clusters can be incorporated into self-a

69 d to probe the mechanism of self-assembly of polyoxometalate clusters in solution.

70 lecular nanostructures like coordination and polyoxometalate clusters is extremely time-consuming sin

71 Despite the vast number of polyoxometalate clusters now known, an ongoing and impor

72 zeolitic channels and on stronger acids HPW (polyoxometalate clusters on silica).

73 Mn-Anderson based polyoxometalate clusters with different terminal groups

74 rometer-scale tubes and membranes built from polyoxometalate clusters.

75 plets are reconfigured into membrane-bounded polyoxometalate coacervate vesicles (PCVs) in the presen

76 which helps to differentiate closely related polyoxometalates coexisting in solution.

77 Nanostructured inverse hexagonal polyoxometalate composite films were cast directly from

78 articles (Ag-NPs) encapsulated in a tungsten polyoxometalate compound (POM) are embedded within the p

79 ns to produce an aqueous solution of reduced polyoxometalate compounds that can be used to generate p

80 nts, to the best of our knowledge, the first polyoxometalate-driven paradigm as an efficient method t

81 the polyoxometalate, forming heterometallic polyoxometalates, e.g., [SiCu(II)Fe(III)Ga(III)(H(2)O)(3

82 O(2) in the first coordination sphere of the polyoxometalate, forming heterometallic polyoxometalates

83 uced into the synthesis of a uranyl peroxide polyoxometalate formulated as K(32)(UO(2))(19)(O(2))(26)

84 on of a tungsten atom (W(VI) to W(V)) in the polyoxometalate framework.

85 racterization of an organic-inorganic hybrid polyoxometalate functionalized by a short link with a tr

86 Herein, using the polyoxometalate H(3)PMo(1)(2)O(4)(0), we introduce the c

87 as an active catalyst, and iron(II) and the polyoxometalate H(5)PMo(10)V(2)O(40) (POM-V2) were ident

88 A well-defined alpha-Keggin polyoxometalate, H(5)PV(2)Mo(10)O(40), can be viewed as

89 at all structural sites in two isostructural polyoxometalates, [H(x)Nb(10)O(28)]((6-x)-) and [H(x)Ti(

90 The polyoxometalate H5PV2Mo10O40 mediates the insertion of a

91 Polyoxometalates have been proposed in the literature as

92 molecular water oxidation catalysts based on polyoxometalates have been reported that combine the adv

93 A series of polyoxometalates have been synthesized and evaluated for

94 Not only can polyoxometalates have gigantic nanoscale molecular struc

95 Polyoxometalates have long been studied as a fascinating

96 elf-assembly of organo-functionalised hybrid polyoxometalates (hereafter referred to as hybrid POMs),

97 alized organic-inorganic hybrid Wells-Dawson polyoxometalate in good yield is presented.

98 study molecularly defined SACs supported on polyoxometalates in catalytic reactions.

99 talyst development, and the possible uses of polyoxometalates in green energy science.

100 Our results show the promise of polyoxometalates in nanoelectronics and give an insight

101 istic investigation elucidating the roles of polyoxometalates in POM-photoelectrode hybrid oxygen evo

102 hould aid in the exploitation of these giant polyoxometalates in solution for various applications.

103 None of the polyoxometalates inhibited the binding of a specific CXC

104 enerally applicable strategy for integrating polyoxometalates into functional architectures and devic

105 Polyoxometalate ions (POMs) have structures similar to c

106 The evolution of solvated polyoxometalate ions and crystalline phases in the solid

107 nd composition suggests reaction pathways in polyoxometalate ions will be highly variable even within

108 Access to asymmetrically functionalized polyoxometalates is a grand challenge as it could lead t

109 ared by pretreatment of the aqua-coordinated polyoxometalates (L = H2O) with NO2 or are formed in sit

110 based on redox-active (vanadate(V)-centered) polyoxometalate ligands, Na10[Co4(H2O)2(VW9O34)2].35H2O

111 c hybrid molecule comprising two Dawson-type polyoxometalates linked by a 2,2'-bipyridine unit, which

112 ution or X SOL), characterized by lanthanide polyoxometalates (LnPOMs) as heavy atoms source, which c

113 very similar to the unique self-assembly of polyoxometalate macroanions into single-layer, spherical

114 onstruct complex chemical systems based upon polyoxometalates, manipulating the templating/self templ

115 demonstrating the crucial role played by the polyoxometalate metal oxide cluster as an intermediary i

116 g a terminal aromatic pyrene platform with a polyoxometalate Mn-Anderson cluster as linker, demonstra

117 nd {Mo(154-x)}, as well as the largest known polyoxometalate {Mo(368)}, with improved yield (up to 26

118 a nanoscale anion, the tetragonal Lindqvist polyoxometalate Mo6O19(2-).

119 been achieved using the ruthenium-containing polyoxometalate molecular catalyst, [{Ru4O4(OH)2(H2O)4}(

120 Here we show that a molybdenum(VI) oxide 'polyoxometalate' molecular nanocluster containing two em

121 Polyoxometalate molybdenum blue (MB) complexes typically

122 ized by linking ditopic amino functionalized polyoxometalate [N(C(4)H(9))(4)](3)[MnMo(6)O(18){(OCH(2)

123 avior of giant toroidal molybdenum blue-type polyoxometalate, namely, the {Mo(154)} species in the pr

124 Niobium polyoxometalates (Nb-POMs) are unique in the aqueous met

125 inorganic hybrid complexes between CB[n] and polyoxometalates not only display a surprisingly high st

126 noted L) and the trivacant [AsW(9)O(33)](9-) polyoxometalate (noted POM) has been investigated.

127 TiO(2) support and ammonium phosphotungstic polyoxometalate (NPW) clusters anchored with isolated Pt

128 ptor anion, alpha-SiV(V)W(11)O(40)(5-) (1, a polyoxometalate of the Keggin structural class), was use

129 Herein, we report a hybrid polyoxometalate organic-inorganic compound, Na2 [(HGMP)2

130 and programmed assembly of a dumbbell-shaped polyoxometalate-organic hybrid molecule comprising two D

131 with a 100% theoretical atom economy using a polyoxometalate oxygen donor has been found.

132 fter as (COD)Ir.POM(8-), where POM(9-) = the polyoxometalate, P2W15Nb3O62(9-)) under H2 is investigat

133 The polyoxometalate phosphotungstic acid has been used to se

134 nt triazine framework (CTF)/H(3)PMo(12)O(40) polyoxometalate (PMo12) heterojunction.

135 een applied to the study of the reduction of polyoxometalate [PMo12O40](3-) adsorbed at a boron doped

136 imentally elusive delta-isomer of the Keggin polyoxometalate polyanion.

137 several nanometers (molecular clusters, i.e. polyoxometalates, polyoxocations, and metal-organic poly

138 ed, dimeric, ZrIV-substituted Lindqvist-type polyoxometalate (POM) (nBu4N)6[{(mu-MeO)ZrW5O18}2], (TBA

139 report the encapsulation of a Ni-containing polyoxometalate (POM) [Ni4 (H2 O)2 (PW9 O34 )2 ](10-) (N

140 f pure approximately 0.75 nm size molybdenum polyoxometalate (POM) anions on 25 mug ( approximately 0

141 SS), [60]fullerene (C60), and Lindqvist-type polyoxometalate (POM) are used as building blocks to con

142 as a nanohybrid material by using S-rGO with polyoxometalate (POM) as a cathode-active material for a

143 Here, we demonstrate aqueous niobium polyoxometalate (POM) carbon capture ability, specifical

144 In the thematic review dedicated to polyoxometalate (POM) chemistry published in Chemical Re

145 In this review we discuss the relevance of polyoxometalate (POM) chemistry to provide model objects

146 In the wide area of polyoxometalate (POM) chemistry, diphosphate/diphosphona

147 hybrid molecules containing a large anionic polyoxometalate (POM) cluster and two C6 and C16 alkyl c

148 Herein, we report a nanoscale polyoxometalate (POM) cluster with a vacancy site compat

149 nteract with the conjugate anion in W and Mo polyoxometalate (POM) clusters and gaseous mineral acids

150 Acid strengths for Keggin polyoxometalate (POM) clusters and zeolites, chosen beca

151 High-nuclearity polyoxometalate (POM) clusters are attractive building b

152 eactions on Bronsted acid catalysts based on polyoxometalate (POM) clusters are described in terms of

153 The assembly of nanoscale polyoxometalate (POM) clusters has been dominated by the

154 The self-assembly of polyoxometalate (POM) clusters remains challenging becau

155 om single-walled carbon nanotubes (SWNTs) to polyoxometalate (POM) clusters results in the spontaneou

156 he contribution of building blocks of Keggin polyoxometalate (POM) clusters to redox processes are ch

157 zation of a new class of hybrid Wells-Dawson polyoxometalate (POM) containing a diphosphoryl group (P

158 in the formation of transition-metal-bridged polyoxometalate (POM) coordination frameworks.

159 a representative series of Keggin and Dawson polyoxometalate (POM) films in contact with a metallic (

160 lay an important structure-directing role in polyoxometalate (POM) growth in solution.

161 upon addition of the well-known Keggin-type polyoxometalate (POM) H(3)PW(12)O(40) (PW).

162 We observed the diffusion and aggregation of polyoxometalate (POM) ions in water by using liquid phas

163 >30 coordination polymers incorporating this polyoxometalate (POM) ligand.

164 and neodymium complexes with five different polyoxometalate (POM) ligands were structurally and spec

165 al core is stabilized by coordination of two polyoxometalate (POM) ligands.

166 Here we show that core-shell polyoxometalate (POM) molecules can act as candidate sto

167 rated as highly effective nanocontainers for polyoxometalate (POM) molecules.

168 nd electrochemical properties of a series of polyoxometalate (POM) oxoclusters decorated with two bod

169 and the redox-active macrocyclic {P(8)W(48)} polyoxometalate (POM) produces a striking synergistic ef

170 The Keggin-type polyoxometalate (POM) PW(12)O(40)(3-) and the catalytic

171 ance fuel cells that are catalyzed solely by polyoxometalate (POM) solution without any solid metal o

172 Polyoxometalate (POM) species-nanoscale inorganic anions

173 cy of silicotungstic acid (H(4)SiW(12)O(40)) polyoxometalate (POM) toward the reaction between furfur

174 self-assembly of hydrophilic Keplerate-type polyoxometalate (POM) {Mo(72)Fe(30)} macroanions into si

175 anion size and charge allows the Keggin-type polyoxometalate (POM), [CuPW(11)O(39)](5-), a catalyst f

176 ecognition processes involving a Dawson-type polyoxometalate (POM), [P2W18O62](6-), a cationic electr

177 This strategy employs a single material, a polyoxometalate (POM), alpha(2)-[P(2)W(17)O(61)](10-), t

178 composed of layered double hydroxide (LDH), polyoxometalate (POM), and dioctadecyldimethylammonium.

179 Here, we present a strategy for synthesizing polyoxometalate (POM)-based coordination networks with u

180 osmotically driven crystal morphogenesis of polyoxometalate (POM)-based crystals is investigated, wh

181 driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing remote terpyr

182 Wells-Dawson [alpha(2)-P(2)W(17)O(61)](10-) polyoxometalate (POM)-supported [Re(CO)(3)](+) complex c

183 ocation process of countercations around one polyoxometalate(POM)-organic hybrid anionic cluster at v

184 Polyoxometalates (POMs) and other metal-based complexes

185 Polyoxometalates (POMs) are a large group of anionic pol

186 Polyoxometalates (POMs) are discrete clusters of redox-a

187 drogen-bonded organic frameworks (HOFs), and polyoxometalates (POMs) are emerging PEM materials, offe

188 Polyoxometalates (POMs) are molecular metal-oxide anions

189 POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-t

190 Predicting the number of electrons that polyoxometalates (POMs) can store, and whether these ele

191 Here we demonstrate that polyoxometalates (POMs) enable the facile formation, cry

192 a host-guest hybrid redox material based on polyoxometalates (POMs) encapsulated within the internal

193 In aqueous solution, low-charged polyoxometalates (POMs) exhibit remarkable self-assembly

194 We report here that some polyoxometalates (POMs) favor polymerization of PrP 27-3

195 Aqueous solutions of polyoxometalates (POMs) have been shown to have potentia

196 Polyoxometalates (POMs) have remarkable properties and a

197 The synthesis of chiral polyoxometalates (POMs) is a challenge because of the di

198 Nb-containing polyoxometalates (POMs) of the Wells-Dawson class inhibi

199 Polyoxometalates (POMs) provide rigid and highly symmetr

200 Polyoxometalates (POMs) represent an important group of

201 of mononuclear lanthanoid complexes based on polyoxometalates (POMs) that exhibit single-molecule mag

202 peroxoniobium compounds to the corresponding polyoxometalates (POMs), alpha(1)-K(7)[P(2)W(17)NbO(62)]

203 ron oxides, previous Fe(III) -oxo cages, and polyoxometalates (POMs), hints that much larger molecula

204 ped to describe the energy landscapes of six polyoxometalates (POMs), Li-U(24), Li-U(28), K-U(28), Li

205 Polyoxometalates (POMs), ranging in size from 1 to 10's

206 , enzymes, ...) and inorganic molecules like polyoxometalates (POMs), which have very interesting app

207 have been demonstrated for the first time in polyoxometalates (POMs), with an arylimido-derivative sh

208 Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymm

209 ters, Ir-based bridging ligands, and W-based polyoxometalates (POMs)-as a multifarious radioenhancer.

210 hiol-functionalised hybrid organic-inorganic polyoxometalates (POMs).

211 Polyoxometalates (POMs, metals=V(V) , Nb(V) , Ta(V) , Mo

212 catalyst hypothesis: (i) six vanadium-based polyoxometalate precatalysts, (n-Bu4N)4H5PV14O42, (n-Bu4

213 that enables the incorporation of a platinum-polyoxometalate (Pt-POM) CH(4) oxidation precatalyst int

214 The polyoxometalates represent a class of polyanionic compou

215 These redox reactions of polyoxometalates require protons, and thus such complexe

216 A ruthenium-substituted polyoxometalate (Ru-POM, {Si[Ru(H(2)O)W(11)O(39)]}(5-))

217 chromophores and deca-anionic tetraruthenate polyoxometalates (Ru(4)POM) as water oxidation catalysts

218 is performed by employing the tetraruthenate polyoxometalate [Ru(4)(mu-O)(4)(mu-OH)(2)(H(2)O)(4)(gamm

219 l fibre with the exposed tip coated with the polyoxometalate salt [(C(4)H(9))(4)N](4)H[PMo(10)V(2)O(4

220 d-loop exploration of the chemical space for polyoxometalate-scaffolding metal-organic frameworks (PO

221 spinning NMR spectroscopy of six-coordinated polyoxometalate solids.

222 of 10-20 nm by post-process immersion into a polyoxometalate solution (phosphomolybdic acid, PMA) in

223 mputationally, while the intricate nature of polyoxometalate speciation is best captured by adjusting

224 Here we investigate a nano-sized Ru4-polyoxometalate standing as an efficient artificial cata

225 rected assembly of a ring-shaped macrocyclic polyoxometalate structural building unit, {P(8)W(48)O(18

226 ew method to identify metallic nanoclusters (polyoxometalate structures) in solution at the single mo

227 ation to minimize steric clashes between the polyoxometalate subunits, in order to stabilize the corr

228 Recently we showed that V-containing polyoxometalates such as (n-Bu4N)7SiW9V3O40 or (n-Bu4N)9

229 s, is described using copper(II)-substituted polyoxometalates, such as {alpha2-Cu(L)P2W17O61}(8-) or

230 sights to those questions with a solubilized polyoxometalate-supported single-atom catalyst which all

231 nner and outer faces of the gamma-CD for the polyoxometalate surfaces.

232 Here we show a reliable and tunable polyoxometalate template-based synthetic strategy to ato

233 ates can be obtained through the Keggin-type polyoxometalate-templated growth of a layer of spherical

234 of them known to date are negatively charged polyoxometalates, there is only a handful of cationic on

235 in the reaction mechanism by protonating the polyoxometalate thereby enabling the activation of the m

236 where oxygen atoms are transferred from the polyoxometalate to the substrate.

237 id growth of tubes occurs from crystals of a polyoxometalate upon addition of an aqueous solution con

238 g aromatic ketones, xanthene dyes (Eosin Y), polyoxometalates, uranyl salts, a metal-oxo porphyrin an

239 999, a catechol dioxygenase derived from a V-polyoxometalate was reported which was able to perform a

240 Previously, a tricopper-substituted polyoxometalate was shown to reduce CO(2) to CO with a v

241 hat SMOF-1 adsorbs anionic Wells-Dawson-type polyoxometalates (WD-POMs) in a one-cage-one-guest manne

242 and water activation on multi-Ru-substituted polyoxometalates were studied using the B3LYP density fu

243 r for small-molecule activation with reduced polyoxometalates, where both electron and proton origina

244 u(+) and Bu3Sn(+) cations coordinated to the polyoxometalate, which were also identified by ESI-MS.

245 y of ([UO2(O2)OH]60)(60-) (U60), an actinide polyoxometalate with fullerene topology, can be induced

246 The technique allows the measurement of polyoxometalates with over 2 orders of magnitude lower a

247 self-assembly of an equilibrated ensemble of polyoxometalates, with the heteropolytungstate anion [AI

248 f the metal oxide-APS with a solution of the polyoxometalate WOC.

249 contrast agent, zirconium-substituted Keggin polyoxometalate (Zr-POM), the soft tissue of the placent