ライフサイエンスコーパス: polysulfide

1 the coordinated thiirane becomes the cyclic polysulfide.

2 ffinity than hydrogenase I for both S(0) and polysulfide.

3 ) and S(2-) ) to sulfite and thiosulfate via polysulfide.

4 enzymatic oxidation of hydrogen sulfide and polysulfides.

5 ) as well as solid-phase associated S(0) and polysulfides.

6 thiosulfate with transitory accumulation of polysulfides.

7 nce of graphite and sulfite, thiosulfate, or polysulfides.

8 pper CSEM inhibitor intercepts the migrating polysulfides.

9 d in a carbon host, which serve to sequester polysulfides.

10 tion kinetics and better trapping of soluble polysulfides.

11 tributing Li(2)S and in sequestering lithium polysulfides.

12 gy barrier for the overall conversion of the polysulfides.

13 ing the dissolution and shuttling of lithium polysulfides.

14 g adsorption and fast dissociation of sodium polysulfides.

15 ees C and subsequent defrosting affected all polysulfides.

16 ne sulfur species, including persulfides and polysulfides.

17 stals from the dense liquid phase of lithium polysulfides.

18 ne sulfur species, including persulfides and polysulfides.

19 ellent physical properties displayed by many polysulfides.

20 ellent physical properties displayed by many polysulfides.

21 the long-standing shuttle effect of lithium polysulfides(5-7), understanding of the interfacial reac

22 Differences in polysulfide accumulation were observed between the two m

23 FisR is highly sensitive to polysulfide, activating sigma(54) -dependent transcripti

24 duplication of a denture anchor in stone via polysulfide, addition silicone, and polyether impression

25 tified as the most active site for enhancing polysulfide adsorption and charge transfer.

26 The resulting platinum polysulfide aerogels possess a highly porous and amorpho

27 In this regard, polysulfide-air redox flow batteries demonstrated great

28 ble and cost-effective alkaline-based hybrid polysulfide-air redox flow battery where a dual-membrane

29 y, has be achieved for this type of alkaline polysulfide-air redox flow battery, with significant sco

30 ectly between Li(2)S and electrolyte without polysulfide and (b) lithium-ion diffusion in Li(2)S.

31 cells produced significantly more H(2)S and polysulfide and exhibited a profound suppression of mito

32 o population, and sustained the formation of polysulfide and Fe3S4, herby also dissolved sulfur.

33 d due to a synergetic effect of both lithium polysulfide and lithium nitrate as additives in ether-ba

34 demonstrates that the combination of organic polysulfide and selenium can not only improve the utiliz

35 decreased the levels of the reduced forms of polysulfide and the antioxidative effect of serum albumi

36 effect of the mediating effect of dissolved polysulfide and the fast diffusion of Mg ion in the amor

37 lectrodes over planar film electrodes toward polysulfide and triiodide reduction, which suggests a st

38 icient sulfur hosts that can capture soluble polysulfides and enable fast reduction kinetics.

39 tion is limited by the solubility of lithium-polysulfides and further conversion from lithium-polysul

40 strong dipole-dipole interaction between Li polysulfides and Li-S cathode materials originates from

41 This pathway uses soluble dimethyl polysulfides and lithium organosulfides as intermediates

42 electrolyte, which can dissolve all lithium polysulfides and lithium sulfide (Li(2) S(8) -Li(2) S).

43 h a unique structure that can capture sodium polysulfides and speed up the reduction reaction of long

44 eferential adsorption of higher order liquid polysulfides and subsequent conversion to lower order so

45 new simple synthetic method for binary metal polysulfides and sulfides was developed by utilizing an

46 with HNO leads to the formation of hydrogen polysulfides and sulfur (S(8)), suggesting a potential r

47 ion-pi interactions between Li(+) of lithium polysulfides and the negatively charged cyclopentadienyl

48 study, quinonoid imine is proposed to anchor polysulfides and to facilitate the formation of Li2 S2 /

49 internal spaces that can accommodate sodium polysulfides and withstand volumetric expansion.

50 accompanied by the dissolution of long-chain polysulfide, and solid-state transition from short-chain

51 10(-4) mA cm(-2) , a rapid redox reaction of polysulfide, and therefore improved sulfur utilization a

52 ring lithiation, dissolution of intermediate polysulfides, and low ionic/electronic conductivity.

53 o common reactive sulfur species like H(2)S, polysulfides, and persulfides, both carbonyl sulfide (CO

54 Polysulfide anions are endowed with unique redox propert

55 Herein, we disclose the use of polysulfide anions as visible light photoredox catalysts

56 e strong affinity of Lewis-acidic Mn(2+) for polysulfide anions generated during the charge-discharge

57 ron reductant, resulting in the formation of polysulfide anions, such as HS2(-), which were confirmed

58 he highest H(2)S capacities for a MOF, where polysulfides are formed inside the pores of the material

59 Polysulfides are often referred to as key reactants in t

60 When polysulfides are present amid the transition between sul

61 and direct mechanistic understanding of how polysulfides are regulated across Li-S batteries startin

62 Hence, although polysulfides are unlikely to be stable in the reducing i

63 ty of polysulfides for IDO1 implicates these polysulfides as important signaling factors in immune re

64 ding of the interfacial reactions of lithium polysulfides at the nanoscale remains elusive.

65 orous and amorphous structure with an intact polysulfide backbone.

66 Lithium polysulfide batteries possess several favorable attribut

67 ation for future grid energy storage.Lithium polysulfide batteries suffer from the precipitation of i

68 st time the occurrence of surface-associated polysulfides being the main oxidation products in the pr

69 We show here that polysulfides bind to inactive ferric IDO1 and reduce it

70 need for material structures with effective polysulfide binding capability and well-defined surface

71 lculations, it was determined that effective polysulfide binding originates from favorable cation-pi

72 te coated with polyaniline (PANI) polymer as polysulfide block to achieve high sulfur utilization, hi

73 Cysteine polysulfide bridging stabilized different dimeric assemb

74 rrier is found to be the phase nucleation of polysulfides, but the amplitude of barrier is mainly due

75 for alleviating dissolution and diffusion of polysulfides, but they experience nonrecoverable structu

76 the reduction of elemental sulfur (S(0)) and polysulfide by hydrogenase I and hydrogenase II, and bot

77 which were confirmed and trapped as organic polysulfides by benzyl chloride.

78 a high yield and purity, relatively free of polysulfide byproducts.

79 particles) into the cathode, the heteropolar polysulfides can be anchored within the cathode due to t

80 Because polysulfanes and polysulfides can catalyze the generation of reactive oxy

81 nts and theoretical calculations reveal that polysulfide capture by the oxides is via monolayered che

82 /flavoprotein oxidoreductase system restores polysulfide-carrying hemoglobin derivatives to ferrous h

83 e a dendrite-free Mg anode with a reversible polysulfide cathode and present a truly reversible Mg/S

84 ke carbon nanotube cathode and a liquid-type polysulfide catholyte.

85 use of lithium sulfide cathodes and lithium polysulfide catholytes, as well as recent burgeoning eff

86 Addition of sulfide or polysulfide caused substantial As retention at acidic co

87 l as a polysulfide reservoir in Li/dissolved polysulfide cells.

88 eveal that Mn(2+) incorporation shortens the polysulfide chain in the gel matrix compared to the Mo(3

89 hus pointing out the gradual decrease of the polysulfide chain lengths.

90 Long polysulfide chains are produced during the first reducti

91 yte, facilitated by the formation of shorter polysulfide chains within the Mn(0.25)Mo(3)S(13) structu

92 ghly conductive coating layer for stabilized polysulfide chemistry, is accomplished by the combinatio

93 ronic interactions between copper and sodium polysulfides, clarifying the facet-dependent mechanisms.

94 metal-chalcogenide aerogels from Pt(2+) and polysulfide clusters ([S(x)](2-), x = 3-6).

95 in significantly increased accumulations of polysulfides compared to controls in both media.

96 n of the poorly soluble and insulating short polysulfide compounds was evidenced, thus leading to the

97 educes a range of disulfide, persulfide, and polysulfide compounds.

98 In this work we uncovered a polysulfide concentration regulating mechanism that oper

99 Initial polysulfide concentrations also appeared to influence de

100 llic molecular compound, ferrocene, as a new polysulfide-confining agent.

101 propose that mitochondria export glutathione polysulfide, containing glutathione and persulfide, for

102 tion by zinc acetate, the surface-associated polysulfides could be precipitated as zerovalent sulfur

103 hort and decomposition leads to a mixture of polysulfides (Cys-S-(S)n-S-Cys).

104 ate is exemplified by an extensive series of polysulfide dianions [Sn]2- (n = 2-9) and related radica

105 evaluate the techniques used to characterize polysulfide dianions and radical anions both in solution

106 Correction for 'The role of polysulfide dianions and radical anions in the chemical,

107 urable network of mobile anions and restrict polysulfide diffusion from mesoporous carbon hosts by an

108 overcome the challenges associated with the polysulfide diffusion in lithium-sulfur batteries.

109 G coating) on a Celgard separator suppresses polysulfide diffusion through its physical and chemical

110 s that the hybrid electrolyte limits lithium polysulfide dissolution and is, thus, ideally suited for

111 However, the polysulfide dissolution and low electronic conductivity

112 urther provide insights into the dynamics of polysulfide dissolution and re-utilization in relation t

113 materials are shown to completely eliminate polysulfide dissolution and shuttling between lithium an

114 an inherent mechanism for preventing lithium polysulfide dissolution and shuttling during electrochem

115 e is normally observed, attributed mainly to polysulfide dissolution and volume expansion.

116 Regulating intermediary polysulfide dissolution by understanding the metamorphos

117 ss of sulfur cathode material as a result of polysulfide dissolution causes significant capacity fadi

118 ctive electrolyte strategy that mediates the polysulfide dissolution dynamics and sodium stability by

119 otection prevents mechanical degradation and polysulfide dissolution in lithium-sulfur battery chemis

120 ivity of Li(2) S composites and inhibits the polysulfide dissolution via the TM S bond, effectively a

121 ed ionic liquid (IL) significantly mitigates polysulfide dissolution, and therefore the parasitic red

122 g with fast reaction kinetics and negligible polysulfide dissolution.

123 g all reported Mg/S batteries by suppressing polysulfide dissolution.

124 Here, diisoropyl xanthogen polysulfide (DIXPS) has been selected as a model organos

125 ulfur and promotes the formation of reactive polysulfides during electrochemical cycling.

126 lysed air electrodes with sulfidised Ni foam polysulfide electrodes, the redox flow battery achieves

127 phene Oxide composite electrode, and sulfide/polysulfide electrolyte deliver power conversion efficie

128 mprovements studied, use of a methanol-based polysulfide electrolyte results in a particularly dramat

129 ormance of QDSCs, the 30% deionized water of polysulfide electrolyte was replaced with methanol to im

130 raction between graphene oxide and sulfur or polysulfides enabled us to demonstrate lithium/sulfur ce

131 nt, molecular tailoring approach for lithium polysulfides, enabling a synergistic enhancement of anod

132 polysulfides to form a solid and recoverable polysulfide-encapsulating layer.

133 e in Zr-MOFs improves sulfur utilization and polysulfide encapsulation to deliver a sustainably high

134 A brand new polysulfide entrapping strategy based on the ferroelectr

135 stigated the apoptosis-modulating effects of polysulfides, especially on the caspase cascade, which m

136 senates A(3)Ta(2)AsS(11) are stabilized in a polysulfide flux.

137 The muM affinity of polysulfides for IDO1 implicates these polysulfides as i

138 ite their potential relevance, the extent of polysulfide formation and its relevance for product form

139 Varying the Fe/S ratio revealed that surface polysulfide formation only becomes dominant when the rem

140 iate at the junction between thiosulfate and polysulfide formation, coordinates ferric hemoglobin and

141 identified in thicker films, resulting from polysulfide generation, but are shown not to improve the

142 Hydrogen sulfide (H2 S) and hydrogen polysulfides (H2 Sn , n>1) are endogenous regulators of

143 Among these molecules, hydrogen polysulfides (H2S(n), n > 1) are recently suggested to b

144 Hydrogen polysulfides (H2Sn) have a higher number of sulfane sulf

145 Endogenous hydrogen polysulfides (H2Sn; n>1) have been recognized as importa

146 Interaction between electrocatalyst and polysulfides has been evaluated by conducting X-ray phot

147 , such as hydrogen sulfide, persulfides, and polysulfides, have recently emerged as key signaling mol

148 together show phosphorene as a highly potent polysulfide immobilizer for lithium-sulfur batteries, en

149 However, the dissolution of high-order polysulfide in electrolytes and low Coulombic efficiency

150 ms originate from the dissolution of lithium polysulfide in liquid electrolytes, causing charge and a

151 The chemical shift of Li polysulfides in (7) Li NMR spectroscopy, being both theo

152 is widely accepted to retard the shuttle of polysulfides in a working battery.

153 he migration, adsorption, and confinement of polysulfides in Li-S cells at work.

154 le for reversible storage/delivery of mobile polysulfides in lithium-sulfur (Li-S) batteries to contr

155 rom the dissolution and diffusion of lithium polysulfides in the electrolyte.

156 their efficient transformation to long-chain polysulfides in the subsequent redox process.

157 systematic strategy for the introduction of polysulfides in the synthesis of epipolythiodiketopipera

158 S to a mixture of thiosulfate and iron-bound polysulfides in which the latter species predominates.

159 Trx/TrxR restored the activity of polysulfide-inactivated caspase-3 in vitro, and TrxR inh

160 sed to show that ring closure to form cyclic polysulfide incorporated inversion of stereochemistry ve

161 amage revealed that dithiothreitol-liberated polysulfide increased from stages 1-3 and decreased in s

162 S (1-3 wt%) to serve as an in situ and local polysulfide injector for the activation of commercial Li

163 reported catalysts were focused on catalyst-polysulfide interactions, and generally exhibit high act

164 Polysulfide intermediates (PSs), the liquid-phase specie

165 to reversibly form different soluble lithium polysulfide intermediates and insoluble lithium sulfides

166 ntent/loading, arising from the shuttling of polysulfide intermediates between the cathode and anode

167 ctively immobilize and catalytically convert polysulfide intermediates during cycling, thus eliminati

168 Confining lithium polysulfide intermediates is one of the most effective w

169 l capacity while inhibiting the formation of polysulfide intermediates that lead to parasitic shuttle

170 The dissolution of polysulfide intermediates, however, results in severe sh

171 ctive material and inhibits diffusion of the polysulfide intermediates.

172 at human RBCs convert garlic-derived organic polysulfides into hydrogen sulfide (H(2)S), an endogenou

173 on the electrolyte due to the dissolution of polysulfides into the electrolyte, along with the format

174 This transformation propels all-phase polysulfide-involving reactions.

175 The polysulfide/iodide flow battery with the graphene felt-C

176 ochemical kinetics of the redox reactions of polysulfide/iodide ions on graphite electrodes, which ha

177 Aqueous polysulfide/iodide redox flow batteries are attractive f

178 However, the crossover of polysulfide is one significant challenge.

179 H(2)S production from organic polysulfides is facilitated by allyl substituents and by

180 MNCS/CNT), which can strongly adsorb lithium polysulfides, is now reported to act as a sulfur host.

181 rsulfide derivatives of coenzyme A, although polysulfide itself is also efficiently reduced.

182 scribe the unique capability of an ultrathin polysulfide layer in controlling the collision behavior

183 of low TrxR activity, early cell exposure to polysulfides leads to enhanced persulfidation of initiat

184 e electrode to chemically reduce in situ the polysulfide Li2S6 in liquid electrolyte to insoluble Li2

185 fferent dimeric assemblies, depending on the polysulfide linker length.

186 the shuttle effect caused by soluble lithium polysulfide (LiPS) intermediates and the sluggish conver

187 is plagued by the high solubility of lithium polysulfide (LiPS) intermediates, causing fast capacity

188 many practical challenges, including lithium polysulfide (LiPS) shuttling.

189 valuation of the reactions regarding lithium polysulfide, lithium nitrate and lithium metal, and prov

190 s have a high specific capacity, but lithium polysulfide (LPS) diffusion and lithium dendrite growth

191 A polysulfide material was synthesized by the direct react

192 Hydrogen polysulfides may also have their own biosynthetic pathwa

193 -3 in vitro, and TrxR inhibition potentiated polysulfide-mediated suppression of caspase-3 activity i

194 for aerobic carbon monoxide (CO) oxidation, polysulfide metabolism and hydrogen utilization were ide

195 The dynamics of intractable polysulfide migration at different length scales often t

196 promising solution by acting as barriers to polysulfide migration, mitigating capacity loss.

197 ppressing the clustering behavior of lithium polysulfide molecules, resulting in a significant enhanc

198 However, their viability is hampered by Na polysulfide (NaPS) shuttling, Na loss due to side reacti

199 lenges, such as the shuttle effect of sodium polysulfides (NaPS) and dendrite growth.

200 er, the notorious shuttle behavior of sodium polysulfides (NaPS) and uncontrollable dendrite growth l

201 which the formation and chain-shortening of polysulfide occur at early stage accompanied by the diss

202 hemically stable with long-chained potassium polysulfide of K(2) S(x) .

203 ite enable the effective trapping of lithium polysulfides on electroactive sites within the cathode,

204 polysulfides on the cathode and reduction of polysulfides on the anode.

205 electrodes, which prevent the dissolution of polysulfides on the cathode and reduction of polysulfide

206 2Fe-2S] cluster may generate a protein-bound polysulfide or persulfide that serves as the immediate S

207 zerovalent, such as thiols, organic di- and polysulfides, or heterocycles.

208 tly visualized the transformation of lithium polysulfides over electrode surfaces at the atomic scale

209 class of PTP inhibitors based upon a cyclic polysulfide pharmacophore that forms a reversible covale

210 two-phase reaction pathway, where the liquid polysulfide phase in the sulfide electrode is thermodyna

211 soluble complexes between SnI(4) and lithium polysulfides play a non-negligible role in suppressing t

212 ctrode from detrimental reactions via silica-polysulfide polar-polar interactions and increase the ce

213 cluding glutathione persulfide and inorganic polysulfide, produced from either H(2) S oxidation or fr

214 teraction between active centres and lithium polysulfides promoted the formation of a dense phase con

215 ediment surface; and high pore water sulfide-polysulfide promotes Mo fixation in pyrite while promoti

216 electrochemical reactivation of the soluble polysulfides, protect the lithium metal electrode from d

217 al effects of their intermediate byproducts, polysulfides (PS), have to be resolved to realize these

218 ain challenged by several factors, including polysulfides' (PSs) dissolution, sluggish sulfur redox k

219 Organic polysulfides (R-S(n)-R'; n > 2) also undergo nucleophili

220 Here, we present a locally confined polysulfide-reactive electrolyte strategy that mediates

221 When polysulfide reacts with the R domain of FisR through the

222 The presence of sulfide/polysulfide redox couple is crucial in achieving stabili

223 ysts evolved H(2) while oxidizing reversible polysulfide redox mediators at a maximum rate of 90.6 um

224 phase conversion and its associated sluggish polysulfides redox kinetics pose a great challenge in tu

225 for growth in high sulfide concentrations; a polysulfide reductase-like complex operon, psrABC (CT049

226 )H-dependent coenzyme A disulfide reductases/polysulfide reductases (CoADR/Psr) have been proposed to

227 more favorable for catalyzing the long-chain polysulfides reduction, while PtNi nanocrystals manipula

228 thermore, during cycling the bulk of soluble polysulfides remains trapped within the cathode matrix.

229 ing of natural micropores function well as a polysulfide reservoir in Li/dissolved polysulfide cells.

230 only provide excellent electron pathways and polysulfide reservoirs, but they can also be used as a s

231 inding of mercury(II) to the sulfur-limonene polysulfide resulted in a color change.

232 Thus, SQR oxidises sulfide to polysulfides; rhodanese enhances the reaction of polysul

233 rSH) thiols to form persulfides (RSS(-)) and polysulfides (RS(S)(n)S(-)) for antioxidant defence and

234 lved sulfide on the production of sulfur and polysulfide (S-PS) and associated iron corrosion was inv

235 sulfur species (i.e., bisulfide (HS(-)) and polysulfides (S(n)(2-))) and dissolved organic matter (D

236 the absorber column and sulfidic bioreactor, polysulfides (S(x)(2-)) are formed due to the chemical e

237 able Li stripping/plating and essentially no polysulfide shuttle as well as fast redox kinetics.

238 rovide valuable mechanistic insight into the polysulfide shuttle effect in lithium-sulfur batteries,

239 erties of the electrolyte cosolvents and the polysulfide shuttle effect in lithium-sulfur batteries.

240 Herein, we present evidence that the polysulfide shuttle in a Li-S battery can be stabilized

241 r every cycle, suggesting the suppression of polysulfide shuttle through the molecular design.

242 Stabilizing the polysulfide shuttle while ensuring high sulfur loading h

243 ry technology, and controlling the inherent "polysulfide shuttle" process has become a key research t

244 fide K(2) S(n) phase sequence, the parasitic polysulfide shuttle, pulverization-driven capacity fade,

245 lfur (Li-S) batteries to control undesirable polysulfide shuttle.

246 ial inorganic-based electrolyte to block the polysulfide shuttle.

247 problems arising from insulating sulfur and polysulfide shuttles as well as remarkably increasing th

248 However, critical challenges such as lithium polysulfide shuttling effects, mismatched interfaces, Li

249 actions but significantly contributes to the polysulfide shuttling process.

250 However, the issue of polysulfide shuttling with its corresponding capacity fa

251 lfide, causing sluggish redox kinetics, (ii) polysulfide shuttling, and (iii) parasitic side reaction

252 eir practical viability is impeded by sodium polysulfide shuttling.

253 tructural failure and efficiently suppresses polysulfide shuttling.

254 cle life and low energy content owing to the polysulfides shuttling during cycling.

255 aneously address the Na dendritic growth and polysulfides shuttling.

256 tely addresses the trade-off between minimal polysulfide solvation and stabilizing sodium interfaces.

257 e for growth of new materials: the potassium polysulfides spanning K(2)S(3) and K(2)S(5), which melt

258 t discharge plateau, S is reduced to soluble polysulfide species concurrently with the formation of a

259 olvation structure and low solubility toward polysulfide species in a relatively low electrolyte conc

260 Concentrations of aqueous polysulfide species were negligible (<1%).

261 nstrate preferential adsorption of a soluble polysulfide species, formed during discharge process, to

262 Finally, short polysulfide species, such as S(3)(2-), S(2)(2-), and S(2

263 problems are mainly caused by the dissoluble polysulfide species, which are a series of complex reduc

264 analyses revealed that organic or synthetic polysulfides strongly and rapidly inhibit the enzymatic

265 Taken together, our results reveal that polysulfides target the caspase-9/3 cascade and thereby

266 f cobalt sulfide as hosts for soluble sodium polysulfides that reduce the shuttle effect and display

267 roposed mitochondrial pathway because it has polysulfides, that is, disulfide and trisulfide, as inte

268 trolyte modulation simultaneously suppresses polysulfide the shuttle effect and lithium dendrite form

269 With adsorbed additives, like LiNO3 and polysulfide, the lithium deposits are strongly textured,

270 e from a high-order polysulfide to low-order polysulfides through solid-liquid two-phase reaction pat

271 r experiences phase change from a high-order polysulfide to low-order polysulfides through solid-liqu

272 and solid-state transition from short-chain polysulfide to magnesium sulfide occurs at late stage.

273 e II, and both enzymes preferentially reduce polysulfide to sulfide rather than protons to H(2) using

274 This design with CSEM allows the dissolved polysulfides to be localized and the electrochemical rea

275 oped carbon dots become highly reactive with polysulfides to form a solid and recoverable polysulfide

276 o sulfite; sulfite spontaneously reacts with polysulfides to generate thiosulfate.

277 sulfides and further conversion from lithium-polysulfides to Li(2)S is limited by the electronically

278 vels, also metabolize garlic-derived organic polysulfides to liberate H(2)S.

279 reversible transformation of soluble lithium polysulfides to solid short-chain sulfur species (Li(2)S

280 the reduction reaction of long chain sodium polysulfides to solid small chain polysulfides, which re

281 -catalytic sites that control the multi-step polysulfide transformation in tandem and direct quasi-so

282 electrolyte as a separator, which blocks the polysulfide transport towards the Li-metal, also has hig

283 A composite separator with a thin-film polysulfide trap is developed for lithium-sulfur batteri

284 diffusion through its physical and chemical polysulfide-trapping capabilities.

285 timulated HeLa cells, short-term exposure to polysulfides triggered the persulfidation and deactivati

286 us cystine and evidence for the formation of polysulfides under these conditions.

287 Allyl-substituted polysulfides undergo nucleophilic substitution at the al

288 rochemically recoverable protective layer of polysulfides using an electrolyte additive.

289 esults testify the Fe(3)N affinity to sodium polysulfides via Na-N and Fe-S bonds, leading to strong

290 al approach to immobilize sulfur and lithium polysulfides via the reactive functional groups on graph

291 Dissolution of lithium polysulfides, volume expansion of sulfur and uncontrolla

292 scopic analysis shows 48.4% of sulfur in the polysulfide was converted to Li2S.

293 tribution between thiosulfate and iron-bound polysulfides was approximately equal.

294 lation of cysteinylated and glutathionylated polysulfides was followed during fermentation for the fi

295 thy and chronic renal failure, both forms of polysulfides were decreased compared with those of healt

296 The iron-bound polysulfides were unstable at physiological glutathione

297 ing the reaction between lithium and lithium polysulfide, which has long been considered as a critica

298 ain sodium polysulfides to solid small chain polysulfides, which results in excellent electrochemical

299 showed that DUF442 speeds up the reaction of polysulfides with glutathione to produce glutathione per

300 sulfides; rhodanese enhances the reaction of polysulfides with glutathione to produce GSSH; PDO oxidi