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1 zenoid compounds (2500 cm(-1) for the M = CN radical anion).
2 iconductors assembled with the TCNQ(.delta-) radical anion.
3 been reduced to a paramagnetic endofulleride radical anion.
4 cation and scanning the tip to generate the radical anion.
5 (IV)-amide with sacrificial trimesitylborane radical anion.
6 eroxide, to produce SOD-Cu(II) and carbonate radical anion.
7 ectron transfer to generate a free iodoarene radical anion.
8 issociation of chloride from the chloroarene radical anion.
9 structure for the 1,7-di-trans-[12]annulene radical anion.
10 ations via ion/ion reaction with the sulfate radical anion.
11 he nonadiabatic ET step for reduction to the radical anion.
12 mation involves rearrangement of the initial radical anion.
13 ration of the neutral at the geometry of the radical anion.
14 al state to be a Au(I) complex with a ligand radical anion.
15 ot appear to further stabilize the generated radical anion.
16 to stabilize the electrochemically generated radical anion.
17 ground-state CH3O anion or an adsorbed CH2O radical anion.
18 uction of GO by electrogenerated naphthalene radical anions.
19 re strongly bound than in isolated fullerene radical anions.
20 cal moieties in SOMO-HOMO converted distonic radical anions.
21 tron transfer, with generation of detectable radical anions.
22 F core as revealed in the EPR spectra of the radical anions.
23 romagnetically coupled to bis(imino)pyridine radical anions.
24 se substrates is the short lifetime of their radical anions.
25 reas the latter are easily reduced to afford radical anions.
26 y this species as the precursor of carbonate radical anions.
27 nds antiferromagnetically coupled to chelate radical anions.
28 ably arising from the production of distonic radical anions.
29 and then allowed to react with fluoranthene radical anions.
30 om SOMOs of the three- to five-membered ring radical anions.
31 er reactions between these siloles and their radical anions.
32 studied, water-soluble fullerenols as stable radical anions.
33 epend markedly on the presence of superoxide radical anions.
34 s of aromatic stabilization in forming their radical anions.
35 suffer from instability of the corresponding radical anions.
36 hange spiral tubes of S = (1/2) (C14H10)(*-) radical anions.
37 elocalization of the unpaired spins over the radical anions.
38 ty relationships when comparing nitrobenzene radical anions.
39 The optical spectra of nine dinitroaromatic radical anions (1,2- and 1,4-dinitrobenzene, 1,5- and 2,
41 ndicating the formation of the corresponding radical anion 2(*-), which was further characterized by
42 reduction of the neutral forms led first to radical anions (2(*-) and 3(*-)) and then to a bis(radic
45 n the formation of the N-nitrosodiethylamine radical anion (5) and nitric oxide (NO) via a triplet ex
47 ayed photoemission in a small cold molecular radical anion, a consequence of the complex electronic s
48 e, having an inverted charge distribution (T radical anion, A radical cation), is not able to repair
49 ron oxidation of guanine in DNA by carbonate radical anions, a decomposition product of peroxynitroso
50 zation reveals that the corresponding borane radical anions activate (cleave) dihydrogen, whilst EPR
51 he substituent on the bridging 5,5'-R(2)bpym radical anion allows the magnetic exchange coupling cons
54 l electron transfer between an anthraquinone radical anion and a triarylamine radical cation in three
55 fluoride from the hexafluorocyclohexadienone radical anion and deprotonated hydroxypentafluorocyclohe
56 ersion of the formazanate complexes to their radical anion and dianion forms occurred at less negativ
58 dy of the electrochemically generated F4TCNQ radical anion and dianion species and their protonation
59 -based simultaneous monitoring of superoxide radical anion and hydrogen peroxide provides the basis f
60 elet CD36 signaling by increasing superoxide radical anion and hydrogen peroxide through a mechanism
61 monitoring cellular production of superoxide radical anion and hydrogen peroxide using hydropropidine
62 erved in the reaction between benzoylnitrene radical anion and NO2, forming benzoate ion and nitrous
65 tion leading from the neutral species to the radical anion and subsequently to the dianion was achiev
66 n well before reaching the generation of the radical anion and was more intense on Au than on Pt.
68 f adjacent, electrochemically generated, NDI radical anions and dianions bind strongly to K(+), Li(+)
69 of PPNs--the ability of their reduced forms (radical anions and dianions) to interact with small radi
70 alino[2,3-b]phenazine) were reduced to their radical anions and dianions, employing either potassium
71 ce unactivated benzenes to the corresponding radical anions and display original selectivities in pre
72 hermal ET with most NDIs, generating NDI(*-) radical anions and NDI(2-) dianions in aprotic solvents,
73 e crystal X-ray structures of three of their radical anions and of three of their dianions were obtai
74 ic studies confirmed the involvement of aryl radical anions and proceeded via a single-electron-trans
75 phenyl to naphthalene was determined for the radical anions and radical cations of molecules with the
76 o measure the proton affinities of all three radical anions and the electron affinities of o- and m-b
77 derive the heats of formation of each of the radical anions and their corresponding carbenes (i.e., a
78 uted energetic and ESR data for [12]annulene radical anions and their valence isomers suggest that 4a
80 of oxidative stress and source of superoxide radical anion (and indirectly, a causative of lipid pero
81 pounds (but by 450 cm(-1) for the M = C(CN)2 radical anion), and by 1000-1400 cm(-1) for the benzenoi
83 hotogeneration of singlet oxygen, superoxide radical anion, and photo-oxidation of added lipids and p
84 on the heptalene radical anion, [16]annulene radical anion, and tri-trans-[12]annulene radical anion
87 ssociation rates for a series of aryl halide radical anions (ArX-: X = Cl, Br) in NMP were measured a
88 operating in this case with the formation of radical anion as a critical step, followed by heterolyti
89 the reaction mechanism suggests a disulfide radical anion as the active species capable of cleaving
91 (3)MLCT(SQ) state (Ru(III) phen-semiquinone radical anion) as the predominant nonradiative decay pat
93 , the presence of adjacent covalently linked radical anions at a fixed location relative to each of t
94 sed to characterize polysulfide dianions and radical anions both in solution and in the solid state,
96 ecomposition of the resulting disulfide bond radical anion breaks the C-S bond at the side chain of C
98 ion and noncovalent stabilization of organic radical anions by C-H hydrogen bonding in pi-stacked pai
99 This highly reactive and very short-lived radical anion can be produced both via photochemical and
100 ion of the polymer and the other involving a radical anion-catalyzed chemical reaction of the polymer
101 diphenylanthracene are 330% and 470% for the radical anion-cation and radical anion-dication annihila
104 or transitions from the ground state of each radical anion, (CO)n(*-) to the lowest singlet and tripl
106 by oxidation of (bi)carbonate to a carbonate radical anion (CO3*) by a bound hydroxyl radical-like sp
109 tion of the electron-poor aromatic ring to a radical anion, coupling of the radical and the radical a
111 GPDI quadruplex suggests the formation of a radical anion delocalized over the neighboring PDI units
113 oxidation products were generated by SO4(*-) radical anions derived from the photolysis of S2O8(2-) a
114 nerating porphyrin radical cations and C(60) radical anions, detected by transient absorption spectro
119 has a significant electron affinity, and its radical anion expels chloride in a facile manner to give
120 of characteristic PTZ radical cation and ANQ radical anion features upon excitation in the transient
121 nitially reduced by one electron to form the radical anion (Fl(rad)(*-)) at E(0)(f) = -1.22 V versus
123 suggest a nucleophilic attack of superoxide radical anion followed by TNT denitration through an as
124 the oxaziridines to generate a copper-bound radical anion, followed by hydrogen atom abstraction and
129 The cyclizations proceed by the trapping of radical anions formed by electron transfer reduction of
133 addition of an electron to the quinone, the radical anion forms strong H-bonded complexes with the v
135 ng constants (Kb) for binding of a series of radical anions from para- and ortho-substituted nitroben
137 e optical spectrum of 2,7-dinitronaphthalene radical anion generated by Na(Hg) reduction in acetonitr
139 otoelectron (NIPE) spectrum of the (CO)5(*-) radical anion gives an electron affinity of EA = 3.830 e
141 delta-) (7,7',8,8'-tetracyanoquinodimethane) radical anion has afforded molecular materials that beha
142 iation of hydrogen squarate and the squarate radical anion has been studied by electrospray ionizatio
145 adiene undergo Cope cyclization, whereas the radical anions having substituents such as the fluoro, n
147 identified the coherently formed tetraiodide radical anion (I4(*)(-)) as a reaction intermediate.
148 Cope cyclization of 2,5-phenyl-1,5-hexadiene radical anions in a flowing afterglow triple quadrupole
151 on for 'The role of polysulfide dianions and radical anions in the chemical, physical and biological
152 ed by generating the (CO)5(*-) and (CO)6(*-) radical anions in the gas phase, using electrospray vapo
153 ibited by charge-delocalized dinitroaromatic radical anions in the solvents THF, HMPA, and DMPU (dime
154 ne radical anion, and tri-trans-[12]annulene radical anion indicate that electron spin resonance (ESR
155 in enhancing the inherent reactivity of the radical anion intermediate formed after electron transfe
156 ng electron density patterns in the putative radical anion intermediate involved in these reactions.
157 transfer from Sm(II) by stabilization of the radical anion intermediate rather than by solely promoti
158 2) as an acceptor of an electron to create a radical anion intermediate which is rapidly protonated,
159 ion proceeds via the formation of a silylone radical anion intermediate, which is further confirmed b
163 electron reduction of the coumarin to form a radical-anion intermediate, which is protonated by the m
171 rganization energy for ring opening of these radical anions is believed to be small because the negat
172 zation in the cross-conjugated, mixed-valent radical anions is proportional to the ferromagnetic cont
173 ch ultimately leads to the formation of host radical anions is responsible for the doping effect.
174 lkyl and vinyl phenyl thioethers by aromatic radical anions is shown to be the most general method ye
179 on transfer/transport in the ground state of radical-anion mixed-valence derivatives occurring betwee
180 cal, peroxyl radicals, the trioxidocarbonate radical anion, nitrogen dioxide, and the glutathionyl ra
182 a nitrogen dioxide, (*)NO(2)) and superoxide radical anion (O(2)(*)(-)) promote Ras guanine nucleotid
183 specific reactive oxygen species (superoxide radical anion (O(2)(-)), hydroxyl radical (HO()) and hyd
185 shows distinctive EPR spectra for superoxide radical anion (O2(*-)) compared to other biologically re
186 t incorporates high reactivity to superoxide radical anion (O2(*-)), more persistent superoxide adduc
192 31+G* level, a nearly planar, bond-equalized radical anion of 1,7-di-trans-[12]annulene (4a(*-)) is l
195 ure the nu(C identical withN) IR band of the radical anion of a CN-substituted fluorene in tetrahydro
196 paramagnetic resonance (EPR) spectra of the radical anion of a tetrakis(silylalkynyl) DCF, generated
197 tive ion photoelectron (NIPE) spectra of the radical anion of cyclopropane-1,2,3-trione, (CO)3(*-), h
199 ten used for both ETD and PTR reactions; the radical anion of fluoranthene (m/z 202) for ETD and the
200 tive ion photoelectron (NIPE) spectra of the radical anion of meta-benzoquinone (MBQ, m-OC6H4O) have
206 reaction between protonated peptide ions and radical anions of 1,3-dinitrobenzene formed exclusively
208 cies in acetonitrile at 233 K, including the radical anions of m- and p-iodonitrobenzene, o-bromonitr
213 ped by Mathivanan, Johnston, and Wayner, the radical anions of several cyclopropyl- and oxiranyl-cont
215 calculations, on the single-electron reduced radical anions of the isosceles triangles confirm the se
216 use a chemical reductant to generate stable radical anions of two highly hindered boranes: tris(3,5-
217 eniently, alkyl halides with either aromatic radical-anions of lithium or lithium metal in the presen
218 nt oxidation pathway via sulfite and sulfate radical anions on droplets possibly via the direct inter
221 pable of assisting in the protonation of the radical anion or the expulsion of the leaving group.
222 lkyl chlorides, by either preformed aromatic radical anions or by lithium metal and an aromatic elect
223 olysis of alkynylcyclobutenones, can display radical, anion, or electrophilic character because of th
225 tion not only by bending the C-F bond of the radical anion out of planarity but also by increasing th
226 ch leads to the formation of the semiquinone radical anions (P)-(+)-1(*-) and (M)-(-)-1(*-), respecti
228 es (intersystem crossing: ISC) and/or to the radical-anion (photoelectron transfer from the diene to
229 rgy (~1 eV) electrons (ECD), or with reagent radical anions possessing an electron available for tran
232 , only its decay product, the triply charged radical anion [Py(SO(3))(4)](*3-), as well as the triply
234 n the Re(I)(CO)3(py)(bpy-Ph)-perylenediimide radical anion (Re(I)-bpy-PDI(-*)) dyad, a prototype mode
235 the second system examined, the benzophenone radical anion reacted with the radical cation of either
238 e (stable neutral species (blue) or unstable radical anion (red)), and (iii) two-electron fully reduc
239 well as the spin density plots of the c-PFA radical anions reveal that the "extra" electron is large
240 a set is used to rationalize the kinetics of radical anion ring opening in a general context by using
243 ate-based, resulting in a bis(imino)pyridine radical anion (S(PDI) = 1/2) antiferromagnetically coupl
246 ase of the BNB-phenalenyl 7 (BMes, NMe), the radical-anion salt K[7(*)] was generated through chemica
248 tion of the compound to an isolable triazole radical anion (see structure: C gray, H white, N blue, B
249 trostilbene (1-) and 4,4'-dinitrotolane (2-) radical anions show the narrow band widths and partially
250 e simple alkyne bridge in 4,4'-dinitrotolane radical anion shows two distinct bands, providing proof
252 (DMPO), hydroxyl radical ((*)OH) and sulfate radical anion (SO4(*-)) were measured from ultrasonic ac
256 ings include the probable bent nature of the radical anion species in ammonia, the likelihood that th
257 e by direct detection of the 4,4'-bipyridine radical anion species localized in the plasmonic hot spo
259 ht account for the existence of a long-lived radical-anion state that permits lateral electron hoppin
260 on point for other systems involving the NDI radical anion, such as systems claimed to perform the ox
263 hough crystals could not be obtained for the radical anion [TCBT]*-, the electrochemistry (E degrees
264 For example, in the presence of a preformed radical-anion, tert-butyl phenyl sulfide cleaves signifi
265 TCT, results in the formation of an unstable radical anion that undergoes immediate dimerization at a
266 transfer event that provides access to arene radical anions that lie outside of the catalyst reductio
267 generated trifluoromethyl radicals leads to radical anions that undergo electron transfer oxidation
268 ducing multiple species including the phenyl radical anion, the phenyl radical, and the benzyne dirad
269 utane thymine dimer and thymine dinucleotide radical anion, thymidylyl(3'-->5')thymidine, can be dire
270 dical anion, coupling of the radical and the radical anion to give a cyclohexadienyl anion, and final
272 bsequent electron transfer from the formed E radical anion to the neutral Z starting material the ove
273 rum of 1,2,4,5-tetraoxatetramethylenebenzene radical anion (TOTMB(*-)) shows that, like the hydrocarb
274 We detect the formation of an intermediate radical anion upon reaction of photogenerated holes with
275 the minimal structural reorganization in the radical anions upon reduction during cyclic voltammetric
276 of a pseudo-para-dinitro[2.2]paracyclophane radical anion using Marcus-Hush theory reveals that its
277 ping of the captodative radical and the aryl radical anion using radical triggered C-Br fragmentation
278 ed to their corresponding radical cations or radical anions via electron abstraction or addition proc
280 In one, the energies of species (alkyne, radical anion, vinyl radical, vinyl anion, dianion, and
284 capturing and studying unstable anions and a radical anions when encapsulated by size-complementary a
285 ssociation spectrum of C(5)H(5)N-CO(2)(-), a radical anion which is closely related to the key interm
286 angement and decarboxylation to form an aryl radical anion which is then oxidized by the [4Fe-4S](+2)
287 radical species especially the negative side radical anion, which dominates the cycling stability of
288 toexcited QDs strongly spin polarize the NDI radical anion, which is interpreted in the context of bo
289 al reduction to the [RSNO-B(C(6) F(5) )(3) ] radical anion, which is susceptible to N-N coupling prio
290 g borylation product and the [Bpin(OMe)](*-) radical anion, which reduces [Ni(II)(IMes)(2)Cl(2)] unde
291 ntrinsic properties of the para-benzoquinone radical anion, which serves as the prototypical electron
293 tructurally and electronically complex C(60) radical anion with a molecular formula of Na(+)(n)[C(60)
294 could proceed via combination of a nitroaryl radical anion with a neutral nitrosoaryl radical, follow
295 also were synthesized by reacting o-benzyne radical anion with carbon dioxide and electron ionizatio
296 xciton coupled singlet excited state, 3) the radical anion with strong through-space interactions bet
297 stem involves the reaction of the anthracene radical anion with the radical cation of 4,N,N-trimethyl
299 died for a series of nitrobenzene derivative radical anions, working as large guest anions, and subst