ライフサイエンスコーパス: reaction with

1 rdination of Au(I) to alkyne to initiate the reaction with 1,5-H shift as a rate-determining step (RD

2 e-2-oxide was demonstrated in the annulation reaction with 1-(2-bromophenyl)-3-phenylprop-2-yn-1-one

3 The bimolecular rate constant for the DA reaction with (1)O(2) determined by competition kinetics

4 nitrogen-radicals to undergo strain-release reaction with [1.1.1]propellane.

5 d to a diluted AFFF to characterize e(aq)(-) reactions with 15 PFASs identified by liquid chromatogra

6 he E. coli PBP2 in its Apo form and upon its reaction with 2 diazabicyclo derivatives, avibactam and

7 te new classes of fused-dihydrotropones upon reaction with 2,4-dioxobutanoates under merely the same

8 extraction with trichloroacetic acid (TCA), reaction with 2-thiobarbituric acid (TBA) and quantifica

9 (XPhos) in toluene, and the products of its reaction with 3-bromopyridine and acetophenone were stud

10 For a multicomponent reaction with 4-nitrobenzaldehyde, conditions have been

11 oles can be obtained in a diaza-[1,2]-Wittig reaction, with 6 equiv of the base 1,2-benzothiazine 1,1

12 Glycosylation reactions with 7 gave >80% yields, and only beta-xylulof

13 IEDDA reactions with 7-oxanorbornenes produce a lower number o

14 The BAT identified severe reactions with 97% specificity and 100% sensitivity.

15 Subsequent selective bioorthogonal reaction with a cell-permeable organic dye enables live

16 electivity for cysteine, and stability after reaction with a commercial tetrazine, which has potentia

17 hesis of molecular P(4) Se(3) and subsequent reaction with a copper precursor, (P-Se)+Cu, and 2) the

18 alkyl radicals that are borylated by direct reaction with a diboron reagent.

19 te-controlled diastereoselective Diels-Alder reaction with a different dienophile to form 2-fold cycl

20 redox mechanism where CH(4) is activated by reaction with a hematite surface oxygen first, followed

21 N electrocatalyses the formic acid oxidation reaction with a mass activity of 12.9 [Formula: see text

22 etermines the outcome of combining a Michael reaction with a porphyrin-based supramolecular system.

23 group facilitates conjugation by undergoing reaction with a second, cysteine-containing protein.

24 phide, Cu(3) P, nanoparticles and subsequent reaction with a selenium precursor, (Cu-P)+Se.

25 rategy, which couples a fast-electrochemical reaction with a spontaneous chemical reaction to bypass

26 This novel methodology combined the Ugi reaction with a spontaneous enamine alkylation on a mult

27 The dihydropyridazine obtained from reaction with a strained cyclooctene shows a residual fl

28 n the fluorescence enhancement obtained upon reaction with a tetrazine-quenched fluorophore and study

29 We investigated this reaction with a variety of Lewis acids.

30 e effective in catalyzing C-N cross-coupling reactions with a diverse selection of amines and aryl ha

31 verage peptide synthesis time in translation reactions with a firefly luciferase-encoding mRNA.

32 mines and a ketone hydride acceptor, undergo reactions with a range of organometallic nucleophiles to

33 amounts of soluble and colored oligomers in reactions with a slow rate of polycatechol formation, in

34 ransfer-catalyzed domino Michael-cyclization reaction with acetylacetone.

35 enantioselective organocatalyzed Diels-Alder reactions with acrolein to form enantiomerically enriche

36 d in RB-sensitized solutions, suggesting EBS reaction with active intermediates ((3)RB(2-)*, O(2)(*-)

37 )(2) C(2) B(10) H(10) ; L=PhC(N(t) Bu)(2) ], reaction with adamantyl azide (AdN(3) ) affords the term

38 dramatic differences in yields from coupling reactions with added redox shuttles (generally >80%) and

39 three-component process; nonclassic Petasis reactions with additional components; Petasis-type react

40 ed by its conversion to 2'-deoxyadenosine by reaction with adenine, and 2-deoxyribose by hydrolysis.

41 nts having mild-to-moderate infusion-related reactions with AK002 (60% in the combined AK002 group an

42 d pathway for singlet alpha-carbonyl carbene reaction with alcohols (ethanol or tert-butanol) identif

43 l, and chemical evolutions during conversion reactions with alkali ions in secondary batteries are co

44 xcess of alkyl halides should be used in the reaction with alkyl phosphite if the alkyl group of the

45 ive transfer of alkyl groups was achieved in reactions with alkyl carbastannatranes affording congest

46 to >98:2 dr-in either diastereomeric form-by reactions with alkyl-, aryl-, heteroaryl-, allyl-, vinyl

47 tero)arenes and arylative radical annulation reactions with alkynes.

48 Hypersensitivity reactions with allopurinol and febuxostat: a study using

49 that engages in dearomative C-C bond-forming reactions with allylpalladium(II) electrophiles generate

50 The method involves an Ugi reaction with aminoacetaldehyde dimethyl acetal, followe

51 Reaction with an acylimidazole reagent is then carried o

52 zed "on chip" by a 1,3-dipolar cycloaddition reaction with an alkynyl-modified dye.

53 nerality has been shown in a radical cascade reaction with an allylboronic ester.

54 imal nucleophilic residue on the protein via reaction with an electrophile.

55 iazomethane 47 is actually formed requires a reaction with an energy barrier below 43 kcal/mol.

56 adsorbed OH* toward Ir(1) and its subsequent reaction with another H*.

57 genic foods and management of acute allergic reactions with antihistamines and epinephrine autoinject

58 >250-500-fold increase in fluorescence upon reaction with AP sites in DNA.

59 ted gas phase chemistry involving elementary reactions with aryl radicals is presented.

60 dium-catalyzed Suzuki-Miyaura cross-coupling reaction with arylboronic acids in good yields.

61 from either 2 or 3, which is demonstrated by reaction with benzaldehyde.

62 nctionality, has been designed such that the reaction with boronic acid bearing drugs induces an in s

63 tically distinct, traditional cross-coupling reactions with C-H functionalization using the same prec

64 ) bis(alkynyl) product can be trapped out by reaction with carbon monoxide or intercepted through irr

65 The functionalization of azulenes via reaction with cationic eta(5)-iron carbonyl diene comple

66 ) (1), as demonstrated in H atom abstraction reactions with certain phenolic ArO-H and hydrocarbon C-

67 Thousands of biochemical reactions with characterized activities are "orphan," me

68 acetyl isocyanate followed by a self-sorting reaction with chloroacetyl isocyanate and 4-bromophenyl

69 heating at 50 degrees C with DABCO and then reaction with chlorophosphines.

70 The rate constants for reactions with Cl atoms with the same compounds were (1.

71 ow-background fluorescence arises from their reaction with CO to release the corresponding highly flu

72 forms amino alcohols to oxazolidinones (upon reaction with CO(2) ) and then to methane (upon reaction

73 dative dehydrogenative C-H/X-H carbonylation reactions with CO constitute one of the most efficient s

74 nised gTSSA-I (74/146; 50.7%), with no cross reaction with common components of gTSSA-II/V/VI recombi

75 s a rare, often difficult-to-predict adverse reaction with complex pathomechanisms.

76 ine addition followed by a type II dyotropic reaction with concomitant re-aromatization of the six-me

77 The comparatively slower rate of reaction with coordinating counteranions can be rescued

78 With such a large rate coefficient, reaction with Criegee intermediates can be a substantial

79 membrane protein complexes and time-resolved reactions with crystallography.

80 Their reaction with CuBr.S(CH(3) )(2) affords Cu(I) complexes

81 res derived from 1,3- and 1,5-dipoles; while reaction with cyclic dienes yields several three-dimensi

82 inverse electron demand Diels-Alder (iEDDA) reaction with cyclooctyne.

83 g of 3 allows for facile ring enlargement in reactions with CyNC, bis(diisopropylamino) cyclopropenyl

84 tate 4, discovered to undergo a substitution reaction with cysteine derivatives.

85 ydroquinazoline moieties capable of covalent reaction with cysteine.

86 We performed computational studies of these reactions with density functional theory (DFT) and show

87 We demonstrate the use of accelerated reactions with desorption electrospray ionization mass s

88 lysis engage in formal C-H functionalization reactions with diazoacetate derivatives, furnishing sp(2

89 that were covalently modified by a chemical reaction with dichlorvos.

90 h mixed lithium-magnesium amides followed by reaction with different electrophiles.

91 nyl compounds, undergo [2 + 2] cycloaddition reactions with different alkynes to generate 1,2-oxaphos

92 selectivity in a series of nucleopalladation reactions with different neutral and anionic Pd catalyst

93 ystem is robust and highly effective for the reactions with different substrates, and some target pro

94 monoxide or intercepted through irreversible reaction with dihydrogen, resulting in selective hydroge

95 reactions changes to a two-step one for the reaction with dimethyl propynamine.

96 application of ynamides as substrates in the reactions with diorganyl dichalcogenides and iron(III) c

97 particular a high K(m) for dioxygen and slow reaction with dioxygen, are proposed to enable their hyp

98 e synthetic access to main mesoionics, their reaction with dipolarophiles, and recent applications in

99 Subsequent reaction with dipyridyl tetrazine leads to bond cleavage

100 lization to proceed via arsenite desorption, reaction with dissolved or surface-bound reduced S, and

101 Reaction with dissolved sulfide was modulated by diffusi

102 ic aldol donors, as well as their subsequent reaction with diverse aldehyde acceptors.

103 c deprotonation at -75 degrees C followed by reaction with DMF gave 2-formyl-4-chloro-3-fluoropyridin

104 covers transition-metal catalyzed insertion reactions with donor/donor and donor carbenes, providing

105 We validated three of those reactions with drug tests and demonstrated novel antifil

106 scherichia coli, was performed in a sandwich reaction with E. coli-specific either aptamer or antibod

107 Coupling enzymatic reactions with electrochemical regeneration of cofactors

108 the carbanions are further functionalized by reaction with electrophiles including CO(2) and aldehyde

109 ively forming the cross-coupled product upon reaction with electrophiles.

110 cluding low-abundance DNA adducts induced by reactions with electrophiles.

111 Drug-induced hypersensitivity syndrome/drug reaction with eosinophilia and systemic symptoms (DiHS/D

112 severe DHR and started in 14/25 with a drug reaction with eosinophilia and systemic symptoms (DRESS)

113 One serious case of drug reaction with eosinophilia and systemic symptoms occurre

114 ng a unique behavior of two-state reversible reaction with fast structural deformation whose lifetime

115 A third footprinting approach is by reactions with fast, irreversible labeling species that

116 Removal during reaction with Fe(2+)((aq)) was observed after 8 h, conco

117 ctivity-based probe that couples Fenton-type reaction with ferrous iron to subsequent protein labelin

118 the nucleophilic addition, as shown for the reaction with fluorenone.

119 FOLP and HFOLP each underwent the aza-Cope reaction with formaldehyde followed by hydrolysis to eli

120 lladium-catalyzed alkyne alkoxycarbonylation reaction with formation of an alpha-methylene-gamma-lact

121 ) was released from these three shales after reaction with fracture fluid, indicating that U is readi

122 ion exists on the rates of peroxymonosulfate reactions with free amino acids.

123 Ph-AH(+)-Np@CB[7] is formed by reactions with free CB[7] and CB[7].Na(+) (where "." rep

124 e each year provide an important surface for reaction with gas-phase pollutants.

125 state to complete the reductive elimination reaction with greater catalytic efficiency.

126 uctase and this enzyme was essential because reaction with GSH alone yielded only little activity.

127 ) substrate reductions as shown by the rapid reaction with H(2) or O(2) .

128 Although reaction with H(2) ultimately leads to complete protonat

129 f the Si=As bond of A, it undergoes addition reactions with H(2) O and NH(3) , forming LZnAs(H)SiOH(L

130 rtners in palladium-catalyzed cross-coupling reactions with (hetero)aryl halides.

131 can be efficiently accessed via the Petasis reaction with high levels of both diastereoselectivity a

132 stability (150 h) toward hydrogen evolution reaction with high mass activity, which is 26 times high

133 d using highly robust copper-catalyzed click reaction with high purity.

134 ed to induce asymmetric photo-polymerization reactions with high enantioselectivity and reactivity.

135 tical areas due to their ability to catalyze reactions with high selectivity.

136 for the hydroformylation of alkenes through reaction with hydrogen and carbon monoxide to produce al

137 tration to form ethanoic acid and CO(2) upon reaction with hydrogen peroxide (150 mM).

138 The reaction with hydrogen peroxide (H(2)O(2)) is considered

139 ction with CO(2) ) and then to methane (upon reaction with hydrogen), simultaneously regenerating the

140 o give superior results in the two-component reactions with imines.

141 eophiles undergo oxidative fluorocyclization reactions with in situ generated chiral iodine(III)-cata

142 ere produced through 4pai electrocyclization reactions with indole, 7-methylindole, and 5-bromoindole

143 ether support Curtin-Hammett control in this reaction, with initial radical addition being quick and

144 go cross-coupling reactions and substitution reactions with ipso selectivity to generate heteroarenes

145 tc showed a lower oxygen consumption rate in reaction with isolated Cytc oxidase, which we propose ma

146 Reactions with isolated gold complexes and DFT calculati

147 alkylation of pyrimidine aldehydes-the Soai reaction, with its astonishing attribute of amplifying a

148 ent direct kinetic measurements of MVK-oxide reactions with key atmospheric species using absorption

149 a hitherto unexplored S(N)2 pathway for the reaction with large transition state stabilization at re

150 r, the ancestors generally catalyzed simpler reactions with less double-bond isomerization and fewer

151 In the presence of 12-crown-4, the reaction with LiCH(2)TMS yields [Ru(PPh(3))(C(6)H(4)PPh(

152 on for their potential in promoting chemical reactions with light.

153 stable complex oxides, kinetically competent reactions with lower initial energy barriers must be dev

154 Reactions with materials inside building envelopes are e

155 nsformed into norbornadienone derivatives by reaction with Me(3)SnLi.

156 emoval of the formate and acetate ligands by reaction with methanol to form esters, interior active s

157 TBA metabolite photohydrates, although this reaction with model DOM was only observed for photohydra

158 romatic systems undergo the iodine-catalyzed reaction with moderate to very good yields in both polar

159 eactive oxygen species via a light-activated reaction with molecular oxygen.

160 Here, electrochemical side reactions with molecular oxygen are shown to occur durin

161 they are susceptible to electrochemical side-reactions with molecular oxygen during device operation.

162 avenges' hydroxyl radicals, preventing their reaction with monoterpenes, and the resulting isoprene p

163 d parabolic reaction rate profile and slower reactions with more acidic catalysts in some cases.

164 ular structure of oxygen (O(2)) makes direct reaction with most organic materials at ambient temperat

165 Integrating chemical and enzymatic reactions with MS-based proteomics, the current method i

166 tically lay out the components of individual reactions with multiple options for downloading the reac

167 tic studies on two rapidly evolving chemical reactions with multiple overlapping spectral components

168 llowed by the diastereoselective Diels-Alder reaction with N-aryl maleimides furnishing isoquinuclidi

169 ailed to achieve a ring-opening nucleophilic reaction with N-unprotected substrates.

170 ts the major products in bifurcating organic reactions with negligible computational cost.

171 the products can participate in various side reactions with newly made surface sites.

172 The reaction with NO results in an almost complete reduction

173 x formation was cluster dependent and that a reaction with NO, which was complete at 8-10 NO molecule

174 Fe-NO model engages in this N-N bond-forming reaction with NO.

175 shear stress stimuli and diverse biochemical reactions with NO.

176 ons with additional components; Petasis-type reactions with noncanonical substrates, mechanism, and p

177 ers and amines and subsequent intramolecular reaction with nucleophiles.

178 ds and their ability to undergo near-perfect reactions with nucleophiles.

179 cluster was significantly less sensitive to reaction with O(2) and NO when SvWhiD was bound to sigma

180 a sequential mechanism (cofactor binding and reaction with O(2) precede substrate binding) have been

181 both cofactor and substrate binding prior to reaction with O(2)) and a sequential mechanism (cofactor

182 After initial OH addition and reaction with O(2), the effective production rates of ph

183 ne-electron transfer to the ring followed by reaction with O(2).

184 -O-Fe(III) and Fe(IV)(O) species in the same reaction with O(2).

185 mined by SO(2) uptake on ash, rather than by reaction with OH as commonly assumed.

186 Gas-phase reaction with OH is expected principally to result in fo

187 l replaces the commonly used water-splitting reaction with one-electron, reversible redox couples at

188 determine the extent of completion of the 48 reactions with one analysis.

189 e-transfer excited states that undergo redox reactions with one or more halogen species are detailed.

190 processes coupling carbon dioxide reduction reactions with organic oxidation reactions are promising

191 s of the CWEDD and the ACTJU is based on its reaction with ortho-phthaldialdehyde and sulfite to form

192 ed to specifically detect ZIKV without cross-reaction with other FLAVs.

193 volved the heterocyclic ring, similar to the reaction with other pyrimidines.

194 ED activation of 9,10-dibromoanthracene in a reaction with oxygen and takes place at ambient temperat

195 distribution is reflected in the reactivity-reaction with oxygen occurs selectively at a position wi

196 s undergo nucleophilic aromatic substitution reactions with oxygen and carbon nucleophiles to provide

197 cies are shown to be competent substrates in reactions with oxygen-based radicals, dichalcogenides, a

198 rent kinetic isotope effects (AKIEs) for the reaction with ozone, however, was nontrivial due to chal

199 isotope enrichments factors (epsilon(C)) for reactions with ozone (epsilon(C) = -3.6 to -4.6 per mill

200 be used to elucidate the contribution of the reactions with ozone or hydroxyl radicals to overall tra

201 up, directly bonded to the nitrogen atom, by reaction with p-toluenesulfonic acid.

202 s identical to those obtained in O(2)-driven reactions with PASC, xyloglucan, or glucomannan.

203 distyrylbenzene-bis-aldehyde (DSB-3), whose reaction with PE produces a fluorescence signal.

204 ch and (b) LTP-Allergy: those that presented reaction with peach and at least another plant-food cont

205 Experimental and computational studies on reactions with phenols support a mechanism involving tur

206 enylprop-2-yn-1-one and in the deoxygenation reaction with phenylboronic acid.

207 ZnO NPs are chemically unstable due to their reaction with phosphates.

208 Irreversible and turnover-rate limiting reaction with pinacolborane (k ~ 7 x 10(-3) M(-1) s(-1))

209 ates or unreactive end-products via e(aq)(-) reactions with precursor structures in AFFF.

210 to control both the inputs and outputs of a reaction with quantum-state resolution.

211 horylpyridines, thereby completing S(N)(H)Ar reaction, with quinolines, the reaction stops at the for

212 lkylation, and carbocarboxylation of alkenes-reactions with rare precedents in the literature-by mean

213 ata, resulting in a sequence of second-order reactions with rate constants of 4.0 +/- 0.4, 2.7 +/- 0.

214 nsights on electrolyte decomposition through reactions with reactive oxygen species identified throug

215 se of the P(4)Se(3) molecules and subsequent reaction with red phosphorus type moieties to produce a

216 In this study, the [Formula: see text] reaction with reduced Hypocrea jecorina LPMO9A (Cu(I)-Hj

217 ave advanced to such a level that polyatomic reactions with relevance to extreme astrochemical and co

218 ano-sized molecular architectures, providing reactions with remarkable rate acceleration, substrate s

219 anced catalytic performances in H/D exchange reactions with respect to (i) monometallic analogues as

220 phase media increased over the aqueous phase reactions with RhB and aqueous scavengers.

221 e hydrolysis of nucleotides by slowing their reaction with RppH, they nevertheless compete with RNA f

222 Y(32)(*) was generated in a bimolecular reaction with [Ru(bpy)(3)](3+) formed by flash photolysi

223 ld (26 examples, 50-92% yield), whereas this reaction with secondary alcohols in the absence of any e

224 lobutanones via a Rh-catalyzed "cut-and-sew" reaction with selectivity factor up to 785.

225 tibility of carbon-heteroatom cross-coupling reactions with sensitive substrates and functionality.

226 g Western blot and specific polymerase chain reaction with sequencing on a different valve sample.

227 Amadori-type rearrangement of dopegal in the reaction with several amino acids and neuropeptides.

228 MA(+) and DMA(+), in their hydride transfer reactions with several hydride acceptors/donors in aceto

229 orial review, an up to date progress of this reaction, with significant recent advancements in terms

230 ncoding a reaction, identified 102 metabolic reactions with significant change in flux in MG1655:: te

231 Intermolecular reactions with simple, all-carbon tetrasubstituted alken

232 otent marine toxin, is readily oxidized upon reaction with singlet oxygen ((1)O(2)).

233 tifying organic hydroperoxide formation from reaction with SO(2) and formic acid, respectively.

234 g 1,2-diboronic esters via a copper-mediated reaction with sodium azide.

235 complex with the HoxEFU assembly to mediate reactions with soluble electron carriers like NAD(P)H an

236 Copper-oxygen sites are known to catalyze reactions with some of the most recalcitrant C-H bonds f

237 ed glucals by Pd-catalyzed Fujiwara-Moritani reaction with styrenes, acrylates, acrylamide, acrylonit

238 rgo mostly similar initial biotransformation reactions, with substitution-type reactions maintaining

239 of the Fe-C5' bond liberates 5'-dAdo(*) for reaction with substrate, but here, we use Omega formatio

240 ated via highly enantiospecific substitution reactions with suitably reactive nucleophiles.

241 ngements and trifluoromethylcyclopropanation reactions, with superior outcomes to approaches using pr

242 re quantified inside a museum gallery, where reactions with surfaces, NO, occupants, and NO(2) accoun

243 sition states for the favored and disfavored reactions with surprising results.

244 e to compare the free energy barrier for the reaction with that for the Mg(2+)-assisted release of th

245 products of its chemical or electrochemical reactions with that material.

246 that exerted by the pyridazine arising from reaction with the analogous alkyne.

247 activator leads to a complete cycloaddition reaction with the antibody-drug conjugate in seconds vs

248 ercalation process-proceeding via topotactic reaction with the cubic close packed oxygen-anion framew

249 itional exocyclic hemiaminal group formed by reaction with the cyclic aminal nitrogen.

250 the integration of catalyzed gas-generation reaction with the designed molecular recognition event,

251 CD38 then performs a base-exchange reaction with the donor NA group deriving from NAAD, pro

252 the Michaelis complex prior to a rapid S(N)2 reaction with the enzymatic nucleophile.

253 yclic hemiaminal group is readily removed by reaction with the formaldehyde scavenger 1,3-cyclohexane

254 es of UiO-66 limit the access of TBA and the reaction with the formate/acetate ligands bound within t

255 was investigated by performing the Maillard reaction with the free anomeric carbon of the maltodextr

256 In addition, the product of subsequent ene-reaction with the N-phenylmaleimide is isolated for the

257 ere successfully substituted by means of the reaction with the organozinc reagents, thereby allowing

258 ands prove to be foreseeable by modeling the reaction with the parent achiral 1,2-bidentate additives

259 ribed that revealed specific features of the reaction with the substrates and inhibitors.

260 transformed into radical cations via ion/ion reaction with the sulfate radical anion.

261 ces was orders of magnitude greater than the reaction with the target compound and scavengers in the

262 The corresponding reaction with the unsaturated N-heterocyclic silylene c-

263 The procedure utilizes a simple one-step reaction, with the derivatising agent N-methyl-bis-trifl

264 ne (SAM) enzymes initiate biological radical reactions with the 5'-deoxyadenosyl radical (5'-dAdo*).

265 The interface reactions with the amide electrolyte lead to the predict

266 hydroxylation, and overoxidation pathways in reactions with the atomic oxidant N(2)O.

267 zes the reversible Fe-Mo alloying-dealloying reactions with the delithiation-lithiation processes, me

268 s attention due to their ability to catalyze reactions with the efficiencies of natural enzymes.

269 (2)MnO(3) by depressing gas release and side reactions with the electrolyte.

270 y >99.5 % without dendrite formation or side reactions with the electrolyte.

271 rough irreversible 1,3-dipolar cycloaddition reactions with the four nitrones present in the DCL.

272 iezopotential) effectively facilitates redox reactions with the free carriers in MoS(2) .

273 change because of transformations driven by reactions with the NO(3) radical that form new absorbing

274 ated the presence of immune-mediated adverse reactions with the response pattern.

275 Analogous exchange reactions with the single-bonded (CO)(3)CpMo-MoCp(CO)(3)

276 mage or deteriorate due to unwanted chemical reactions with the surrounding agent.

277 c insights into metal-mediated bond-cleavage reactions, with the goals of understanding the main fact

278 hanisms are operative in these rearrangement reactions, with the pathway depending on the identity of

279 The silylation reactions with these catalysts produce high yields of he

280 Reductive protonation reactions with these compounds converge at stable exampl

281 ium simplicissimum, and subsequent enzymatic reactions with these compounds generated two additional

282 teins and peptides that were recalcitrant to reaction with thiol or amine nucleophiles under mild aqu

283 sted nucleophilic factor, beta(nuc), for the reactions with thiolates and with the ability of the lea

284 e addition products [i.e., formed via (photo)reaction with thiosulfate, hydroxylamine, and ammonia] a

285 occurring guaiazulene, were investigated in reactions with three electrophilic iron complexes of var

286 sed on replacing uninteresting or unobserved reactions with time delays.

287 thiolato-iron-carbide complex: an analogous reaction with toluylsulfenyl chloride affords the cluste

288 of various 1,3-diynes by the hydrosilylation reaction with triethyl- or triphenylsilane catalyzed by

289 quently subjected to a dipolar cycloaddition reaction with trimethylsilyl amino esters.

290 using solid-phase synthesis and subjected to reaction with trimethylsilyl trifluoromethanesulfonate (

291 spectrometer via an ion/ion charge inversion reaction with tris-phenanthroline magnesium dications.

292 The regioselectivity of the reaction with unactivated terminal alkene is significant

293 tions and have not previously catalyzed such reactions with unactivated alkenes.

294 trans-diastereoselective Heck-type coupling reaction with various arene diazonium salts to furnish 2

295 hasic reaction media to accelerate enzymatic reactions with various hydrophobic reagents.

296 rom benzocyclobutenol, undergoes Diels-Alder reaction with vinylphosphine oxides, yielding the corres

297 romatic substitution (S(N)Ar) is a classical reaction with well-known reactivity toward electron-poor

298 ollow up chemistry, such as the halogenation reaction with XeF(2) or SO(2)Cl(2) with the dipyridinium

299 opane is exceptionally selective for S(N)2@I reactions with yields upward of 90%.

300 on-carbon and carbon-heteroatom bond forming reactions with ynamides have been developed and now sign