ライフサイエンスコーパス: redox potential

1 D tumor model, governed by the Cu(+2)/Cu(+1) redox potential.

2 , the concentrations of ions, the pH and the redox potential.

3 for free and Brine Releasable (BR) VSCs and redox potential.

4 , such as membrane voltage, calcium, pH, and redox potential.

5 steep gradients in solute concentrations and redox potential.

6 ing Cd(II) as this metal has a more negative redox potential.

7 s complex displayed a lower and irreversible redox potential.

8 , and pheomelanin possesses a more oxidative redox potential.

9 of matrix superoxide/H2O2 production at this redox potential.

10 heir flexibility in tuning the Fe(3+)/Fe(2+) redox potential.

11 cathepsins through modulation of the lumenal redox potential.

12 ts oxidation level into large changes in its redox potential.

13 ified susceptible neurons by their increased redox potential.

14 otal 1((I))-CO intermediate at the 1((II/I)) redox potential.

15 (+), NADH, NADPH, histidine, and glutathione redox potential.

16 catalysis smoothly proceeds at the 1((II/I)) redox potential.

17 bit relatively low solubility and inadequate redox potentials.

18 duce multiple bonds without unreasonably low redox potentials.

19 ommunity compete for hydrogen in soil at low redox potentials.

20 zed structures with reduced optical gaps and redox potentials.

21 (-1) s(-1), respectively, and correlate with redox potentials.

22 olor changes, is achieved by tuning external redox potentials.

23 itu determination of reduced ZnO nanocrystal redox potentials.

24 l straddle the water oxidation and reduction redox potentials.

25 d water, with respect to vacuum and to water redox potentials.

26 nment between the solid band edges and water redox potentials.

27 presence of Sec is not tied to unusually low redox potentials.

28 while allowing sensitivity to drugs with low redox potentials.

29 and (2) the matching of cobalt and dioxolene redox potentials.

30 s, with diverse coordination chemistries and redox potentials.

31 d to be a facile, reversible process at high redox potentials.

32 wn biofilms (>20 um), and at different anode redox potentials.

33 d habitat stability are associated with high redox-potentials.

34 n CH3CN), multiple electron transfers at low redox potentials (-1.7 and -1.9 V versus Ag/Ag(+)), and

35 OleTJE heme iron has an unusually positive redox potential (-103 mV versus normal hydrogen electrod

36 ed similar affinities for Cu(2+) (12-31 nM), redox potentials (242 and 251 mV), and electron paramagn

37 st specific capacity (3861 mAh/g) and lowest redox potential (-3.04 V vs standard hydrogen electrode)

38 egulatory disulfide bond with a low midpoint redox potential (-335 mV at pH 7.9).

39 From the pH dependency of the GOx redox potential, a pK(a) of 7.2 has been determined for

40 ysis to a shift in the distal [Fe4S4](2+/1+) redox potential, a previously experimentally inaccessibl

41 rategies the most important properties, i.e. redox potentials, absorption and emission maxima or fluo

42 e terminal transfer of electrons onto higher redox potential acceptors in the extracellular space.

43 pplied potentials are believed to affect the redox potential across the cell membrane and disrupt red

44 thereby anodically shifting the metal ion's redox potential and (ii) optimizes the bond strength bet

45 py, and 3) nicotinamide adenine dinucleotide redox potential and adenosine triphosphate/adenosine dip

46 studies elucidate the contributions of metal redox potential and ammonia acidity to this effect.

47 combinations of parameters (temperature, pH, redox potential and availability of molecular precursors

48 ant exhibited a reductive shift in mycothiol redox potential and compromised stress response.

49 mannii DsbA (AbDsbA) enzyme has an oxidizing redox potential and dithiol oxidase activity.

50 s(V) under abiotic conditions, even with low redox potential and high Fe(II) content (4.5 mM).

51 Here, we identified cytoplasmic redox potential and intracellular redox sensor, WhiB4, a

52 rin electron density, which affects cofactor redox potential and ligand affinity.

53 alysis and established relationships between redox potential and O2-adsorption strength, we conclude

54 lationship between long-range correlation of redox potential and oxidation rates of circumneutral mic

55 By designing the cluster to have a high redox potential and steric protection of the core-locali

56 igration, while soil characteristics such as redox potential and surface salinity developed later in

57 Correlation between the AOA and the redox potential and the biological activity of the tococ

58 s an electron injection site, modulating the redox potential and the catalytic properties of the H-cl

59 erenol (0.1 muM) decreased the mitochondrial redox potential and the ratio of reduced to oxidated glu

60 e result of a clear correlation between heme redox potential and the strength of electronic coupling

61 etal has the lowest standard electrochemical redox potential and very high theoretical specific capac

62 is thought to be crucial for maintenance of redox potential and vitality of the cell but is poorly u

63 e biosynthesis, while reducing mitochondrial redox potential and/or ATP synthesis impaired proline bi

64 hybrid flow/nonflow cells, noting also their redox potentials and demonstrated concentrations of tran

65 st-principles calculations of proton-coupled redox potentials and magnetizations reveal that the Ni-o

66 lustrate structural effects on their various redox potentials and on the p Ka values of the correspon

67 ring photodoping, allowing correlation of NC redox potentials and reduction levels.

68 APBA; however, the binding did not alter the redox potentials and the apparent diffusivities of ions.

69 s between these binding modes modulate the Q redox potentials and the rate of electron transfer (eT)

70 ation by peak cU(aq), we reanalyzed measured redox potentials and total concentrations of aqueous ura

71 omposition, (iii) reducing agent, (iv) metal redox potential, and (v) addition of surfactants for con

72 mia metabolic circuitries feeding anabolism, redox potential, and energy required for tumor propagati

73 s (H(+)), chloride (anions), the glutathione redox potential, and H(2)O(2) Simultaneous analyses of t

74 timuli, e.g. light, temperature, metal ions, redox potential, and mechanical stress.

75 ity, defects in neuronal function, decreased redox potential, and reduced numbers of presynaptic mito

76 Severe changes in the environmental redox potential, and resulting alterations in the oxidat

77 and the effect of sorbent concentration, pH, redox potential, and the sulphite and iron content of th

78 be converted into each other by changing the redox potential, and this redox switch caused a major al

79 tudies of the ground electronic state (GES), redox potentials, and C-H amination of [Rh2(II,III)(O2CC

80 Cu(II) as these metals have relatively high redox potentials, and microbial electrolysis cells for r

81 PeT + w) values from experimentally measured redox potentials, and validate the voltage sensitivities

82 , between the pro-oxidant parameters and the redox potentials, antioxidant capacities and lipophilici

83 ) ), this Mn-oxide is predicted to show high redox potentials ( approximately 4.2 V vs Na/Na(+) ) wit

84 pH, enzyme, and redox potential are the most frequently used biological

85 The trends in these redox potentials are explained in terms of the acidity o

86 ve as the reservoir for electrons, but their redox potentials are tuned by the choice of ligand at Mn

87 e porphyrin (AlPor, AlPorF(3), or AlPorF(5)) redox potentials are tuned by the substitution of phenyl

88 ations indicate that both UQ and MQ have low redox potentials around -260 and -230 mV, respectively,

89 The role of the redox potential as a factor contributing to the NO-gener

90 Our study highlights redox potential as a pivotal factor that could serve as

91 e NAD(+) or NADH at about the same operating redox potential as the NADH/NAD(+) pool and comprise the

92 ives with carboxylic acids can improve their redox potential as well as their charge capacity.

93 refore not necessarily be explained by lower redox potentials, as has often been claimed.

94 O-O bond cleavage is shown to correlate with redox potentials, as well as the steric properties of th

95 hondrial metabolic potential and an abnormal redox potential, associated with reduced nicotinamide ad

96 e bound DLC electrode was confirmed with the redox potential at around -79 mV vs NHE in 0.1 M phospha

97 king at physiological or neutral pH, the GOx redox potentials at pH 7.4 and pH 7.0 are of main intere

98 the redox couple, the OCP deviates from the redox potential because of additional background half re

99 hors show that cobalt moieties have a higher redox potential, bind oxygen more weakly and are less ac

100 f phenolic compounds (by UPLC-PDA) and their redox potential by cyclic voltammetry (CV), antioxidant

101 for measuring the intracellular glutathione redox potential by direct and quantitative measurement o

102 Theoretical redox potential calculations clearly indicate that the r

103 ourbaix diagram, subtle variations in pH and redox potential can redirect a non-equilibrium crystalli

104 on (including Li(+), Na(+), and K(+)) at low redox potentials, carbon materials can serve as ideal an

105 tion state of the polymer, in the absence of redox potential change, resulting in increased emission.

106 e bacterial growth kinetics by measuring the redox potential changes of the carbon nanodots over time

107 We found that measured redox potential changes reflect changes in the free ener

108 terrestrial environments subject to periodic redox potential changes such as peatlands, marshes, and

109 pecies within this group, we identified that redox potential changes with diet and is the main factor

110 CO(2)-to-CO electrocatalysis at the Co(I/0) redox potential, computational studies suggested that th

111 The redox potential, Cu-Cu spectroscopic features, and a val

112 The redox potential decreases as the number of bound Li atom

113 Determination of the effective redox potential demonstrates that coordination of water

114 en spectroscopically characterized and their redox potentials, determined by cyclic voltametry, revea

115 ered mode can be used only in cases when the redox potential difference of reactions occurring at opp

116 ties, i.e., its (electro)chemical stability, redox potential, diffusion coefficient and the influence

117 This indicates a difference in redox potential distribution of the redox-active functio

118 stic conductance, determine the shift in the redox potential due to mechanical stretching of the meta

119 of oxidants generates shifts in the cellular redox potential during early stages of plant infection w

120 to a reordering in the anionic and cationic redox potentials during cycling.

121 ents of photon capture, electron fluxes, and redox potentials during photosynthesis cause reactive ox

122 gnificant effects on the oligomerization and redox potential (E degrees ') of the enzyme.

123 20H2), a stronger reductant with a mid-point redox potential (E'0) of -360 mV; E'0 of NAD(P)H is -320

124 s found to offer the optimal balance of high redox potential (E(1/2) = +1.19 V vs Fc(+/0)) and charge

125 A highly negative glutathione redox potential (E(GSH) ) is maintained in the cytosol,

126 roGFP-based specific bioprobe of glutathione redox potential (E(GSH); Grx1-roGFP2) and measured subce

127 ation leads to a characteristic fall in bulk redox potential (E(h)), the degree of which is dependent

128 Our genomic analysis suggests that the redox potential effect stems from a reduced number of an

129 allow the quantification of the glutathione redox potential (EGSH) in the cytoplasm and the mitochon

130 Redox potential (Eh) measurements are widely used as ind

131 is not expected to be stable at the measured redox potentials (Eh) in our experiments.

132 tammetry, where several parameters including redox potential, electron transfer rate, and surface cov

133 Using a genetic biosensor of mycothiol redox potential (EMSH), we demonstrated that a modest de

134 tailored to be responsive to pH variations, redox potential, enzymatic activation, thermal gradients

135 er will be formed outside templates when the redox potential exceeds the potential windows of nonaque

136 e examples reveals that solvent, spin state, redox potential, external co-reductants, and ligand arch

137 Measured redox potential for glucose oxidation was lower than 0 V

138 ated Cu(II) ATSM-F3 displays the appropriate redox potential for selective accumulation in hypoxic ce

139 ere measured that reveal that changes in the redox potential for the Cu(III)/Cu(II) couple are only p

140 e (UME) and its application to determine the redox potential for the deoxygenation of ZnO.

141 n historically discarded due to the negative redox potential for the NO,H+/HNO couple.

142 The two enzymes had a similar redox potential for their regulatory redox-active disulf

143 60-year history of this field, the Pd(II/0) redox potentials for catalytically relevant Pd complexes

144 e obtained O-H bond strengths and associated redox potentials for charge-neutral H-atom reductions of

145 The calculated proton-coupled redox potentials for the PCET reactions at the GCC phena

146 ot only to a much broader range of available redox potentials for the resulting phenanthro[9,10-d]imi

147 were conducted with two paddy soils covering redox potentials from E(H) -260 to +200 mV.

148 inhibition by formation of pH, nutrient, or redox potential gradients; but these explanations are of

149 compounds have been examined, and reversible redox potentials have been compared with results obtaine

150 mbagin effectively altered the intracellular redox potential in Mtb suggestive of oxidative stress in

151 -lactam resistance (e.g. beta-lactamase) and redox potential in Mtb.

152 hile either the macrophyte or SMFC increased redox potential in sediments, redox potentials near the

153 e transport model capable of reproducing the redox potential in space and time together with the site

154 nt reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monome

155 "sets" signaling at distinct, nonoverlapping redox potentials in support of multiplexing and error co

156 o [4Fe-4S] clusters adjacent to the Cbl have redox potentials in the range expected for Cbl reduction

157 al expansion" (i.e., a further separation of redox potentials) in single-pyridinium EPs (4, 5), where

158 risons reveal that for C-terminal motifs the redox potentials increased between 20-25 mV when the sel

159 nity to study the influence of the porphyrin redox potential independently of other factors.

160 d 4-chlorobenzonitrile, having two different redox potentials indicates that the reaction does not in

161 ce in driving force is opposite the trend in redox potentials, indicating that basicity is a key fact

162 When the differences in monomer redox-potential induced by the environment are small (as

163 ive phosphorylation to convert mitochondrial redox potential into ATP.

164 erting temperature-dependent electrochemical redox potentials into electrical power, can harvest wast

165 This shift in redox potential is attributed to the requirement for bot

166 ccase from Trametes versicolor, where the T1 redox potential is increased by ~350 mV over that of the

167 Redox potential is of key importance in the control and

168 sors, which however do not allow quantifying redox potentials, lack specificity, and the possibility

169 edox states, precise control of a molecule's redox potential, leading to a single output voltage in a

170 ty and reversibility in relation to a single redox potential leads to an impasse: the catalyst underg

171 se complexes, the phosphonate groups provide redox-potential leveling through charge compensation and

172 For its high theoretical capacity and low redox potential, Li metal is considered to be one of the

173 onstrate a correlation between intracellular redox potential (measured using optical nanosensors) and

174 ed the implementation of the constant pH and redox potential molecular dynamics (C(pH,E)MD) method in

175 SMFC increased redox potential in sediments, redox potentials near the anode (approximately 6 cm dept

176 vious approaches to measuring the biological redox potential noninvasively in real time are limited t

177 poly(ethyleneglycol)methacrylate) with a low redox potential of -0.58 V vs. SCE.

178 Cyclic voltammetry reveals a record redox potential of -1.70 V vs. saturated calomel electro

179 The disulfide has a standard redox potential of -261 mV and is efficiently reduced by

180 ca 3.2 m in the anolyte and a relatively low redox potential of 2.2 V vs. Li(+) /Li.

181 logical effects are consistent with the high redox potential of 5-Me-PCA, which distinguishes it from

182 eveals that a mechanical force can shift the redox potential of a molecule, change its redox state, a

183 Despite the high specific capacity and low redox potential of alkali metals, their practical applic

184 NMR further reveal that C91 has the highest redox potential of all cysteines in MAL.

185 ns caused regionally distinct changes in the redox potential of cholangiocytes that differentially se

186 Furthermore, the higher redox potential of copper and the enhanced weakening of

187 lly favorable reaction, with a less negative redox potential of CoxB (E'0 = -231 mV) as compared with

188 In addition, the redox potential of DsbP (-161 mV) is more reducing than

189 lla oneidensis could potentially control the redox potential of environments relevant to the geologic

190 ion in M. oryzae, we measured the amount and redox potential of glutathione (E(GSH)), as the major cy

191 However, the low redox potential of lithium metal renders it prone to cor

192 ve to HbA is consistent with the much higher redox potential of LtHb.

193 ctively ablating the change in intracellular redox potential of Mtb, signifying the importance of thi

194 DeltaEm_b can be markedly increased, and the redox potential of one of the hemes can stay above the l

195 ort that is electrochemically gated near the redox potential of P700, with current extending farther

196 ulted in higher oxidative shift in mycothiol redox potential of PknG mutant compared with the wild ty

197 which is much higher than the thermodynamic redox potential of SmI2(H2O)n determined by electrochemi

198 -bound residues to the dynamic tuning of the redox potential of TauD.

199 dentified based on the Bronsted basicity and redox potential of the active site, explaining the chang

200 electronics, where careful attention to the redox potential of the backbone relative to the organic

201 uctive half-reaction and have determined the redox potential of the bound flavin to be -123 +/- 7 mV.

202 try show that the cage anodically shifts the redox potential of the encapsulated quinone by a signifi

203 and might play a key role in adjusting a low redox potential of the FADH(*)/FAD pair required for fer

204 e (TauD), revealed a strong link between the redox potential of the Fe(II)/Fe(III) couple and conform

205 Fc(+) and adsorbed Fe(II) increases with the redox potential of the ferrocene derivative, as expected

206 work, we have intensively characterized the redox potential of the first meter of soil in an infiltr

207 NAD(+), total NAD contents, and NAD(+)/NADH redox potential of the healthy human brain were revealed

208 tions at these residues are sensitive to the redox potential of the internal solution, providing evid

209 The charge separation is directed by the redox potential of the involved bases and thus controlle

210 ined in terms of the large difference in the redox potential of the isolated subunits.

211 2) evolution was found to correlate with the redox potential of the ligand.

212 shell control the catalytic activity via the redox potential of the metal oxide and of the OCl(-).

213 bridging oxygens and thereby perturbing the redox potential of the Mn ion.

214 tant to the carboxylate basicity than to the redox potential of the oxidant.

215 tive to the carboxylate basicity than to the redox potential of the oxidant.

216 The pH dependent redox potential of the oxidoreductase glucose oxidase (G

217 mum when electrons are injected at the known redox potential of the protein.

218 The redox potential of the quinone/semiquinone couple of fla

219 the 'OFF' state, and show that the mid-point redox potential of the redox switch affords it sensitivi

220 es in a system is associated with the pH and redox potential of the solution, having efficient comput

221 wever, little attention has been paid to the redox potential of the species that lie between the dono

222 ectron transfer reactions, yet the effective redox potential of these powerful reductants has not bee

223 The high redox potential of this catalyst system is achieved by a

224 In this study, we show that the redox potential of wild-type TauD varies by 468 mV betwe

225 Changes in redox potentials of cardiac myocytes are linked to sever

226 A potentiometric method for measuring redox potentials of colloidal semiconductor nanocrystals

227 en shown to have a significant effect on the redox potentials of compounds such as 1,4-dinitrobenzene

228 ey to rechargeability lies in exploiting the redox potentials of Cu to reversibly intercalate into th

229 The measured redox potentials of MK-2 differed in three organic solve

230 The redox potentials of oxygenated nitrogen compounds predic

231 ddition, to aid readers, we have assimilated redox potentials of photocatalysts and substrates for a

232 can be explained by differences in predicted redox potentials of PSII electron acceptors that control

233 erns the motifs' reactivity, we measured the redox potentials of Sec-containing motifs and their corr

234 The Li-binding thermodynamics and redox potentials of seven different quinone derivatives

235 uents at the N(3) position, which govern the redox potentials of the Cu(+2)/Cu(+1) redox couples, ROS

236 lization, the aqueous dispersibility and the redox potentials of the different oxidative environments

237 The ground- and excited-state redox potentials of the donor and acceptor were chosen t

238 ectrochemical studies that gave insight into redox potentials of the four mitochondrial complexes and

239 Further, DFT-based investigations of the redox potentials of the Li-bound quinone derivatives pro

240 pled protonation of H99 is required for high redox potentials of the metal.

241 erent acidities of the M-H bonds and overall redox potentials of the molecules.

242 ive force while simultaneously measuring the redox potentials of the NADH/NAD(+) and ubiquinol/ubiqui

243 ed by cyclic voltammetry and showed that the redox potentials of the nitrones are largely influenced

244 fine-tuning of the electronic properties and redox potentials of the photocatalyst in both the excite

245 ndependent of material and controlled by the redox potentials of the photogenerated charge carriers,

246 l selection by LOX and the adjustment of the redox potentials of their protein-bound catalytic metals

247 The optical gap and redox potentials of these copolymers were fine-tuned by

248 The redox potentials of these ligands are controlled by func

249 between hydraulic retention time, power and redox potential on inactivation efficiency, also indicat

250 dency of the reduction mechanism and the GOx redox potential on the presence of halides, especially o

251 nstant, regardless of the proteins' in vitro redox potentials or their putative positions in the aero

252 sitive to pH change and respond as change in redox potential over time as pH of the medium changes du

253 tumor microenvironment like low pH, elevated redox potential, over-expressed enzymes and hyperthermia

254 Versatile peroxidase (VP) is a high redox-potential peroxidase of biotechnological interest

255 NN up to 172 cm(-1)), decreases the Fe(0)-N2 redox potential, polarizes the N-N bond, and enables -N

256 Higher radiation doses increased the redox potential, promoted the lipid oxidation and elevat

257 y designed to target different areas of this redox potential range and are monitored by surface-enhan

258 f -470 to +130 mV vs NHE, which includes the redox potential range occupied by cells in a state of ox

259 racellular nanosensors to cover a much wider redox potential range of -470 to +130 mV vs NHE, which i

260 lly occurs between redox couples at standard redox potentials ranging from +0.8 to -0.5 V.

261 ismutase in humans and plays a major role in redox potential regulation.

262 The appearance of higher-redox-potential respiratory quinone, ubiquinone (UQ), is

263 The redox potentials revealed lower values for the electron-

264 d organs can be ischemic, the measurement of redox potential (RP) in blood serum reflects the prooxid

265 2 (TRPM2) channel is known to be a cellular redox potential sensor that provides an important pathwa

266 which reports at a distinct, nonoverlapping redox potential, serving as a drift-correcting reference

267 to the bioreactor, that is, by maintaining a redox potential set-point value, appeared to be ineffect

268 lculated affinity change associated with the redox potential shift observed for [4Fe4S] cluster prote

269 Ga(Sbx)N1-x are found to straddle the water redox potentials showing excellent suitability for solar

270 n the local microenvironment, such as pH and redox potential, significantly affect the antimicrobial

271 Redox potentials span a 400-mV range (+349 mV vs. standa

272 ristic sigmoid plots when represented versus redox potential suggesting that all changes are the resu

273 ay's thioredoxins, exhibit strongly reducing redox potentials, suggesting that thioredoxins served as

274 trongly affected by the nitroxyl/oxoammonium redox potential than by steric effects.

275 tain a [4Fe-4S] cluster with a more positive redox potential than the wild-type.

276 mation of a single disulfide bond with a low redox potential that can be efficiently reduced by the N

277 These molecules exhibit redox potentials that are 470-500 mV higher than those o

278 ical determination of the bond strengths and redox potentials that define the ground-state thermodyna

279 lytes) with the necessary combination of (1) redox potentials that exceed the potential limits of wat

280 ctroscopic determination of the one-electron redox potentials that have been difficult to establish v

281 At the redox potential, the conductance changes abruptly as the

282 p between local coordination environment and redox potential; this gives rise to the observed overlap

283 ion of free radicals from energy stored in a redox potential through a 2e(-)/1H(+) transfer process,

284 obial metabolism markedly reduces gut pH and redox potential through the production of short-chain fa

285 oduce up to 20-25 kcal mol(-1) of additional redox potential, thus creating powerful reductants under

286 ters at the AuxI site and are able to assign redox potentials to each of the three iron-sulfur cluste

287 tive to glycation, albumin concentration, or redox potential, unlike other methods to quantify HSA-bo

288 jury, and in situ mapping of the hepatic GSH redox potential using a redox-sensitive green fluorescen

289 rabbit vitreous and maintains a steady-state redox potential using reduced and oxidized forms of glut

290 receptor, Aer, monitors cellular oxygen and redox potential via FAD bound to a cytosolic PAS domain.

291 on of glycolytic ATP production and cellular redox potential via HDAC3-mediated PGK1 deacetylation.

292 Surprisingly, the midwave redox potential was positively shifted with respect to t

293 catalytic activity were maintained, and its redox potential was reduced modestly by 20 mV possibly d

294 a variety of aryl halides, and, owing to its redox potential, was found to be the first organic donor

295 inc wire as one pole, characterized by a low redox potential, were used.

296 Fused mitochondria exhibit an altered redox potential, which dramatically enhances cell death.

297 O2 exceptional availability and high O2/H2O redox potential, which may in particular allow highly en

298 and do not follow the trend in one-electron redox potentials, which appear to dominate HAT reactivit

299 the entropic and enthalpic contributions to redox potentials with Q and with the identity and hydrop

300 nt enzymes to ROS scavenging and glutathione redox potential within each intracellular compartment.