ライフサイエンスコーパス: redox-active

1 The redox active 1,3,5-triazine derivative (MPT) was used as

2 macrocyclic polyamide cage that incorporates redox-active 1,4-dithiin units.

3 Now a redox-active 2D copper-benzoquinoid (Cu-THQ) MOF has bee

4 ts N-terminal alpha helix domain and hosts a redox-active [2Fe-2S] cluster in its C-terminal cytosoli

5 e [2Fe-2S] clusters of mitoNEET close to the redox-active [2Fe-2S] cluster of anamorsin.

6 the importance of the oxidation state of the redox-active [4Fe4S] cluster in the DNA damage detection

7 blished ability to serve as a tightly bound, redox-active active site cofactor for enzyme function, e

8 ron transfer (PCET) steps along a pathway of redox active amino acids (Y122beta <--> [W48beta?] <-->

9 sp-82 also enhanced the function of Tyr as a redox-active amino acid in the rHbS betaF41Y/K82D varian

10 ubunits, alpha and beta, through a series of redox-active amino acids (Y(122)*[beta] <-> W(48)?[beta]

11 lies on hole hopping escape routes formed by redox-active amino acids.

12 electivity for Trp and is tolerant to other, redox-active amino-acid residues.

13 Redox-active analytes that do not support direct electro

14 It was shown to contain a redox active and acid labile [2Fe-2S] cluster which is l

15 a facile way for the successful synthesis of redox active and bioengineering of reduced graphene oxid

16 Both sites are redox active and electron transfer is proton-coupled, su

17 general scope for detecting a broad range of redox active and nonredox active species simultaneously,

18 it such activity, the copper complex must be redox active and resistant to dissociation.

19 emonstrate that the optimal leaving group is redox-active and are consistent with a Ni(I)/Ni(III) cat

20 s synthetic approaches to prepare functional redox-active and conjugated homopolymers as well as the

21 ing the ratios of alkyl-ferrocene containing redox-active and inactive links during MOF synthesis ena

22 find that the cluster coordinated by UvrC is redox-active and participates in DNA-mediated charge tra

23 ity of chelating S-donor ligands secures the redox-active and potentially toxic Cu(I) ion, while thei

24 Pyrogenic carbonaceous matter (PCM) is redox-active and promotes both abiotic and biotic reacti

25 These cubanes are redox-active, and calculations reveal that the Co ions b

26 Redox-active anthraquinone molecules represent promising

27 Diverse organisms secrete redox-active antibiotics, which can be used as extracell

28 ovar Typhimurium as model microbes, a common redox active aryldiazonium salt is employed to intervene

29 e find that Pol delta bound to DNA is indeed redox-active at physiological potentials, generating a D

30 ribe a single-molecule junction comprising a redox-active, atomically precise cobalt chalcogenide clu

31 Here, we report a rationally designed redox-active Au(I) bis-N-heterocyclic carbene that induc

32 ows for the facile preparation of asymmetric redox-active Au(I) bis-N-heterocyclic carbenes.

33 repare air-stable Cu(II) complexes featuring redox-active azo-aromatic scaffolds, 2-arylazo-(1,10-phe

34 Here we report a redox active binary logic gate (RLG) which can store a "

35 shown that pyocyanin can be used as a rapid, redox-active biomarker for identifying Pseudomonas aerug

36 olypyridyl cobalt(II) complex bearing both a redox-active bipyridine ligand and pendant proton relays

37 Through the strategic design of a novel, redox-active bipyridyl- N-heterocyclic carbene macrocycl

38 ghlight the utility of Fe(4)S(4) clusters as redox-active building blocks in preparing new classes of

39 haracterization of Bim1 shows that it is not redox active, but very sensitive to H(2)O(2), which acce

40 he use of a chiral amine catalyst, bearing a redox-active carbazole unit, which could rapidly reduce

41 n of O(2) into H(2)O(2), based on the use of redox-active carbenium species.

42 iple allowed aliphatic photocoupling between redox-active carboxylate derivatives and electron-poor o

43 proteins have the capacity to serve as both redox active catalysts and purely electron transfer cent

44 l sites are relatively common, examples with redox-active cations are rare.

45 This study reports the first example of a redox-active Ce(4+) ion-bound Mn(IV) -oxo complex and it

46 nductive holder as well as an accumulator of redox active centers on the surface of the electrode, an

47 ion theories that assume iron to be the sole redox-active centre.

48 ate single-electron devices wherein a single redox-active cluster is connected to two macroscopic ele

49 ion by a d(0) Zr(IV) center with an appended redox-active Co(-I) site serving as an electron reservoi

50 , and they are typically used as oxidants or redox-active cocatalysts.

51 opper-dependent amine oxidases produce their redox active cofactor, 2,4,5-trihydroxyphenylalanine qui

52 al micronutrient manganese (Mn) functions as redox-active cofactor in active sites of enzymes and, th

53 We then show how enzymes tune redox-active cofactors and recruit oxidants to improve t

54 e, suggesting a potential protective role of redox-active cofactors for preventing protein oxidative

55 Among the several redox-active cofactors that participate in intricate ele

56 heterocyclic metabolites that often serve as redox-active cofactors.

57 sities, validating the promise of unmodified redox-active COFs that are easily incorporated into elec

58 The Lewis base catalyst was shown to form a redox-active complex with either the boronic esters or t

59 Natural organic matter (NOM) is an important redox-active component of natural porous media and predo

60 rafine particles (UFP, dp < 0.1-0.2 mum) are redox active components of PM.

61 d hsmR or hsmA have increased sensitivity to redox-active compounds and reduced colonization persiste

62 Beverages containing redox-active compounds might produce H(2)O(2) during she

63 Bacteria in soils encounter redox-active compounds, such as phenazines, that can gen

64 e stress following treatment with a range of redox-active compounds.

65 r in determining sensitivity or tolerance to redox-active compounds.

66 previously overlooked side-reactions between redox-active conjugated polymers and molecular oxygen in

67 ectron equivalents limiting the transport of redox-active contaminants.

68 or two binuclear mixed-valence Cu(+1)/Cu(+2) redox-active coordination compounds, 72k and 61k, was co

69 Catalysis is driven by the redox-active copper ion, and in most cases, SODs also ha

70 Heterocoronene, a new redox-active core fragment, is utilized for the synthesi

71 Redox-active covalent organic frameworks (COFs) are prom

72 ile electrodeposition process for creating a redox-active crystalline layer (denoted as RZx) on pyrol

73 t for bacteria and an essential cofactor for redox-active cuproenzymes.

74 characterization and bioelectrocatalysis of redox-active cyclodextrin-coated nanoparticles.

75 These redox-active cyclophanes demonstrate that geometry-match

76 the rate constant of the oxidation of PDI's redox-active Cys residues (Cys(53) and Cys(397)) by hydr

77 at peroxynitrite preferentially oxidizes the redox-active Cys residues of PDI to the corresponding su

78 Furthermore, substitution of the redox active cysteine pair C52 and C57 in the N terminus

79 tein fusion to cytosolic proteins with known redox-active cysteines, we identified the yeast glycolyt

80 thionine sulfoxide reduction involving three redox-active cysteines.

81 the small Lewis acidic NiO clusters and the redox-active CZ support, which also stabilizes the small

82 ompounds (Ce, Nd, Sm, Gd; Am, Bk, Cf) of the redox-active dioxophenoxazine ligand (DOPO(q); DOPO = 2,

83 transfer reducing equivalents from FAD to a redox-active disulfide bridge, which further reduces dis

84 (AhpF), catalyzes the rapid reduction of the redox-active disulfide center of the antioxidant protein

85 oting adsorption/activation by making use of redox active dopants such as Mn linked to oxygen vacanci

86 due to the energy splitting between two key redox-active dpi* frontier molecular orbitals (FMOs).

87 luate the change in (64)Cu-ATSM signal after redox-active drug treatment.

88 signal, but treatment of hypoxic cells with redox-active drugs resulted in a more dramatic change th

89 The DNA binding is measured by a redox active dye, methylene blue, that intercalates in d

90 between a surface-adsorbed dye and a soluble redox-active electrolyte species in the dye-sensitized s

91 direction has been facilitated by the use of redox-active electrolytes that add faradaic charge stora

92 dox flow batteries, which are applied to two redox-active electrolytes: 2,6-dihydroxyanthraquinone (D

93 Crystallographic defects exist in many redox active energy materials, e.g., battery and catalys

94 S)-2-methyl-3-hydroxypentanoyl-ACP (6a) with redox-active, epimerase-inactive EryKR6 from module 6 of

95 Simple activation via redox-active ester formation was followed by nickel-medi

96 ectron transfers between the Ir catalyst and redox-active ester substrate to afford a carbocation int

97 Thus, carboxylic acids, once converted to redox-active esters (RAEs), can be utilized as formally

98 Redox-active esters have recently emerged as useful surr

99 N-hydroxyphthalimide (NHPI) based redox-active esters were found to be convenient starting

100 ges a gap in the cross-coupling of aliphatic redox-active esters with aryl zinc reagents.

101 l radicals upon reductive decarboxylation of redox-active esters without auxiliary photocatalysts.

102 arboxylative amination of simple and complex redox-active esters.

103 lic acids, by-passing their preactivation as redox-active esters.

104 shifted absorptions that possess long-lived, redox-active excited states that are useful for various

105 Redox-active Fe(3+/2+) complexes represent a new design

106 "Green rust" (GR), a redox-active Fe(II)-Fe(III) layered double hydroxide, is

107 Redox-active ferrocenyl derivatives allowed for electroc

108 (OPFRs) coated on inert (NH(4))(2)SO(4) and redox-active FeSO(4) particles were systematically deter

109 In the presence of LE, TAPTA released a redox-active fragment whose oxidation at an electrode pr

110 ple-charge-state clusters are reminiscent of redox-active fullerenes (e.g., C60(n), where n = +1, 0,

111 PCM may itself contain redox-active functional groups that are capable of oxidi

112 oxygen-rich compounds bear a high density of redox-active functional groups, and their adsorption lea

113 The redox-active gold nanoparticles (raGNPs) enhanced the el

114 As a redox-active greenhouse gas, CH(4) degrades water or emi

115 ferential sorption of NOM components rich in redox-active groups (e.g., quinone, polyphenols) and (ii

116 e redox function of Grx1, the only cytosolic redox-active Grx in trypanosomes.

117 CCP-HATN integrated with the electrochemical redox-active HATN and the robust sp(2) carbon-carbon lin

118 spontaneous formation of host-guest POM@SWNT redox-active hybrid materials.

119 ailed to account for roughly half of NADPH's redox active hydrogen.

120 This result indicates that locking the redox-active IF-TTF units in close proximity promotes in

121 A series of uranyl compounds with the redox-active iminoquinone ligand have been synthesized,

122 Here we explore the tuning of redox active immobilised molecular metal-chalcoxide elec

123 In this work, dimeric structures of the redox-active indenofluorene-extended tetrathiafulvalene

124 The fact that phyllosilicates-which are not redox active-induced oxidative cleavage indicates that s

125 also support rapid electron transfer between redox active intercalators.

126 Tethering the redox-active iodophenyl subunit to a tetra-alkylammonium

127 We introduce a redox-active iron complex, Fe-PyC3A, as a biochemically

128 Prebiotic chemistry driven by redox-active iron hydroxide minerals on the early Earth

129 H67D mice displayed elevated redox-active iron levels in the brain by 32% compared to

130 bate through pro-oxidant chemistry involving redox-active labile iron and H2O2.

131 work, gold electrodes were modified using a redox-active layer based on dipyrromethene complexes wit

132 nols to aid the design and optimization of a redox-active leaving group for C(sp(3))-O arylation.

133 edent, we show here that Ni complexes of the redox-active ligand (tBu,Tol)DHP ((tBu,Tol)DHP = 2,5-bis

134 eries of rare earth compounds containing the redox-active ligand [{2-(tBuN(O))C6 H4 CH2 }3 N](3-) .

135 d intramolecular electron transfer between a redox-active ligand and redox-active metal.

136 A family of neodymium complexes featuring a redox-active ligand in three different oxidation states

137 ligand and 2,2':6',2"-terpyridine (tpy) as a redox-active ligand, chemical and electrochemical kineti

138 ydroxide complexes supported by a tridentate redox-active ligand.

139 ions on the reduction of cobalt complexes of redox active ligands and explored the reactivity of redu

140 ort that two-coordinate Cu(I) complexes with redox active ligands in coplanar conformation manifest s

141 ht into main group catalysis and the role of redox-active ligands during catalysis.

142 tron reduction, leading to a hypothesis that redox-active ligands play a key role in promoting reduct

143 standing how strong trans effect ligands and redox-active ligands work together to enable rapid elect

144 This contribution covers the fields of redox-active ligands, entatic state reactivity, energy c

145 Q6 (ubiquinone or CoQ6) and a mitochondrial redox-active lipid essential for electron and proton tra

146 iron bridging nitride complex supported by a redox-active macrocycle.

147 ciation between the {Mo(3)S(4)} core and the redox-active macrocyclic {P(8)W(48)} polyoxometalate (PO

148 oarenes and arylboronic acids catalyzed by a redox-active main-group catalyst (1,2,2,3,4,4-hexamethyl

149 using cyclic voltammetry by coupling of the redox active marker aminoferrocene.

150 ctron transport and ion intercalation in the redox active material.

151 Eumelanin is also a promising redox-active material for energy conversion and storage,

152 ieve a significantly higher concentration of redox-active materials and enhance the cell performance.

153 application is limited by low solubility of redox-active materials and poor performance at high curr

154 While redox-active materials based on conducting and semicondu

155 e of molecule designs for the development of redox-active materials for high-performance nonaqueous R

156 eries, made from inexpensive and sustainable redox-active materials, are promising storage technologi

157 n bonding and its effect on guest binding in redox-active materials.

158 or increasing the charge storage kinetics of redox-active materials.

159 gen Pseudomonas aeruginosa produces colorful redox-active metabolites called phenazines, which underp

160 e results show that modulating extracellular redox-active metabolites can influence the fitness of a

161 illustrate this point, we use the example of redox-active metabolites, and in particular phenazines,

162 pH-sensitivity of RZx (~ 53 mV/pH), secreted redox-active metabolites/compounds from whole cells are

163 acilitating the transfer of electrons to the redox active metal centers where O2 is reduced to water.

164 rials containing coordinatively unsaturated, redox-active metal cations.

165 , to our knowledge, of P.A. anion bound to a redox-active metal center.

166 lt, we now appreciate that COX relies on its redox-active metal centers (heme a and a3, CuA and CuB)

167 iven the fact that iron is the most abundant redox-active metal in the human body.

168 The deoxyribozymes do not require redox-active metal ions and function with a combination

169 acts with highly oxidizing radicals and bind redox-active metal ions in a similar manner as antioxida

170 we describe the combination of an archetypal redox-active metal sulfide cluster, Fe(4)S(4), with an o

171 er, the sub-200-femtosecond lifetimes of the redox-active metal-to-ligand charge transfer (MLCT) exci

172 n transfer between a redox-active ligand and redox-active metal.

173 en evolving electrocatalytic MOFs based on a redox-active metallo-linker, this work explores uncharte

174 Redox active metalloenzymes catalyse a range of biochemi

175 lyzed radical DNA cleavage reactions require redox-active metals and lead to mixtures of products.

176 er, in the human body there are also present redox-active metals such as iron, which is the most abun

177 s, including low abundance and high costs of redox-active metals, expensive separators, active materi

178 iolin and demonstrated that it is reversibly redox-active (midpoint potential -474.5 mV), indicating

179 dependent on the molecule structure and the redox-active mineral used, and much less on the preequil

180 oorganisms to gain energy by respiring solid redox-active minerals, also facilitates the wiring of ce

181 re we introduce a new strategy for preparing redox-active MOF thin-film electrodes with finely tuned

182 new prospects in the design and synthesis of redox-active MOFs with targeted properties for the desig

183 rated that this coating adds hydrophilicity, redox-active moieties, and additional mesoporosity, whic

184 adical production that is mediated by native redox-active molecular shuttles and active bacterial met

185 This small, redox-active molecule is now known to play an important

186 ed poly-(3-hexylthiophene) films and a model redox-active molecule, ferrocenedimethanol.

187 effectively detected using unmodified SPGEs, redox active molecules namely Hoechst-33258 and a portab

188 transfer, ET, from a conductive electrode to redox-active molecules at fixed positions within the ele

189 he quantitative controlled delivery of ionic redox-active molecules from a nanopipette to a substrate

190 ial system to explore the rational design of redox-active molecules in nonaqueous systems.

191 Although redox-active molecules often display multiple redox stat

192 Phenazines are a class of redox-active molecules produced by diverse bacteria and

193 underlying electrode system is accessible to redox-active molecules through the hydrophilic polymeric

194 redox sensing, we found that antioxidant and redox-active molecules were capable of reducing the expr

195 However, new organic redox-active molecules with good chemical stability and

196 Organic rechargeable batteries, composed of redox-active molecules, are emerging as candidates for t

197 the high selectivity towards nanometer-sized redox-active molecules, enable efficient and stable oper

198 molecular interactions between two different redox-active molecules.

199 The multi-redox active MPT undergoes four chemically and electroch

200 but also demonstrate that deeply submerged, redox-active nanoparticles could be entirely accessible

201 nstrated by controlled assembly of POM-based redox-active nanoparticles.

202 NT) is featured with abundant pai-conjugated redox-active naphthalene diimide units, a robust cyclic

203 al covalent organic cage consisting of three redox-active naphthalene-1,4:5,8-bis(dicarboximide) (NDI

204 attribute of a particular microbial strain, redox-active natural products likely play fundamental, u

205 Unfortunately, the redox-active nature of metal cofactors makes them especi

206 es that facilitate voltammetric detection of redox active neurochemicals in a multianalyte solution.

207 is approach could provide a general entry to redox-active NHC-CDI adducts and their persistent radica

208 actor ligands: Hemilabile, MN2S2 ligands and redox-active, nitrosyl ligands, whose interplay guides t

209 M. barkeri cells and redox-active, nonenzymatic soluble organic compounds in

210 Redox-active organic materials have been considered as o

211 Redox-active organic molecules have drawn extensive inte

212 Redox-active organic molecules such as anthraquinone-2,6

213 strategy is reported for the development of redox-active organic semiconductors based on donor-accep

214 Combined with recycling solutions, redox-active organic species could decrease the pressure

215 The implementation of redox active organics in nonaqueous redox flow batteries

216 When oligomeric redox-active organics (RAOs) were paired with microporou

217 n mechanisms for all five classes of aqueous redox-active organics and organometallics for which cycl

218 sed molecules represent a class of promising redox-active organics for potential grid-scale energy st

219 tration of surface engineering of functional redox-active organometallic molecule can be efficient in

220 g cluster that synthesizes tricholignan A, a redox-active ortho-hydroquinone.

221 new class of easily prepared, versatile, and redox-active oxido clusters that should contribute to an

222 ion and (ii) the production and secretion of redox-active, P. aeruginosa-produced phenazines, which r

223 motion of mixed-valence interactions between redox-active, pai-conjugated scaffolds is of interest wh

224 The redox-active part of the systems studied has the composi

225 anism of long-distance electron transfer via redox-active particulate natural organic matter (NOM) is

226 Rather, Sfh5 is a redox-active penta-coordinate high spin Fe(III) hemoprot

227 d have been only partially oxidized and thus redox-active, perhaps able to promote prebiotic chemical

228 ing initial stages of infection, Pa produces redox-active phenazine metabolites, including pyocyanin

229 This property is shared by other redox-active phenazines produced by P. aeruginosa.

230 er the electrons to conducting anode via the redox active pheromone lipoproteins localized at the cel

231 lementation and relevance of cooperating and redox-active pincer ligands within the mechanistic scena

232 tic generation of ROS in vivo after inhaling redox-active PM species (oxidative potential, OP).

233 level due to self-charge injection into the redox active polymeric system.

234 raised much attention as organocatalysts and redox active polymers.

235 These redox-active polymers are strongly bound to electrode su

236 e first time the effectiveness of asymmetric redox-active polymers for integrated reactive separation

237 s achieved using an asymmetric design of two redox-active polymers, poly(vinyl)ferrocene (PVF) and po

238 ith (-)-epigallocatechin-3-gallate (EGCG), a redox-active polyphenol from green tea, for 32 consecuti

239 nic from simulated groundwaters at pH 8 by a redox-active polyvinylferrocene (PVF)-functionalized ele

240 Furthermore, it is likely that a redox-active precipitate formed in the ZVI-amended bioca

241 A new metal oxide framework based on the redox-active Preyssler anion linked with Co(H(2)O)(4)(2+

242 res functionalized with different numbers of redox-active probes encapsulated within their cavity, ei

243 and electrochemical interrogation of a novel redox active progesterone derivative progesterone thiose

244 observed antioxidant protection involve both redox active properties of P. trunciflora components, as

245 ool by utilizing novel bioelectrode based on redox active protein hemoglobin (Hb) has been offered he

246 Several cytoplasmic and membrane-associated redox-active protein genes were differentially regulated

247 It has been shown recently that many non-redox-active proteins are good electronic conductors, th

248 ioelectronics research has mainly focused on redox-active proteins because of their role in biologica

249 in engineering approaches aimed at designing redox-active proteins for diverse biotechnological appli

250 ing in gene mutations, altered expression of redox-active proteins, iron metabolism, and DNA repair,

251 measurements of the conductance of three non-redox-active proteins, maintained under potential contro

252 esent an electrochemical sensing platform of redox-active pyocyanin using transparent carbon ultramic

253 Iron complexes bound by redox-active pyridine dialdimine (PDAI) ligands catalyze

254 Coordination of FeCl3 to the redox-active pyridine-aminophenol ligand NNO(H2) in the

255 c, but in complex I the binding site for its redox-active quinone headgroup is approximately 20 A abo

256 However, the existing works require mixing redox-active reagents in the solution which can interfer

257 lts illustrate a new mode of sensors wherein redox active recognition units are voltage-activated to

258 adding photoactive, catalytically active, or redox-active recognition sites, or even charges and dipo

259 The eDMA allows for the detection of redox-active reporter molecules irrespective of their el

260 ting between VER and heme group suggest that redox active residue C227 of GraS participates in the in

261 s to this generalization are the presence of redox-active residues (such a triphenylamine or pyrene).

262 (RBD1), a PSII assembly factor containing a redox-active rubredoxin domain and a single C-terminal t

263 tion in meta-selective processes) and form a redox active ruthenium species, to enable site-selective

264 rochemical methodology for XEC that utilizes redox-active shuttles developed by the energy-storage co

265 alysis as a generic platform to target other redox-active side chains for native conjugation.

266 ly(ferrocenylsilane) backbone of alternating redox-active, silane-bridged ferrocene units and tetraal

267 However, the redox active site utilization of imide electrodes remain

268 s, which render the efficient utilization of redox active sites (82.9%), excellent structural stabili

269 16 mA h g(-1) , with high utilization of its redox-active sites and superb cycling stability (91 % af

270 e low electrochemical accessibility of their redox-active sites has limited COF-based devices either

271 Results provide further evidence that redox-active sites on soil surfaces drive ground-level N

272 designable topologies, and defined catalytic/redox-active sites), which have motivated increasing eff

273 chemically mediated carbon capture utilizing redox-active sorbents such as quinones is emerging as a

274 system, where a 70 muL droplet containing a redox active species (ferrocyanide) is sandwiched betwee

275 r electrodes with kinetic selectivity toward redox active species and help guide synthetic approaches

276 methane, and we looked for concentrations of redox-active species ([SO(4)] >= 6; [Fe] >= 0.3) to dete

277 c efficiency due to the high permeability of redox-active species across the battery's membrane.

278 tron transfer kinetics and thermodynamics of redox-active species encapsulated into supramolecular as

279 is supported on a surface, the diffusion of redox-active species to the electrode is partially block

280 abels catalyzed the oxidation of a dissolved redox-active species, which was detected at a soft micro

281 are abundant in argillaceous rocks as their redox-active structural iron may control the sorption me

282 chanism of ROS generation, we tested several redox-active substances, such as 9,10-phenanthrenequinon

283 exploits intramolecular coupling of multiple redox active substituents within a single molecule.

284 molecules were designed to contain a pair of redox-active substituents, quinone and hydroquinone grou

285 ine (SubPz) core with other chromophores and redox active systems has been examined.

286 Because polyphenols are redox-active, they can be used as a probe to detect AuNP

287 alently functionalized graphene oxide with a redox active thiourea-formaldehyde polymer, yielding a m

288 The redox-active TM locating at octahedral site guarantees a

289 tively charged, positively charged, neutral, redox-active) to abiotically fragment a well-characteriz

290 gly donating pyridyl-carbene ligand with the redox-active tpy ligand proves to be useful in boosting

291 regulator, SurR, is among a handful of known redox-active transcriptional regulators.

292 uinone species and depend on the presence of redox-active transition metal ions such as iron and copp

293 opping typically involves spatially arranged redox-active tryptophan or tyrosine residues.

294 ctron equilibrium distribution among the two redox active type 1 (T1) Cu sites and the TNC.

295 The first contained a redox-active Tyr in beta subunits (F41Y), a substitution

296 two maquette systems containing one pH- and redox-active tyrosine (alpha(3)Y and peptide A), and two

297 Redox-active tyrosines (Ys) play essential roles in enzy

298 the relative conformational dispositions of redox-active units in macrocycles are key to achieving h

299 a given residue to be simultaneously pH- and redox-active, we have employed our methodologies to stud

300 provide new tools for mechanistic studies on redox-active Ys in proteins and on functional and aberra