ライフサイエンスコーパス: reduction potential

1 ompound II pKa in diminishing the compound I reduction potential.

2 s a small DeltaEm of +18 mV on the Mo(VI/IV) reduction potential.

3 c) and is generally thought to increase the reduction potential.

4 flux/emission were assessed to estimate CH4 reduction potential.

5 ated T cells, consistent with their measured reduction potential.

6 hich is attributed to its high excited-state reduction potential.

7 a reducing agent because of its low standard reduction potential.

8 hiol metabolites and the buildup of cellular reduction potential.

9 to the free energy of reduction and thus the reduction potential.

10 mous with a high chemical reactivity and low reduction potential.

11 differences attributed to acceptor size and reduction potential.

12 over a range of pH(MER) at constant applied reduction potential.

13 ical anions that lie outside of the catalyst reduction potential.

14 for the P450-II O-H bond strength and P450-I reduction potential.

15 stidine is hydrogen-bonded to N2, tuning its reduction potential.

16 nly in the presence of substrates with a low reduction potential.

17 he Fe(IV) and Ce(IV) centers have comparable reduction potentials.

18 hoto)redox chemistry is limited by their low reduction potentials.

19 on potentials, pKa values, and 2 e(-)/2 H(+) reduction potentials.

20 elation between the 1 e(-) and 2 e(-)/2 H(+) reduction potentials.

21 VIEs), reorganization energies, and standard reduction potentials.

22 ive sites are generally found to lower their reduction potentials.

23 irectly to the quantum chemically calculated reduction potentials.

24 y, in good agreement with the order of their reduction potentials.

25 basis for determination of (L)Pd(II)(OAc)(2) reduction potentials.

26 evant properties, such as bond strengths and reduction potentials.

27 ion is greater for anthraquinones with lower reduction potentials.

28 uest electron-acceptor molecules with varied reduction potentials.

29 e yellow to dark blue electrochromism at low reduction potentials.

30 tate reactivity model, and 2) the Mn(III/IV) reduction potentials.

31 tematically varying pH (5.0 to 8.0), applied reduction potentials (-0.53 to -0.17 V vs SHE), and Fe(2

32 tials are expected to be high, we find a low reduction potential, 0.38 V (vs Normal Hydrogen Electrod

33 idyl complexes, and impressive excited-state reduction potentials ((1)E(-/)* = 1.59 V; (3)E(-/)* = 1.

34 al calculations that predict a very negative reduction potential (-1.37 V vs SCE) for the formation o

35 ty of the abiotic FnY pKa's (6.4 to 7.8) and reduction potentials (-30 to +130 mV relative to Y at pH

36 itionally, pssm2-Fd exhibited a low midpoint reduction potential (-336 mV versus a standard hydrogen

37 an activity that is attributable to the high reduction potential (354 mV vs SHE) of the copper site.

38 ed with analogous nonaqueous solvents with a reduction potential 450 mV positive of onset and 90% Far

39 translated into an estimated radiation dose reduction potential (+/-95% confidence interval) of 16%

40 these factors can lead to a 200 mV shift in reduction potential across these peptides, which is dete

41 for both minerals), indicating that the clay reduction potential also influences its reactivity.

42 unds demonstrate a linear dependence between reduction potential and acidity with a slope of approxim

43 The reduction potential and capacity of various polycyclic a

44 th, systematic elevation in the ground-state reduction potential and decrease in the HOMO-LUMO gap wa

45 = -1.22 V versus Fc/Fc(+) (E(0)(f) = formal reduction potential and Fc = ferrocene).

46 encing the Cu site directly by adjusting its reduction potential and geometry.

47 f phenyl groups about the fulvene raised the reduction potential and helped to stabilize the electroc

48 aterial displays a particularly high initial reduction potential and is further stable for at least 5

49 With the measured reduction potential and pK(a), the O-H bond dissociation

50 om the reduction of ZnO is a function of the reduction potential and presents a sigmoidal curve that

51 s tuning of important properties such as the reduction potential and solubility by adding functional

52 in a linear free energy relationship between reduction potential and the Hammett substituent constant

53 There was a strong correlation between reduction potential and the quantity of 4-ClNB reduced b

54 utation approach to determine their standard reduction potentials and aqueous solubility.

55 s with a wide range of excited triplet state reduction potentials and CDOM oxidized TMPD at near diff

56 Reduction potentials and free energy barriers calculated

57 directly correlates with the Mn/Fe cofactor reduction potentials and is inversely related to divalen

58 Computational methods for calculating reduction potentials and pKa's for molecular electrocata

59 ew synthetic method that avoids incompatible reduction potentials and rates would be critical to grow

60 orial ligands were observed to exhibit lower reduction potentials and slower reduction rates than ana

61 In all cases, the reduction potentials and the calculated LUMO-positions a

62 O(2)-derived reduced species, such as pK(a), reduction potential, and BDFE; these may be relevant to

63 tion analyses of CB1190 abundance, oxidation-reduction potential, and dissolved oxygen measurements i

64 eversibility without dendrite formation, low reduction potentials, and high specific capacities.

65 ation equilibria, copper binding affinities, reduction potentials, and nitrite reductase activities o

66 rly identical effective conjugation lengths, reduction potentials, and pi* orbital energies and deloc

67 al [4Fe-4S] cluster is shown to have a lower reduction potential ( approximately <-450 mV) than the o

68 cient n-doping of host semiconductors, whose reduction potentials are beyond the thermodynamic reach

69 Although Mn(III)/Mn(II) and Mn(IV)/Mn(III) reduction potentials are expected to be high, we find a

70 Questions remain as to what the reduction potentials are from a life cycle perspective a

71 The quantum chemically calculated reduction potentials are in excellent agreement with exp

72 ation resolved the tetrathionate/thiosulfate reduction potential as +198 +/- 4 mV versus SHE.

73 p blue LED source, can exhibit excited-state reduction potentials as high as 3 V and can participate

74 lectron reduction of phenol derivatives with reduction potentials as negative as approximately - 3 V

75 atic interface enabled direct measurement of reduction potentials associated with each metallocofacto

76 tion correlated well with the standard state reduction potential at pH 7.0 (E degrees 'H) of all of t

77 and replacements at AuxII also show that the reduction potential at this site can be manipulated by c

78 on published values of the nonstandard state reduction potentials at pH 7.0 (E'H) showed that the abi

79 All triads show reduction potentials at similar or less negative potenti

80 Although RSNOs possess relatively negative reduction potentials, B(C(6) F(5) )(3) coordination incr

81 Dose reduction potentials based on both reading sessions were

82 rature for contaminants and relative mineral reduction potentials based on ECRP measurements, qualita

83 ation is proposed to decrease the Mn(III/II) reduction potential below that of type 1 Cu(II/I) by for

84 esium or rubidium ions) exhibit an effective reduction potential below the standard reduction potenti

85 this Mn catalyst operates at a lower applied reduction potential but requires the presence of a weak

86 e primary coordination sphere and tuning its reduction potential by deleting a hydrogen bond in the s

87 6-difluorophenyl)porphyrinate) increased its reduction potential by more than 890 mV, experimentally

88 (C(6) F(5) )(3) coordination increases their reduction potential by over 1 V into the physiologically

89 Measuring the reduction potentials by spectroelectrochemical redox tit

90 In this Review, we illustrate how the reduction potential can be increased by using the free e

91 [7] complexation of pyridinium salts induced reduction potential changes ranging between +50 and -430

92 aster heme dissociation rate and has a lower reduction potential compared to wild-type myoglobin.

93 energy light and possess lower oxidation and reduction potentials compared to their pyrrolic analogue

94 opulation and biochemical parameters, as the reduction potential, could be envisaged.

95 quivalent nitro groups were identified whose reduction potential depends upon their respective locati

96 Part of the reduction potential difference of the T1 sites in high v

97 afforded an estimate of the chlorine formal reduction potential E degrees (Cl(*/-)) = 1.87 V vs NHE

98 The pH dependence of the reduction potential E degrees for a metalloprotein indic

99 ion provided an estimate of the Br(*) formal reduction potential E(Br(*)/Br(-)) = 1.22 V vs SCE in ac

100 A reliable estimate for the normal reduction potential E(o) is derived for the electrochemi

101 lize experimental aqueous-phase one-electron reduction potential ( E(H)(1)) of NAC as a predictor, an

102 The reduction potential (E degrees ') is a critical paramete

103 While heme reduction potential (E degrees ') of different HCO types

104 (NAd) exhibits an extremely low one-electron reduction potential (E degrees (red) = -1.98 V vs [Cp(2)

105 , methods by which the enzyme fine-tunes the reduction potential (E degrees ) of its active site and

106 y changing either the pKa of the base or the reduction potential (E degrees ) of the oxidant.

107 derscore the importance of the excited-state reduction potential (E(-/*)) parameter as a general desi

108 In addition, we show that the heme reduction potential (E(m)(0)) has a regulatory role in c

109 nation of equilibrium protein disulfide bond reduction potentials (E degrees ') by isotope-coded cyst

110 as allowed the first determination of formal reduction potentials (E degrees ') for a Y residing with

111 le model and is used to determine the formal reduction potential, E(0)'.We observed that E(0)' is a s

112 the metal which has the most positive formal reduction potential, E(0), or exhaustively deplete it fr

113 a function of the solution pH value and the reduction potential, E(H), of the interfacial Fe(3+)/Fe(

114 M(-1) cm(-1), at 450 nm and an excited-state reduction potential, E(Ir(+*/0)) = 1.76 V vs NHE.

115 tation and the experimental (and calculated) reduction potential (E1/2) of complexes 1, 3, and 5, the

116 Electrochemical studies reveal that the reduction potentials (E1/2) span a window of 500 mV and

117 dynamic CRPs were developed to determine the reduction potentials (ECRP) of suspended minerals by spe

118 esults were in agreement with changes in the reduction potential (EH) of the Fe(III) oxide/Fe(II)aq r

119 Measuring the oxidation-reduction potential (Eh) requires an interface that is n

120 We measured reduction potential (EH) values in solutions containing

121 ay-Fe(II) in the clay minerals and different reduction potentials (Eh) of the clay minerals.

122 ons to fundamental redox properties, such as reduction potentials (EH).

123 This analysis yielded standard reduction potential (EH0) values of 768 +/- 1 mV for the

124 Molecular tuning of reduction potentials enabled the extent of hole transfer

125 ccur vigorously due to the low oxidation and reduction potential energies of the ITO thin films at hi

126 low pKR+ values (pKR+ < 5) and less negative reduction potentials (Ered > -0.5 V).

127 i or Mn substitution is due to the different reduction potential for anionic redox.

128 tent with the more favorable electrochemical reduction potential for PDIs in the quadruplex relative

129 The estimated reduction potential for the [W(CNIph)6](+)/*W couple is

130 the anionic semiquinone and a remarkably low reduction potentials for both the oxidized/semiquinone (

131 clusters and the active site H-cluster, and reduction potentials for each cluster were determined.

132 ential, when considering the distribution of reduction potentials for the compounds.

133 for this reaction (log(k)) and one-electron reduction potentials for the NAC (E1NAC) normalized to 0

134 ant contribution to the observed decrease in reduction potential found experimentally in DNA repair p

135 This reduction-potential-gated strategy enables access to res

136 action pairs, the enzyme exhibits a distinct reduction-potential gradient along the same aromatic res

137 otential multicopper oxidases (MCOs) have T1 reduction potentials >600 mV (vs normal hydrogen electro

138 t effects on the 1 e(-) versus 2 e(-)/2 H(+) reduction potentials, have important implications for de

139 e to productively engage aryl chlorides with reduction potentials hundreds of millivolts beyond the p

140 air of electrons is acquired at intermediate reduction potential (i.e. intermediate reducing power),

141 erric (or Fe(IV)O(Por(*))/Fe(III)OH(2)(Por)) reduction potential in aromatic peroxidase has allowed u

142 he compound II/ferric (or Fe(IV)O/Fe(III)OH) reduction potential in horseradish peroxidase and the tw

143 ammetry data demonstrate that the U(VI)/U(V) reduction potential in these complexes is modulated over

144 oach to determine "effective" biogeochemical reduction potentials in heterogeneous iron systems.

145 Regions with high reduction potential include India, Bangladesh, western E

146 r the discrepancy in calculated and observed reduction potentials, including surface adsorption of py

147 proteins remains a challenge due to the high reduction potentials involved and the reactive nature of

148 Despite its low reduction potential, it remains competent to oxidize Fe(

149 o, comparisons of [(L)Cu(II/I)](n+) compound reduction potentials (L = various N4 vs (DMA)N3S ligands

150 At the same time, the low reduction potentials lead to endergonic reduction steps

151 We also discuss how changes in the oxidation/reduction potential may affect the function of proteins

152 Comparison of ECRP with reduction potentials measured potentiometrically using a

153 We found that the one-electron reduction potential, measured for the deprotonated subst

154 iation we reported for the first time robust reduction potential measurements of reactive iron specie

155 ree basic chemical parameters: metal complex reduction potential, metal ion availability, and adsorba

156 We introduce the Precipitation Reduction Potential midpoint impact representing the cha

157 h ascorbate, which makes the electrochemical reduction potential more negative and shifts the equilib

158 SmI2(H2O)n reacts with substrates that have reduction potentials more positive than -2.21 V vs SCE,

159 Because of its position and pH-dependent reduction potential, N2 has long been considered a candi

160 ate cases, where the electron acceptor has a reduction potential near the oxidation potential of KOtB

161 Calculated one-electron reduction potentials, nonaqueous pKa's, reaction free en

162 onates the N-heterocycles that reduces their reduction potentials notably and on the other hand it ac

163 based dopant CN6-CP studied herein, with its reduction potential of +0.8 versus Fc/Fc+ and the lowest

164 capacity of lithium metal and has a negative reduction potential of -2.37 V vs. the standard hydrogen

165 ile solution with an estimated excited-state reduction potential of -3.45 V versus Cp2Fe(0/+).

166 by optical and EPR spectroscopies; it has a reduction potential of -370 mV vs the standard hydrogen

167 This stability and modest reduction potential of 0.99 V vs NHE is in part attribut

168 established, allowing for calculation of the reduction potential of 1 as -0.525 +/- 0.01 V vs Fc(+/0)

169 Despite having a similar reduction potential of 43-44% in 2100, the two types of

170 and 5H(2-) differ by about 4 units, and the reduction potential of 5H(-) is shifted anodically by ab

171 fashion as a single ensemble with a standard reduction potential of 650 mV.

172 nt and remarkably high Fe(III)-OH/Fe(II)-OH2 reduction potential of 680 mV vs Ag/AgCl at pH 5.2.

173 Over the same time, the reduction potential of all three suspensions increased b

174 raordinarily difficult because of the -1.9 V reduction potential of CO2.

175 x, correspondingly lowering the one-electron reduction potential of compound I, the active catalytic

176 In those states, the reduction potential of Cu increases, leading to the pres

177 The reduction potential of Cu(A)CcP is comparable to native

178 lance between ground-state and excited-state reduction potential of donor acceptor systems for effici

179 Computations indicate that the reduction potential of enolized RuBP (near 0.49 V) is co

180 veals that the energetic performance and GHG reduction potential of fast pyrolysis-derived fuels are

181 The metal ions alter the reduction potential of Fe4S4 in a favorable manner for p

182 Moreover, the risk reduction potential of foods was calculated by multiplyi

183 ction for strong C-H bonds, while the higher reduction potential of HS Fe(III)-OOH allows it to be ac

184 y, each metric was used to estimate the dose reduction potential of IR algorithms while maintaining i

185 ctive reduction potential below the standard reduction potential of lithium ions.

186 Herein, we report the ability to tune the reduction potential of metal-free phenothiazine-based ph

187 odify both NBT and TNBT, but only change the reduction potential of NBT after modification, (2) addit

188 s) and comprehensively evaluated the Nr-loss reduction potential of newer varieties (2000 and after)

189 ential MCOs is balanced by an ~100 mV higher reduction potential of NI due to the more positive prote

190 tentials less positive than the two-electron reduction potential of O2.

191 The reduction potential of PN from shipping strongly depends

192 -80 degrees C, allowing determination of the reduction potential of S as -1.17 V vs Fc(+/0).

193 nd SAFIRE and to estimate the radiation dose reduction potential of SAFIRE.

194 he life cycle environmental consequences and reduction potential of segregating fattening pig urine a

195 In addition, the reduction potential of SelS was determined to be -234 mV

196 nd molecules that are needed to maximize the reduction potential of SmI(2) is significantly smaller t

197 two of its major effects are increasing the reduction potential of SmI(2), and in the case of a liga

198 resembles HMPA in its ability to enhance the reduction potential of SmI2, and reactivity studies show

199 HMPA is known to increase the reduction potential of SmI2.

200 that there is no simple relation between the reduction potential of the active site and the catalytic

201 orrelation between the reaction rate and the reduction potential of the carbazole unit tethered to th

202 yl results in a positive shift of the formal reduction potential of the carbonyl couple.

203 bioreduced SWy-2 and NAu-2 correlated to the reduction potential of the clay (EH,clay, R2=0.95 for bo

204 ion of calcium in the OEC is to modulate the reduction potential of the cluster to allow electron tra

205 f NH groups leads to a positive shift in the reduction potential of the Co(I/0) couple, therefore dec

206 ial of both junction electrodes approach the reduction potential of the diazonium terminal groups.

207 The low reduction potential of the distal [4Fe-4S] cluster therm

208 electrophiles is strongly influenced by the reduction potential of the electrophile, which is respon

209 ty of the linking blocks greatly affects the reduction potential of the Fe(4)S(4) cluster and the ele

210 ely weak Fe(II) exudate complexes alters the reduction potential of the Fe(III)-Fe(II) redox couple,

211 c high spin heme per subunit with a standard reduction potential of the Fe(III)/Fe(II) couple of -233

212 ame similar to lactoperoxidase, the standard reduction potential of the Fe(III)/Fe(II) couple shifted

213 of the redox intermediates, and the standard reduction potential of the Fe(III)/Fe(II) couple, and we

214 erall order of activity correlating with the reduction potential of the formally Fe(III) dimeric dian

215 ating liver lesions and to estimate the dose reduction potential of the IR algorithm in question.

216 riving force for substrate activation at the reduction potential of the molecule, and impede access t

217 atalytic activity due to the decrease in the reduction potential of the photo-generated electrons wit

218 constants, but FOWA was used to estimate the reduction potential of the previously undetected exo-pro

219 The reduction potential of the protein for low and high surf

220 otein film electrochemistry that defines the reduction potential of the S4O6(2-)/S2O3(2-) couple.

221 DMABN(*+), which was attributed to the lower reduction potential of the SDZ-derived radical compared

222 4-N4-Ts)(OTf)2], which has the most positive reduction potential of the series.

223 ing to the enzyme active site attenuates the reduction potential of the substrate, enabling single-el

224 osubstrate ATP, ACATs raise the Co(II)/Co(I) reduction potential of their cob(II)alamin [Co(II)Cbl] s

225 or 1,4-naphthoquinone, is carried out at the reduction potential of their first voltammetric peak, co

226 nificantly higher than the estimated average reduction potential of typical (3)CDOM* samples, these r

227 (F-Tyr) analogues that modulated the pKa and reduction potential of Y21 by 3.5 pH units and 200 mV, r

228 The reduction potential of ZnO NPs is a strong function of 1

229 Reduction potentials of 3-nitrotyrosinate (NO2YO(-))-mod

230 retically calculated electron affinities and reduction potentials of [-P-S-S-P-] and O2.

231 ed out to probe the 1 e(-) and 2 e(-)/2 H(+) reduction potentials of a number of common quinones.

232 viologen (BV), which has one of the highest reduction potentials of all electron-donor organic compo

233 Agreement between half-cell reduction potentials of different redox couples provides

234 hat this is not due to a perturbation of the reduction potentials of either the heme or the molybdenu

235 th and the position of the heteroatom on the reduction potentials of encapsulated guests.

236 rality of the above relationship between the reduction potentials of heterometallic oxido clusters an

237 ) suggest a general relationship between the reduction potentials of heterometallic oxido clusters an

238 for its unidirectional behavior is that the reduction potentials of its electron-relaying FeS cluste

239 e the geometry of ion pairing and allows the reduction potentials of molecules to be determined in th

240 In contrast, the formal reduction potentials of NDI derivatives in solution are

241 ue to its strong basicity coupled with large reduction potentials of nearby V(V) ions.

242 ceptor separations decreased with increasing reduction potentials of p-benzoquinones.

243 he cNORs, the calculations show that the low reduction potentials of the active site cofactors are op

244 The computational studies show that the reduction potentials of the active site cofactors in the

245 mino acid sites, although the unusually high reduction potentials of the adjacent Fe-S centers in thi

246 and plays a critical role in determining the reduction potentials of the electrons transferred to the

247 f C60 in nonpolar solvents and increases the reduction potentials of the entrapped fullerene.

248 etween the deposited concentrations, and the reduction potentials of the fission product oxide specie

249 heir relative contributions, dictated by the reduction potentials of the flavin cofactor and the subs

250 31G** basis set, providing a distribution of reduction potentials of the naturally occurring quinones

251 erties correlate with the differences in the reduction potentials of the respective Cu(II) centers.

252 The Ir(III/IV) reduction potentials of the two isomers differ by 340 mV

253 mainly due to the vastly different standard reduction potentials of the two metals and high oxophili

254 The reduction potentials of these clusters and other related

255 As a result, life-cycle GHG emission reduction potentials of these ethanol types, though stil

256 The reduction potentials of these novel Lewis acid adducts w

257 Supramolecular modulation of reduction potentials of two series of bis(pyridinium)alk

258 The origin of the dependence of the reduction potential on the surface concentration is inve

259 spin delocalization, and anodic shift of the reduction potential only for 1S .

260 idence for carbonate affecting Fe(3+)/Fe(2+) reduction potentials or the mechanism of nitrobenzene re

261 rmal potential of the two standard oxidation-reduction potential (ORP) calibrants, ZoBell's and Light

262 organic carbon (TOC) amounts, and oxidation-reduction potential (ORP) displayed significant correlat

263 videnced by the parallel trends in oxidation-reduction potentials (ORP) and Tc dissolution kinetics.

264 ursors; SiCl4 and GeCl4 in an Ar flow with a reduction potential over -1.0 V (vs RHE).

265 in patients with a renal indication for dose reduction (potential overdosing) and use of a reduced do

266 134 different quinones, probing their 1 e(-) reduction potentials, pKa values, and 2 e(-)/2 H(+) redu

267 , but none have been reported to demonstrate reduction potentials powerful enough to reduce benzene.

268 Radiation dose reduction potential ranged from 56% to 60% and from 4% t

269 aturated hydrocarbons and alkyl halides with reduction potentials ranging from -1.6 to -3.4 V vs SCE.

270 for characterizing PCET reactions, including reduction potentials, redox-dependent p K(a) values, and

271 s hypothesized that the temporal increase in reduction potential results from clay mineral dissolutio

272 e having spectroscopic characteristics and a reduction potential similar to those of PioC, is unable

273 The longer oligomers have reduction potentials similar to those reported for pyrid

274 Electrochemical studies reveal that the reduction potentials span a window of 700 mV and are dep

275 Para-quinones with high reduction potentials, such as DDQ and chloranil, are wid

276 take advantage of organic cations with lower reduction potential than lithium to build an electricall

277 at elevated temperatures, has a larger load reduction potential than manure storage (up to 4.6 log u

278 ic acid (DOTA) tetra(glycinate) has a higher reduction potential than most Eu(II) chelates reported t

279 molecular orbitals and >0.2 V more negative reduction potentials than [Cu(II) (TPMA)Br](+) , indicat

280 rate the insight about protein tuning of the reduction potential that is provided by the binding ther

281 le point of zero net current denotes the CO2 reduction potential that varies with pH according to the

282 Each of these complexes, with Co(III/II) reduction potentials that span nearly 400 mV, mediate hi

283 However, at this reduction potential, the formation of 1((I))-CO restrict

284 With a high specific capacity and a low reduction potential, the Li-metal anode has attracted ex

285 Owing to their low reduction potentials, the inexpensive organic dye eosin

286 based ligands modulate the (L)Pd(II)(OAc)(2) reduction potential, thereby tuning the ability of Pd(II

287 With their broad optical absorption and low reduction potentials, these materials could be candidate

288 s reduce emissions by 45 +/- 9% with further reduction potential to 2050.

289 ' rate constants correlate with one-electron reduction potential values of the NACs (EH,NAC1) accordi

290 of fluoride into the framework to raise the reduction potentials via an inductive effect.

291 s carried out by amperometry method in which reduction potential was fixed at -0.77 V vs. Ag/AgCl.

292 sites and thus having varying Eu(III)/Eu(II) reduction potentials were prepared.

293 Thus, oxidation and reduction potentials were split by up to 210 mV, and mod

294 Lightweighting has the greatest GHG emission reduction potential when implemented in the near-term, w

295 sentially no effect on the overall Mo(VI/IV) reduction potential, whereas the H1163A and H1184A varia

296 se of an intrinsic redox probe, working in a reduction potential, which avoids potential interference

297 a weaker influence of pyridines on the iron reduction potential, which may be the basis for the obse

298 has been fine-tuned to span a wide range of reduction potentials while leaving the metal binding sit

299 ics are thermodynamically estimated from its reduction potential, while the remainder of the model is

300 toredox cycles provide access to an extended reduction potential window capable of engaging a wide ra