ライフサイエンスコーパス: reductive elimination

1 K-enolate generated in situ, and subsequent reductive elimination.

2 merization and a carbon-halogen bond-forming reductive elimination.

3 -C bond, followed by migratory insertion and reductive elimination.

4 sing Ir(ppy)(3) supports a turnover-limiting reductive elimination.

5 to Ni(III) , however, is required to trigger reductive elimination.

6 ide ligand prior to an inner-sphere SN2-type reductive elimination.

7 ting step from C-H oxidative addition to C-B reductive elimination.

8 on-rich diarylamines undergo faster rates of reductive elimination.

9 "upper" ring of the ligand slows the rate of reductive elimination.

10 ability of the amido complex with respect to reductive elimination.

11 he most widespread are M-H homolysis and R-H reductive elimination.

12 alladium followed by C-C bond-forming [3,3']-reductive elimination.

13 s can undergo both C(aryl)-X and C(aryl)-CF3 reductive elimination.

14 lenging, turnover-limiting C(sp(3))-C(sp(3)) reductive elimination.

15 appears to be an isomerization prior to C-B reductive elimination.

16 Ni(III) species that readily participate in reductive elimination.

17 ation and turnover-limiting, propene-forming reductive elimination.

18 undergo high yielding aryl-CF3 bond-forming reductive elimination.

19 ediate wherein the stereodetermining step is reductive elimination.

20 selectivities for C(aryl)-X and C(aryl)-CF3 reductive elimination.

21 n, or by insertion into the M-P bond and C-H reductive elimination.

22 tion, beta-hydride elimination, and C-H bond reductive elimination.

23 Caryl-I reductive elimination over Caryl-CF3 reductive elimination.

24 -coordinate intermediate that undergoes slow reductive elimination.

25 se eventually leads to poly-naphthalenes via reductive elimination.

26 ArAr' intermediate, which then undergoes C-C reductive elimination.

27 cle involving rate-limiting C-C bond-forming reductive elimination.

28 ted Pd(III) dimer ultimately gives ArCl upon reductive elimination.

29 nometallic processes, oxidative addition and reductive elimination.

30 irecting group to facilitate the C(sp(3))-Ph reductive elimination.

31 around the Au(I) center and a rate-limiting reductive elimination.

32 t directs oxidative addition and facilitates reductive elimination.

33 ound alkyls such as alkyne insertion and C-H reductive elimination.

34 Sonogashira coupling, amidopalladation, and reductive elimination.

35 eps: radical addition-SET-oxidative addition-reductive elimination.

36 n and transmetalation, and CCl(3) CN-induced reductive elimination.

37 te transmetallation and the C-C bond-forming reductive elimination.

38 y to bind and facilitate C(sp(3) )-C(sp(3) ) reductive elimination.

39 wed by intramolecular oxidative addition and reductive elimination.

40 rior to undergoing irreversible inner-sphere reductive elimination.

41 erentially to any other challenging C-O bond reductive elimination.

42 he photocatalyst is only involved to trigger reductive elimination.

43 ate at reducing the barrier to Csp(3)-Csp(3) reductive elimination.

44 fic allyl-isomerization and C-C bond-forming reductive elimination.

45 ially redox-neutral fashion, as opposed to a reductive elimination.

46 ation, carbopalladation of a pai-bond and/or reductive elimination.

47 , and directly delivers the intermediate for reductive elimination.

48 eversible migratory insertion to give, after reductive elimination, 2,3-dihydropyridine products in g

49 e nitroalkane enolates is attributed to slow reductive elimination, a consequence of the hard nature

50 e elusive synthesis of diethyl ether through reductive elimination, a remarkable feature currently be

51 ia glutathione-dependent alkyltransferase or reductive elimination activities.

52 ts is determined in the subsequent competing reductive elimination and beta-hydride elimination steps

53 and leads to distinct steric control in the reductive elimination and beta-hydride elimination trans

54 etic transformation involving intramolecular reductive elimination and concomitant PMe3 elimination,

55 4)PPh(2))(ZnMe)] (5), that is formed via C-H reductive elimination and features unsaturated Ru and Zn

56 eta(5)-C(5)Me(5))Rh(bq)H] induced C(sp(2))-H reductive elimination and generated the bimetallic compl

57 Formally a six-electron reductive elimination and oxidative addition, respective

58 he arene by Au(III) precedes product-forming reductive elimination and subsequent cycle-closing reoxi

59 Pd(II) chemistry includes transmetallation, reductive elimination and the field of C-H activation re

60 reduction, where two electrons come from H2 reductive elimination and the other two come from iron o

61 ither ligand-coupling or S(N)2 displacement (reductive elimination), and this is shown to be substrat

62 me ester to enable the C-C bond formation by reductive elimination, and intramolecular condensation o

63 with subsequent migratory alkyne insertion, reductive elimination, and intramolecular oxidative addi

64 le-metal two-electron oxidative addition and reductive elimination are common fundamental reactions f

65 Oxidative addition and reductive elimination are defining reactions of transiti

66 d iron(II)-SciOPP species that form prior to reductive elimination are identified, where both species

67 s and fluorine effect-induced regioselective reductive elimination are independently involved to enab

68 ntermediates by oxidative addition and their reductive elimination, are much better understood.

69 nsformations, such as oxidative addition and reductive elimination, are two-electron processes and es

70 l as less electron-rich ligands accelerating reductive elimination as a nitronate-specific mechanism.

71 ide-bridged structures establishes binuclear reductive elimination as a viable mechanism for photogen

72 r the nitrogen extrusion followed by Au(III) reductive elimination as the key step.

73 The energetic span analysis reveals the reductive elimination as the turnover determining step f

74 l analogue underwent C(sp(3))-N bond-forming reductive elimination at 140 degrees C in DMF to afford

75 g oxidative addition, ligand metathesis, and reductive elimination at a C(s)-symmetric phosphorus tri

76 ower barrier for C-CN oxidative addition and reductive elimination at benzylic positions in the absen

77 he steric environment can be used to promote reductive elimination at carbon centers.

78 system has been shown to favor aryl thiolate reductive elimination at elevated temperatures and in so

79 to a lower-energy HOMO, as well as high C-O reductive elimination barriers, which become rate-determ

80 iarylplatinum(II) complex accelerates biaryl reductive elimination by a factor of 64,000.

81 Several reductive elimination decomposition pathways of catalyst

82 monstrated protonolysis, oxidatively induced reductive elimination, deoxygenation, and elimination re

83 that undergoes at -90 degrees C accelerated reductive elimination enantioselectively and exclusively

84 Furthermore, the reductive elimination event was probed with (18) O-label

85 nylation process, and accelerating the final reductive elimination event.

86 ies on precise timing of transmetalation and reductive elimination events.

87 on of products resulting from subsequent B-C reductive elimination (for both indium and thallium).

88 tion of aryl iodides into acid chlorides via reductive elimination from ((t)Bu3P)(CO)Pd(COAr)Cl.

89 C-C reductive elimination from [PdL(2)(C(6)F(5))(2)] to form

90 We report a C-F reductive elimination from a characterized first-row ary

91 mechanism for this reaction proceeds via C-N reductive elimination from a Cp*Ir(V) nitrenoid complex

92 ign of specialized ligands, which facilitate reductive elimination from a destabilized metal center.

93 However, carbon-carbon bond reductive elimination from a limited number of Au(III) c

94 key C(alpha)-C(sp(3) ) bond is generated by reductive elimination from a palladium intermediate.

95 mpeting sp(3)-C-N and sp(3)-C-F bond-forming reductive elimination from a Pd(IV) fluoro sulfonamide c

96 of an unprecedented and fast aryl C(sp(2))-X reductive elimination from a series of isolated Pt(IV) a

97 es are formed selectively through a stepwise reductive elimination from a tetraplatinum precursor and

98 between the two aryl rings result in faster reductive elimination from Ar-Au(X)-Ar and lead to the p

99 to Au(I), and remarkably fast Caryl-CF3 bond reductive elimination from Au(III) cations.

100 ry of a borane-catalyzed formal C(sp(3))-CF3 reductive elimination from Au(III) that accesses these c

101 orming step of the coupling reactions is the reductive elimination from cationic gold(III) intermedia

102 nd and conformational freedom on the rate of reductive elimination from diaryl-gold(III) species.

103 to undergo a subsequent transmetalation and reductive elimination from either an in situ formed fluo

104 complex is reported to catalyze alkyl-alkyl reductive elimination from high-valent transition metal

105 For the first time, the C(sp(2))-N reductive elimination from isolated amidoaryl Pd(IV) com

106 on, a result of the high kinetic barrier for reductive elimination from octahedral Ir(III) complexes.

107 ermore, rare examples of C(sp(3))-Br and -Cl reductive elimination from Pd(II) as well as transfer hy

108 of the mechanism of C(sp(3))-N bond-forming reductive elimination from sulfonamide-ligated Pd(IV) co

109 Among the computed mechanisms, the reductive elimination from the C-bound enolate Pd comple

110 eta(2)-N2)] was synthesized by photochemical reductive elimination from the corresponding zirconium b

111 ier of 23.9 kcal/mol (363 K) for a concerted reductive elimination from the isolated, three-coordinat

112 igand-free nickel(II) salts, in which facile reductive elimination from the nickel metal center is in

113 indicated that the rate-determining step was reductive elimination from the palladium(II) species bea

114 the oxidant to promote the desired selective reductive elimination from the Pd(IV) centre, as well as

115 Reductive elimination from the presented nickel(III) com

116 (a) of the Ni-bound amine and the barrier to reductive elimination from the resultant Ni(II)-amido co

117 on is reversible, proving the possibility of reductive elimination from the species NacNacAlH(X).

118 The rates of reductive elimination from these C-bound fluoroenolate c

119 y, a section on Pd(IV) chemistry focusses on reductive elimination from these complexes (Section 5).

120 We also show that aryl-aryl bond reductive elimination from these oxidized species is not

121 of Pd(II) to Pd(III) dimers and subsequently reductive elimination from these Pd(III) dimers (Section

122 microenvironment-catalyzed C(sp(3))-C(sp(3)) reductive elimination from transition metal complexes [A

123 s found to enable carbon-oxygen bond-forming reductive elimination from unstable alkyl palladium inte

124 reviously studied alkyl-alkyl and aryl-alkyl reductive eliminations from Au(III).

125 Subsequent reductive elimination furnishes the allyl-aryl coupled p

126 The ensuing reductive elimination furnishes the desired arylated pro

127 ce two protons into two hydrides, from which reductive elimination generates H2.

128 an 8pi insertion of tropone, and subsequent reductive elimination generates the [5-6-7] fused tricyc

129 Each Ni(III) undergoes separate, but fast reductive elimination, giving rise to Ni(I) species.

130 Concerted reductive elimination has been studied with 6a directly

131 s that nitrenes are not generated and thus a reductive elimination has occurred.

132 metalation, C-Br oxidative addition, and C-C reductive elimination in a model gold complex are shown.

133 roamides, and difluoroacetonitrile underwent reductive elimination in high yields.

134 iting insertion, by lowering the barrier for reductive elimination in the linear-selective pathway.

135 ion" highlights the ability of Zn to promote reductive elimination in these heterobimetallic systems.

136 metallic reactions, i.e. oxidative addition, reductive elimination, insertion and elimination reactio

137 study highlights that irreversible C(aryl)-P reductive elimination is a feasible decomposition or act

138 ents suggest the mechanism of the subsequent reductive elimination is a unimolecular process occurrin

139 Reductive elimination is accelerated by electron-donatin

140 Reductive elimination is an elementary organometallic re

141 insertion into the Ir-C bond followed by C-H reductive elimination is involved for the high branched

142 the interplay between oxidative addition and reductive elimination is key for a potential catalytic c

143 mide], the energies for the regiocontrolling reductive elimination is predicted to be more in favor o

144 Fast C-F reductive elimination is proposed to occur from an aryl-

145 support the conclusion from experiment that reductive elimination is rate-determining and forms the

146 Interestingly, the reductive elimination is rate-determining for the major

147 It is suggested that the C-C bond-forming reductive elimination is the enantiodetermining step in

148 d similar enantioselectivities implying that reductive elimination is the stereodetermining step.

149 ring expansion of cyclobutanol followed by a reductive elimination) is found to be energetically more

150 migratory insertion, oxidative addition, and reductive elimination; it accounts for conformational sa

151 , a decarboxylative C(sp(3) )-C(sp(2) ) bond reductive elimination leads to gamma-aryl secondary alky

152 s show the oxidative addition/intramolecular reductive elimination likely to be the lowest-energy pat

153 d uptake and deprotonation could not undergo reductive elimination meaning a "dead-end route".

154 An unprecedented concerted reductive elimination mechanism for benzoxazole formatio

155 with an oxidative addition/olefin insertion/reductive elimination mechanism for each regioisomeric p

156 reaction proceeds via an oxidative addition/reductive elimination mechanism involving a Ni(IV) inter

157 The oxidative addition-reductive elimination mechanism via an unstable Cu(III)

158 provides direct experimental support for the reductive elimination mechanism.

159 hed oxidative addition, transmetalation, and reductive elimination mechanistic paradigm, would potent

160 sm for all species is via oxidative addition/reductive elimination (OA/RE).

161 is presented to support that this dinuclear reductive elimination occurs by tautomerization of the m

162 Turnover-limiting C-C reductive elimination occurs from a spectroscopically ob

163 evealed: 1) C(sp(3) )-C(sp(2) ) bond-forming reductive elimination occurs from both centers, but the

164 f the latter suggests that a C(sp(3))-I bond reductive elimination occurs preferentially to any other

165 These studies indicate that reductive elimination occurs readily for more nucleophil

166 ,6-trimethylphenyl (Mes)) to 1-Ph results in reductive elimination of 1 equiv of bibenzyl (PhCH(2)CH(

167 tinum(IV) complex underwent highly selective reductive elimination of 2-fluoromesitylene upon heating

168 try, we examined the chemoselectivity in the reductive elimination of a dinuclear Pd(III) complex bea

169 These enzymes catalyze the reductive elimination of a halide and constitute the ter

170 roethenes and chlorethanes by catalyzing the reductive elimination of a halogen.

171 Reductive elimination of alkane followed by alkene bindi

172 The rate of reductive elimination of an amido complex based on a Bre

173 Heating of 1.[H][Ar(F)] regenerates 1 by C-H reductive elimination of Ar(F)-H, where experimental and

174 was found to be consistent with the rates of reductive elimination of benzene from a series of isoele

175 In contrast to the reductive elimination of benzylamines from bisphosphine-

176 The proposed mechanism of exchange involves reductive elimination of Bu(t)3SnH from 1 to afford vaca

177 Reductive elimination of carbon-carbon bonds occurs in n

178 a-Si elimination but either ethylene loss or reductive elimination of cis-disposed aryl and SiMe3 moi

179 arene C-H bond; rather, it appears to be the reductive elimination of cyclohexane during the hydrogen

180 Selective reductive elimination of ethane (Csp(3)-Csp(3) RE) was o

181 ed four [e(-)/H(+)] and is poised to undergo reductive elimination of H(2) coupled to N(2) binding an

182 late-Ni(III)-H species undergoes bimolecular reductive elimination of H(2).

183 n of the coordinated bond and the subsequent reductive elimination of H(2).

184 key in the binding and activation of N2 via reductive elimination of H2 .

185 1,3,5-benzenetricarboxylate) via bimetallic reductive elimination of H2 from putative [M(IV)6(mu3-O)

186 Thus, substrate binding causes reductive elimination of H2 that formally reduces the me

187 as the key catalytic intermediate formed by reductive elimination of H2 with concomitant N2 binding,

188 ion that drives the re/oa equilibrium toward reductive elimination of H2 with N2 binding/reduction.

189 ride complexes, the dominant photoprocess is reductive elimination of H2.

190 propose a mechanism involving the homolytic reductive elimination of hydrogen.

191 e-dependent membrane proteins catalyzing the reductive elimination of iodide from iodothyronines thro

192 I)-Me complex (DPEphos)RhMeI2 (1) results in reductive elimination of MeI.

193 conditions were employed to investigate the reductive elimination of RuPhos (2-dicyclohexylphosphino

194 that the reaction does not occur via initial reductive elimination of SiH4, but rather by a metathesi

195 [Ga(4)L(6)](12-) tetrahedral metallocage on reductive elimination of substrate by encapsulated Au(II

196 pe hydrogenation cycle with rate determining reductive elimination of the alkane.

197 onic structure of 2 and the mechanism of the reductive elimination of the benzene molecule in its rea

198 addition of the C-H bond in this mechanism, reductive elimination of the C-Si bond occurs to generat

199 dly, its exposure to UV light affords, after reductive elimination of the entire PCO group, the unpre

200 rom Ni(0) species generated in situ from the reductive elimination of the highly reactive hydride int

201 was found to be inconsistent with the direct reductive elimination of the mixed Cl/OAc containing Pd(

202 resulting Cu(I) complex into the Ar-X bond, reductive elimination of the new sp(3) C-X bond, and fin

203 Then, the subsequent C-C reductive elimination of the regioselective linear produ

204 ease based on a unique example of photolytic reductive elimination of the tetrahedral P(4) molecule f

205 In this model, H2 is produced by reductive elimination of the two bridging hydrides of E4

206 FeMo-cofactor through a mechanism involving reductive elimination of two [Fe-H-Fe] bridging hydrides

207 to the one suggested by spectroscopy, with a reductive elimination of two hydrides just before nitrog

208 fin on the PdH Heck intermediate followed by reductive elimination of vinylarene; (c) reinsertion of

209 tion, these compounds undergo reversible C-C reductive elimination offering a unique approach to cycl

210 l transformation of the compound by means of reductive elimination or other mechanisms and is therefo

211 e well-suited for catalytic cycles involving reductive elimination or oxidative addition as a limitin

212 insertion into the M-H bond, followed by P-C reductive elimination, or by insertion into the M-P bond

213 onformational biasing element to promote C-C reductive elimination over an alternative C-N bond-formi

214 s are quantitative and heavily favor Caryl-I reductive elimination over Caryl-CF3 reductive eliminati

215 ated to a metal ion of possible relevance to reductive elimination/oxidation addition reaction chemis

216 We proposed a reductive elimination/oxidative addition (re/oa) mechani

217 as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry invol

218 The reversible H(2) and C-H reductive elimination/oxidative addition equilibrium smo

219 thermodynamically and kinetically reversible reductive-elimination/oxidative-addition exchange of N2

220 with a preference for an oxidative addition-reductive elimination pathway for Ir(III).

221 istic studies suggest an oxidatively induced reductive elimination pathway on rhodium(III) in an elec

222 action operates through an inner-sphere 3,3'-reductive elimination pathway, which is both rate-defini

223 transformation follows an oxidative addition-reductive elimination pathway.

224 t on subtle conformational effects governing reductive elimination pathways from high-valent palladiu

225 species might be prevalent due to accessible reductive elimination pathways, remains undefined.

226 on at the alkyl group, indicating that these reductive eliminations proceed by a concerted pathway.

227 ry to perform the difficult C-N bond-forming reductive elimination, producing a Ni(I) complex, which

228 g allyllithium intermediate to LPdAr(Br) and reductive elimination provide the 1,1-diarylprop-2-enes,

229 inant removal, such as (i) dechlorination by reductive elimination rather than hydrogenolysis and (ii

230 Rare cases of directly observed reductive elimination (RE) of methyl halides from Rh(III

231 Recently, photolytic reductive elimination (re) of the E(4)(4H) hydrides show

232 (4H) is poised to bind and reduce N2 through reductive elimination (re) of the two hydrides as H2, co

233 supramolecular capsule Ga(4)L(6)(12-) on the reductive elimination reaction from gold complexes and a

234 upports the transition state to complete the reductive elimination reaction with greater catalytic ef

235 idative addition is now well-established but reductive elimination reactions are not yet general in t

236 These products are not just the result of reductive elimination reactions but may also arise via r

237 an investigation of C(sp(3))-O bond-forming reductive elimination reactions from Pd(IV) complexes.

238 The C(sp(2))-X reductive elimination reactions of all isolated Pt(IV) c

239 (III) species undergo transmetalation and/or reductive elimination reactions to form new C-C or C-het

240 ound impact on the chemoselectivity of these reductive elimination reactions.

241 clopropylcarbinyl)nickel complex, which upon reductive elimination releases the cyclopropane.

242 upling reactions, including C-C bond-forming reductive elimination, represents a significant challeng

243 (transmetalation --> oxidative addition --> reductive elimination), resulting in the isolation and c

244 Fast reductive elimination results in the formation of the hy

245 inversion), transmetalation (retention), and reductive elimination (retention).

246 The reductive elimination selectivity varies dramatically as

247 ion state, rather than an oxidative addition/reductive elimination sequence, as we proposed in the ca

248 -stage 'oxidative addition, transmetalation, reductive elimination' sequence, there are a number of f

249 leads to an overall reduced barrier for the reductive elimination step compared to the formation of

250 ts inability to catalyze C-H silylation; the reductive elimination step to form the silylation produc

251 cross-coupling products via an outer-sphere reductive elimination step via triplet spin state from t

252 The reductive elimination step was investigated by DFT calcu

253 C-O bond-forming step (formally known as the reductive elimination step) to occur via a Ni(III) alkox

254 ability of Zn to promote a rate-limiting C-H reductive elimination step, and calculations attribute t

255 ugated alkenes involving a C(sp(3))-C(sp(3)) reductive elimination step.

256 ) intermediate preceding the product-forming reductive elimination step.

257 oordinated ligands during oxidative addition/reductive elimination steps allowed us to perform the ca

258 e elimination and facilitate transmetalation/reductive elimination steps.

259 ubstituted phenethylamines via a challenging reductive elimination that affords a quaternary carbon.

260 iments were consistent with unimolecular C-C reductive elimination that occurred either by a concerte

261 Reductive elimination therefrom provides bis-heteroaryl

262 (-) and [Cu(III)](C6F5)(OPh) unstable toward reductive elimination to [Cu(I)](solvent) and PhO-C6F5.

263 de abstraction, migratory insertion, and C-F reductive elimination to achieve a net C-C bond construc

264 (III) complexes can undergo facile C(aryl)-P reductive elimination to afford phosphonium salts, which

265 cterized that is effective for H-transfer or reductive elimination to deliver alkenylated or pyridini

266 ching), alkyl halide oxidative addition, and reductive elimination to enable alkyl-alkyl fragment cou

267 llographic analysis revealed that a putative reductive elimination to forge C(sp(3))-OC(sp(3)) using

268 ed Ni(II) complexes, upon oxidation, undergo reductive elimination to form carbon-halogen bonds.

269 While reductive elimination to form Fe(eta(6)-biphenyl)(SciOPP

270 m the silylation product is much slower than reductive elimination to form the alkene hydroarylation

271 , and the rate-limiting step was shown to be reductive elimination to form the C-C bond.

272 he turnover-limiting step of the reaction is reductive elimination to form the C-N bond.

273 ickel-aryl intermediate and rate-determining reductive elimination to form the carbon-carbon bond.

274 C, consistent with irreversible unimolecular reductive elimination to form the cyclobutane product.

275 IV) species, which then undergoes facile C-C reductive elimination to form the final product.

276 allow the direct observation of bimolecular reductive elimination to generate ethane and biphenyl, r

277 tive addition can be shown to be followed by reductive elimination to give an N- (or O-)borylated pro

278 1) decoordination of the protonated base and reductive elimination to give the BCB product and (2) pr

279 the reactivity of the arene and changes from reductive elimination to pi-complexation for arenes bear

280 a vinylgold(III) intermediate that undergoes reductive elimination to provide the heterocyclic coupli

281 ipate in challenging C(sp(2))-F bond-forming reductive elimination to yield aryl fluoride products.

282 ergoes a second alkyne insertion followed by reductive elimination to yield pyrrole and a Ti(II) spec

283 oxide bond, followed by rate-determining C-H reductive elimination to yield the ether product.

284 ansferring hydrogen in the rate-limiting C-H reductive elimination transition states.

285 proved inert toward C(sp(2))-I bond-forming reductive elimination under all conditions examined (up

286 Reductive elimination via ligand-bridged binuclear inter

287 ws that Fro-DO accelerates turnover limiting reductive elimination via LUMO lowering.

288 aryl halide and C-N coupling with amine via reductive elimination was also probed using DESI-MS.

289 echanistic study of the nucleophile-mediated reductive elimination was conducted using an oxime-deriv

290 This tendency to undergo reductive elimination was exploited in the investigation

291 Reductive elimination was faster from complexes containi

292 Clean reductive elimination was observed for all compounds in

293 nt Ni(IV) complexes, aryl-CF(3) bond-forming reductive elimination was reported to occur readily.

294 orine plays an essential role, followed by a reductive elimination where the C-C bond formation is co

295 th a number of problems, including difficult reductive elimination, which often leads to beta-hydride

296 Herein we present an N-N bond-forming reductive elimination, which proceeds via a mixed-valent

297 mit competing C(sp(3))-C(sp(2)) bond-forming reductive elimination, while the presence of Lewis acidi

298 ulated DeltaG() values for isomerization and reductive elimination with a series of sulfonamide deriv

299 reaction of D2 with the N2-bound product of reductive elimination would generate dideutero-E4 [E4(2D

300 the mass-selected Me(3)CuR(-) anions undergo reductive elimination, yielding both the cross-coupling