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1 easured in a single alignment medium that is rhombic.
4 e orientation of the riboses relative to the rhombic alignment tensor of the molecule studied, a stem
7 entify an unusual EPR signal with very small rhombic anisotropy and g values of 2.02, 1.99, and 1.96.
10 controlled by the His-Fe-His vector, and the rhombic axes are controlled by the mean of the imidazole
11 several Raman bands revealed an increase of rhombic B(1g) distortion with respect to native HRP in w
12 ifferent molecular environments, including a rhombic Be2 X2 (X=C, N) core, a vertical Be-Be axis in a
14 ental observations, it is proposed here that rhombic calcite microcrystals form exclusively in meteor
16 ), g-strain and broadening from the possible rhombic character of the Zeeman interaction are small.
17 tical spectrum; (2) its EPR spectrum showing rhombic character to its Type 1 center and nitrite pertu
18 eutral radical, the g-matrix has significant rhombic character, but this is significantly decreased i
19 We observe twinning of two-dimensional (2D) rhombic colloidal crystals of hard Brownian rhombic plat
20 ulation of these spectra yield the axial and rhombic components of the Mn(2+) (S = (5)/(2)) zero-fiel
23 is key feature, which is not readily seen in rhombic crystals of square colloids, facilitates observa
24 uidistant between two 'anchor' metal ions: a rhombic dipolar interaction tensor, T approximately [T,
26 he coupling of band III to modes with strong rhombic distortion of the heme macrocycle calls into que
29 ll {110}-faceted gold nanostructures, namely rhombic dodecahedra (RD) and triangular bipyramids (BPs)
31 l-regulated crystal orientation not only for rhombic dodecahedra all of whose facets are equivalent,
33 ra, {100}-truncated rhombic dodecahedra, and rhombic dodecahedra are approximately 200, 140, 270, and
34 overcomes this failure mode by leveraging Li rhombic dodecahedra as nucleation seeds, enabling the su
35 the three-dimensional Pt anisotropy of Pt-Ni rhombic dodecahedra can be tuned by controlling the rati
40 corner-truncated octahedra, {100}-truncated rhombic dodecahedra, and rhombic dodecahedra are approxi
42 e for a particular crystal morphology (e.g., rhombic dodecahedra, stacked clusters, and smooth rods).
43 the shapes of spheres, cubes, octahedra and rhombic dodecahedra, we investigate the entire self-asse
44 ic NPs of three shapes-cubes, octahedra, and rhombic dodecahedra-on substrates and investigate their
48 mechanical vibrations to assemble 3D printed rhombic dodecahedral and truncated octahedral grains int
51 s on the three-dimensional toric code on the rhombic dodecahedral lattice with boundaries and prove t
52 l, {100}-truncated rhombic dodecahedral, and rhombic dodecahedral structures have been synthesized.
54 ncated rhombic dodecahedral, {100}-truncated rhombic dodecahedral, and rhombic dodecahedral structure
57 r-truncated octahedral, all-corner-truncated rhombic dodecahedral, {100}-truncated rhombic dodecahedr
59 on of ultrasonic irradiation afforded hollow rhombic-dodecahedral crystals of the C-methylcalix[4]res
60 ron microscopy (TEM), we show that cubic and rhombic dodecahedron (RD) ZIF-8 NPs convert into hollow
61 plasmonic Au nanoparticles - nanocube (NC), rhombic dodecahedron (RD), and octahedron (OC) - exposin
62 gh the 14 axes to the 24 edges such that the rhombic dodecahedron becomes a Pt-rich frame enclosing a
63 At the micrometer scale, the anisotropic rhombic dodecahedron crystal habit couples with photonic
64 ubic habit from cube-shaped nanoparticles, a rhombic dodecahedron habit from octahedron-shaped nanopa
65 ies defined by the mesoscale crystal (here a rhombic dodecahedron) by controlling the spacing between
66 esults in Pt segregation to the 14 axes of a rhombic dodecahedron, forming a highly branched, Pt-rich
67 on morphology of metallic Li to be that of a rhombic dodecahedron, which is surprisingly independent
72 polyhedrons, namely, truncated octahedrons, rhombic dodecahedrons, hexagonal prisms, cubes, gyrobifa
74 pectra for ferrous N694G and an intermediate rhombic electron paramagnetic resonance (EPR) signal for
75 is from a transient species that displays a rhombic electron paramagnetic resonance (EPR) signal wit
76 es a novel Ni(p)(+) species (A(red)*) with a rhombic electron paramagnetic resonance spectrum (g valu
79 rk, the change from "large g(max)" to normal rhombic EPR signal occurs between axial ligand plane dih
80 ation (under argon) the H cluster exhibits a rhombic EPR signal that is not seen in the as-purified e
81 t of the enzyme results in conversion of the rhombic EPR signal to a g = 6 signal, consistent with fo
82 over many similar sites, the A-center has a rhombic EPR signal with a g-tensor, g(A) = [2.248(4), 2.
85 , these molecules are highly anisotropic and rhombic EPR spectra for the Ce(III) complex are reported
86 structures with apical oxo ligands, exhibit rhombic EPR spectra, and 3-5 are electrochemically reduc
89 uration, high fluid:solid ratio) exhibit the rhombic form/morphology, whereas calcite microcrystals c
90 ndicative of meteoric diagenesis whereas non-rhombic forms are associated with marine burial conditio
93 -band EPR spectrum of the radical exhibits a rhombic g tensor with dual gx values (2.00550 and 2.0060
96 the [4Fe-4S](+) of PFL-AE, changing it from rhombic (g = 2.02, 1.94, 1.88) to nearly axial (g = 2.01
97 O(2) to generate an intermediate (H) with a rhombic, g < 2 EPR spectrum; (2) a form of the enzyme wi
98 en well documented, has the highest level of rhombic heme (41-fold greater than for HbA(0)), even tho
101 dandelion-like assemblages from Pt NCs, and rhombic/hexagonal platelet assemblages from PdS NCs and
102 e with two or three cysteinate ligands and a rhombic high spin (S = 2) Fe(II) center (E/D = 0.28, D =
104 high-spin (S = 1) ground state and displays rhombic high-frequency and -field electron paramagnetic
105 active site iron center in oxidized SOR from rhombic high-spin ferric (S = 5/2) to axial-like low-spi
107 weak signal at g = 4.3, which we ascribe to rhombic iron and a free radical signal at g(ave) = 2.01.
109 kwise, from the average pointing axis of the rhombic lattice yielding a form of nonlocal chiral symme
110 diameter and ~250 nm height, that provides a rhombic-lattice canvas of a thousand pixels each, with p
111 which have higher symmetry but can also form rhombic lattices at high densities, each rhombic particl
112 s are more frequently expressed in the lower rhombic lip (LRL) and embryonic dorsal brainstem than in
114 ield that adjoins a germinal zone, the lower rhombic lip (LRL), functions as a progenitor domain by c
117 imordium contains two germinative zones, the rhombic lip (RL) and the ventricular zone (VZ), which ge
122 fferentiation, hbNES cells transit through a rhombic lip (RL) progenitor state at day 7, demonstratin
128 regulator in both the normal and transformed rhombic lip and identifying ZIC1 as an exquisitely conte
129 eal molecular organization of the cerebellar rhombic lip and introduce Lmx1a as an important regulato
130 Math1 expression delimits the extent of the rhombic lip and is required for the generation of the hi
132 cification of cerebellar cell types from the rhombic lip and its upregulation inhibits their producti
133 indbrain, arise from precursors in the lower rhombic lip and migrate anteroventrally to reach their f
134 that DCN neurons in mice are produced in the rhombic lip and migrate rostrally in a subpial stream to
135 Our results suggest that UBCs arise from the rhombic lip and migrate via novel pathways to their fina
137 of Lmx1a, these cells precociously exit the rhombic lip and overmigrate into the anterior vermis.
138 1 is the defining molecule of the cerebellar rhombic lip and Pax6 is downstream in the Math1 pathway.
139 associated with premature regression of the rhombic lip and posterior vermis hypoplasia in Lmx1a(-/-
140 hl1 homeobox gene is highly expressed by the rhombic lip and rhombic lip-derived migratory neurons.
142 ere derived from neuronal progenitors of the rhombic lip and that cerebellar ectopia were derived fro
144 arate progenitor pools located mainly in the rhombic lip and the cerebellar ventricular zone, respect
145 interface between columnar epithelium of the rhombic lip and the expanding squamous epithelium of the
146 existence of spatial compartmentation in the rhombic lip and the interplay between Wls, Math1, and Pa
150 ory progenitor populations-specifically, the rhombic lip and ventricular zone progenitors, respective
152 Thus, proliferating precursors within the rhombic lip are specified to be granule cells very early
153 the earliest granule cell progenitors at the rhombic lip as they separate from the ventricular zone o
154 g granule cell progenitors isolated from the rhombic lip at E14 or from the external germinal layer a
155 nce for an hCPe contribution directly by the rhombic lip at late embryonic stages when hRPe is no lon
156 ansformed our understanding of the embryonic rhombic lip by revealing the inductive cues, regional or
158 introduce Lmx1a as an important regulator of rhombic lip cell-fate decisions, which are critical for
159 ggests that Sef may normally function in non-rhombic lip cells and prevent them from responding to FG
161 When transplanted into younger neural tube, rhombic lip cells maintain their characteristic molecula
164 n hindbrain specification and generate upper rhombic lip derivatives on exposure to bone morphogeneti
165 trin orchestrates the migration of hindbrain rhombic lip derivatives to form the precerebellar nuclei
169 more than one cell type, indicating that the rhombic lip does not consist of a homogeneous population
170 ull mice have embryonic abnormalities of the rhombic lip due to loss of mesenchyme-secreted signaling
172 ess p75NTR when they migrate either from the rhombic lip during embryonic development or from the EGL
173 ulture experiments, Tbr2+ UBCs migrated from rhombic lip explants directly into the developing white
175 d in grafted progenitors: transplanted early rhombic lip fails to subsequently produce granule cell p
176 ing human tissues(3)-particularly within the rhombic lip germinal zone, which produces all glutamater
178 Thus, we demonstrate that the cerebellar rhombic lip gives rise to multiple cell types within rho
180 Distinct ZIC1 mutations affect cells of the rhombic lip in diametrically opposed ways, suggesting th
182 subgroups to their unified beginnings in the rhombic lip in the early stages of human development.
183 ence of Wls-positive cells in the Math1-null rhombic lip indicates that Wls expression is independent
189 ve cells and their progeny that arise in the rhombic lip of the cerebellar primordium during embryoge
190 of CN neurons that do not originate from the rhombic lip or ventricular zone of the cerebellar primor
193 zone precursors and glutamatergic cell from rhombic lip precursors, mirroring distinct origins for t
194 iotemporal expansion of both ventricular and rhombic lip primary progenitor zones to include subventr
195 ental progression has been assumed, with the rhombic lip producing non-mitotic hRPe, and seemingly un
196 e neural tube, derivatives of early and late rhombic lip progenitors display patterns of migration an
198 addition, Lmx1a is expressed in a subset of rhombic lip progenitors which produce granule cells that
200 nterplay between Wls, Math1, and Pax6 in the rhombic lip provides novel views of early cerebellar dev
201 dbrain dorsal interneurons that comprise the rhombic lip relay sensory information and coordinate mot
202 Oncogenic transformation of early Prtg(+ve) rhombic lip stem cells initiates group 3 medulloblastoma
203 s, PPHLN1 is expressed in the most primitive rhombic lip stem cells, and targeting PPHLN1 splicing re
204 ker of the cells in the interior face of the rhombic lip throughout normal mouse cerebellar developme
206 granule cell precursors are generated at the rhombic lip together with neurons of the lateral pontine
208 red gene interactions during the presence of Rhombic lip versus the presence of distinct internal gra
209 2+ UBCs appeared to migrate out of the upper rhombic lip via two cellular streams: a dorsal pathway i
211 blishment of a neural progenitor population (rhombic lip) that gives rise to multiple hindbrain struc
212 ated protein kinase pathway is active in the rhombic lip, a germinal zone that generates diverse type
213 iferative state, order of emergence from the rhombic lip, and molecular profile of either the constit
214 mutant mice, Tbr2+ UBCs accumulated near the rhombic lip, consistent with impaired migration through
216 d along the dorsal-most region of the caudal rhombic lip, gives rise to the cochlear and precerebella
217 Sef is expressed immediately adjacent to the rhombic lip, overlapping with FGF15 and FGFR1, which is
219 rsors of cerebellar granule neurons from the rhombic lip, the dorsal aspect of the midbrain/hindbrain
220 erivatives is intrinsically specified at the rhombic lip, the orderly temporal transition in cell typ
221 ns arising from the ventricular zone and the rhombic lip, two distinct germinal zones of the embryoni
222 generated from a unique progenitor zone, the rhombic lip, whereas the inhibitory neurons and astrocyt
223 which gives rise to isthmic nuclei, and the rhombic lip, which generates deep cerebellar nuclei and
224 enitor zones, the ventricular zone and upper rhombic lip, which give rise to distinct cell types in t
225 n orientated, active migration away from the rhombic lip, which is apparently independent of either g
228 which have a severe cerebellar malformation, rhombic lip-derived cells migrated to the NTZ, despite r
229 nd positioning of fissures, whereas in upper rhombic lip-derived cells the genes are more important i
231 -lateral coordinates into the adult, whereas rhombic lip-derived granule cells undergo lateral to med
232 ineage appears to be unique among the varied rhombic lip-derived lineages in its proliferative respon
234 et shows that WNT medulloblastomas match the rhombic lip-derived mossy fiber neuronal lineage and emb
235 ctive deficit occurs without affecting other rhombic lip-derived nuclei, despite expression of Math1
236 poptosis, indicating that VZ/SVZ-derived and rhombic lip-derived progenitor cells show differential r
252 Molecular signatures encoded within a human rhombic-lip-derived lineage trajectory aligned with phot
253 selective knock-out of P/Q-type channels in rhombic-lip-derived neurons including the PF and MF path
255 use many precerebellar nuclei originate from rhombic lips, the first analysis of neuronal migrations
256 esponsible for the strong positive axial and rhombic magnetic anisotropy of the high-spin Co(II) ion
260 y of Phanerozoic limestones characterized by rhombic microcrystals also exhibit petrographic and/or g
262 ed of hybrid plasmonic waveguide (HPW)-based rhombic nano-antenna, polarization beam splitter, couple
263 ignificantly contributes to constructing the rhombic nanoporous network, whereas carboxylic acid amph
266 orm rhombic lattices at high densities, each rhombic particle has a distinguishable bidirectional poi
267 ioheme I, and the known essentially constant rhombic perturbation of heme pocket sites on the hyperfi
268 han that of the axial His, that modulate the rhombic perturbation to the heme's in-plane electronic a
269 -order transition between the square and the rhombic phase and different regimes of elasticity, as we
271 ncated icosahedron or soccer ball--and the 2 rhombic polyhedra reported by Johannes Kepler in 1611.
274 Fe-NO adduct of FeSOD (NO-FeSOD) exhibit two rhombic S = 3/2 signals of comparable population; E/D =
278 ituted ImiS demonstrated the appearance of a rhombic signal after 10 ms that is assigned to a reactio
280 For the paral-[FeOMTPP(1-MeIm)(2)]Cl, a rhombic signal with g(1) = 1.54, g(2) = 2.51, and g(3) =
282 ](+) exhibits both "large g(max)" and normal rhombic signals, suggesting the presence of both "perpen
283 present different shapes, such as hexagonal, rhombic, six-cornered star, dumbbell, or dendritic.
287 of the component spins of the triplets have rhombic symmetry because of electron spin delocalization
289 n I-II-helix VIII dimers interact to form a "rhombic" tetramer via an interface involving residues fr
291 surface occupy the positions of atoms in the rhombic triacontahedral cluster, the building block of t
293 2D nanoporous molecular networks containing rhombic voids are demonstrated to be accessible from low
294 allel = 98 x 10(-4) cm(-1), and another more rhombic, with a smaller A parallel value of 69 x 10(-4)
295 /- 2 cm(-1) (where D and E are the axial and rhombic zero-field splitting parameters, respectively) a
297 The fast QTM rate suggested a significant rhombic ZFS parameter E, as expected from the low (virtu