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1 ng the concept of oxygen vacancy defects and solvolysis.
2 ivergence away from rearrangement and toward solvolysis.
3 ophile facilitated by a Lewis-acid-catalysed solvolysis.
4 ete mechanistic scheme for allyl carboxylate solvolysis.
5        Free R1P undergoes both C-OP and CO-P solvolysis.
6  complete esterification without substantial solvolysis.
7 ediately loses chloride ion in an S(N)1-like solvolysis.
8  C5 methyl ester modestly slowed the rate of solvolysis (1.8x, pH 3) without altering the inherent re
9 ending on the sequence, but undergo complete solvolysis above 80 degrees C.
10 -based probes, PVSN and PVS are resistant to solvolysis and are cell-permeable and thus hold promise
11 been reflected in their faster rates of both solvolysis and enzymatic hydrolysis.
12 te, sialyl-galactose, in both acid-catalyzed solvolysis and enzymatic transfer reactions.
13 s were found to be much more reactive toward solvolysis and hydrolysis, much less effective DNA alkyl
14                      It is demonstrated that solvolysis and internal return can be explained by the s
15 (2) in hydroxylic solvents proceed with both solvolysis and rearrangement.
16 2), CN, or CO(2)R) can be induced to undergo solvolysis and substitution reactions through an elimina
17 such as solubility, solvent complexation, or solvolysis, and makes the resulting process highly envir
18 mass through methods such as hydrogenolysis, solvolysis, and reductive catalytic fractionation.
19                                          The solvolysis data allowed determination of the nucleofugal
20                                    Using the solvolysis data, the nucleofugality of bromide in these
21                                     From the solvolysis data, the nucleofugality of dimethyl sulfide
22                                              Solvolysis/dehydrohalogenation rates of 2-chloro-2-methy
23            Observations of unexpected silane solvolysis distributions in the HAT-initiated hydrogenat
24  analogues proved remarkably reactive toward solvolysis even at pH 7, where the reaction is uncatalyz
25                                 While recent solvolysis experiments and NMR spectroscopic studies on
26                                 A sequential solvolysis/hydride shift/intramolecular reduction cascad
27 motes either the formation of an N-B bond or solvolysis if 1 equiv of water is present.
28                         In the basic region, solvolysis in (18)O-labeled water and H(2)O/MeOH mixture
29 in (PCB), was cleaved from the apoprotein by solvolysis in alcohols and alcoholic aqueous solutions.
30                                  The rate of solvolysis in aqueous buffer of analogue 1S was 50-fold
31 hylsilyl-endo-2-norbornyl mesylate undergoes solvolysis in CD3CO2D only 2.6 times faster than endo-2-
32                     The latter undergo rapid solvolysis in hydroxylic solvents even at room temperatu
33 es dramatically accelerated 6 activation and solvolysis in methanolic solutions ("pH 7.4") compared w
34 Winstein-Trifan experiment confirms that exo-solvolysis is accompanied by sigma-bridging in the trans
35  developed here is that 1-adamantyl chloride solvolysis is assisted by hydrogen bond donation departi
36 3))(HOCH(3))), and the rate constant for its solvolysis is k(max) = 1.5 x 10(-4) s(-1).
37 bridging in the transition state, while endo-solvolysis is not; sigma-bridging eventually occurs in a
38 ater extent than that of tert-butyl chloride solvolysis, most likely due to lessened steric interacti
39                                              Solvolysis of 1-(trimethylsilylmethyl)cyclopropyl mesyla
40 ain the increased sensitivity of the rate of solvolysis of 1-adamantyl chloride over tert-butyl chlor
41 lore the nature of the cations formed in the solvolysis of 2-bicyclo[3.2.1]octanyl tosylate the 2-bic
42 on has been applied to the specific rates of solvolysis of 2-phenyl-2-ketoethyl bromide and tosylate
43       Comparisons with the specific rates of solvolysis of 2-phenylethyl bromide and methyl tosylate
44 arge Et3P-mediated rate enhancements for the solvolysis of 6 compared with 13 and a N(7)-substituted
45                                              Solvolysis of 6-OMs and 18-OMs effected skeletal rearran
46      The rate of nonenzymatic acid-catalyzed solvolysis of 8-vinyladenine from the stem-loop RNA is d
47 thanol, representing the first report on the solvolysis of a charged species in an ionic liquid.
48 is divergent synthetic approach involves the solvolysis of a transient and highly labile tertiary-pro
49 sylate derivatives but rate-enhancing in the solvolysis of a-CF(3) benzylic analogs.
50 by visible light because of the photoinduced solvolysis of acetonitrile or py ligands.
51                                           In solvolysis of alkyl halides Hal-(CH(2))(n)-C(BCH(3))(11)
52 sylate derivatives but rate-enhancing in the solvolysis of alpha-CF(3) benzylic analogs.
53                                          The solvolysis of alpha-d-glucopyranosyl fluoride in hexaflu
54 ic bromopolyene cyclization initiated by the solvolysis of an enantiomerically enriched vicinal bromo
55  dagger) vs approximated DeltarG degrees for solvolysis of benzhydryl aryl/alkyl carbonates and benzh
56                        The specific rates of solvolysis of benzoyl fluoride have been determined at 2
57 air distribution function (PDF) study of the solvolysis of bismuth disalicylate, a model for the meta
58                       The rate constants for solvolysis of CH(3)SCH(2)Cl, a model for GS-CH(2)Cl, ran
59                                          The solvolysis of cis-4-phenylazo benzyl mesylate is faster
60 of KIEs is quite different than observed for solvolysis of CMP-NeuAc.
61 lazo group is slightly rate-retarding in the solvolysis of cumyl chloride and benzyl mesylate derivat
62 lazo group is slightly rate-retarding in the solvolysis of cumyl chloride and benzyl mesylate derivat
63                             For example, the solvolysis of cyclobutyl or cyclopropylmethyl derivative
64 monium and chloronium ions are generated (by solvolysis of enantiomerically enriched precursors) and
65                                          The solvolysis of exo-7-isodeltacyclyl brosylate generates t
66                                              Solvolysis of exo-8-deltacyclyl brosylate proceeds direc
67                                              Solvolysis of kallolide A and isokallolide A in [(18)O]-
68                                              Solvolysis of lithium thiolate ion pairs in ethanol sign
69                        The specific rates of solvolysis of N,N,N',N'-tetramethyldiamidophosphorochlor
70 n the reaction mixtures was a Mg2+-dependent solvolysis of nerolidyl diphosphate.
71 as studied theoretically for the case of the solvolysis of norborn-2-en-7-ylmethyl-X systems by defin
72                                   Subsequent solvolysis of organotrifluoroborates in the presence of
73             The mechanism of the heterolytic solvolysis of p-tolyldiazonium cation in water was studi
74             By comparing the SQase-catalyzed solvolysis of PSPP in the absence of NADPH3 to the react
75                                              Solvolysis of pure Z-trifluoroacetate (p-CH3) gives smal
76 m is proposed involving (a) rate-determining solvolysis of RCN by THF followed by rapid oxygenation o
77    By comparison, the difference in rates of solvolysis of structurally related tosylates were nearly
78        The first-order rate constants of the solvolysis of sulfonium salts were determined in mixture
79  utilized to suggest that the higher rate of solvolysis of tert-butyl chloride in aqueous ethanol is
80                                    Undesired solvolysis of the amide group in the side chain of Asn o
81                                          The solvolysis of the endo epimer presents a more complex pi
82 tylinosine by a modified Appel reaction, and solvolysis of the glycosyl linkage gave 6-(imidazol-1-yl
83 alculations of the activation free energy of solvolysis of the pyrophosphate bond in a conformational
84                                              Solvolysis of the S-(halomethyl)glutathione intermediate
85                                              Solvolysis of the urea products generates alpha-alkenyla
86 cates neighboring-group participation in the solvolysis of tosylates but not in the hydrolysis of ace
87                                          The solvolysis of two diastereomers may give the same two pr
88 he elementary reaction pathways of the S(N)1 solvolysis on an in situ real-time single-molecule elect
89 nsformations (acylation, S(N)Ar, silylation, solvolysis, Pd catalyzed C-S cross-coupling and cycloadd
90 ls-Alder reaction, which following an S(N)2' solvolysis process to displace the iodo group affords a
91 eventually trapped by water to form the sole solvolysis product 12b.
92 ported data are consistent with the retained solvolysis product being formed in an S(N)i (D(N)(++)*A(
93 eported for the reactions of 2 proceeding to solvolysis products and 3.
94                    Reactions of 1 proceed to solvolysis products and both 2 and 3; since 2 slowly und
95                     The ratio of cyclized to solvolysis products decreases with the increase in ring
96 vent demonstrated that the C2 alkoxyl of the solvolysis products originated from the solvent, suggest
97 e C2 hydroxyl with an alkoxyl group to yield solvolysis products that display net retention of config
98  conversion of alcohols 1 and 8 into various solvolysis products, including dimeric ethers 2 and 9, w
99            These compounds are the expected "solvolysis" products from PSPP.
100                                  First-order solvolysis rate constants are reported for solvolyses of
101                                          The solvolysis rate constants of the bromides of well-define
102 B) leaving groups have been derived from the solvolysis rate constants of X,Y-substituted benzhydryl
103           Using well-described electrofuges, solvolysis rate constants were determined in mixtures co
104  the following trends when compared with the solvolysis rate constants: (i) electron-rich sulfonyl ch
105   Substituents on the phenyl ring affect the solvolysis rate of benzhydryl benzoates by both field an
106 t pH 7), a pH-independent (H(+) independent) solvolysis rate profile at pH 3/4-7, and a much reduced
107  for the acyl series (RCOCl), for which both solvolysis rates and HBDEs increase in the order R = Bu
108 sis of the kinetic data and comparisons with solvolysis rates for the structurally related silphin-1b
109                                              Solvolysis rates of 2-trimethylsilylbenzocyclobutyl deri
110 ree triazoles have also been determined from solvolysis rates of substituted cumyl trifluoroacetates.
111            The activation parameters for the solvolysis reaction are as follows: DeltaH(++) = 81.4 +/
112 rect SN2Ar process is the best model for the solvolysis reaction for dynamic reasons, and its Gibbs f
113 pe effect (KIE) measurements, the TS for the solvolysis reaction in hexafluoro-2-propanol, we synthes
114  step in the formation of photo-Favorskii or solvolysis reaction products in water.
115                 The transition state for the solvolysis reaction was modeled computationally using th
116 ontrolling the temperature and pressure of a solvolysis reaction.
117 benzhydrylium ion (Ph)2CH(+), even though in solvolysis reactions (80% aqueous ethanol at 25 degrees
118 hylsilyl-anti-7-norbornyl triflate undergoes solvolysis reactions 1.8 x 10(4) faster than 7-norbornyl
119 3-diarylalyl cations are generated faster in solvolysis reactions and also react faster with nucleoph
120 en shown to undergo clean pseudo-first-order solvolysis reactions in DMSO-d(6) to give products deriv
121  of this reaction to the Winstein scheme for solvolysis reactions is noted.
122       Complete Gibbs energy profiles for the solvolysis reactions of benzhydryl fluorides are constru
123                                           In solvolysis reactions, all of these processes follow firs
124 uoromethanes) were prepared and subjected to solvolysis reactions, which were followed conductometric
125 anions led to ultrafast half-lives for these solvolysis reactions.
126 tance of external and internal return in the solvolysis reactions.
127                               A study of the solvolysis reactivity and regioselectivity of N-BOC-C5-C
128 th 2 and 3; since 2 slowly undergoes further solvolysis, specific rates are obtained by a modified Gu
129 here benzoyl chloride also shows bimolecular solvolysis, the appreciable k(Cl)/k(F) values are propos
130     Next to rapid hydrolytic degradation and solvolysis, the poly(oxanorbornene-fused gamma-butyrolac
131 t with imidazoles at C6 followed by glycosyl solvolysis to provide 2-chloro-6-(substituted-imidazol-1
132 rom classical physical-organic chemistry and solvolysis to self-assembly and supramolecular chemistry
133 rgies of transfer of the tert-butyl chloride solvolysis transition state is that there is no change i
134 ucts of the 2-bicyclo[3.2.2]nonanyl tosylate solvolysis were found to have nonclassical structures.
135                       Compound 1 is inert to solvolysis with alcohols, even at elevated temperatures,
136 s and find that the majority of them undergo solvolysis within a few weeks, at both sulfuric acid con

 
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