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1  Stille coupling with an appropriate pyridyl stannane.
2 pecific silver-mediated fluorination of aryl stannanes.
3 than by transmetalation of the corresponding stannanes.
4 of aryl/heteroaryl halides with aryl/hetaryl stannanes.
5 s only with direct aryl radical reduction by stannane (0-10%).
6 tting the stage for the acquisition of vinyl stannane 13 and its subsequent palladium-catalyzed Still
7 ladium-catalyzed coupling of the vinyl 6'(E)-stannanes 14 with (E) and (Z) ethyl 3-iodoacrylate gave
8 ediated Stille cross-coupling of the vinylic stannane 4 and the alkenyl bromide 5 to produce a highly
9  which was coupled in a Stille reaction with stannane 68 to give 2 after cleavage of the TIPS ether.
10 ng showed that the alkyls originate from the stannane and not from ambient impurities, and that trial
11 tille coupling of an acetylene-derived vinyl stannane and vinyl iodide of approximate equal complexit
12 yl groups) can be generated from (2-azaallyl)stannanes and (2-azaallyl)silanes through an intramolecu
13 r-mediated Stille-type coupling between aryl stannanes and alpha-diimines bearing 8-bromonaphthylimin
14  a mild copper-mediated fluorination of aryl stannanes and aryl trifluoroborates with N-fluoro-2,4,6-
15 or carbon-carbon bond formation between aryl stannanes and olefins via Pd(II) catalysis in the presen
16                                        While stannanes and silanes have shown potential, their toxici
17 rated by tin-lithium exchange of (2-azaallyl)stannanes and underwent [pi4s+pi2s] and [pi6s+pi4s] cycl
18 to both enantiomeric forms of an epoxy vinyl stannane, and a series of coupling reactions, including
19 l ketene imines, a silyl cyanide, an alkynyl stannane, and an allylic stannane were applicable to the
20 ere derived from lactones, glycals, glycosyl stannanes, and halides, via methods displaying various l
21                          A bulky substituted stannane Ar*SnH3 (Ar*=2,6-(2',4',6'-triisopropylphenyl)p
22 substrate (C(1)-C(27) fragment) with a vinyl stannane as the main coupling processes to assemble the
23 ircumvents isomerization by the synthesis of stannanes as intermediates and their use in a Stille cou
24 triles, esters, amides, carbamates, silanes, stannanes, boronic esters, as well as arenes, and furnis
25  (ee 99%) were generated from the respective stannanes by tin-lithium exchange at temperatures rangin
26 ectron-rich, heterocyclic, and hindered aryl stannanes can be employed as coupling reagents.
27 acetylenes into functionalized phenanthrenyl stannanes can be initiated via two potentially equilibra
28 whereas the double allylation of (2-azaallyl)stannanes cannot be stopped at monoallylation.
29 o depend on the codonor used to generate the stannane cation radical intermediates.
30 terodimer cation radicals formed between the stannane cation radicals and the neutral codonors, which
31      Kinetics show the fragmentations of the stannane cation radicals occur by a bimolecular, nucleop
32 eric effects on both the nucleophile and the stannane cation radicals were observed.
33 re found to react more slowly than analogous stannane cation radicals; however, loss of the thermodyn
34 ble Stille cross-coupling with a trienyl-bis-stannane closing the macrolactone and installing the sen
35 er, the first X-ray structure of a [Ru(sigma-stannane)] complex (12a) is presented, which indeed feat
36  epoxidation/enzymatic kinetic resolution of stannane-containing substrates that led selectively to b
37          We established that oligosaccharide stannanes could be prepared from monosaccharide stannane
38 l Stille cross-coupling reaction employing a stannane-enolether, to directly afford adamantyl-enoleth
39 des to the corresponding trifluoromethylated stannane ether intermediates at room temperature in high
40 with methacryloyl chloride and vinyltributyl stannane followed by Pd-catalyzed Heck annulation.
41  the functionalized five-membered ring vinyl stannane from the monoterpene R-(-)-carvone featuring a
42 se high E/Z 1-bromo-1-fluoroalkenes and aryl stannanes gave (Z)-alpha-fluorostilbenes in high stereos
43 rst, methods for the preparation of anomeric stannanes have been developed and optimized to afford bo
44 ce on the bulk solution concentration of the stannane, hinting that more than one alkyl can be transf
45  allylation of aldehydes with fluorous allyl stannanes illustrates the usefulness of the new fluorous
46 st provided cyclic nonstabilized (2-azaallyl)stannanes in moderate to good yields.
47 fonyl)vinyl AA-esters undergo smooth sulfone-stannane interchange to stereoselectively give the corre
48 ed at the concomitantly formed square-planar stannane(IV) as air-stable adducts.
49                         The same (2-azaallyl)stannanes may be transmetalated by n-butyllithium to gen
50 n one alkyl can be transferred from a single stannane molecule.
51 I)-mediated homodimerization of complex aryl stannane monomers.
52 yl ethers using InI(3) and organosilicon or -stannane nucleophiles to synthesize (Z)-beta-alkoxyalken
53                   Pairs of diastereoisomeric stannanes of known stereochemistry bearing atropisomeric
54 s reactions between various olefins and aryl stannanes of varying electron density.
55 did not suffer from competitive reduction by stannane, offering an advantage over the use of diazo an
56  the double allylation of either (2-azaallyl)stannanes or (2-azaallyl)nitriles, both of which thereby
57 pper complexes deriving from the diphosphine-stannane [Ph2P(o-C6H4)Me2Sn-SnMe2(o-C6H4)PPh2] 1.
58 uch as allylic silanes, boronates, germanes, stannanes, pivalates, phosphonates, phthalimides, and to
59 ocol avoids usage of the arylboronic acid or stannane precursors for the synthesis of 5-(2-furyl, or
60                         The (trifluoromethyl)stannane reagent, Bu3SnCF3, was found to react under CsF
61 ) macrocyclic iodide with a C(29-46) oxazole stannane side chain to establish the complete phorboxazo
62  metal-catalyzed addition of metal hydrides (stannanes, silanes, and germanes) and bimetallic species
63  (Ge(4)H(10)), tetrasilane (Si(4)H(10)), and stannane (SnD(4)) hydride precursors, allowing the simul
64                   For one atropisomer of the stannanes, the tin-lithium exchange is fully stereospeci
65 s byproducts during the synthesis of the DHA stannanes, this approach allowed the regioselective inco
66 eta face directs deuterium transfer from the stannane to C2'(C3') on the alpha face of the furanose r
67 talyzed reactions with silanes, germanes and stannanes to form disiloxanes, and R(3)SiOER(3) E = Ge,
68                              The (2-azaallyl)stannanes tolerate enolizable hydrogens in these cycload
69 )methanethione, on treatment with silanes or stannane under heating or microwave irradiation undergoe
70 trate that configurationally stable anomeric stannanes undergo a stereospecific cross-coupling reacti
71 nnanes could be prepared from monosaccharide stannanes via O-glycosylation with Schmidt-type donors,
72 cyanide, an alkynyl stannane, and an allylic stannane were applicable to the present reaction system
73 2-azaallyllithium species derived from these stannanes were shown to undergo efficient [3 + 2] cycloa
74 or the preparation of the cyclic (2-azaallyl)stannanes, which are precursors to the nonstabilized 2-a
75 9% ee) were generated from the corresponding stannanes, which themselves were prepared by Hoppe-Beak
76 in; and Stille coupling of a C(28) trimethyl stannane with a C(29) oxazole triflate.
77 tille cross-coupling reaction of propargylic stannanes with 5-iodo-1,3-oxazoles to produce 1,1-disubs
78 nesium reagents and (3-methylthio-2-azaallyl)stannanes with a Ni(0) catalyst provided cyclic nonstabi
79 ished rates of cross-couplings of 1,2-cis C1-stannanes with aryl halides.