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1 layer WS(2) films are highly crystalline and stoichiometric.
2 The peptide/siRNA quaternary complex forms stoichiometric, 10 nm nanoparticles, that show fast cell
4 00 reactions of central metabolism with full stoichiometric accounting of energy production and consu
5 llular respiratory capacity and requires the stoichiometric accumulation of rRNAs and proteins encode
6 This reaction does not require the use of stoichiometric activating reagents, and avoids the use o
8 onomy by circumventing the need for wasteful stoichiometric activation of hydroxy groups into halides
10 was independently synthesized from 1 by the stoichiometric addition of a one-electron oxidant and a
13 tes in clinical and developmental stages are stoichiometric agents, i.e., each metal complex reacts o
14 mblies should therefore not be understood as stoichiometric aggregates, but as combinatorial ensemble
15 ted alkenyl boronic esters when treated with stoichiometric allyl acetate and a palladium catalyst.
16 yl-1,9-(2,4,6-Ph(3)C(6)H(2))dipyrrin) with a stoichiometric amount of 1-azido-4-(tert-butyl)benzene N
20 f imine, azobenzene hydrogen acceptors, or a stoichiometric amount of tBuOK with hydrazobenzene, allo
22 tyrosinase-like fashion and (ii) addition of stoichiometric amounts (1 or 2 equiv) of Lewis acids (LA
23 water-splitting cycle that produces close to stoichiometric amounts (~90%) of H(2) and O(2) (illustra
24 SmI(2) in synthesis, the reagent is used in stoichiometric amounts and has a high molecular weight,
25 ell as glucose as the reducing agent used in stoichiometric amounts for in situ cofactor recycling.
28 Tf over a mixture of photoredox catalyst and stoichiometric amounts of Bronsted acids or substoichiom
29 bonylation of unactivated alkyl iodides with stoichiometric amounts of carbon monoxide is presented.
31 rtho-hydroxyarylaldehydes in the presence of stoichiometric amounts of Et(3)N in dichloroethane at 80
33 Li(3) N, N(2) can be reduced to N(3-) while stoichiometric amounts of H(-) are oxidised to H(2) .
34 ses create the unique possibility to replace stoichiometric amounts of oxidizing or reducing reagents
35 werful radical cascades have been developed, stoichiometric amounts of reagents and/or additives are
38 oaded one {= state (0,0)}, was actuated with stoichiometric amounts of two inputs (IN-1 = Zn(2+), IN-
41 taneous degradations of DMA and mono-MA, the stoichiometric analysis draws the same conclusions witho
43 quantitative chemical proteomic workflow for stoichiometric analysis of ubiquitination is reported, n
44 nt chemical proteomics tool for quantitative stoichiometric analysis of ubiquitination signaling path
47 hed more light on this process, we provide a stoichiometric analysis to identify potentially rate-lim
48 solate reactive intermediates, platforms for stoichiometric and catalytic functionalization, countera
49 Many different approaches involving both stoichiometric and catalytic versions have provided a fu
50 cribe common themes and unique mechanisms of stoichiometric and enzymatic suppressors of CRISPR-Cas.
52 vable autocatalytic systems, by applying our stoichiometric and kinetic analysis to autocatalysis eme
54 ncapsulate volatile fission products, in its stoichiometric and much more effective electride forms.
55 Linear sweep voltammetry (LSV) shows that stoichiometric and structural control leads to the evolu
56 otein and absolute quantification reveal the stoichiometric and structural remodelling of metabolical
57 these reactions have been achieved by using stoichiometric, and often hazardous, reagents to activat
58 with rubidium iodide, for substoichiometric, stoichiometric, and overstoichiometric preparations, whe
59 abiotic experiments using substoichiometric, stoichiometric, and superstoichiometric concentrations o
60 pirational contributions, both catalytic and stoichiometric, and the latest insights in catalyst desi
62 gh formation of biomolecular condensates-non-stoichiometric assemblies of protein and/or nucleic acid
64 eproduced, as individual proteins lose their stoichiometric balances and the cellular machinery that
65 arth-abundant manganese in the presence of a stoichiometric base, making the overall process economic
68 rativity was examined assuming two different stoichiometric binding models and using a Bayesian appro
71 ction of triphenylphosphine oxide (TPPO)-the stoichiometric byproduct of some of the most common synt
75 role of the MPAA ligand is characterized in stoichiometric C-H activation and catalytic C-H function
76 g group or intermolecular), and the context (stoichiometric C-H activation or within a variety of cat
79 tracted proteins from these microdomains via stoichiometric capture of lipids and proteins in styrene
80 hemical communication, which is triggered by stoichiometric chemical inputs and by obeying the AND tr
82 in these reactions have been reported using stoichiometric chiral reagents(5,6), catalytic asymmetri
83 lavin T fluorimetry estimates rapid and near-stoichiometric coassembly of CATCH(+) and CATCH(-) at co
84 and inorganic ions are identified and their stoichiometric coefficients estimated, 3) the remaining
85 eved through the formation of 2:1 host-guest stoichiometric complex assemblies, resulting in an encap
86 t the TDP2 UBA domain binds K63-Ub3 in a 1:1 stoichiometric complex that relieves a UBA-regulated aut
87 Remarkably, prenylated KRAS4b forms a 2:1 stoichiometric complex with CaM in a nucleotide-independ
89 dings indicate that Rcf1 does not serve as a stoichiometric component, i.e. as a subunit of complex I
90 we seek a comprehensive understanding of the stoichiometric composition and organisation of Pdu MCPs.
91 ration-quenching effect, except these are in stoichiometric compounds with precise interatomic distan
92 e, we derive, from basic principles, general stoichiometric conditions for catalysis and autocatalysi
93 one-pot procedure, in water and using nearly stoichiometric conditions, is discussed in terms of the
98 bonds between hydrocarbons and CO(2) require stoichiometric consumption of very resource-intensive re
99 ixture composition alone, demonstrating that stoichiometric control can be a tool as powerful as dire
101 ighted plant nitrogen, leading to the strong stoichiometric convergence of ground-layer plant communi
106 genic and DNA damage signals, regulating the stoichiometric cyclin: CDK inhibitor ratio for ultrasens
107 onger SPOP-DAXX interactions dominate at sub-stoichiometric DAXX concentrations leading to the format
108 bond functionalization reactions such as the stoichiometric dehydrogenation of alkanes, with density
113 nature of hydrogen limits the structural and stoichiometric determination of the system by X-ray scat
114 ging technique facilitates identification of stoichiometric differences between particles and stoichi
115 leotides (model compounds) were evaluated by stoichiometric displacement and linear gradient elution
116 acterization of the drug load profile (i.e., stoichiometric distribution of the number of conjugated
117 om each of the lake communities had narrower stoichiometric distributions and more commonly exhibited
118 Black indium oxide comprises amorphous non-stoichiometric domains of In(2)O(3-x) on a core of cryst
120 -coordinate cross-linked gels to verify that stoichiometric excessive metal ion cross-linker concentr
121 e conformation, bound by OlyA, is induced by stoichiometric, exothermic interactions with cholesterol
123 yocyte reprogramming over previously defined stoichiometric expression of GMT or uncontrolled express
130 Based on these results, we propose a new stoichiometric framework in which all plant element cont
134 oth layer-controlled defective GaS(0.87) and stoichiometric GaS prove to be promising platforms for s
136 intrinsic small bandgap semiconductors, off-stoichiometric GFO NCs, produced under either Fe-rich or
137 chiometric differences between particles and stoichiometric gradients and phase heterogeneities withi
138 Remarkably, regardless of the large off-stoichiometric growth conditions (inducing disorder by s
141 ese reactions require strategies that employ stoichiometric hazardous reagents and are associated wit
142 nd modular method proceeds in the absence of stoichiometric heterogeneous reductants and uses an inex
143 R'PH.BH(3), using a CAAC, which behaves as a stoichiometric hydrogen acceptor to release monomeric ph
144 These findings affect our interpretation of stoichiometric imbalances among microbes and soils and a
145 etry, makes the gates largely insensitive to stoichiometric imbalances in the inputs, and the modular
147 ains of In(2)O(3-x) on a core of crystalline stoichiometric In(2)O(3), and has 100% selectivity towar
148 operties of the host frameworks enable rapid stoichiometric inclusion of a wide range of target molec
149 lationships in single-cell measurements into stoichiometric information, one in which each cell subpo
150 6 achieves this remarkably effective and sub-stoichiometric inhibition by interacting not with the mo
155 PR) is a powerful technique for studying 1:1 stoichiometric interactions but has limited application
156 odel of cortical pulling forces in which the stoichiometric interactions of microtubules and force ge
157 nternal electric field) for both Sr-rich and stoichiometric interfaces, while the DFT-calculated char
158 overview of this field, including the early stoichiometric investigations, catalytic reaction develo
162 tituting elements in lithium-rich as well as stoichiometric layer-layer compounds for stabilizing the
164 fe-cycle inventories were calculated using a stoichiometric life-cycle inventory framework that coupl
166 zolate metal-organic framework (MOF) uptakes stoichiometric loadings of Groups 1 and 2 metal halides,
169 mononuclear uranyl(VI) complexes is found on stoichiometric mackinawite; however, equivalent adsorpti
171 d into the 10(17) cm(-3) range in highly off-stoichiometric material, in quantitative agreement with
172 e all characters of all symmetries of 26,938 stoichiometric materials, and find 3,307 topological ins
179 demand (COD(th)) as well as theoretical and stoichiometric methane potential (TMP, and SMP) were als
180 mer ligands were synthesized by installing a stoichiometric mixture of amine-modified sulfobetaine an
181 wth by initially constructing a genome-scale stoichiometric model for this important crop plant and t
182 nd breast cancer patients into a multi-scale stoichiometric model of a cancer cell population: signif
184 MOMA) and the Escherichia coli (E.coli) core stoichiometric model to investigate the network-wide eff
188 strain selection and design process, we used stoichiometric modelling (FBA, pFBA, FVA and MOMA) and t
190 also uncovered important differences in the stoichiometric modulation between calcium-permeable and
192 prediction revealed that the results of the stoichiometric network analysis are plausible and in goo
194 y O(2)/CO(2) gas mixture (1:2 molar ratio at stoichiometric operation) at the anode and H(2) at the c
195 gn the mechanism of C-H activation in either stoichiometric or catalytic reactions may be misleading,
196 s covering main-group homogeneous catalysis, stoichiometric organic synthesis, low-valent main-group
197 s as coupling partners obviates the need for stoichiometric organometallic reagents and tolerates a b
198 lcohol synthesis but traditionally relies on stoichiometric organometallic reagents that are difficul
201 inetic analysis, ultrafast spectroscopy, and stoichiometric organometallic studies has enabled the el
202 pporting catalytic turnover with O(2) as the stoichiometric oxidant and establish an important founda
203 Current single-catalyst methods require stoichiometric oxidant in addition to hydride (H(-)) sou
209 ary alcohols to aldehydes by O(2) instead of stoichiometric oxidants (for example, Mn(VII) , Cr(VI) ,
210 thus transforming the role of quinones from stoichiometric oxidants into catalytic single-electron a
215 be stoichiometrically homeostatic but their stoichiometric plasticity has rarely been examined, part
216 Labeling reactions may utilize close-to-stoichiometric precursor quantities and short reaction t
217 ctra (including the leaf economic spectrum), stoichiometric principles, and the variation of phenotyp
218 y is that aggregation-based inhibition, as a stoichiometric process, is sensitive to protein concentr
219 his latter Ni(III) species to participate in stoichiometric product formation, the complex was not a
222 s core-shell nanoparticles composed of quasi-stoichiometric PuO2 cores and hydrolyzed Pu(IV) moieties
224 such as PMHS, can serve as a replacement for stoichiometric quantities of allylmetal reagents, which
225 rnative to conventional methods that require stoichiometric quantities of high-energy reductants.
226 We devised an alternative approach using stoichiometric quantities of palladium oxidative additio
227 ding (e.g., 10 mole %) and a need for (super)stoichiometric quantities of undesirable oxidants, such
229 rcolation models show that there are limited stoichiometric ranges for transport along Fe and Mn path
230 degrees C), on the co-pigmentation effects, stoichiometric ratio (n), the equilibrium constant (K) a
235 formation proceeding in mild conditions in a stoichiometric ratio of reactants and has high functiona
236 E particle size ratio, DNA surface coverage, stoichiometric ratio, and thermal annealing pathways.
239 suming complete oxidation to CO(2), observed stoichiometric ratios closely resembled the theoretical
242 of their dissociation constants, tuning the stoichiometric ratios of reaction mixtures, and implemen
244 n of the bulk binary precursors in the right stoichiometric ratios yields phase-pure thin films of Cu
245 Sylgard 184 premixes are either mixed in non-stoichiometric ratios, or they are blended with softer t
247 cation occurs readily in a one-pot, two-step stoichiometric reaction at room temperature to form uran
248 pped with complementary reactive polymers, a stoichiometric reaction leads to reorganization of the u
249 (t-Bu) (2), generated independently from the stoichiometric reaction of [Fp(t-BuPA)][BF(4)] with TMAF
251 ive, the reaction mechanism was probed using stoichiometric reaction studies, a Hammett analysis, and
252 ion of a cobalt(II)-substrate complex from a stoichiometric reaction suggests that alkene insertion i
253 identification of reaction intermediates by stoichiometric reactions and NMR experiments, together w
254 sformation has been studied in-depth through stoichiometric reactions of the key diazatitanacyclohexa
256 deuterium labeling, kinetic, catalytic, and stoichiometric reactions with plausible intermediates we
264 ion-dependent pH homeostasis that exhibits a stoichiometric relationship with the ATP-generating capa
266 acid hydrolysis is demonstrated to generate stoichiometric release of nucleobases from intact oligon
267 Taken together, our results demonstrate the stoichiometric requirement of GHMT expression for struct
268 es: (1) metabolite uptake sufficient for the stoichiometric requirement to sustain observed growth, (
271 increasing temperature may not only induce a stoichiometric shift but also loose the coupling between
272 ither involve hazardous reagents or generate stoichiometric side products, leading to challenges in s
273 paper we introduce the concept of Effective Stoichiometric Spaces (ESS) to guide the reconstruction
274 n contrast to the known FM metallic phase in stoichiometric Sr(2) FeReO(6) , an FMI state with a high
275 vant to C(sp(2) )-C(sp(3) ) coupling through stoichiometric studies and also explore their catalytic
279 gs, we propose that Hig1 type 2 proteins are stoichiometric subunits of CIV, at least when within a I
286 oxylic acids and alcohols in the presence of stoichiometric triethyl phosphite and dioxygen in air as
287 ocal, STED, and electron microscopy reveal a stoichiometric tuning of AZ scaffolds and nanoarchitectu
288 offers new insights into understanding plant stoichiometric variations across a full set of mineral e
290 nd parainfluenza viruses, and maintained the stoichiometric viral proportions when the samples contai
291 to the lattice V(3+)/V(5+) concentrations of stoichiometric VO(2) and that electronic transitions are
294 n intrinsic magnetic topological insulator-a stoichiometric well ordered magnetic compound-could be a
296 that recombinant HBx is soluble and exhibits stoichiometric zinc binding when expressed in the presen
299 s at room temperature in the presence of sub-stoichiometric Zn and either 1,5-cyclooctadiene or 4-(N,