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1 an electrophile to synthesize S-(o-halo)aryl sulfilimines.
2 be the mechanism of styrene elimination from sulfilimines, a Hammett analysis was performed with subs
3 rmined through the synthesis of a deuterated sulfilimine and is consistent with significant C-H bond
4       N-Ethyloxycarbonyl-S,S-dibenzothiphene sulfilimine and N-t-butyloxycarbonyl-S,S-dibenzothiphene
5                                          N-H sulfilimines and CH2-S,C-sulfonium ylides have low BDEs,
6                               Recently, both sulfilimines and deuterated organic molecules have garne
7 Os) catalyse the biocatalytic oxygenation of sulfilimines and sulfenimines to form enantiomerically e
8 alkylamines, furnishing structurally diverse sulfilimines and sulfoximines including unconventional i
9         The synthesis of a variety of chiral sulfilimines and sulfoximines is described.
10                               The sulfoxide, sulfilimine, and sulfur ylid prepared from this common i
11                       The elimination in the sulfilimine appears to be more favorable by about 2 kcal
12                                  N-protected sulfilimines are prepared by imination of sulfides with
13 e physicochemical and in vitro properties of sulfilimines are reported and compared to those of sulfo
14 p for medicinal chemistry, the properties of sulfilimines are significantly less well studied, and no
15 propyl,S-(hetero)aryl and S,S-di(hetero)aryl sulfilimines are so far neglected but potentially valuab
16           Product studies suggest that these sulfilimines are superior sources for sulfonylnitrenes,
17 gnetic resonance spectroscopy to show that a sulfilimine bond (-S=N-) crosslinks hydroxylysine-211 an
18 ulin (Ig) domains are required for efficient sulfilimine bond formation.
19                      Peroxidasin forms novel sulfilimine bonds between opposing methionine and hydrox
20 121-alpha565, each of which is stabilized by sulfilimine bonds between their C-terminal NC1 domains.
21 ctrometry analyses of peptides revealed that sulfilimine bonds specifically cross-link alpha1 to alph
22  mediates the formation of specific covalent sulfilimine bonds to reinforce collagen IV in basement m
23 inary NC1 crosslinks, recently identified as sulfilimine bonds, which comprehensively locked the cryp
24                                 We show that sulfilimines can be chemically and configurationally sta
25 dium catalyzed synthesis of sulfoximine (and sulfilimine) carbamates, especially for previously low-y
26 es reveal that the scaffold is stabilized by sulfilimine chemical bonds (S = N) that covalently cross
27  of N-t-butyloxycarbonyl-S,S-dibenzothiphene sulfilimine confirms that the oxazolidinone is the major
28 l drug scaffolds is studied in two series of sulfilimine-containing analogs of imatinib and hNE inhib
29                              The collagen IV sulfilimine cross-link and its catalyzing enzyme, peroxi
30  were investigated for the occurrence of the sulfilimine cross-link by electrophoresis, MS, and multi
31                      We explored whether the sulfilimine cross-link is a fundamental requirement in t
32 ediates that oxidize methionine, forming the sulfilimine cross-link.
33 ity of Pxdn and facilitates the formation of sulfilimine cross-links in collagen IV.
34 es the formation of structurally reinforcing sulfilimine cross-links within the collagen IV network,
35 h that the triad-a collagen IV scaffold with sulfilimine cross-links, peroxidasin, and hypohalous aci
36 s bromide as a cofactor for the formation of sulfilimine cross-links.
37 network by determining the chain identity of sulfilimine-cross-linked NC1 domains derived from the al
38 l oxidant that promotes the formation of the sulfilimine crosslink in collagen IV in basement membran
39 enous NC1 domains, as the NC1 trimer becomes sulfilimine crosslinked with the existing chains.
40 actor for peroxidasin-catalyzed formation of sulfilimine crosslinks, a posttranslational modification
41                 Chloride ions, together with sulfilimine crosslinks, stabilized the assembled hexamer
42                                    The vinyl sulfilimine cyclization method was applied to the total
43                           Styryl-substituted sulfilimines cyclize in a stereospecific manner and prod
44 al methods were applied to the photolysis of sulfilimines derived from dibenzothiophene that were exp
45 and in vitro drug-like properties shows that sulfilimines deserve a place in the medicinal chemist's
46      We establish that Br(-) is required for sulfilimine formation within collagen IV, an event criti
47  intermediate that energetically selects for sulfilimine formation.
48 etic route for synthesizing trideuteromethyl sulfilimines from sulfenamides utilizing cost-effective
49  are significantly less well studied, and no sulfilimine has progressed to the clinic to date.
50 and N-t-butyloxycarbonyl-S,S-dibenzothiphene sulfilimine have been utilized as precursors to ethoxyca
51 duct in all cases to date, and the yields of sulfilimine have varied widely.
52                                              Sulfilimines have so far received little attention as a
53 cyl sulfenamides with alkyl halides provides sulfilimines in 47% to 98% yields.
54 m that features a 6n-electrocyclization of a sulfilimine intermediate followed by spontaneous ring-co
55                  The asymmetric synthesis of sulfilimine intermediates by the first Ru-catalyzed enan
56                         The oxidation of the sulfilimine intermediates is also described, and provide
57 ro)aryl iodides and boronic acids to provide sulfilimine intermediates that undergo thermal eliminati
58 nts provides efficient access to a series of sulfilimine intermediates.
59                             Furthermore, the sulfilimine/isocyanate metathesis reaction with 4,4'-met
60 ophilic addition of the nitrogen atom of the sulfilimine onto the highly electrophilic dichloroketene
61 C-sulfonium ylides have low BDEs, unless the sulfilimine or S,C-sulfonium ylide is stabilized by an e
62  been observed following photolysis of these sulfilimine precursors by time-resolved infrared (TRIR)
63 erives from the triplet excited state of the sulfilimine precursors, rather than through equilibratio
64 nylsulfilimine or N-benzoyl dibenzothiophene sulfilimine produces PhNCO and also benzoylnitrene.
65                                            A sulfilimine product was readily converted to an N-acyl a
66                These are stabilized by novel sulfilimine (-S=N-) cross-links, a covalent cross-link t
67 ed ylides include the following: sulfoxides, sulfilimines, S,C-sulfonium ylides, and selenoxides.
68                                       In the sulfilimine series, sulfoximines are generated in up to
69                                           In sulfilimine synthesis, sulfoxide has been an inevitable
70 kenyl iodide and boronic acid inputs to give sulfilimines that then undergo concerted elimination of
71 m-catalyzed imination of these electron-rich sulfilimines then delivers a varied range of sulfondiimi
72  N-pivaloyl S-tert-butyl acetate substituted sulfilimine to the corresponding sulfoximine, treatment
73  ideal procedure for the sulfide to sulfonyl sulfilimine transformation is described.
74 f ever-increasing interest, selected product sulfilimines were oxidized to the corresponding sulfoxim
75 rray of both aryl and alkyl trideuteromethyl sulfilimines were prepared in high yields with excellent
76 lity had little effect when aryl-substituted sulfilimines were used but exhibited a major effect on t
77 free metathesis reaction of C-chiral allylic sulfilimines with aryl isocyanates.
78 veral aryl-, furanyl-, and vinyl-substituted sulfilimines with dichloroketene proceeded at 25 degrees
79 ive gamma-lactamization reaction of naphthyl sulfilimines with trichloroacetyl chloride in the presen
80 3 h a wide range of acyclic and cyclic NTces-sulfilimines with various functional groups and (hetero)