ライフサイエンスコーパス: sulfoxide

1 ted protein 1 inhibitor or vehicle (dimethyl sulfoxide).

2 he S-oxidation products (aryl diphenylmethyl sulfoxides).

3 rsible process, generally shifted toward the sulfoxide.

4 xFP) were prepared and dissolved in dimethyl sulfoxide.

5 behavior to drugs pre-dissolved in dimethyl sulfoxide.

6 ere compared with dissolved PhIP in dimethyl sulfoxide.

7 ations in a molar ratio of 1.5:1 in dimethyl sulfoxide.

8 be mistaken for the side chain loss from Met sulfoxide.

9 to causing oxidation of Met residues to Met-sulfoxide.

10 e posttranslationally oxidized to methionine sulfoxide.

11 i.e., glycerol, ethylene glycol and dimethyl sulfoxide.

12 y targeted, forming predominantly methionine sulfoxide.

13 the solvents deuterochloroform and dimethyl sulfoxide.

14 delivering isoquinolinones and methyl phenyl sulfoxide.

15 HD was oxidized to the nontoxic HD-sulfoxide.

16 in a mixture of thexyl alcohol and dimethyl sulfoxide.

17 via initial addition of the alkoxide to the sulfoxide.

18 henium catalyst containing a tethered chiral sulfoxide.

19 to CRM197 by reductive amination in dimethyl sulfoxide.

20 ion of the sulfur group to the corresponding sulfoxide.

21 radical cation that in turn led to diphenyl sulfoxide.

22 rhodium-catalyzed transfer of carbamates to sulfoxides.

23 strategies for the synthesis of enantiopure sulfoxides.

24 Dimethyl sulfoxide 2 M was used as cryoprotector for slow freezin

25 characterizations support the assignment of sulfoxide 4 as the native EgtE substrate and the involve

26 e radical cations of a series of aryl benzyl sulfoxides (4-X-C6H4CH2SOC6H4Y(+*)) have been generated

27 Fresh culture contained only traces of sulfoxides 5 and 7, but these increased during storage o

28 nt the chiral macrocyclic structure biotin-l-sulfoxide[6]uril as a host molecule that binds anions in

29 The biotin-l-sulfoxide[6]uril generally exhibits stronger recognition

30 Biotin-l-sulfoxide[6]uril is prepared in a highly diastereoselect

31 The absolute configuration of stereogenic sulfoxide acceptors at the edge of the pi-acidic surface

32 anism leading to aryl 1-methyl-1-phenylethyl sulfoxides accompanied by products derived from Calpha-S

33 erexpression, genotype D virus, and dimethyl sulfoxide added to culture medium.

34 on of S-allylcysteine (SAC), S-allylcysteine sulfoxide (alliin), S-methylcysteine (SMC), and S-ethylc

35 ions (M - HO-B(N(CH3)2)2) for N-oxides, but sulfoxides also formed diagnostic C ions (M - O horizont

36 of the response of Na-O2 cell chemistry with sulfoxide, amide, ether, and nitrile electrolyte solvent

37 ido sulfonate (10:2-FTSAS) and fluorotelomer sulfoxide amido sulfonate (10:2-FTSAS-sulfoxide) were al

38 d profile and increased levels of methionine sulfoxide, an oxidative stress biomarker, in the brains

39 er but also from such weak acids as dimethyl sulfoxide and acetonitrile.

40 ng on the order of 30 kJ mol(-1) in dimethyl sulfoxide and acetonitrile.

41 e, namely allyl methyl sulfide, allyl methyl sulfoxide and allyl methyl sulfone.

42 A systematic study revealed that graphitic sulfoxide and carboxyl dopants of graphene were the effi

43 two kinds of substrates, S-methyl-L-cysteine sulfoxide and L-cysteine, and had both cysteine sulfoxid

44 tive etching agent and a mixture of dimethyl sulfoxide and methanol as a dilute solvent.

45 sulfur and nitrogen atoms in many drugs into sulfoxide and N-oxide functionalities is a common biotra

46 Dimethyl sulfoxide and polyurethane were assigned as surrogates t

47 flexible Lewis pairs; however, the analogous sulfoxide and sulfone groups are not.

48 Irgarol sulfoxide and terbutryn sulfoxide were detected in the e

49 lly manipulating the oxidation states of the sulfoxide and the amide functional groups, halogenating

50 The method is developed for the sulfoxide and trichloroacetimidate glycosylation protoco

51 selectively to nontoxic 2-chloroethyl ethyl sulfoxide and vinyl ethyl sulfoxide using nearly stoichi

52 g strategy utilizing aryl(heteroaryl) methyl sulfoxides and alcohols to afford alkyl aryl(heteroaryl)

53 Cyanopyridone derivatives containing sulfoxides and sulfones showed cellular activity against

54 bution, and only photo-oxygenation products (sulfoxides and sulfones) were found.

55 Being mono-aza analogues of sulfoxides and sulfones, sulfimides and sulfoximines, re

56 e effect of two solvents (water and dimethyl sulfoxide) and two MALDI matrices (2,5-dihydroxybenzoic

57 imesitylboranes paired with phosphine oxide, sulfoxide, and sulfone Lewis basic groups are explored.

58 energy of hydrogen in acetonitrile, dimethyl sulfoxide, and water to be 57.4, 55.5, and 30.0 kcal/mol

59 Moreover, aryl methyl sulfoxides, dibenzyl sulfoxides, and dimethylsulfoxide could be utilized to g

60 droxides and their keto tautomers, sulfates, sulfoxides, and N-oxides.

61 In addition, the lipophilicity of ethers, sulfoxides, and sulfones is dramatically increased upon

62 Experimental data of ethanol and dimethyl sulfoxide are shown as proof-of-concept.

63 Trifluoromethyl sulfoxides are a new class of trifluoromethylthiolating

64 Furthermore, sulfoxides are able to capture nucleophiles and electrop

65 Sulfoxides are capable of forming stable complexes with

66 Sulfoxides are classical functional groups for directing

67 Alkynyl sulfoxides are important building blocks with a unique r

68 s a renaissance period in the application of sulfoxides arising from their versatility in directing C

69 release can be influenced by adding dimethyl sulfoxide as a co-solvent for electrospinning.

70 lity of nucleophilic addition to an appended sulfoxide as a means to form a bond to aryl(heteroaryl)

71 C-S lyase reaction using either thioether or sulfoxide as a substrate in the presence or absence of r

72 ocol using iodine as a catalyst and dimethyl sulfoxide as an oxidant under green chemistry conditions

73 iodine as a catalyst (30 mol %) and dimethyl sulfoxide as an oxidant under metal-free reaction condit

74 employing iodine as a catalyst and dimethyl sulfoxide as an oxidant.

75 ion of imidazo[1,2-a]pyridines with dimethyl sulfoxide as the carbon synthon (CH2) using H2O2 as a mi

76 Employment of sulfoxides as electrophiles in cross-coupling reactions

77 , the use of sulfoxides, particularly chiral sulfoxides, as ligands in transition metal catalysis is

78 an oxidized aS in which all methionines are sulfoxides (aS4ox); a fully lysine-alkylated aS (acetyl-

79 Plasma levels of albendazole sulfoxide (ASOX), the active metabolite of albendazole,

80 mation-friendly reactions to run in dimethyl sulfoxide at room temperature.

81 proach, leveraging the high IR absorbance of sulfoxides at 10.6 mum, for selective dissociation and d

82 While current sulfoxide-based cross-linkers are effective for in vivo

83 Importantly, using a disuccinimidyl sulfoxide-based cross-linking MS platform, we mapped the

84 A sulfoxide-based imidazopyridazine analog 45, arising fro

85 nstrates the robustness and applicability of sulfoxide-based MS-cleavability in conjunction with vari

86 rations may compete with crucial ligand (bis-sulfoxide) binding and inhibit catalysis.

87 We also provide brief descriptions of metal-sulfoxide bonding and strategies for the synthesis of en

88 A Pd(II)/bis-sulfoxide/Bronsted acid catalyzed allylic C-H oxidation

89 reaction is reported under palladium(II)/bis-sulfoxide/Bronsted base catalysis.

90 rated in situ from CS(2) and KOH in dimethyl sulfoxide by a simple method and used as a novel synthet

91 Quantification of the abundant methionine sulfoxide by NMR and MS gave highly comparable values.

92 in, 1 atm O2 or air) with reduced Pd(II)/bis-sulfoxide catalyst loadings while providing higher turno

93 atively nontoxic product 2-chloroethyl ethyl sulfoxide (CEESO) without formation of the highly toxic

94 strated the robustness and predictability of sulfoxide chemistry in designing MS-cleavable cross-link

95 b with the MEK inhibitor trametinib dimethyl sulfoxide (CombiDT therapy) increases response rate and

96 mologous series containing five new nonionic sulfoxide containing polypeptides was described.

97 On the contrary, sulfoxides containing chirality at the sulfur atom have

98 etermine their feasibility for analyzing new sulfoxide-containing cross-linked products.

99 aration of small peptides tethered to chiral sulfoxide-containing macrocyclic rings.

100 ision induced dissociation as amine-reactive sulfoxide-containing MS-cleavable cross-linked peptides,

101 es, we have previously developed a series of sulfoxide-containing MS-cleavable cross-linkers to facil

102 solid foundation for further development of sulfoxide-containing MS-cleavable cross-linkers with new

103 viously developed a series of amine-reactive sulfoxide-containing MS-cleavable cross-linkers.

104 evelopment of a new acidic residue-targeting sulfoxide-containing MS-cleavable homobifunctional cross

105 ne propionate (1 mg/kg) or vehicle (dimethyl sulfoxide, control), 1 h before infection with rhinoviru

106 bly transfected with HBV DNA, while dimethyl sulfoxide could increase NTCP protein level despite tran

107 e homobifunctional cross-linker, dihydrazide sulfoxide (DHSO).

108 Moreover, aryl methyl sulfoxides, dibenzyl sulfoxides, and dimethylsulfoxide c

109 nd 5000-8000 for water and 2000 for dimethyl sulfoxide; differences between samples were revealed in

110 o 'cooked kidney bean' aroma, while dimethyl sulfoxide, dimethyl sulfone and ethyl methyl sulfone wer

111 s and alkynes, mediated by a multifunctional sulfoxide directing group, exploits nonprefunctionalized

112 romoethane (extraction solvent) and dimethyl sulfoxide (disperser solvent) was injected rapidly into

113 h strategically involves the use of dimethyl sulfoxide (DMSO) acting as an organic solvent for simult

114 temperature solution calorimetry in dimethyl sulfoxide (DMSO) and differential scanning calorimetry.

115 d that CSOD can tolerate up to 3.9% dimethyl sulfoxide (DMSO) and up to 10% serum, which shows its co

116 ssolving 4m concentrated LiNO(3) in dimethyl sulfoxide (DMSO) as an additive for a fluoroethylene-car

117 er to ever higher concentrations of dimethyl sulfoxide (DMSO) as the temperature was reduced.

118 ffer saline solution containing 10% dimethyl sulfoxide (DMSO) at 21 degrees C.

119 ellent yields using only KO(t)Bu in dimethyl sulfoxide (DMSO) at rt.

120 octanesulfonic acid (PFOS), or 0.4% dimethyl sulfoxide (DMSO) daily from 0-5 d post fertilization (dp

121 Dimethyl sulfoxide (DMSO) disrupts the hydrogen-bond networks in

122 Dimethyl sulfoxide (DMSO) has been broadly used in biology as a c

123 epG2/NTCP cells was attributable to dimethyl sulfoxide (DMSO) in culture medium, NTCP overexpression,

124 a medium comprised of Ficoll 70 and dimethyl sulfoxide (DMSO) in presence or absence of fetal bovine

125 d involves mixing volatile additive dimethyl sulfoxide (DMSO) into aqueous PEDOT:PSS solutions follow

126 ilute aqueous electrolyte by adding dimethyl sulfoxide (DMSO) into ZnCl(2)-H(2)O, in which DMSO repla

127 Dimethyl sulfoxide (DMSO) is a common solvent and biological addi

128 Dimethyl sulfoxide (DMSO) is a promising solvent for this battery

129 Dimethyl sulfoxide (DMSO) is widely used in a number of biologica

130 n 153 (C153) in a series of toluene/dimethyl sulfoxide (DMSO) mixtures and find that the experimental

131 Compound 7 in dimethyl sulfoxide (DMSO) or ethanol solutions exists in the form

132 etylenes in the presence of KOBu(t)/dimethyl sulfoxide (DMSO) or NaOBu(t)/DMSO systems under exceptio

133 Dimethyl sulfoxide (DMSO) or sulfide ligands have positive and ne

134 erovskite films are obtained from a dimethyl sulfoxide (DMSO) solution via a transitional SnI2.3DMSO

135 ketoximes and acetylene in the KOH/dimethyl sulfoxide (DMSO) superbase medium (here abbreviated as t

136 hree solvents: water, methanol, and dimethyl sulfoxide (DMSO) were investigated at varying concentrat

137 s Medium (KM) supplemented with 10% dimethyl sulfoxide (DMSO), 15% human serum albumin (HSA) and 0.1%

138 Dimethyl sulfoxide (DMSO), but not pyrenebutyrate (PB), ethanol,

139 glycol (EG), propylene glycol (PG), dimethyl sulfoxide (DMSO), glycerol (GLY), and methanol (METH; li

140 CPAs such as dimethyl-sulfoxide (DMSO), propylene glycol (PG), and formamide (

141 he media contains a small amount of dimethyl sulfoxide (DMSO), the adduct is able to move to a solven

142 ly polyhydroxylated alcohols and/or dimethyl sulfoxide (DMSO), which can damage cell membranes.

143 t HOBr reacts very fast with DMS to dimethyl sulfoxide (DMSO), with a second-order rate constant of 1

144 tible poly(methyl methacrylate) and dimethyl sulfoxide (DMSO)-compatible poly(2-hydroxyethyl methacry

145 (cRbm20(DeltaRRM)-raloxifene), with dimethyl sulfoxide (DMSO)-injected mice (cRbm20(DeltaRRM)-DMSO) a

146 agent in a common organic solvent, dimethyl sulfoxide (DMSO).

147 mediates as the dominant pathway in dimethyl sulfoxide (DMSO).

148 d to K(2)CrO(4), HgSO(4) salts, and dimethyl sulfoxide (DMSO).

149 with 5% ammonium persulfate (AP) or dimethyl sulfoxide (DMSO).

150 ce of a hydroxyl radical scavenger (dimethyl sulfoxide, DMSO), and different pH values.

151 Compared to carboxyl dopants, the sulfoxide dopants further improved the electron communic

152 subject to cross-linking with disuccinimidyl sulfoxide (DSSO) and analyzed using hybrid MS2-MS3 metho

153 te in XL-MS experiments using disuccinimidyl sulfoxide (DSSO) cross-linker.

154 ariable-length derivatives of disuccinimidyl sulfoxide (DSSO) to better understand the effects of spa

155 and adopts a folded conformation in dimethyl sulfoxide due to Coulombic forces.

156 ene (TTF) in 1.0 m LiClO4 dissolved dimethyl sulfoxide electrolyte are reported.

157 dy of oxygen reduction on gold in a dimethyl sulfoxide electrolyte containing phenol as a proton sour

158 alyst combined with an ionic liquid/dimethyl sulfoxide electrolyte.

159 The sulfoxides engage in metal-free C-H trifluoromethylthiol

160 nol, but activity was observed with dimethyl sulfoxide extracts.

161 surface bound red blood cells from dimethyl sulfoxide for antigen typing.

162 of representative samples of enantioenriched sulfoxides for chiral HPLC to enable reproducible result

163 and reveal selectivity over flavin-catalyzed sulfoxide formation.

164 A novel approach to produce diaryl sulfoxides from aryl benzyl sulfoxides is reported.

165 in water that were dependent on distance of sulfoxides from chain backbones, overall side-chain leng

166 SO2), 6:2 fluorotelomerthiohydroxyl ammonium sulfoxide (FTSHA-SO), 6:2 fluorotelomer sulfonamide alky

167 d to allow the identification of N-oxide and sulfoxide functionalities in protonated polyfunctional d

168 mation on the environment of the N-oxide and sulfoxide functionalities.

169 Only ions with N-oxide or sulfoxide functionality formed diagnostic adducts that h

170 dation of aliphatic and aromatic sulfides to sulfoxides, giving quantitative conversions, high prepar

171 e prenyl group and cleavable properties of a sulfoxide group in the gas phase to produce a signature

172 Sulfoxide groups bestowed water solubility for all homol

173 o form stable isolable alpha-diazo-beta-keto sulfoxides has been achieved for the first time.

174 dynamic kinetic resolution (DKR) of allylic sulfoxides has been demonstrated by combining the Mislow

175 In recent times, sulfoxides have been given a new lease on life owing to

176 ds with different functional groups, such as sulfoxides, hydroxylamines, N-oxides, anilines, phenol,

177 ains of ADAMTS13 were oxidized to methionine sulfoxide in an HOCl concentration-dependent manner.

178 mg/kg body weight) or vehicle (20% dimethyl sulfoxide in saline) was administered intravenously at r

179 anions is introduced that affords aryl alkyl sulfoxides in high yields.

180 presented to elucidate the effect of chiral sulfoxides in inducing backbone alpha-helicity.

181 ing of amorphous enantioenriched aryl benzyl sulfoxides in the solid state can lead to substantial va

182 tributed to an allergic reaction to dimethyl sulfoxide) in the 29 patients enrolled, who received 42

183 he MS-cleavable cross-linker, disuccinimidyl sulfoxide, inter-protein cross-links spanning all MSC co

184 with diacetoxyiodobenzene directly converts sulfoxides into sulfoximines.

185 lfoxide could be utilized to generate diaryl sulfoxides involving multiple catalytic cycles by a sing

186 protocol to access substituted amino dienyl sulfoxides is also reported.

187 This practical access to alkynyl sulfoxides is expected to facilitate the application of

188 A novel route to access alkynyl sulfoxides is reported herein by using ethynyl benziodox

189 o produce diaryl sulfoxides from aryl benzyl sulfoxides is reported.

190 a metal or through the action of an external sulfoxide ligand.

191 ail the history of the development of chiral sulfoxide ligands for asymmetric catalysis.

192 ur in the reaction of 1 with mCPBA, yielding sulfoxide-ligated [Fe(II)(N3Py(amide)S(O)R)](BF4)2 (4).

193 ique aroma of Lentinula edodes, and cysteine sulfoxide lyase (C-S lyase) is the key enzyme in this tr

194 foxide and L-cysteine, and had both cysteine sulfoxide lyase and cysteine desulfurase activity.

195 teine desulfurase and not a type of cysteine sulfoxide lyase.

196 = 7, 9, and 11) of methionine (M)/methionine sulfoxide (M-ox) within the peptide sequences (PEP(Au) =

197 Mg) as well as the feasibility of asymmetric sulfoxide-magnesium exchanges (from the perspective of A

198 tem: oxidation of the methylthio groups into sulfoxides make them electron-deficient and allows their

199 roducts and Cys-SO2H, Cys-SO3H, and Met(329) sulfoxide may be potential biomarkers to assess exposure

200 The system I(2)/dimethyl sulfoxide mediates the one-step transformation of alpha-

201 We show that methionine sulfoxide, methionine sulfone, N-formylkynurenine, kynur

202 ecies (ROS) oxidize methionine to methionine sulfoxide (MetSO) and thereby inactivate proteins.

203 ecies (ROS) oxidize methionine to methionine sulfoxide (MetSO) and thereby inactivate proteins.

204 ROS oxidize methionine to methionine sulfoxide (MetSO), rendering several proteins nonfunctio

205 -Sulfox-1, which is equipped with a reactive sulfoxide moiety.

206 leimide with remarkable stereocontrol by the sulfoxide moiety.

207 s illustrated in the synthesis of methionine sulfoxide (MSO).

208 e the catalytic reduction of either dimethyl sulfoxide or trimethylamine N-oxide.

209 tively and quantitatively oxidized to either sulfoxides or sulfones by treatment with dilute hydrogen

210 pment and utilization of a novel chiral aryl sulfoxide-oxazoline (ArSOX) ligand.

211 However, the use of sulfoxides, particularly chiral sulfoxides, as ligands i

212 he phosphoric acid is to furnish a Pd(II)bis-sulfoxide phosphate catalyst that promotes allylic C-H c

213 o[(1,3-dibenzyl)imidazol-2-ylidene](dimethyl sulfoxide) platinum(II) 3a induced G2/M phase arrest.

214 methylmethionine was obtained, with dimethyl sulfoxide producing significantly less DMS with a maximu

215 lmost barrierless sulfoxidation leads to the sulfoxide product complexes.

216 and small molecules yielding stable alkenyl sulfoxide products at rates more than 100x greater than

217 ulfenate anion intermediates, and alkyl aryl sulfoxide products, the use of a mild method to generate

218 Further thermal coordination of the chiral sulfoxide ( R)-methyl p-tolylsulfoxide to the photoprodu

219 theoretical modeling support a novel mode of sulfoxide racemization which occurs via a rhodium pi-all

220 Formation of sulfoxide radical cations was unequivocally established

221 he same process occurring in aryl tert-butyl sulfoxide radical cations.

222 Enzymes of the dimethyl sulfoxide reductase (DMSOR) family catalyse two-electron

223 Mononuclear molybdoenzymes of the dimethyl sulfoxide reductase (DMSOR) family catalyze a number of

224 The methionine sulfoxide reductase (MSR) enzyme converts MetSO back to

225 Methionine sulfoxide reductase (MSR) enzyme converts MetSO back to

226 ioxidant enzymes, among which are methionine sulfoxide reductase (Msr) enzymes, which are critical fo

227 periplasmic molybdenum-dependent methionine sulfoxide reductase (MsrP).

228 Methionine sulfoxide reductase A (MsrA) is an enzyme involved in re

229 led the redox relay mechanisms of methionine sulfoxide reductase A of the pathogen Corynebacterium di

230 ling by targeting the antioxidant methionine sulfoxide reductase A to modulate liposarcoma cell survi

231 oxide dismutase (SOD2), catalase, methionine sulfoxide reductase A, and the 20S proteasome subunits P

232 ues of diverse targets, including methionine sulfoxide reductase A, myosin light chain kinase, and Ru

233 nd that a cytosolic pool of human methionine sulfoxide reductase B2 (MsrB2) is strongly recruited at

234 droplets in a manner reversed by methionine sulfoxide reductase enzymes.

235 d is regulated by the cytoplasmic methionine sulfoxide reductase Mxr1 (MsrA) and a previously unident

236 MsrPQ is a newly identified methionine sulfoxide reductase system found in bacteria, which appe

237 ia coli and the electron acceptor methionine sulfoxide reductase, also from E. coli, strongly hinted

238 cular alkenal reductase PTGR1 and methionine sulfoxide reductase.

239 ter solute-binding protein, and a methionine sulfoxide reductase.

240 thionine residues is catalyzed by methionine sulfoxide reductases (Msrs).

241 a model, we show that of the two methionine sulfoxide reductases (MXR1, MXR2), deletion of mitochond

242 e intracellular and extracellular methionine sulfoxide reductases (SpMsrAB1 and SpMsrAB2, respectivel

243 Methionine sulfoxide reductases are conserved enzymes that reduce o

244 Peptide methionine sulfoxide reductases are conserved enzymes that reduce o

245 f stereospecific enzymes known as methionine sulfoxide reductases.

246 Cd-MsrB catalyzes methionine sulfoxide reduction involving three redox-active cystein

247 Alternatively, MsrA catalyzes methionine sulfoxide reduction linked to the mycothiol/mycoredoxin-

248 Alkyl aryl sulfoxides resulted in up to quantitative yield and with

249 ) by catalyzing the oxidation of Met(7) to a sulfoxide, resulting in an aggregation-incompetent pepti

250 s (OSCs): S-allylcysteine, S-allylcysteinine sulfoxide, S-methylcysteine, and S-ethylcysteine are abu

251 ted by photochemical oxidation of the parent sulfoxides sensitized by 3-cyano-N-methylquinolinium per

252 of the bridging sulfur from sulfide (S), to sulfoxide (SO), to sulfone (SO2).

253 l acceptors have been determined in dimethyl sulfoxide solution at 20 degrees C.

254 equilibria of LMC, LEMC and LEDC in dimethyl sulfoxide solutions are also investigated.

255 o predict the stability trends in a dimethyl sulfoxide solvent from the gas-phase binding energy part

256 , FRET experiments in formamide and dimethyl sulfoxide suggest that interactions between hydrophobic

257 Due to the base sensitivity of the starting sulfoxides, sulfenate anion intermediates, and alkyl ary

258 The sulfoxide, sulfilimine, and sulfur ylid prepared from th

259 ssess a stereogenic sulfur atom and includes sulfoxides, sulfinamides, N-sulfinyl ureas, sulfoximines

260 riazolium anion recognition units containing sulfoxide, sulfone, and sulfoximine groups at C4 unveils

261 Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other deriva

262 The sulfoxide synthase EgtB represents a unique family of no

263 ecular mechanics study into the mechanism of sulfoxide synthase enzymes as compared to cysteine dioxy

264 ive-site setup of the enzyme that drives the sulfoxide synthase reaction.

265 ure of the gamma-glutamyl cysteine utilizing sulfoxide synthase, MthEgtB from Mycobacterium thermophi

266 Sulfoxide synthases are nonheme iron enzymes that cataly

267 atform to examine the catalytic mechanism of sulfoxide synthases by comparative enzymology, but also

268 products thiodiglycol (TDG) and thiodiglycol sulfoxide (TDGO) in water and sediment samples using gas

269 eir main transformation products (disulfoton sulfoxide, terbufos sulfone and disulfoton sulfone).

270 nd onions (N-acetyl-S-(1Z)-propenyl-cysteine-sulfoxide) that can be used to enhance dietary assessmen

271 methyl thioether with preference for the (S)-sulfoxide, the evolved mutant I67Q/P440F/A442N/L443I is

272 Molecular inks based on dimethyl sulfoxide, thiourea (TU), and metal salts have been used

273 thode which produces alcohols, epoxides, and sulfoxides through bioelectrochemical hydroxylation, epo

274 n proceeding via coordination of an internal sulfoxide to a metal or through the action of an externa

275 e [2,3]-sigmatropic rearrangement of allylic sulfoxides to allylic sulfenates is a reversible process

276 Diazo transfer to beta-keto sulfoxides to form stable isolable alpha-diazo-beta-keto

277 employed with alkyl 2-(trimethylsilyl)ethyl sulfoxides to liberate the requisite alkyl sulfenate ani

278 rganic solvents such as glycerol or dimethyl sulfoxide, to promote vitrification and prevent ice form

279 lter cell viability in untreated or dimethyl sulfoxide-treated cells; however, it did increase the CG

280 These amido dienyl sulfoxides undergo highly selective Diels-Alder cycloadd

281 es of MTEGE can be selectively oxidized into sulfoxide units, leading to full disassembly of the mice

282 -chloroethyl ethyl sulfoxide and vinyl ethyl sulfoxide using nearly stoichiometric 3 % aqueous H2 O2

283 ent malignant neoplasms; trametinib dimethyl sulfoxide was approved by the US Food and Drug Administr

284 ies, particularly when solvation by dimethyl sulfoxide was taken into account by applying the SMD con

285 iodide and solid sodium hydroxide in methyl sulfoxide was used for the first time for analysis of bl

286 Interestingly, when dimethyl sulfoxide was used instead of Triton((R)) X-100 in the e

287 n and the base promoted elimination of alkyl sulfoxides was overridden.

288 Irgarol sulfoxide and terbutryn sulfoxide were detected in the effluents (average concen

289 s(34)-sulfonic acid (Cys-SO3H), and Met(329) sulfoxide were greatly increased.

290 oxidative stress such as urinary methionine sulfoxide were observed in Hhip (+/-) but not in Hhip (+

291 l, ethanol, caffeine, nicotine, and dimethyl sulfoxide were tested as model chemical stressors.

292 clic and benzofused ketone derived beta-keto sulfoxides were successfully explored as substrates for

293 elomer sulfoxide amido sulfonate (10:2-FTSAS-sulfoxide) were also occasionally reported after the AFF

294 ve utilized the chemical denaturant dimethyl sulfoxide which, in conjunction with a short thermal den

295 ntial variation in enantiopurities, even for sulfoxides which do not show detectable levels of self-d

296 , hydrotris(pyrazolyl)borate; DMSO, dimethyl sulfoxide), which has a fluctuating valence due to two m

297 e bromination using HBr paired with dimethyl sulfoxide, which serves as the oxidant as well as cosolv

298 etonitrile, pure or as mixture with dimethyl sulfoxide, which were added postcolumn to the eluting sa

299 The reaction of chiral (hetero)aryl benzyl sulfoxides with Grignard reagents affords enantiomerical

300 compatible with aryl, heteroaryl, and alkyl sulfoxides with up to 90% yield.