ライフサイエンスコーパス: supercooled

1 ft for pure liquid water as it is cooled and supercooled.

2 s found to be stable from ambient (300 K) to supercooled (259 K) temperatures, although a lower-densi

3 ture, from ambient temperature to the deeply supercooled and amorphous states, and of water diffusive

4 on of the phase diagram, where water is both supercooled and at negative pressure.

5 s for packing fractions corresponding to the supercooled and glassy regimes, which are probed via con

6 We review the recent research on supercooled and glassy water, focusing on the possible o

7 ion fine structure features was observed for supercooled and normal liquid water droplets prepared fr

8 ical sulfur generation, we show that liquid (supercooled) and solid elementary sulfur possess very di

9 report direct computational evidence that in supercooled aqueous nanodroplets a lower density core of

10 are often restricted to aprotic solvents or supercooled aqueous solutions.

11 Our work sheds light on water's supercooled behavior and opens the door to experimental

12 Only particle-resolved data from liquids supercooled below the MCT crossover can reveal the micro

13 The first mode, occurring for isothermally supercooled bubbles, generates a strong Marangoni flow t

14 We find that the onset of the Boson peak in supercooled bulk water coincides with the crossover to a

15 he two competing scenarios for understanding supercooled bulk water.

16 Here we report viscosity of water supercooled close to the limit of homogeneous crystalliz

17 ability of anthropogenic aerosols to freeze supercooled cloud droplets remains debated.

18 rument, it appears that the variation in the supercooled cloud fraction is negatively correlated with

19 ulations, show that the 20% variation in the supercooled cloud fraction is quantitatively important i

20 20 degrees C, the global average fraction of supercooled clouds in the total cloud population is foun

21 and their multiplication factors in slightly supercooled clouds using a multisensor, remote-sensing t

22 to the cold cloud layer effectively glaciate supercooled clouds.

23 within a confluent layer and the dynamics of supercooled colloidal and molecular fluids approaching a

24 est near the alpha-relaxation time scale for supercooled colloidal fluids, but were also present, alb

25 ration between adjacent nucleation sites for supercooled condensate is properly controlled with chemi

26 owth of ice bridges across the population of supercooled condensate.

27 table liquid-liquid critical point at deeply supercooled conditions and that this critical point is c

28 water has a second critical point at deeply supercooled conditions was formulated to provide a therm

29 the displacement and density correlations at supercooled conditions, which are consistent with observ

30 inates at a critical point located at deeply supercooled conditions.

31 a lower-density liquid would be expected at supercooled conditions.

32 ive due to rapid ice nucleation under deeply supercooled conditions.

33 the SHB lifetime at 227 K suggests that the supercooled critical point may correspond to a phase tra

34 A transition in the rapidly supercooled disordered material, from an ergodic liquid-

35 At T < 40 degrees C the supercooled disordered state evolves into a metastable D

36 Remarkably, the DDQC forms only from the supercooled disordered state, whereas the sigma phase gr

37 liquid-liquid phase transition (LLPT) in the supercooled domain.

38 so observed a rotary action in the suspended supercooled drop driven by repetitive transitions (a pol

39 ir ice-nucleating ability when immersed in a supercooled droplet.

40 the edge-to-edge separation between adjacent supercooled droplets decreases with growth time, deliber

41 ese observations are consistent with charged supercooled droplets or ice particles as intermediates i

42 In supercooled droplets the enrichment of the subsurface in

43 nteraction of rapidly solidifying, typically supercooled, droplets with surfaces, and to harvest bene

44 ing point for investigating the structure of supercooled (electro)sprayed droplets that are used to p

45 the relaxation times near the surface of the supercooled equilibrium liquid films of these molecules

46 shorter beta-relaxation time scales, in both supercooled fluid and glass colloidal phases.

47 acteristic cluster size grew markedly in the supercooled fluid as the glass transition was approached

48 mensional dynamics of particles in colloidal supercooled fluids and colloidal glasses.

49 rcooled fluids is more stretched than for 3D supercooled fluids and does not exhibit a plateau, which

50 The process by which supercooled fluids form stable, crystalline solids has b

51 The dynamic modulus for 2D supercooled fluids is more stretched than for 3D superco

52 lusters, which serve as tracers in colloidal supercooled fluids.

53 Nanotubes crystallize inside the supercooled, glass-coated liquid-carbon drops.

54 e structural and thermodynamic properties of supercooled glycerol-water microdroplets at dilute condi

55 Our group previously showed that supercooled ice-free storage at -6 degrees C can extend

56 nature of the dynamics of fluids as they are supercooled, leading to the concept of a dynamic crossov

57 The nature of the transformation by which a supercooled liquid 'freezes' to a glass--the glass trans

58 ntify a previously unidentified high-density supercooled liquid (HD-SCL) phase with a liquid-liquid p

59 a glass cannot exceed that of the metastable supercooled liquid (SCL) state, unless crystals are nucl

60 les that determine many important aspects of supercooled liquid and glass phenomenology.

61 The dynamics of supercooled liquid and glassy systems are usually studie

62 ultaneously explains both the equilibrium of supercooled liquid and the thermal hysteresis observed i

63 The increasingly sluggish response of a supercooled liquid as it nears its glass transition (for

64 icles from an equilibrium configuration of a supercooled liquid at a temperature T.

65 sure-temperature region similar to where the supercooled liquid Bi is observed.

66 r is a notoriously poor glassformer, and the supercooled liquid crystallizes easily, making the measu

67 Our results reveal a transient dense supercooled liquid crystallizes into a semi-disordered d

68 -phase clouds consisting of ice crystals and supercooled liquid droplets are constrained by global sa

69 ozen droplets harvest water from neighboring supercooled liquid droplets to grow ice bridges that pro

70 he need for realistic representations of the supercooled liquid fraction in mixed-phase clouds in GCM

71 The supercooled liquid has been probed experimentally to nea

72 Its supercooled liquid has divergent thermodynamic response

73 n, we have simulated an atomistic model of a supercooled liquid in three and four spatial dimensions.

74 e of the microphase-separated domains in the supercooled liquid influences the ability to form stable

75 A redox-active supercooled liquid is obtained by forming a "solvate ion

76 On heating, the glass transition into the supercooled liquid is shown by the 85Al and 84Al glasses

77 sed-form expression for the fragility of the supercooled liquid metal in terms of few crucial atomic-

78 k at low q values that is not present in the supercooled liquid or melt-quenched glasses.

79 ike o and A15, HCP nucleates directly from a supercooled liquid or soft solid without proceeding thro

80 ates requires thermalizing the system in the supercooled liquid phase, where the thermalization time

81 temperature increase, the alloy reenters the supercooled liquid phase, which forms the room-temperatu

82 an 1,000 kelvin have been developed, but the supercooled liquid region (between the glass transition

83 tion temperature of up to 1,162 kelvin and a supercooled liquid region of 136 kelvin that is wider th

84 alloys have a hidden amorphous phase in the supercooled liquid region.

85 al evidence of surface-induced nucleation in supercooled liquid silicon and germanium, and we illustr

86 that Zr-based metallic alloy, heated to the supercooled liquid state under hydrostatic pressure and

87 the properties expected for the equilibrium supercooled liquid state, and optimal stability is attai

88 ing from the disordered structure and unique supercooled liquid state, promote the fast coalescence o

89 d metallic glasses are prepared by quenching supercooled liquid under pressure.

90 Ice crystals in the atmosphere nucleate from supercooled liquid water and grow by vapor uptake.

91 ays where a particle is either immersed in a supercooled liquid water droplet (immersion freezing mod

92 diative properties of clouds containing both supercooled liquid water droplets and ice particles (mix

93 nt in mixed-phase clouds, which contain both supercooled liquid water droplets and ice particles, aff

94 vel, mixed-phase clouds (i.e., consisting of supercooled liquid water drops and ice crystals).

95 he fraction of four-coordinated molecules in supercooled liquid water explains its anomalous thermody

96 ate that ice nucleated and grown from deeply supercooled liquid water is metastable stacking disorder

97 nding liquid-liquid critical point (LLCP) in supercooled liquid water remains a topic of much debate.

98 We prepared bulk samples of supercooled liquid water under pressure by isochoric hea

99 The self-diffusion of supercooled liquid water, D(T), is obtained from G(T) us

100 lenge theories that connect amorphous ice to supercooled liquid water.

101 arrangements of the type responsible for the supercooled liquid's high viscosity account quantitative

102 nd that Ice 0 is structurally similar to the supercooled liquid, and that on growth it gradually conv

103 In the supercooled liquid, many quantities, for example heat ca

104 Akin to supercooled liquid, the pressure-induced metastable liqu

105 stems from the swift atomic diffusion in the supercooled liquid, which matches or even surpasses the

106 observational evidence for the glaciation of supercooled liquid-water clouds at industrial aerosol ho

107 rements also indicate substantial regions of supercooled liquid.

108 re temperature range of the existence of the supercooled liquid.

109 A "supercooled" liquid develops when a fluid does not cryst

110 n or more cell sizes that are reminiscent of supercooled liquids and active nematics.

111 known to occur in confined liquids, exist in supercooled liquids and emerge in liquids driven from eq

112 We propose an Eulerian formulation of supercooled liquids and glasses that allows for a simple

113 cage stage characteristic of the dynamics in supercooled liquids and glasses, consistent with its int

114 in a propensity for these materials to form supercooled liquids and glasses, rather than undergoing

115 lar forces give rise to complex behaviour in supercooled liquids and glasses.

116 behavior similar to the plateaus observed in supercooled liquids and glasses.

117 nal entropy on the structure and dynamics of supercooled liquids and metallic glasses, which are asso

118 precise picture of dynamic heterogeneity in supercooled liquids and other complex systems.

119 xperimental study of the coherence length in supercooled liquids and other glass formers.

120 Which phenomenon slows down the dynamics in supercooled liquids and turns them into glasses is a lon

121 teresting behavior that has been observed in supercooled liquids appears to be related to dynamic het

122 Supercooled liquids are characterized by their fragility

123 e at the nanoscale, one may expect to obtain supercooled liquids below the bulk homogeneous nucleatio

124 Kauzmann paradox (KP) suggests that deeply supercooled liquids can have a lower entropy than the co

125 Classic supercooled liquids exhibit specific identifiers includi

126 tended to predict the dynamical behaviour of supercooled liquids in general.

127 hing the glass transition, the relaxation of supercooled liquids is controlled by activated processes

128 al information and the dynamic properties of supercooled liquids is one of the great challenges of ph

129 Supercooled liquids near the glass transition exhibit th

130 dered materials such as metallic glasses and supercooled liquids occurs via the cooperative rearrange

131 al microscopic dynamics, akin to the ones in supercooled liquids or glasses.

132 Studies of these supercooled liquids reveal a considerable diversity in b

133 For decades, scientists have debated whether supercooled liquids stop flowing below a glass transitio

134 consensus on a theory of the transition from supercooled liquids to glasses, the experimental observa

135 uctural glasses including window glasses and supercooled liquids, and may be applicable across many s

136 ic perspective of the relaxation behavior of supercooled liquids, associated expanded phase diagram,

137 In supercooled liquids, dynamical facilitation refers to a

138 a polyamorphous phase transition between two supercooled liquids, involving a change in the packing o

139 rmation about the local molecular packing in supercooled liquids, meaning that the order parameter of

140 mployed single molecule approach to studying supercooled liquids, the measurement of rotational dynam

141 sure the configurational entropy Sigma(T) in supercooled liquids, using a direct determination of the

142 Glasses are often described as supercooled liquids, whose structures are topologically

143 y collected data of probes in small molecule supercooled liquids.

144 dying dynamics of complex systems, including supercooled liquids.

145 the elementary units of relaxation in deeply supercooled liquids.

146 e or glassy phases, superheated crystals, or supercooled liquids.

147 ve crossover MSD behaviors commonly found in supercooled liquids.

148 ariations linked to dynamic heterogeneity in supercooled liquids.

149 e balance is what distinguishes glasses from supercooled liquids.

150 o considered for the dynamics of glasses and supercooled liquids.

151 tation in governing structural relaxation in supercooled liquids.

152 materials, such as meta-stable undercooled (supercooled) liquids, have been widely recognized as a s

153 The existence of ferroelectric order in supercooled low-density liquid water is confirmed by the

154 therefore exhibits the characteristics of a supercooled magnetic liquid.

155 hexadecane into its triclinic phase from the supercooled melt was directly observed with time-resolve

156 quid phase transition in this metallic alloy supercooled melt.

157 low to high density liquid transition in the supercooled melt.

158 relevant length scales in crystallization of supercooled metallic glasses, thus offering accurate pro

159 he fast kinetics and structural behaviour of supercooled metallic liquids within the nanosecond to pi

160 pha), when the glassy state is approached in supercooled molecular liquids.

161 In contrast, the liquid-crystal phase in supercooled n-butanol is found to inhibit transformation

162 ctrochemical advantage while maintaining its supercooled nature and the liquid shows a high energy de

163 of surface or bulk preference at either the supercooled or ambient condition, a phenomenon not previ

164 distinguishable at the critical point in the supercooled phase.

165 tructure similar to that of dense fluids and supercooled phases at intermediate range up to 4.2 A, an

166 with cryoprotectants to facilitate long-term supercooled preservation.

167 us phases to two liquid waters in the deeply supercooled regime (below 228 kelvin) to explain many of

168 r simulations with the mW water model in the supercooled regime around T(H) which reveal that a sharp

169 rystallization and gain access to the deeply supercooled regime down to T = 229.3 K.

170 Despite its importance in distinguishing the supercooled regime from the high-temperature regime, the

171 dipolar elastic excitations, delineates the supercooled regime from the high-temperature regime.

172 e hydrogen-bonding environment in the deeply supercooled regime surprisingly remain in bulk water eve

173 eveals a first-order phase transition in the supercooled regime with the critical point at ~207 K and

174 r below the freezing point, in the so-called supercooled regime, has nowadays been observed in severa

175 In this supercooled regime, the relaxation dynamics also proceed

176 n viscosity and diffusion coefficient in the supercooled regime.

177 r, consistent with experiments in the deeply supercooled regime.

178 h extrapolation of the IAPWS equation in the supercooled regime.

179 4)Y(2)C(15)B(6) metallic glass powder in the supercooled region are investigated by an integrated ex-

180 Studies of liquid water in its supercooled region have helped us better understand the

181 ater anomalously increase on moving into the supercooled region, according to power laws that would d

182 of water in the experimentally inaccessible supercooled region.

183 lable from lower-field NMR investigations on supercooled samples, involving mostly nonlabile nuclei.

184 aea strain 34H (Cp34H) in subzero brines and supercooled sea water through long-term incubations unde

185 demonstrate that evaporation from a freezing supercooled sessile droplet, which starts explosively du

186 els for supercooled water, liquid carbon and supercooled silica predict a LDL-HDL critical point, but

187 0 mM) at pH 8.5 at 22 +/- 2 degrees C and in supercooled solution at -6 +/- 2 degrees C.

188 The rate of the reaction decreased 6-fold in supercooled solution at -6 +/- 2 degrees C.

189 the two structural species postulated in the supercooled state are seen to exist in bulk water at amb

190 l in its elementary form S(8), can stay in a supercooled state as liquid sulfur in an electrochemical

191 Cooling to a supercooled state is controlled, followed by 3 h of SNMP

192 molecular liquids have been observed in the supercooled state, suggesting an intimate connection wit

193 liquids can be maintained for some time in a supercooled state, that is, at temperatures below their

194 emperature range that provides access to the supercooled state.

195 tigated over a wide temperature range in the supercooled state.

196 cular structure and dynamics of water in its supercooled state.

197 standing its putative exotic behavior in the supercooled state.

198 The combination of supercooled storage and E-Sol5 helped to preserve ATP an

199 Supercooled storage at -4 degrees C showed markedly lowe

200 However, RBC metabolism during supercooled storage in standard or alkaline additives re

201 sion include alkaline additive solutions and supercooled storage to extend storage by reducing metabo

202 While supercooled storage with E-Sol5 offers a promising alter

203 echnology, be it a rain droplet falling on a supercooled surface; in inkjet printing, where often mol

204 strong evidence of dynamic heterogeneity in supercooled systems.

205 sonance experiments of mouse and human aS at supercooled temperatures (263 K) are used to understand

206 -ray absorption spectroscopy from ambient to supercooled temperatures at relative humidity up to 95%.

207 formation of optically thin liquid clouds at supercooled temperatures--a process potentially necessar

208 table crystal phase exist at the same deeply supercooled thermodynamic condition, and that the transi

209 not include the necessity for liquids to be supercooled to below their melting point before freezing

210 he physical requirement that liquids must be supercooled to below their melting point before freezing

211 of the crystallization from liquid hydrogen, supercooled to temperatures below the melting point, usi

212 ations, here we show that glassy dynamics in supercooled two- and three-dimensional fluids are fundam

213 ic (long-range order-making) "ice makers" of supercooled water (SCW).

214 ced ring-flipping rate constant of Phe 45 in supercooled water allowed very precise determination of

215 hase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids o

216 erpolation between ambient pressure data for supercooled water and high pressure data for stable wate

217 g the liquid below the melting point such as supercooled water and silicon.

218 nces intramolecular spatial interactions via supercooled water and uses the resulting spatial correla

219 ications for NMR-based structural biology in supercooled water are addressed.

220 pared to bulk water often forming metastable supercooled water at subzero temperatures on the Celsius

221 othesis of ferroelectric phase transition in supercooled water can be traced back to 1977, due to Sti

222 s of a typical storm cloud, in which ice and supercooled water coexist, no direct influence of the pl

223 study of halide anion solvation in a deeply supercooled water droplet (with diameter approximately 1

224 Supercooled water droplets are widely used to study supe

225 the process that occurs for atmospherically supercooled water droplets at the air-water interface.

226 ice nucleation by particles immersed within supercooled water droplets.

227 However, supercooled water exhibits fascinating and complex dynam

228 ctural transformations of transiently heated supercooled water films, which evolved for several nanos

229 riments indicate that the surface tension of supercooled water follows a smooth extrapolation of the

230 ral relaxation and crystallization of deeply supercooled water for 170 K < T < 260 K.

231 e putative liquid-liquid phase transition in supercooled water has been used to explain many anomalou

232 However, fast crystallization of supercooled water has impeded identification of the LLT

233 loud droplets can explain why low amounts of supercooled water have been observed in the atmosphere n

234 of the Boson peak reported in experiments on supercooled water in nanoconfined pores, and in hydratio

235 the proposed liquid-liquid critical point in supercooled water in the No-Man's Land regime, and indic

236 redictions of two-state "mixture" models for supercooled water in the supercritical regime.

237 , and the "fragile-to-strong" transition for supercooled water is interpreted by adding a "critical p

238 Understanding deeply supercooled water is key to unraveling many of water's a

239 hat ice that crystallizes homogeneously from supercooled water is neither of these phases.

240 . suggested that the anomalous properties of supercooled water may be caused by a critical point that

241 report direct computational evidence that in supercooled water nano-droplets ice nucleation rates are

242 gion of temperatures, T, and pressures where supercooled water rapidly crystallizes-a region often re

243 , no data are available for the viscosity of supercooled water under pressure, in which dramatic anom

244 ported volume-based freezing rates of ice in supercooled water vary by as many as 5 orders of magnitu

245 a metastable liquid-liquid critical point in supercooled water whereby two distinct liquid phases of

246 escribes all available experimental data for supercooled water with better quality and fewer adjustab

247 oled water droplets are widely used to study supercooled water(1,2), ice nucleation(3-5) and droplet

248 de range of temperatures (from 400 K down to supercooled water) and pressures (from ambient up to mul

249 ar prevented decisive measurements on deeply supercooled water, although this challenge has been over

250 geneous freezing rates of ice in droplets of supercooled water, both in air and emulsion oil samples,

251 /or chemical exchange processes occurring in supercooled water, can be expected to be well estimated

252 results demonstrate that dust, by glaciating supercooled water, can decrease albedo, thus compensatin

253 mics simulations of very specific models for supercooled water, liquid carbon and supercooled silica

254 r a liquid-liquid phase transition (LLPT) in supercooled water, which would unify our understanding o

255 hepcidin was determined at 325 and 253 K in supercooled water.

256 le at ambient T can be effectively slowed in supercooled water.

257 pport for a liquid-liquid transition in bulk supercooled water.

258 structure functions measured for ambient and supercooled water.

259 uid-liquid transition (LLT) in high-pressure supercooled water.

260 ved water models are needed for the study of supercooled water.

261 at 298 K and the critical point at 227 K in supercooled water.

262 c heat (the Gruneisen parameter Gamma(s)) in supercooled water.

263 ucleation rate in a freestanding nanofilm of supercooled water.

264 ng analogies with the features of liquid and supercooled water.

265 is interpreted within the thermodynamics of supercooled water.

266 me, motional modes of a protein dissolved in supercooled water: the flipping kinetics of phenylalanyl