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1 deactivating the 1,2-H shift kinetically and thermodynamically.
2 aporation effects are controlled kinetically/thermodynamically.
3 gas subjected to spin current can be treated thermodynamically.
4 ead to cleavage of this bond, very favorable thermodynamically.
5 1) The semiquinone, Q(B) (*-), is stabilized thermodynamically; 2) the resulting E(m) Q(B)/Q(B)H(2) (
6 ified yeast F(1)F(0) ATP synthase, although, thermodynamically, a sufficiently high driving force was
7 atization renders the overall transformation thermodynamically accessible despite the moderate reacti
8 ate signaling and transcription factors, and thermodynamically activate substrates for oxidation or b
9 hth key metabolite is molecular oxygen (O2), thermodynamically activated for reduction by one electro
10 ated muscle thin filaments are thought to be thermodynamically activated in response to an increase i
11 ein function, in which binding of one ligand thermodynamically activates the binding of another, diff
17 ate that an extensional flow readily unfolds thermodynamically and kinetically stable proteins, expos
18 uence the nucleation and growth process both thermodynamically and kinetically, which contributed to
20 table than those prepared at low pH and were thermodynamically and morphologically similar to natural
22 e self-assembly of graphene sheets is driven thermodynamically, as graphite is found to act as a 2D s
23 at the structure alternatives are controlled thermodynamically by the nucleation, while kinetically b
25 t molecular machines are extremely efficient thermodynamically compared with their macroscopic counte
26 dency of Ail is offset by the evolution of a thermodynamically compromised primary sequence that bala
28 ooled conditions was formulated to provide a thermodynamically consistent interpretation of numerous
29 s assessing the plausibility of a connected, thermodynamically consistent proto-metabolism under diff
30 sis in the forward and reverse reactions are thermodynamically consistent, complying with the expecte
31 vious mathematical models, we present a new, thermodynamically consistent, statistical-mechanical mod
32 pic space, the reversibility of reactions is thermodynamically constrained in modern metabolic networ
33 predicted gene essentiality as accurately as thermodynamically constrained networks, but predicted su
35 nvolves the space group change Cc->Pc and is thermodynamically continuous, while the second, Pc->P1 a
36 ctions with electrophiles are kinetically or thermodynamically controlled and whether the rates are a
38 lent modification, or through the use of new thermodynamically controlled covalent bond forming metho
41 monstrate a straightforward strategy for the thermodynamically controlled fabrication of multicompone
46 such features, Schiff base condensations are thermodynamically controlled, which, in the case of reac
47 fect-induced local polar heterogeneities are thermodynamically coupled with the host polarization to
51 methodology shows that both solvents should thermodynamically decompose in the double layer prior to
52 0.55 V in overpotential with respect to the thermodynamically demanding reduction-first pathway, whi
56 a phenyl ring is because the cyclization is thermodynamically disfavorable, subsequently deactivatin
57 igned to stabilize otherwise kinetically and thermodynamically disfavored 6-membered alkyl palladacyc
58 annane cation radicals; however, loss of the thermodynamically disfavored aryl radicals remains compe
59 ones is kinetically controlled, and slightly thermodynamically disfavored in the five-membered ring s
60 the formation of the unsaturated alcohols is thermodynamically disfavored over the saturated aldehyde
63 romatic hydrocarbon benzene, C-C cleavage is thermodynamically disfavored, and is brought about only
64 an that for water (pK(a)(H3O(+)) = 0), which thermodynamically disfavors a concerted proton transfer
65 ly separate GSH and GAQ gating, which report thermodynamically distinct initial and final steps, resp
66 ism is more complex and instead involves two thermodynamically distinct solid solutions in which the
67 s the epimerization of the cis-isomer to the thermodynamically downhill trans-isomer via a hypothesiz
68 s the free energy released in the process to thermodynamically drive proton pumping across its membra
69 ed to an energy transduction step that could thermodynamically drive proton pumping in complex I.
72 triggered by a hydrometalation event and is thermodynamically driven by the refunctionalization of a
73 chanism for axial configuration is primarily thermodynamically driven by the vapor-liquid-solid growt
74 in the absence of ribosomal DNA, whereas the thermodynamically driven components assemble but lose te
75 ce modification, as opposed to promoting the thermodynamically driven dissolution common for molecule
76 the alloyed interface of core/shell QDs is a thermodynamically driven process to minimize the lattice
77 nd show that a small number of particles are thermodynamically driven to rearrange in regions of low
80 ms such as gases or liquids is predominantly thermodynamically driven-a mixture of two gases will ten
85 oxorubicin-GSH adduct formation kinetics are thermodynamically estimated from its reduction potential
86 rature hydrogenation requires materials that thermodynamically favor metal atom isolation over cluste
88 functional theory (DFT) simulations found a thermodynamically favorable and non-OH(*) mediated pathw
89 sociation despite the overall reaction being thermodynamically favorable at ambient temperatures and
90 bcg4 dimer suggested that desmosterol showed thermodynamically favorable binding at the putative ster
92 sampled on the ground state, with the former thermodynamically favorable by approximately 3 kcal/mol.
93 phase spaces are studied, and more than ten thermodynamically favorable compositions with a hardness
94 ino acids with a catalytically efficient and thermodynamically favorable diol formation pathway, crea
95 enesis and two CO(2) reduction pathways, are thermodynamically favorable even under very low substrat
96 membered ring can be achieved instead of the thermodynamically favorable five-membered rings under ap
97 acement (AGR) reactions because they are not thermodynamically favorable for bulk-sized Au under thes
98 which desaturates rather than performing the thermodynamically favorable hydroxylation of substrate.
99 zation is also predicted to be slightly more thermodynamically favorable in the polymerase relative t
100 s indicated that fibrinogen has a strong and thermodynamically favorable interaction with zeolite nan
101 nucleation sites, allowing the formation of thermodynamically favorable nanofibrils following Ostwal
102 pattern conducive to the proton relay is not thermodynamically favorable on the ground state but beco
103 the 2,9-Me(2)-phen ligand are due to a more thermodynamically favorable oxidative addition of aryl C
104 A key step in the proposed mechanisms is a thermodynamically favorable PCET reaction composed of in
105 e (BH(3) -HCOO)(-) centers that display more thermodynamically favorable reaction and potentially fas
108 terminate neurotransmission by coupling the thermodynamically favorable transport of ions to the the
109 er reactions slow down when they become very thermodynamically favorable, a counterintuitive interpla
110 more kinetically accessible, as well as more thermodynamically favorable, than cyclizations of the an
115 ever, two factors can make the C-S scissions thermodynamically favorable: increased entropy, characte
116 cts, and is a nucleated process that remains thermodynamically favored at lower temperatures, but is
117 vored spin-pairing, and the formation of the thermodynamically favored diamagnetic five-coordinate S-
118 le interactions between two trans THFAs or a thermodynamically favored dimer with a double hydrogen-b
119 boronic acid is ortho to the azo group, the thermodynamically favored E isomer binds weakly with dio
120 terestingly, we find that these features are thermodynamically favored even in the absence of a heter
121 ggregates, which can be transformed into the thermodynamically favored J-aggregates by seed-induced l
123 uanosin-N1-yl radical (dG(N(1)-H)(*)) is the thermodynamically favored one-electron oxidation product
124 s that undergo rapid 1,2-boron shift to form thermodynamically favored secondary radicals, allowing f
127 ne-dimensional fibrous nanostructures as the thermodynamically favored states in solvents of low pola
128 bond cleavage is energetically feasible and thermodynamically favored through an electrophilic rearr
130 m this ferric intermediate, hydroxylation is thermodynamically favored, but chlorination is intrinsic
133 taG (r) ) can identify whether a reaction is thermodynamically favourable and quantify the accompanyi
134 emperatures, while the hcp structure is more thermodynamically favourable at lower temperatures.
136 ulfide and intermediate sulfur compounds are thermodynamically favourable in the groundwater, which i
137 vation energy for atom dispersion by forming thermodynamically favourable metal-defect bonds and the
138 Subvalent doping by Ge on the Nb site is thermodynamically favourable process and a potential str
141 r respective ATP yield categories and remain thermodynamically feasible across a wide range of ATP/AD
143 Computational studies indicate that it is thermodynamically feasible to synthesize FAU with SAR=2-
147 tence of high- and low-temperature phases is thermodynamically impossible during a second-order phase
148 s, enabling them to adopt what are otherwise thermodynamically inaccessible functional conformations.
149 Ostwald's rule of stages and proceed toward thermodynamically increasingly stable, more dense phases
150 lidin-5-ones is favored both kinetically and thermodynamically independently of the solvent, in agree
154 The protein drug, rhGM-CSF, was partitioned thermodynamically into a dextran dispersed phase of the
155 they chemical, mechanical or electrical, are thermodynamically irreversible and therefore suffer from
156 s, and quantifies their number-density that, thermodynamically, is more representative of metabolism
157 e O2s exciton, which is the most favored one thermodynamically, is unreactive because of a high prope
158 e highest tested pH(MER) of 7.5 and thus the thermodynamically least favorable conditions for iron ox
160 Theoretical calculation suggests that the thermodynamically less favorable core-shell Ag@Au nanost
161 ergy differences make cryptomelane formation thermodynamically less favorable than birnessite formati
162 and consequently enables the observation of thermodynamically less favored and therefore low populat
163 ving hydrogen atom assisted isomerization of thermodynamically less stable isomers of [4]-helicene mi
165 ent iodine form (I-CF(3)) of the reagents is thermodynamically less stable than its acyclic ether iso
166 nomeric ApoE3 and ApoE4, which renders ApoE4 thermodynamically less stable, less structured, and topo
167 r, the efficient synthesis of diastereopure, thermodynamically less stable, Z-alkenes is still challe
169 Among the various gas-to-liquid methods, the thermodynamically-limited Methane DehydroAromatization (
172 tions revealed that dealkylation reaction is thermodynamically more favorable than deprotonation.
173 chloramine, and tribromamine are found to be thermodynamically more favorable than was previously bel
176 eletons, which were further transformed into thermodynamically more stable 1H- and 6H-tautomers, resp
177 spontaneously rearranged into the larger and thermodynamically more stable complex [NH(4)(+)C o-Me(2)
179 d in the transformation of ferrihydrite into thermodynamically more stable goethite or magnetite.
180 o-called diazocines, have emerged, which are thermodynamically more stable in their bent cis-form.
181 ny of these ligands are azobenzenes that are thermodynamically more stable in their elongated trans-c
182 poorly crystalline into more crystalline and thermodynamically more stable iron (oxyhydr)oxides.
185 ne month, the PCO-isomer rearranges into the thermodynamically more stable POC-isomer of the cage-lik
186 RAF pathways are faster, but HAT yields thermodynamically more stable radical products, indicati
188 ntal facts indicate that m-C(2)B(10)H(12) is thermodynamically more stable than o-C(2)B(10)H(12).
189 pounds with polycyclic structures, which are thermodynamically more stable than the corresponding pi-
190 ron oxyhydroxide (ferrihydrite structure) is thermodynamically more stable than the equivalent undope
191 ow that the perovskite (SH(-) )(H3 S(+) ) is thermodynamically more stable than the Im3 m structure o
193 dimerization of norbornadiene (NBD) into its thermodynamically most stable dimer, heptacyclo[6.6.0.0(
194 eriments, RRKM calculations predict that the thermodynamically most stable isomer - the polycyclic ar
195 rom the nonbulky end of the rod to reach the thermodynamically most stable state before unfolding-med
196 trong aliphatic C-H bond is activated, while thermodynamically much weaker aliphatic C-H groups, that
200 hange of interlayer K(+) for Cs(+) is nearly thermodynamically nonselective, recent experiments show
201 Gold nanoparticle tags are prepared with thermodynamically optimized nucleic acid toehold probes
202 olysulfide phase in the sulfide electrode is thermodynamically phase-separated from the superconcentr
205 e of L, with smaller phosphines favoring the thermodynamically preferred (from DFT calculations) tran
206 versely, HA from Ch positions other than the thermodynamically preferred C7 or C4 has never been repo
212 the problem becomes purely geometrical: the thermodynamically preferred state should maximize the nu
215 ion potential of the distal [4Fe-4S] cluster thermodynamically restricts the Fdox/Fdred ratio at whic
218 lective construction of bis-spiroketals with thermodynamically similar stereoisomers, providing a new
220 n ethylamine pendant arm was found to form a thermodynamically stable (log K(MnL) = 19.01, pMn = 9.27
221 ex [NH(4)(+)C o-Me(2)-2.2.1] was found to be thermodynamically stable (negligible intermolecular rear
223 higher formation energy, as compared to the thermodynamically stable 2H phase, thus in standard chem
224 , in the carbon family, graphite is the most thermodynamically stable allotrope, conversion of other
225 lattice, where complete conversion into the thermodynamically stable alpha-domain is shown in dyspro
226 s and ending with kinetically accessible and thermodynamically stable amyloid fibril structures.
227 ntrast to azobenzenes the Z configuration is thermodynamically stable and the E isomer is metastable.
228 also give rise to such structures which are thermodynamically stable at moderate to low temperatures
229 these observations and predicts that LAMP is thermodynamically stable below a critical chiAC, above w
232 are relatively unknown compared to the more thermodynamically stable calcium carbonate polymorph, ca
235 superhelicity is necessary, which leads to a thermodynamically stable complex between hnRNP K and the
236 h pair of orientational BN isomers, the more thermodynamically stable compound has the lower HOMO ene
237 ond anvil cell, we report the discovery of a thermodynamically stable compound of helium and sodium,
238 an extremely complex phase diagram, with new thermodynamically stable compounds K3Cl, K2Cl, K3Cl2, K4
240 f metastable cross-alpha-helical crystals to thermodynamically stable cross-beta-sheet-like fibrils b
241 (e.g., SiO(2), phosphine oxides, SO(2)) with thermodynamically stable E-O bonds, which accrue in larg
242 the nucleation density dramatically under a thermodynamically stable environment, yielding uniform a
245 structures are available, they refer to the thermodynamically stable forms but little or no informat
246 rs over several tens of seconds during which thermodynamically stable inner-sphere Rb(+) slowly trans
248 in evaluating the hypothesis that DOM forms thermodynamically stable molecular aggregates that as a
249 l alcohol) (PVA), are used to illustrate the thermodynamically stable morphologies of GO and relevant
250 ing support for not only metastable but also thermodynamically stable multimeric clusters in aqueous
252 beta(16-22) Our results reveal that the only thermodynamically stable phases are the solution phase a
257 cal nucleation mechanism via the assembly of thermodynamically stable prenucleation clusters, as well
258 showing that the pyrrole adduct is the most thermodynamically stable product compared to Michael add
259 found that B/CRAF heterodimers are the most thermodynamically stable RAF dimers, suggesting that RAF
260 self-assemble into colloidal monolayers with thermodynamically stable rafts exhibiting chiral structu
261 y preferentially via processes which produce thermodynamically stable ring structures, e.g. diketopip
262 repetitive DNA sequences that can fold into thermodynamically stable secondary structures such as ha
263 oS2 nanosheets, inhibiting conversion to the thermodynamically stable semiconducting state (2H) when
264 the two pathways diverge to produce distinct thermodynamically stable species (parallel and antiparal
266 a low capacity for base pairing, it forms a thermodynamically stable structure with a rather complex
269 ork here is to chemically probe the range of thermodynamically stable tetraboride compounds with resp
270 fectly matches experimental data, it is more thermodynamically stable than previously proposed recons
271 ic gradient, yielding products that are less thermodynamically stable than the starting materials.
272 e trifluoromethylthio analogue exists in the thermodynamically stable thioperoxide form (O-SCF(3)), a
273 design and synthesis of a polymer containing thermodynamically stable whilst kinetically labile coord
274 drite-suppression capability, SSEs should be thermodynamically stable with a high interface energy ag
275 ulations, we report that the nucleation of a thermodynamically stable, atomically thick CuCr(1-x)Al(x
276 ture conditions, we show that TDP-43(NTD) is thermodynamically stable, well-folded and undergoes reve
278 omparable to those of the native tissue, (2) thermodynamically-stable extra-cellular matrix (ECM), (3
279 ep switching process with the formation of a thermodynamically-stable intermediate twinning structure
282 [4Fe4S] cluster potential, which corresponds thermodynamically to a ~500-fold increase in DNA-binding
283 rand displacement and errors were elucidated thermodynamically to show that sequences are able to spe
284 lexes can induce chemical reactions that are thermodynamically too demanding for common precious meta
285 n reactions using phosphate is that they are thermodynamically unfavorable in aqueous conditions.
287 namically favorable transport of ions to the thermodynamically unfavorable transport of neurotransmit
288 gy drives an N(2) splitting reaction that is thermodynamically unfavorable under standard conditions,
289 (nJ = 1) by a Ca(2+)-selective ionophore is thermodynamically unfavorable, thereby requiring a Li(+)
294 th chemically stable N-N bonds but which are thermodynamically unstable in that the formation of stab
296 light illumination, cations are able to move thermodynamically uphill over a broad range of concentra
299 of relevance to drug discovery was analyzed thermodynamically using transition state theory and nume
300 d against 2 reveal that [Cu2O](2+) is likely thermodynamically viable in copper-dependent methane mon