ライフサイエンスコーパス: thiolate

1 ethylcyclam (TMC) macrocycle with a tethered thiolate.

2 coordination modes between the metal and the thiolate.

3 mild method involving C-S cleavage of added thiolate.

4 t springs, arsenic was nearly quantitatively thiolated.

5 CB[8] assembly interactions between pairs of thiolates.

6 etal-cluster arrangements via their cysteine thiolates.

7 re of the sulfide ligands is replaced by Cys thiolates.

8 [8]) and (2) ligand exchanges between the Pt thiolates.

9 ) is 1 order of magnitude lower than that of thiolates.

10 y component for efficient etching of gold by thiolates.

11 significant ways from more ubiquitous metal thiolates.

12 Reaction of thiolate 1 with carbene-stabilized diiodo-bis-silylene (

13 nocluster (NC) protected by a mixed shell of thiolate (2,4-dimethylbenzenethiolate, SPhMe2) and phosp

14 efore, the chemical behavior of the simplest thiolated acetic acid derivatives, TAA and methylthioace

15 we demonstrate the temperature influence on thiolate addition to MCs containing the N-methylbenzothi

16 Thus, thiolate addition to PhOBtz resembles 1,6-conjugate addi

17 strates a strong enthalpic driving force for thiolate addition to PhOBtz that is absent for PhOMeBtz

18 -withdrawing group to reduce the barrier for thiolate addition to the acrylamide.

19 The monoaddition product of thiolate addition, prepared and isolated at lower temper

20 moiety exhibits greater selectivity for the thiolate addition, with dye 2 being more reactive toward

21 splays impressive temperature sensitivity to thiolate addition, with the brightly colored phenolate f

22 olate favored upon heating and the colorless thiolate adduct favored upon cooling.

23 ine substituents to the phenolate caused the thiolate adducts to dissipate over time for p-QM regener

24 The thiolated AFM1 aptamer was immobilized on gold nanoparti

25 is reaction proceeded via the formation of a thiolate-alkylammonium tight ion pair and activation of

26 d nanoparticles to a suite of guest ligands (thiolates, amines, carboxylates, inorganic ions, and pro

27 Thus, in this system the loss of thiolate and binding of N(2) require reduction beyond th

28 Compared to known Cu(II)-thiolate and Cu(II)-alkylperoxo complexes from the liter

29 ies of low-valent diiron complexes featuring thiolate and dinitrogen ligands.

30 ndicative of linear bridging of Cu(I) by Cys thiolate and His imidazole groups, whereas the coordinat

31 Increased covalencies in both iron-thiolate and iron-sulfide bonds would stabilize the oxid

32 Other than thiolate and phosphine ligands, alkynyls are also briefl

33 e a distinct preference for the locations of thiolate and selenolate ligands that emerges over time.

34 hydrogen bond strength between the cysteine thiolate and the backbone amide of the highly strained I

35 d thiol-disulfide exchange between the Cys56-thiolate and the mixed disulfide intermediate formed in

36 ochemical cisplatin sensor fabricated with a thiolated and methylene blue (MB)-modified oligo-adenine

37 Thiolates and BSA were more efficient at ligand exchange

38 Pt(II) thiolates and CB[8] form 2:1 assemblies, with both metal

39 ally characterized gold cluster protected by thiolates and provides important insight into the struct

40 ic factor, beta(nuc), for the reactions with thiolates and with the ability of the leaving group.

41 of the resulting alkyl group (R') to another thiolate, and subsequent elimination of a sulfur atom fr

42 The thiyl radical generated from the thiolate anion adsorbed on a CdSe QD plays a key role by

43 posed as the hydrogen-bond donor stabilizing thiolate anion formation within the cofactor, glutathion

44 onsible for stabilization of the glutathione thiolate anion, this phosphorylation-induced interaction

45 also confirmed that this reaction involves a thiolate-anion form of C32 and follows the S(N)2 mechani

46 ence of sulfide can lead to the formation of thiolated anions; however, their contributions to total

47 netic gold nanoparticles self-assembled with thiolated antibodies (antiHER2/Hyd@AuNPs-APTMS-Fe3O4) co

48 Among the three thiolated antifouling diluents used in this study, the m

49 binary self-assembled monolayer of specific thiolated aptamer and 6-mercapto-1-hexanol (MCH), whose

50 functionalized the gold nanoparticles with a thiolated aptamer to achieve the required selectivity th

51 Based on the incubation of the thiolated aptamer with CT26 cells, the electron-transfer

52 cise molecular formula [Ag25(SR)18](-) (-SR: thiolate) are synthesized, and their single-crystal stru

53 It also was the major thiolated arsenic species in the rhizosphere with concen

54 ed intermolecular charge transfer within the thiolate-aryl halide electron donor-acceptor complex per

55 milability of thiolate to produce a terminal thiolate as a proton shuttle is a key feature in both me

56 elimination of a sulfur atom from the second thiolate as a thioether (RSR').

57 Peptide studies identified the Cys thiolate as the most reactive nucleophile for these meta

58 As on plants should include experiments with thiolated As species.

59 Au25(SR)18 and Ag44(SR)30 (RS- = alkyl/aryl thiolate) as model compounds.

60 key results include finding a preference for thiolate attachment at the C(4)-site to generate an enam

61 e effects suggested stepwise mechanisms with thiolate attack on NO2-CLA as rate-controlling step.

62 es to a solution of dissolved glutathione (a thiolate-based Hg chelator).

63 We found that thiolates bind to the planar (100) facets of the nanocry

64 as linkers in the immobilization process of thiolated biomolecules (such as DNA) on microcantilever

65 ort reversible insertion of NO into a copper-thiolate bond in an engineered copper centre in Pseudomo

66 was designed to bind Au nanoparticles with a thiolate bond.

67 isulfides can be converted to covalent metal-thiolate bonds by exposure to free thiols, leading to th

68 synthetic mimics of cytP450 indicate that a thiolate-bound ferric porphyrin coexists in organic solu

69 Unlike the native enzyme, most synthetic thiolate-bound ferric porphyrins are unstable in air unl

70 carbonyl adducts are reported in a series of thiolate-bound iron porphyrins.

71 tonation on the thiolate or reduction on the thiolate-bound metal.

72 Traut's Reagent (TR) was used to thiolate Bovine serum albumin (BSA) in solution followed

73 ing a protein-bound dinitrosyl iron complex, thiolate-bridged di-iron tetranitrosyl complex, or octan

74 ization of the unpaired electron through the thiolate-bridging ligand.

75 while the urea group binds the nucleophilic thiolate by hydrogen bonding.

76 on of mesoionic heterocycles 1,3-diazolium-4-thiolates by [3 + 2] cycloadditions of munchnones with a

77 Uniquely, for such a material, this gold-thiolate can be transformed into a wire-like conducting

78 molysin (alphaHL) for detecting a variety of thiolate-capped gold nanoclusters.

79 -stability of CuNPs and the structure of the thiolate capping ligand; of the eight different ligands

80 lay only moderate temperature sensitivity to thiolate capture and release.

81 Then, thiolated capture probe (CP) with methylene blue (MB) la

82 he kinetics of ligand exchange, with bulkier thiolates causing dramatic rate retardations, as well as

83 lly higher than in the corresponding ferrous-thiolate CO adducts.

84 t coordinatively saturated mononuclear metal-thiolate complex ReL3 (L = diphenylphosphinobenzenethiol

85 describe an uncommon example of a manganese-thiolate complex, which is capable of activating dioxyge

86 The spectroscopically observable tris(thiolate) complex [Ru(dppbt)3](+) (1(+)) (dppbt = diphen

87 The reduction of an iron(II) tris(thiolate) complex with 1 equiv of KC(8) leads to a therm

88 lfide (beta-HgS) directly from linear Hg(II)-thiolate complexes (Hg(SR)2) in natural organic matter a

89 description, and role of multinuclear metal-thiolate complexes in aqueous Au-Cu nanoparticle synthes

90 The presence of metal-thiolate complexes is then shown to be critical for the

91 ted reactivity of dinuclear non-heme Mn(II) -thiolate complexes with O2 , which dependent on the prot

92 hose prepared by the chemisorption of alkane thiolated compounds.

93 LV and -TRV, with EPR demonstrating cysteine thiolate coordination of heme iron in both cases.

94 ybridization ability similar to those of its thiolated counterpart.

95 s from the reaction of RSNO and a copper(II) thiolate [Cu(II)]-SR intermediate formed upon reaction o

96 sites based on tris(pyrazolyl)borate copper thiolates [Cu(II)]-SR to unravel the factors involved in

97 suggests use of the Btz acceptor for direct thiolate detection.

98 ltrasmall gold nanoparticles are coated with thiolated dextran, and hydrophobic acetal groups are ins

99 This iron(II) thiolate dinuclear complex, [Fe(II)(2)(LS)(LSH)] ([Fe(2)

100 ntermediate, thereby preventing the possible thiolate dioxygenation side reaction.

101 A protein containing both thiolated dipeptide 4 and a 7-methoxycoumarin fluorophor

102 (Gly-Phe (2) and Phe-Gly (3)), as well as a thiolated dipeptide analogue (4) and a fluorescent oxazo

103 mide formation, thiolate-thioester exchange, thiolate-disulfide interchange and conjugate addition) t

104 Equilibration between Chol and Phos via thiolate-disulfide interchange reactions has revealed th

105 s that illustrate Ni-ion mediated reversible thiolate/disulfide transformation are unknown.

106 on of physically immobilized single stranded thiolated DNA (ss th-DNA) probe of N. meningitides onto

107 ticles (AuNPs) are stable in the presence of thiolated DNA after a freeze-thaw cycle.

108 A thiolated DNA aptamer with established affinity for pros

109 The MoS(2) flakes were modified with a thiolated DNA probe complementary to the target biomarke

110 ize the effect of contaminants in commercial thiolated DNA probe, the electrode surface was functiona

111 Thiolated DNA probes and alkanethiols were stably immobi

112 detection involved a hybridization study of thiolated DNA sequences.

113 They can then be functionalized with thiolated DNA through stepwise thiolyne chemistry using

114 try, in which a target-specific monolayer of thiolated DNA(TTgamma) pinned down the analyte jointly w

115 The presence of the thiolate donor is critical to both pathways, and mechani

116 lead to S-oxygenation of the intramolecular thiolate donors and does not react with exogenous sulfur

117 argon causes the dissociation of one of the thiolate donors and gives an eta(6)-arene species which

118 cies are proposed to S-oxygenate metal-bound thiolate donors in nonheme thiol dioxygenases, but 2 doe

119 In these experiments, the thiolated end of the FNA tether was covalently immobiliz

120 hanism and indicate that the particular heme-thiolate environment of the NOS enzymes can stabilize an

121 e obliquely considered the role of oxygen in thiolate etching of gold.

122 By using thiolated ferrocene, a complementary detection mode on t

123 drogels via oxidative removal of the surface thiolates, followed by CO2 supercritical drying to produ

124 ding mode aligns the pendant lariat cysteine thiolate for coordination with the iPGM transition metal

125 ons of up to 17 ligands of the 18 ligands in thiolate for selenolate exchanged Au(25)(SeR)(18- x)(SR)

126 e that the results were not dependent on the thiolate, for SR we used both butanethiolate and phenyle

127 slowly reversible, covalent adduct with the thiolate form of active-site Cys191 2-VIC displayed kine

128 phic water acts as a general base during GSH thiolate formation, stabilized by interaction with Arg-1

129 role in stabilizing the leaving glutathione thiolate formed.

130 lectrode surface, previously modified with a thiolated forward primer.

131 rgo insulin-like growth factor-1 (IGF-1), in thiolated gelatin (gelatin-SH)/ poly(ethylene glycol) di

132 l polymer containing crystal violet (CV) and thiolated gold nanocluster ([Au(25)(Cys)(18)]) activated

133 llographic structure of the largest reported thiolated gold nanomolecule, Au133S52.

134 sion has been widely observed for ultrasmall thiolated gold nanoparticles (AuNPs) but our understandi

135 assy carbon electrode (GC) was modified with thiolated graphene oxide (T-GO) to elevate the active su

136 ing streptavidin modified-gold nanoparticles/thiolated graphene oxide, followed by its conjugation wi

137 degradation in air by stabilizing the ferric thiolate ground state in contrast to its synthetic analo

138 nase which transfers two oxygen atoms to the thiolate group of cysteine.

139 dinuclear Mn(III) complex with two terminal thiolate groups (Mn(III)2), with the concomitant product

140 m of approximately 80 Cu(I) ions, mainly via thiolate groups, with average affinities in the (1-2) x

141 Incorporation of cationic liposomes with thiolated HA allowed for facile surface decoration of NP

142 The penta- or hexa-coordinate thiolate heme (9<=pH<=11) and the penta-coordinate imida

143 moiety is mainly derived from the studies on thiolate-heme containing epoxidases, such as cytochrome

144 d an earth-abundant, noble-metal-free nickel-thiolate hexameric cluster co-catalyst assembled in situ

145 03 gold atoms protected by 2 sulfidos and 41 thiolates (i.e., 2-naphthalenethiolates, S-Nap), denoted

146 (III) redox couple such as strongly donating thiolates in Ni superoxide dismutase.

147 Comparison with analogous reactions of thiolates indicated that the intrinsic reactivity of HS(

148 hiols (Alk-SH) provide the corresponding bis-thiolated indole derivatives.

149 the ligand-effected modification of the gold-thiolate interface independent of the kernel structure,

150 ivity to the detailed structure of the metal-thiolate interface.

151 Metal core-thiolate interfaces in these clusters play a crucial rol

152 es catalysis through a methyl radical/Ni(ii)-thiolate intermediate.

153 dichroism spectroscopy identified the Ni(II)-thiolate intermediate.

154 methyl-nickel(III) or methyl radical/Ni(II)-thiolate intermediates.

155 ommodated on the exposed sulfur of the MN2S2 thiolate (Lewis base).

156 addition and elimination of a single surface thiolate ligand (-SR) on gold nanoclusters can be realiz

157 f a AuNP and the local binding geometry of a thiolate ligand (glutathione) on the AuNP are correlated

158 Au(25)SR(18)](-) nanoclusters adds an excess thiolate ligand and generates a new species, [Au(25)SR(1

159 phyrins are unstable in air unless the axial thiolate ligand is sterically protected.

160 es exhibit values of 20, suggesting that the thiolate ligand of [Fe(IV)(O)(TMCS)](+) plays a unique r

161 Strong electron-donation from the axial thiolate ligand of cytochrome P450 has been proposed to

162 d redox catalysis and in preventing cysteine thiolate ligand oxidation.

163 ion of the proximal helix that encircles the thiolate ligand).

164 -which peak for the best electron donor, the thiolate ligand-afford a slim and narrow barrier through

165 re M is a monocation, and SPh is an aromatic thiolate ligand.

166 les greater electron donation from the axial thiolate ligand.

167 ns suggest appreciable spin leakage onto the thiolate ligand.

168 84 +/- 8% of Hg(II) was bonded to two axial thiolate ligands and one or two equatorial N/O electron

169 cts, large noble-metal clusters protected by thiolate ligands behave as giant molecules of definite c

170 .2 nm in gold core diameter) protected by 80 thiolate ligands is surprisingly non-metallic based on U

171 In particular, the SERS signal from the thiolate ligands on Ag nanoparticle surfaces can be util

172 t to a double-edged sword role played by the thiolate ligands on Au25 nanoclusters for CO oxidation.

173 e crystallographic analysis reveals that the thiolate ligands on the nanocluster form local tetramers

174 of Hg(II) and [CH3Hg(II)](+) complexes with thiolate ligands through a model bacterial cytoplasmic m

175 m(II) complexes bearing terpyridyl (tpy) and thiolate ligands were used to test the design of a "dual

176 work is to demonstrate how the use of bulky thiolate ligands, such as adamantanethiol, versus the co

177 ([CH3Hg(II)](+)) are commonly complexed with thiolate ligands.

178 ule with a precise number of metal atoms and thiolate ligands.

179 articles have been synthesized with aromatic thiolate ligands.

180 particles functionalized with small-molecule thiolated ligands exhibit exchange efficiencies as low a

181 Herein, we report a five-coordinate bis-thiolate ligated Fe(III) complex, [Fe(III)(S2(Me2)N3(Pr,

182 (2) at -135 degrees C in 2-MeTHF generates a thiolate-ligated (peroxo)diiron complex Fe(III)(2)(O(2))

183 Reaction of 1 with O(2) generates a rare thiolate-ligated cobalt-superoxo species Co(O(2))(Me(3)T

184 e P450 (P450) and chloroperoxidase (CPO) are thiolate-ligated haem proteins that catalyse the activat

185 n(IV)hydroxide pK(a) approximately 12 in the thiolate-ligated heme enzyme cytochrome P450, this resul

186 t dehaloperoxidase and tyrosine hydroxylase, thiolate-ligated heme-dependent cytochrome P450, and fou

187 Herein, we describe an alkyl thiolate-ligated iron complex that reacts with dioxygen

188 f S-oxygenation versus H atom abstraction in thiolate-ligated nonheme metalloenzymes that react with

189 work demonstrates that a single mononuclear, thiolate-ligated nonheme {FeNO}(7) complex can exhibit r

190 visible light in acetonitrile to generate a thiolate-ligated, nonheme iron(III)-nitro complex, [Fe(I

191 ectrum (370 nm and 428 nm) characteristic of thiolate ligation.

192 that gold nanoparticles functionalized with thiolated macromolecules, such as poly(ethylene glycol)

193 dily postfunctionalized into cross-linked or thiolated materials but, more remarkably, can also be fu

194 S. putrefaciens thiolated methylated arsenicals, converting MAs(V) into

195 At basic pHs, the thiolate mini-heme protein can catalyze O(2) reduction w

196 erocyanine (TMC), the mechanically activated thiolate moiety of which undergoes rapid thiol-ene click

197 s have been controlled by tuning the oxidant/thiolate molar ratio (X) that governs the rate of NP con

198 A trinuclear T-shaped nickel thiolate molecular complex has been designed to activate

199 by rational design of a small pi-conjugated thiolated molecule that controls, to a great extent, the

200 ribe ligand exchange behavior with a second, thiolated molecule.

201 f ligand exchange between different types of thiolated molecules on the surface of gold nanoparticles

202 brous materials using thiol-ene reactions of thiolated molecules to presented norbornene groups is de

203 ge efficiencies as low as 2% when exposed to thiolated molecules under identical exchange conditions.

204 volume, but had no negative effect on higher thiolated molybdates.

205 nd an array of four microchemiresistors with thiolate-monolayer-protected-Au-nanoparticle interface f

206 cept, size-sensitive incorporation of a gold-thiolate nanocluster, Au133(SR)52, selectively in the bM

207 atomically precise monolayer-protected gold thiolate nanoclusters are an intensely researched nanoma

208 ee atomically precise anion-templated silver thiolate nanoclusters, two of which form one- and two-di

209 mpared to the discrete staple motifs in gold:thiolate nanoparticles, the Cu-thiolate surface of Au(52

210 face motifs of parent [Ag44(SR)30](4-) (SR = thiolate) nanoparticles (NPs), leading to bimetallic NPs

211 ized particles (HOPs) from polydisperse gold thiolate nanoplatelets with cysteine surface ligands.

212 A comparison of Au-thiolate NCs with Au-phosphine ones further reveals the

213 Compared to the Au-thiolate NCs, the Ag/Cu/Cd-thiolate systems exhibit diff

214 Here, we use a bidentate thiolate-NHC-gold(I) complex that is easily grafted onto

215 The resulting thiolate-NHC-stabilized gold nanorods are stable towards

216 he synthesis of an S = 1/2, terminally bound thiolate-Ni(III)-H complex.

217 upling to the terminal hydride ligand of the thiolate-Ni(III)-H species is comparable to that of the

218 Upon warming, the featured thiolate-Ni(III)-H species undergoes bimolecular reducti

219 ese complexes demonstrate reversible Ni(II) -thiolate/Ni(II) -disulfide (both bound and unbound disul

220 and a racemic chain mechanism mediated by a thiolate nucleophile.

221 nd the catalyst's hydroxyl group orients the thiolate nucleophile.

222 adily undergoing two addition reactions with thiolate nucleophiles and the (Z)-enamine being much les

223 tions give a binding energy of CO2 to benzyl thiolate of -66.3 kJ mol(-1), consistent with the experi

224 nction of the number of metal core atoms and thiolates on the nanocluster shell.

225 being much less reactive toward addition of thiolate or amine nucleophiles.

226 and PerR sense peroxide when it oxidizes key thiolate or iron moieties, respectively; they then induc

227 e dative donation through protonation on the thiolate or reduction on the thiolate-bound metal.

228 reported EDLs-which bind to the QDs through thiolates or dithiocarbamates-is however limited by the

229 ting Raman reporters SQ2 and SQ5 followed by thiolated PEG encapsulation (SH-PEG, SH-PEG-COOH) denote

230 tobenzoic acid ( p-MBA), tiopronin (TP), and thiolated PEG(7) (S-PEG(7)).

231 characterization, and application of a novel thiolated-PEG surface modifying molecule (DSPEG2) that c

232 Briefly, thiolated peptide nucleic acid (PNA) probes were firstly

233 ryl intermediate (APO-II) from APO, the heme-thiolate peroxygenase from Agrocybe aegerita, is describ

234 he oxidant to the engineered unspecific heme-thiolate peroxygenase PaDa-I.

235 A thiolated pH-responsive DNA conjugated gold nanorod (GNR

236 Thiolated PNA molecules are firstly self-assembled onto

237 It was further passivated by a thiolated poly(ethylene glycol)-biotin to improve its ca

238 ionalizing the nanoparticles in solutions of thiolated polyethylene glycol (PEG-SH) with or without P

239 uid-phase eutectic gallium-indium core and a thiolated polymeric shell.

240 reactions readily produced the corresponding thiolated polymers and flexible cross-linked thin-film m

241 By developing and crosslinking the thiolated polypeptide via formation of disulfide bonds p

242 state compared to the five-coordinate ferric-thiolate precursor complexes.

243 In the absence of mixed metal-thiolate precursors, nanoparticles form with a Cu-S shel

244 We also show that the thiolated precursors were successfully engaged in a Frie

245 pai-back-donation by the electron-rich alkyl thiolate presumably facilitates this reactivity by incre

246 5 detection have demonstrated here, based on thiolated probe-functionalized gold nanorods (GNRs) deco

247 f an unprecedentedly large, 2.2 nm diameter, thiolate protected gold nanocrystal characterized by sin

248 netic exchange environments are observed for thiolate protected gold nanoparticles, but the correlati

249 ermally reversible isomerization between two thiolate-protected 28-gold-atom nanoclusters, i.e. Au28(

250 spectroscopic studies on atomically precise thiolate-protected Au25, Au38, Au144, Au333, Au approxim

251 Here we show that single crystals of thiolate-protected clusters can be grown in large quanti

252 nonlinear optical scattering experiments on thiolate-protected gold clusters (Au130(SR)50, Au144(SR)

253 f the research activity currently focuses on thiolate-protected gold nanoclusters, important progress

254 , as well as carrier dynamics of a series of thiolate-protected gold NCs ranging from tens to hundred

255 Thiolate-protected metal clusters are materials of ever-

256 iples, which is able to address stability of thiolate-protected metal nanoclusters as a function of t

257 uctural determination of atomically precise, thiolate-protected metal nanoclusters, our understanding

258 ochrome P450 monooxygenases (P450s) are heme-thiolate proteins whose role as drug targets against pat

259 hrome P450 monooxygenases (CYPs/P450s), heme thiolate proteins, are well known for their role in orga

260 d so far to depict PN interactions with hemo-thiolate proteins, i.e., leading to the formation and ac

261 mutants exhibit lower stability and cysteine thiolate protonation on reduction.

262 be accomplished with the target miRNA for a thiolated RNA probe assembled onto a gold nanoparticles

263 ccurs from a hydride on Fe' with a proton on thiolate S and requires a propitious orientation of the

264 tion of a reactive quinone that oxidizes the thiolate side chain of cysteine residues; events that we

265 Thiolated single-stranded DNA (ssDNA) probe was hybridiz

266 Attachment of thiolated single-stranded nucleic acid oligomers to the

267 tranded coiled coils (3SCCs) containing tris-thiolate sites to evaluate these concepts.

268 mic hydrazone functionalized with a C6 alkyl thiolate spacer (C6 HAT) was characterized on a number o

269 m of disulfide bonds breaking to form a S-Li thiolate species upon discharge and reforming upon charg

270 m, can be conclusively described as a ferric thiolate species.

271 quantify repeated reactions between sub-kDa thiolated species in real time and at concentrations dow

272 nates were the most prominent and ubiquitous thiolated species, with trithioarsenate typically domina

273 (III) , Cr(V) , and Cr(VI) (primarily Cr(VI) thiolates) species.

274 re, the binding and patterning structures of thiolates (SR) on the Au(100) crystalline facet are reve

275 nanostructured GaN substrates modified with thiolated ssDNA (single stranded DNA) can be successfull

276 which Cys(145) is in the negatively charged thiolate state and His(41) is doubly protonated and posi

277 The ferric thiolate state is favored by greater enthalpy and is air

278 a novel "thiol-blocked" [(PDT)Mo(V)O(S(Cys))(thiolate)](-) structure, which is supported by new EXAFS

279 This S-glyco-modification produces 3-thiolated sugars in hemiacetal form, rather than typical

280 ate sulfurs; the average spin-density on the thiolate sulfurs is approximately the same for 2 and 8,

281 on does not proceed via direct attack at the thiolate sulfurs; the average spin-density on the thiola

282 otifs in gold:thiolate nanoparticles, the Cu-thiolate surface of Au(52)Cu(72) forms an extended cage.

283 ompared to the Au-thiolate NCs, the Ag/Cu/Cd-thiolate systems exhibit different coordination modes be

284 While the thiolate tails do not significantly affect the rate of t

285 lex dimers bearing different tpy "heads" and thiolate "tails" scrambles to afford up to 10 ternary as

286 relevant organic reactions (amide formation, thiolate-thioester exchange, thiolate-disulfide intercha

287 photoinduced electron transfer (PeT) from a thiolate to Cy in their triplet excited state and then t

288 cleavage facilitated by the hemilability of thiolate to produce a terminal thiolate as a proton shut

289 nge through nucleophilic attack of the Cys53-thiolate to the GSSG-disulfide followed by the deprotona

290 Nucleophilic addition of thiolates to diethyl acetylenedicarboxylate in chlorofor

291 nzyme M reductase (MCR) involves Ni-mediated thiolate-to-disulfide conversion that sustains its catal

292 through the cleavage of the S-C bond in one thiolate, transfer of the resulting alkyl group (R') to

293 eal the formation of a three-coordinate tris(thiolate) trigonal planar complex upon substrate binding

294 coding regions lead to an increased level of thiolated tRNA and enhanced thermotolerance of indica ri

295 Thus, cells use thiolated tRNAs to perceive amino acid sufficiency, bala

296 ontribution of the free cysteine side chain (thiolate) versus the parent residue at an experimental p

297 f approximately 0.1 nm Loss of the HRM axial thiolate via redox processes, including oxidation to a d

298 usters, bearing either inorganic sulfides or thiolate with interstitial carbide motifs, are reported.

299 ted higher nucleophilicity with respect to a thiolate with similar basicity.

300 s as a general base to generate the Cys(820) thiolate within the low dielectric binding interface and