ライフサイエンスコーパス: transition metal complex

1 sents the first example of a dihydrodisilene transition metal complex.

2 ation barrier yet observed for a mononuclear transition metal complex.

3 ation of the (2)E excited state in a Cr(III) transition metal complex.

4 hysical diffusion (D(PHYS)) of the polyether-transition metal complex.

5 ation reactions with a photon harnessed by a transition metal complex.

6 cids to avoid deleterious protonation of the transition metal complex.

7 and subsequent relaxation of a photoexcited transition metal complex.

8 t-triggered molecular phenomena involving 3d transition metal complexes.

9 ty of main-group species that mimics that of transition metal complexes.

10 process is well documented for a variety of transition metal complexes.

11 fairly unexplored area of cycloheptatrienyl transition metal complexes.

12 of TEMPO's reactivity toward all low-valent transition metal complexes.

13 lylated stannylenes with zerovalent group 10 transition metal complexes.

14 ans of generating the first fluorido-cyanido transition metal complexes.

15 al relaxation, as commonly observed in heavy transition metal complexes.

16 gy transfer processes via variation of pH in transition metal complexes.

17 sion and understanding how CO(2) reacts with transition metal complexes.

18 "spin crossover" phenomenon observed in many transition metal complexes.

19 ne reactions with coordinated isocyanides in transition metal complexes.

20 y when describing excited-state formation in transition metal complexes.

21 on d-orbital energy levels and splitting in transition metal complexes.

22 family of supramolecular compounds based on transition metal complexes.

23 deposition method using thiourea coordinated transition metal complexes.

24 that dominate the photophysics of first-row transition metal complexes.

25 ool for studying the complex photophysics of transition metal complexes.

26 ntial for the development of new photoactive transition metal complexes.

27 luminescent and photoredox-active first-row transition metal complexes.

28 ic noble gas compounds, and a wide number of transition metal complexes.

29 d photosynthetically relevant earth-abundant transition metal complexes.

30 charge-transfer photochemistry of first row transition metal complexes.

31 operties compared to traditional mononuclear transition metal complexes.

32 the origin of room temperature coherence in transition metal complexes.

33 ost important organic reactions catalyzed by transition metal complexes.

34 the tautomeric forms of side-on silaldimine transition metal complexes.

35 ative mechanism as classically observed with transition metal complexes.

36 ronsted acids, organocatalysts, enzymes, and transition metal complexes.

37 ctivation of a CH bond of methane by soluble transition metal complexes.

38 orted metal catalysts as well as homogeneous transition metal complexes.

39 nitrenium nitrogen (N(nit))-bound first-row transition-metal complexes.

40 rue combination of these properties in ionic transition-metal complexes.

41 ripodal ligands and subsequently fluorescent transition-metal complexes.

42 he emerging kinetic model proposed for other transition-metal complexes.

43 be achieved via the rational design of ionic transition-metal complexes.

44 t motion in the excited state of polynuclear transition-metal complexes.

45 informing the rational design of photoactive transition-metal complexes.

46 opportunity for the accelerated discovery of transition-metal complexes.

47 f the catalysts reported so far are based on transition-metal complexes.

48 ypical preference for 5-membered chelates in transition-metal complexes.

49 mic problem of bond dissociation energies in transition-metal complexes.

50 uorides by monofluoroalkylation catalyzed by transition-metal complexes.

51 lysis (NCC) with small organic molecules and transition-metal complexes.

52 are normally observed almost exclusively for transition-metal complexes.

53 , has been applied to diamond-NV centers and transition-metal complexes.

54 sfer ((2)LMCT) state that is rarely seen for transition-metal complexes.

55 t is mediated by a set of well-characterized transition-metal complexes.

56 metal-organic frameworks, and small-molecule transition-metal complexes.

57 n by reductive coupling of CO2 on low-valent transition-metal complexes.

58 e catalytic cyclic polymer synthesis by a 3d transition metal complex: a V(V) alkylidyne, [(dBDI)V=C(

59 in which both the metal and the ligand of a transition metal complex actively participate in chemica

60 ivity through the use of organocatalysts and transition metal complexes, allowing also the extension

61 advance in main group chemistry that mimics transition-metal complexes, among which various boron-co

62 The appropriate choice of the transition metal complex and metal surface electronic st

63 g interactions between the partially aquated transition metal complex and posttransition metal ion re

64 loyed as ancillary ligands to stabilize late transition metal complexes and are conventionally consid

65 ries involving reactions of hydrosilanes and transition metal complexes and characterization of the p

66 rochemical reduction of solutions of various transition metal complexes and fullerene or fullerene ad

67 photophysics and photochemistry of first-row transition metal complexes and highlight key distinction

68 On a separate note, transition metal complexes and nanoparticles have a well

69 nding about the role of weak interactions in transition metal complexes and, thus, will have implicat

70 lthough numerous synergistic combinations of transition-metal complexes and chelating directing group

71 Many transition-metal complexes and some metal-free compounds

72 ainly owing to the reactivity of high-valent transition-metal complexes and the challenges associated

73 ronic and structural dynamics of photoactive transition-metal complexes and will be applicable to a w

74 harged species, including organic molecules, transition metal complexes, and "ship-in-a-bottle" nanoc

75 photocatalytic activation available to these transition metal complexes, and of the general reactivit

76 matic molecules, peptides, oligonucleotides, transition metal complexes, and, broadly, molecules with

77 Transition metal complexes are attractive compounds as p

78 Transition metal complexes are attractive PSs due to the

79 In this review, various click-derived transition metal complexes are discussed in terms of the

80 mental understanding of symmetry breaking in transition metal complexes are discussed.

81 ies of groups 2 to 16 and a few sigma-bonded transition metal complexes are experimentally known, but

82 Transition metal complexes are highly promising PDT agen

83 These heteroatom-tolerant neutral late transition metal complexes are in fact highly active sys

84 alence-isoelectronic cyclic thiozone, S3) in transition metal complexes are investigated in this pape

85 Transition metal complexes are of increasing interest as

86 ucleophilic RCF(2)M or difluorocyclopropenyl transition metal complexes are rare.

87 Second- and third-row transition metal complexes are widely employed in photoc

88 l control of the photophysical properties of transition-metal complexes are revolutionizing a wide ra

89 Transition-metal complexes are used as photosensitizers,

90 Transition-metal complexes are widely used in the physic

91 ed species, such as octahedral low-spin d(6) transition metal complexes, are not expected to particip

92 Acetic acid was found to be superior to transition metal complexes as a catalyst for this ring-e

93 uires the use of organometallic compounds or transition metal complexes as catalysts.

94 t, indeed, these reactions were catalyzed by transition metal complexes as opposed to Bronsted acids

95 This Review surveys the field of molecular transition metal complexes as well as recent boron examp

96 hodologies reported to activate methane with transition metal complexes as well as the few examples o

97 n transformations with mononuclear first-row transition metal complexes at mild potentials.

98 C(sp(3))-C(sp(3)) reductive elimination from transition metal complexes [Au(III), Pt(IV)] is explored

99 lex DNA as the anion and polyether-decorated transition metal complexes based on M(MePEG-bpy)(3)(2+)

100 the polymer-based LEC (p-LEC) and the ionic transition metal complex-based LEC (iTMC-LEC).

101 ydroxybenzenesulfonephthalein-type dye and a transition metal) complex-based total protein determinat

102 The first transition-metal complex-based two-photon absorbing lumi

103 dium allows for the preparation of the first transition-metal complex bearing a cyclic arylaminocarbe

104 as been useful for the synthesis of isolable transition-metal complexes bearing reactive ligands.

105 rable effort has been devoted to identifying transition metal complexes, biological catalysts, or sim

106 ble interaction of molecular oxygen with the transition-metal complex bonded to the stationary phase

107 igning a protein to accommodate a non-native transition metal complex can broaden the scope of enzyma

108 Coordination of molecular nitrogen to transition metal complexes can activate and even rupture

109 hotophysical and photochemical properties of transition metal complexes can be controlled by the appr

110 ese transformations show that while cyaphido transition metal complexes can be readily accessed using

111 Furthermore, it is shown that transition metal complexes can be used to catalyze oxida

112 In particular, transition metal complexes can display magnetic bistabil

113 um yield of 4.4%, shows that main group/late transition metal complexes can mimic the behavior of the

114 Paramagnetic transition metal complexes can serve as quantum bits, st

115 Herein, we show that visible-light-activated transition-metal complexes can be triplet sensitizers th

116 er coordination sphere of metalloenzymes and transition-metal complexes can have on reactivity.

117 NPs are combined with optical properties of transition metal complexes, can be obtained with differe

118 resenting a rare example of high-valent late transition metal complexes capable of activating strong

119 understanding at the molecular level of how transition-metal complexes catalyse reactions, and in pa

120 fuels calls for electrogenerated low-valent transition metal complexes catalysts designed with consi

121 Transition metal complexes catalyze many important react

122 tes a catalytic pathway unlike that found in transition metal complex-catalyzed processes.

123 vel strategy for chirality transfer from the transition-metal complex cation to the lead halide frame

124 Herein, we report the chiral transition-metal complex cation-based lead halide, R-CDP

125 lowing for an accelerated exploration of the transition metal complex chemical space.

126 ny classes of elementary reactions involving transition-metal complexes cleave C-H bonds at typically

127 Electron transfer in mixed-valent transition-metal complexes, clusters and materials is ub

128 Electron spin relaxation in paramagnetic transition metal complexes constitutes a key limitation

129 pentacoordinated, and hexacoordinated chiral transition metal complexes containing a stereogenic meta

130 communication reports the first examples of transition metal complexes containing an RNNNNNNR 2- lig

131 me these challenges and to prepare first-row transition metal complexes containing at least one trz l

132 Transition metal complexes containing heme and non-heme

133 oped a model for understanding the shapes of transition metal complexes containing multiple bonds.

134 dvances made in the synthesis of luminescent transition metal complexes containing N-heterocyclic car

135 thesis of the first completely characterized transition-metal complex containing a sulfur-bound 4,6-d

136 lf-propagating combustion synthesis of novel transition-metal complexes containing high nitrogen ener

137 The proposal that paramagnetic transition metal complexes could be used as qubits for q

138 ation of far-red/NIR-emitting COUPY dyes and transition metal complexes could effectively tackle in v

139 ew of C-H activation methods promoted by NHC-transition metal complexes, covering the literature sinc

140 By simple ligand exchange of the cationic transition-metal complexes [(Cp*)M(acetone)3 ](OTf)2 (Cp

141 der cycloadditions mediated by the first-row transition metal complex [Cr(Ph2phen)3](3+), where Ph2ph

142 res commonly used as ligands for photoactive transition metal complexes designed to interact with bio

143 Here we describe transistors incorporating a transition-metal complex designed so that electron trans

144 computational studies reported herein, late transition metal complexes (e.g., Pt, Co, etc.) in the d

145 We report that visible light absorbing transition metal complexes enable the [2+2] cycloadditio

146 cis effect where an axial ligand at adsorbed transition-metal complexes enables lateral bonding among

147 rise to large excited-state energy losses in transition-metal complexes, enables the observation of s

148 The transition metal complexes [eta(6)- (2beta-carbomethoxy-

149 mechanism similar to that proposed for other transition metal complexes, experimental and DFT studies

150 probe the reaction dynamics of the benchmark transition-metal complex Fe(CO)5 in solution, that the p

151 direct observation of bimolecular SB-CS in a transition metal complex, [Fe(III)L(2)](PF(6)) (L = [phe

152 Transition metal complexes featuring a metal-nitrogen mu

153 binding of hydrogen bond donors to group 10 transition metal complexes featuring a single fluoride l

154 Although other transition metal complexes featuring aNHCs as ligand hav

155 ataalkene and boraalkene complexes and other transition metal complexes featuring the eta(2)-B,C coor

156 ic consequences of the Jahn-Teller effect in transition metal complexes, focussing on copper(ii) comp

157 dge, this is the first report of a first-row transition metal complex for application in trimodal lun

158 be used to develop earth-abundant first-row transition metal complexes for photo- and electrocatalyt

159 e highlight recent advances in the design of transition metal complexes for photodynamic therapy (PDT

160 reactivity has spurred research on first-row transition metal complexes for potential applications in

161 on of the rich redox chemistry accessible in transition metal complexes for the realization of SB-CS.

162 in, launched a new era in the application of transition metal complexes for therapeutic design.

163 iency and highlights the necessity to screen transition-metal complexes for similar ultrafast decays

164 first time a kappa(1)-difluorocyclopropenyl-transition metal complex, formed by reaction of alkynylA

165 A large ring containing two pairs of transition metal-complexing fragments with alternating b

166 predicting relative T(1) relaxation times in transition metal complexes from dynamic ligand field pri

167 te state-of-the-art information on first-row-transition metal complexes, from titanium to zinc in reg

168 cloadditions, oxidative addition of bonds by transition-metal complexes, H-abstractions by oxo-metal

169 based on transfer hydrogenation mediated by transition metal complexes harnessing native cofactors.

170 Electrocatalysis using transition metal complexes has been discussed as an attr

171 To date, light-switch behavior by transition metal complexes has generally been regarded a

172 No Earth-abundant first-row transition metal complexes have displayed emission >1000

173 Bioactive NHC-transition metal complexes have shown promise as anti-ca

174 echanism-based performance optimization, and transition-metal complexes have been extensively explore

175 Transition-metal complexes have long attracted interest

176 tivation of small molecules, mainly based on transition metal complexes, have been developed.

177 lecular catalysts of these reactions, mostly transition metal complexes, have been proposed, renderin

178 er-oxidation catalysts reported thus far are transition-metal complexes, however, here we report cata

179 noxidative, ligand coordination is common in transition metal complexes; however, this bonding motif

180 tion of multiple quantum coherences within a transition metal complex illustrates an emerging method

181 Growing interest in the use of first-row transition metal complexes in a number of applied contex

182 t and sustainable utilization of photoactive transition metal complexes in a plethora of technologies

183 rk is highlighted that specifically examines transition metal complexes in combination with IR with a

184 for rationally designing the electronics of transition metal complexes in general.

185 or charge-transfer states of first-row-based transition metal complexes in solution, barring those ba

186 exist very few excited-state simulations of transition metal complexes in solution.

187 starts with alkyl halides as initiators and transition metal complexes in their oxidatively stable s

188 orbital magnetic effects can arise in linear transition metal complexes in which orbital degeneracies

189 mental photochemical properties of first-row transition-metal complexes in comparison to well-explore

190 tabilizing unusually low-coordination number transition-metal complexes in low formal oxidation state

191 Herein, we report a first-row transition metal complex, in which photoinduced dissocia

192 y demonstrates how rational ligand design of transition-metal complexes (including underexplored seco

193 Although scores of transition metal complexes incorporating ammonia or wate

194 hemists by expanding the synthesis of exotic transition-metal complexes incorporating substituted 1,3

195 the first detailed study of a two-coordinate transition-metal complex indicating strong covalency in

196 antification by examining a tetracoordinated transition metal complex into which a reference and a fi

197 Fragile transition metal complex ions such as [Cr(H2O)4Cl2](+),

198 This protocol describes the synthesis of two transition metal complexes, [Ir{dF(CF3)2ppy}2(bpy)]PF6 (

199 sm study of C-F reductive elimination from a transition metal complex is described.

200 The binding and activation of dioxygen by transition metal complexes is a fundamentally and practi

201 rstanding of the nature of excited states of transition metal complexes is important for understandin

202 ing readily available phosphine derived late transition metal complexes is presented.

203 Crucial to many light-driven processes in transition metal complexes is the absorption and dissipa

204 Hydroamination of alkenes catalyzed by transition-metal complexes is an atom-economical method

205 of sp(2) C-H bonds of alkenes to single-site transition-metal complexes is complicated by the competi

206 om the electrochemical reduction of acids by transition-metal complexes is one of the key issues of m

207 decomposition behavior of the high-nitrogen transition metal complexes, it was discovered that nanos

208 Electrophilic transition metal complexes like {M(II)(EtXantphos)(2)}(2

209 Square-planar d(8)-configured transition metal complexes, [M(II)(dppe)(N(3))(2)] ([1(M

210 Many transition metal complexes mediate DNA oxidation in the

211 Many transition-metal complexes mediate DNA oxidation in the

212 Many transition-metal complexes ML(n) decompose diazo compoun

213 Transition metal complexes (Mn --> Zn) of the dipyrromet

214 m the conventional two-electron catalysis by transition metal complexes, MRC operates through one-ele

215 search on systems like electrophosphorescent transition metal complexes, nucleobases, and amino acids

216 nal examinations of the efficacy of model d6 transition metal complexes of the form [(Tab)M(PH3)2X]q

217 Olefin-transition metal complexes of this type occur extensivel

218 Since the dawn of organometallic chemistry, transition metal complexes of unsaturated organic molecu

219 In our continuing work of exploring late transition metal complexes of unusually high oxidation s

220 Main-group and transition-metal complexes of 2 have been accessed, and

221 ent from that of reactions catalyzed by late-transition-metal complexes of Pd, Pt, and Ir.

222 Transition-metal complexes of radical ligands can exhibi

223 visible-light-absorbing organic molecules or transition-metal complexes of ruthenium, iridium, chromi

224 The preparation of first-row transition-metal complexes of texaphyrin, a porphyrin-li

225 New designs for light-activated transition metal complexes offer photoactivatable prodru

226 and bridging end-on coordination of N(2) to transition metal complexes offer possibilities for disti

227 he chemical and photophysical solutions that transition metal complexes offer, and it puts into conte

228 3) under UV excitation, comparable to chiral transition metal complexes or purely organic emitters.

229 ring-cleavage reactions using stoichiometric transition-metal complexes or enzymes in bacteria are st

230 Our understanding of transition-metal complexes originates from Alfred Werner

231 Phosphine-ligated transition metal complexes play a pivotal role in modern

232 ic coupling matrix element (H(DA)) for eight transition metal complexes possessing donor-acceptor (D-

233 Transition metal complexes provide a promising avenue fo

234 ccurate modeling and predictive synthesis of transition metal complexes relevant for applications ran

235 of advances in this field, the geometries of transition-metal complexes remain limited to a few well-

236 Polypyridyl transition metal complexes represent one of the more tho

237 ively), which proceed without the need for a transition-metal complex, represent reaction pathways th

238 -sensing layer used in this work comprised a transition metal complex, Ru(Ph2phen)3(2+), entrapped in

239 In this subfield of photocatalysis, a transition metal complex serves a double duty by harvest

240 tand scaffolds with the high reactivities of transition metal complexes still remains a major challen

241 lectivity trends found for C-H activation by transition metal complexes, strained cycloalkanes, inclu

242 alkyl reductive elimination from high-valent transition metal complexes [such as gold(III) and platin

243 A transition metal complex targeted for the inhibition of

244 r main-group elements more resembles that of transition-metal complexes than that of their lighter ma

245 providing the first example of a mononuclear transition metal complex that behaves as a single-molecu

246 While diamagnetic transition metal complexes that bind and split H(2) have

247 e rational design of well-defined, first-row transition metal complexes that can activate dioxygen ha

248 e use of luminophores based on more abundant transition metal complexes that do not rely on Pt or Ir

249 y toward the realization of new heteroleptic transition metal complexes that may be used as highly an

250 try and in asymmetric catalysis using chiral transition metal complexes that P-chirogenic phosphorus

251 view on the reactivity of well-defined, late-transition metal complexes that result in the making and

252 C-F bonds can undergo oxidative addition to transition metal complexes, this reaction has appeared i

253 may offer a basis for the development of new transition metal complexes through suitable choice of li

254 H bonds across olefin C C bonds catalyzed by transition-metal complexes through C-H activation and ol

255 eview also introduces theoretical studies of transition metal complexes [TM]-E which carry naked tetr

256 Transition metal complex (TMC)/AuNP hybrids have recentl

257 l for mechanistic and data-driven studies of transition metal complexes (TMCs), but most analyses ass

258 urveying the combinatorial space of possible transition metal complexes (TMCs), but they rely on accu

259 Supramolecular anchoring of transition metal complexes to a protein scaffold is an a

260 erage the ability of visible light-absorbing transition metal complexes to catalyze a broad range of

261 he design, synthesis, and binding studies of transition metal complexes to target the surface histidi

262 ors (HBDs)(5,6) that bind anions of cationic transition-metal complexes to achieve enantiocontrol and

263 d has stimulated the development of numerous transition-metal complexes to effect chemo-, regio-, and

264 revealed reactivity which can mimic that of transition-metal complexes toward small molecules such a

265 The reactions of transition metal complexes underpin numerous synthetic p

266 oup is a ligand of great importance for many transition-metal complexes used in catalysis.

267 A) is presented that automatically generates transition metal complexes using a search space constrai

268 on spins has also been proposed in first-row transition-metal complexes via optically detected magnet

269 lated stannylenes toward zerovalent group 10 transition metal complexes was studied.

270 (x)(P)* pincer ligands and the corresponding transition metal complexes were studied with the nucleus

271 ute-solvent interactions plays a key role in transition metal complexes, where charge transfer states

272 al donor ligands in main group compounds and transition metal complexes which are experimentally not

273 Polynuclear transition metal complexes, which frequently constitute

274 ice based on a spin-coated active layer of a transition-metal complex, which shows high reproducibili

275 cs have appeared as alternative catalysts to transition-metal complexes, which traditionally catalyze

276 A cobalt-terpyridine transition metal complex with pendant pyrene moieties ha

277 s on recent developments in N,O-ligated late transition metal complexes with an emphasis on preparati

278 s of the coordination polyhedra of a host of transition metal complexes with bi- and multidentate lig

279 t experimental evidence for such behavior in transition metal complexes with charge transfer excited

280 The other 3d transition metal complexes with different ligands show r

281 that millisecond T2 times are achievable in transition metal complexes with nuclear spin-free enviro

282 developments in the search for new first-row transition metal complexes with partially filled 3d subs

283 Our study contributes to making first-row transition metal complexes with partially filled d-orbit

284 mple method for predicting the structures of transition metal complexes with pi-bonds.

285 Development of first-row transition metal complexes with similar luminescence and

286 on supramolecular strategies to encapsulate transition metal complexes with the aim of controlling t

287 nderstanding of the electronic structures of transition metal complexes with the triplesalophen ligan

288 While the existence of transition metal complexes with two thermally accessible

289 intermediates formed through the reaction of transition-metal complexes with dioxygen (O2 ) is import

290 ighlight the untapped potential of first-row transition-metal complexes with doublet states, particul

291 ts have developed large numbers of dinuclear transition-metal complexes with extraordinary properties

292 bicyclic alkenes can be readily activated by transition-metal complexes with facial selectivity, beca

293 sfer agent, providing a convenient access to transition-metal complexes with highly electron-rich pho

294 cientific challenge to access Earth-abundant transition-metal complexes with long-lived charge-transf

295 o new ligand design principles for first-row transition-metal complexes with photophysical and photoc

296 thesised functional compounds, behaving like transition-metal complexes with respect to facile activa

297 t allows the covalent anchoring of molecular transition-metal complexes with sub-nanometer precision

298 o introduce additional design principles for transition-metal complexes, with implications for severa

299 talysts--a chiral nucleophile and an achiral transition metal complex working in tandem.

300 In addition, upon reaction with late transition metal complexes, [Zn(2)(eta(5)-Cp*)(2)] was f