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1 junctions of tubules likely to reinforce the triplet.
2 Magnetic data show this complex to be a triplet.
3 for the transition into formally independent triplets.
4 d by separation into weakly bound, localized triplets.
5 to two consecutive non-canonical A*G-C base triplets.
6 photoprotective quenching of harmful (B)Chl triplets.
7 red triplets within long stretches of d(CGA) triplets.
8 nt Cl(*) radical migration forms a localized triplet 1,3-diradical intermediate that, after intersyst
11 t exciton transfer from silicon to molecular triplet acceptors can critically enable new technologies
13 thods, RETrace achieved higher accuracy (88% triplet accuracy from an ex vivo HCT116 tree) at a highe
17 ability of the PheB24-PheB25-TyrB26 aromatic triplet and opens a new direction for therapeutic insuli
18 spin-dependent inter-system crossing between triplet and singlet manifolds, indicating that optically
19 by changing the 5'-nucleobase of the d(CGA) triplet and the frequency and position of the altered tr
20 ted with neurodegeneration revealed that the triplets and the affected offspring are heterozygous car
23 early demonstrating the relationship between triplet aromaticity and singlet-triplet energy gap, conf
24 isms underlying the stability of microtubule triplets, as well as centriole architectural integrity r
27 very and tolerance profile of doublet versus triplet bortezomib-based regimens in patients with initi
29 ndent interplay between emissive singlet and triplet charge-transfer states and amide-localized tripl
31 investigated the addition of panitumumab to triplet chemotherapy with fluorouracil/folinic acid, oxa
33 gets a linear combination of the singlet and triplet configurations involving the HOMO and LUMO rathe
34 to show how flies combine local pairwise and triplet correlations to reduce variability in motion est
35 This independent modulation of singlet and triplet decay rates is highly desirable for the design o
38 t oxygen obtained from photosensitization of triplet dioxygen is shown to react with an alkene surfac
40 with very low surface trap densities as the triplet donor and polyacenes which either favour or proh
42 e demonstrate that it is possible to control triplet dynamics by coupling organic molecules to lantha
46 on (enhanced use of photon energy and larger triplet energies for coupling with common absorbers) mot
47 megaB97XD*) was used to rigorously calculate triplet energies, while a systematic analysis of electro
48 theoretical model, indicated a large singlet-triplet energy gap (DeltaE(S-T) = -45 kcal/mol), a high
49 ship between triplet aromaticity and singlet-triplet energy gap, confirming this novel strategy for m
52 rbit coupling(9-11) or tuning of the singlet-triplet energy splitting(12,13) via molecular design.
53 cal and electronic properties, small singlet-triplet energy splitting, narrow emission line widths, a
54 likely due to elevation of the zeta-carotene triplet energy state above that of BChl a These findings
55 ements, a direct proxy for the efficiency of triplet energy transfer (TET), as well as transient abso
57 nneling-to-hopping transition for long-range triplet energy transfer between nanocrystal light absorb
58 motor pillars confirms efficient triplet-to-triplet energy transfer between the porphyrin linkers an
59 his class of oximes can be harnessed via the triplet energy transfer from a commercially available ir
60 t absorption spectroscopy is used to confirm triplet energy transfer from CdSe to transmitter, and th
61 the excess vibrational energy available from triplet energy transfer leads to hot and nonstatistical
63 are consistent with a reaction course via a triplet enone intermediate and the formation of a 1,4-di
67 ergo efficient upconversion via a lanthanide-triplet excitation fusion process: this process enables
69 t the co-existence of efficient ISC and long triplet excited lifetime in a heavy atom-free bodipy hel
71 ransfer (PeT) from a thiolate to Cy in their triplet excited state and then triplet-to-singlet inters
74 ing fluorophores, photoswitching agents, and triplet excited state quenchers for single-molecule and
75 the reaction proceeds via cyclization in the triplet excited state to yield a 1,4-diradical; intersys
76 y, suggesting an intersystem crossing to the triplet excited state with subsequent phosphorescent dec
82 deep red to near-IR emission involving their triplet excited states in the solid state and in PMMA fi
83 atial restriction efficiently rigidified the triplet excited states of carbon dots from non-radiative
84 prove beneficial for researchers to achieve triplet excited states of organic chromophores for numer
85 ecades, exploring the pathways to access the triplet excited states of organic chromophores has been
86 relative energies of the lowest singlet and triplet excited states, enhancing the yield of triplet-t
88 strated that QDs impart stereoselectivity to triplet excited-state [2 + 2] cycloaddition reactions of
91 range tunneling to long-range hopping during triplet exciton transfer from CdSe nanocrystals to anthr
92 Photoexciting these structures drives spin-triplet exciton transfer from silicon to anthracene thro
94 addition, the delocalization of the neutral triplet exciton was also determined in the oligomers and
95 iconductor nanocrystals interfaced with spin-triplet exciton-accepting organic molecules have emerged
98 on, a localized buildup of slow-decaying(14) triplet excitons and charges(15) gradually reduces the b
102 The generation, control and transfer of triplet excitons in molecular and hybrid systems is of g
103 phenomenon, we study charge separation from triplet excitons in polycrystalline pentacene using an e
105 is via the efficient extraction of the dark triplet excitons into quantum dots (QDs) where they can
106 uorescent materials that efficiently convert triplet excitons into singlets through reverse intersyst
107 nerated singlet excitons can be converted to triplet excitons on sub-10-picosecond timescales with un
108 -scale fluorescence arising from upconverted triplet excitons that are directly created through energ
109 ause singlet fission produces two low-energy triplet excitons that have been unexpectedly difficult t
110 ch provides sufficient statistical space for triplet excitons to separate and avoid annihilation-and
111 cess of splitting a singlet exciton into two triplet excitons, has been proposed as a mechanism for i
112 n, converting singlet excitons into pairs of triplet excitons, have potential as photovoltaic materia
113 a function of driving force for singlet and triplet excitons, including inverted regimes for the dis
114 singlet exciton is roughly isoergic with two triplet excitons, the limiting step is the triplet-tripl
115 These results provide a new way to control triplet excitons, which is essential for many fields of
118 nglet fission-that is, the generation of two triplets from a lone singlet state-has recently resurfac
119 up to 1100 nm and almost degenerate singlet-triplet ground states with weak antiferromagnetic intera
120 ree survival was numerically improved in the triplet group-16.0 months-compared with 10.3 months in t
121 ed by a nine-fold arrangement of microtubule triplets held together by an inner protein scaffold.
122 nes such as butadiynylcyclopropenylidene and triplet heptatriynylidene, thus offering a versatile str
123 tition per se, and underscores that treating triplets in the sequence independently and averaging acr
124 ability of ribosomes to accurately recognize triplet interactions between codons on mRNAs and anticod
125 nitrene formation proceeding via a transient triplet intermediate before reaching a planar singlet sp
128 minant structure in the wild type exhibits a triplet involving the unpaired nucleotide U40 and the ba
130 centrioles lacking a full set of microtubule triplets, its overactivity results in over-elongated and
134 ctroscopy in solution reveals much prolonged triplet lifetime of PTC-1(2H) relative to monomer refere
136 his molecule has an exceptionally long-lived triplet LMCT excited state (tau = 350 mus), featuring hi
138 s CUG directs translation of a conserved 260-triplet-long overlapping open reading frame (ORF), which
142 igand stretching vibrational wavepacket on a triplet metal-centered ((3)MC) excited state surface.
144 et of non-tubulin components attached to the triplet microtubule (MT), many are at the junctions of t
146 system crossing leads to the population of a triplet minimum of the thietane intermediate in as short
147 ific differences in the interaction of their triplet motifs determine the profound differences in KCN
149 radical chemistry (intersystem crossing with triplet O(2)) does not seem to be involved in O(2) activ
151 explore how hypophosphorylation of Cx43 at a triplet of serine residues (S325/S328/S330) in the regul
153 the option to skip bases between the target triplets of otherwise adjacent fingers in each zinc-fing
154 loss of m(5) C impacts the decoding of some triplets of these two amino acids, leading to reduced tr
155 omega(flap) = +/-44 deg) and C(2v)-symmetric triplet (omega(flap) = 0 deg) stem from nonclassical ele
157 erlapping such as competing structures, base triplets, or other 3D non-antiparallel interactions.
158 functionalized derivative leads to efficient triplet pair separation, giving rise to an overall tripl
161 omophores about the molecular axis following triplet-pair separation contributes to the increase in e
162 This work demonstrates that a real, emissive triplet-pair state acts as an intermediate in both singl
164 inglet states matches that of the correlated triplet-pair state, which we attribute to singlet/triple
165 Combined with existing data that indicate triplet pairing in UTe(2), the presence of chiral states
170 totype carbenes with distinct multiplicities-triplet pentadiynylidene (HCCCCCH) and singlet ethynylcy
177 (hole); the separation rates for singlet and triplet polaron pairs: k(S,s) = (44.59 +/- 0.01) MHz, k(
179 x10(5) m(-1) cm(-1) at 630 nm), satisfactory triplet quantum yield (Phi(T) =52 %), and long-lived tri
181 we explore an important resource for singlet-triplet qubits: a transverse sweet spot (TSS) that enabl
183 ed to assess the efficacy and safety of this triplet regimen in patients with relapsed or refractory
192 of MutL proteins that has been implicated in triplet repeat expansion, but its action in this deleter
195 the stability and versatility of the d(CGA) triplet repeat motif and provides constraints for using
199 ocess, injecting entanglement in the form of triplet resonating valence bonds into the ordered ferrom
200 local moments and conduction electrons, from triplet resonating valence bonds to Kondo-entangled sing
202 (anti-head-to-tail), or exclusively 5 in the triplet-sensitized photoreaction, in the presence of ben
203 em catalysis by reacting with the oxime as a triplet sensitizer in the first catalytic cycle and a re
206 TT) singlet-fission intermediates toward two-triplet separation (T...T) using spin-state-averaged den
208 d across noninvasive studies of streaming of triplets; show percept-related changes in frontoparietal
209 otion percepts incorporate both pairwise and triplet spatiotemporal correlations that could theoretic
210 owever, even in fibers, the formation of the triplet species increases with increasing peptide/porphy
211 a structure of (.) OH...OP(.) , for which a triplet spin multiplicity with a binding energy of -3.20
213 ealed that access to high spin states (e.g., triplet spin state tetrahedral Ni(II) species) is critic
215 proximal position with F shifts the singlet-triplet splitting by +4.5 +/- 0.4 kcal mol(-1) from orth
216 harmonic vibrational frequencies and singlet-triplet splittings are computed using the benchmarked fu
218 quantum yield (Phi(T) =52 %), and long-lived triplet state (tau(T) =492 mus), leading to unprecedente
219 o transmitter, and the formation of a bridge triplet state as an intermediate for the hopping mechani
221 also to predict their reactivities based on triplet state energy transfer and transition state energ
222 e rate constant for charge transfer from the triplet state is surprisingly small, ~10(7) s(-1), prese
223 hat Dexter electron exchange from the ligand triplet state is the dominant energy transfer mechanism
225 erno-Buchi reaction that utilizes the unique triplet state reactivity of oximes, specifically 2-isoxa
226 t intersystem crossing to the lowest excited triplet state upon halogenation was a key mechanistic st
227 As compared to the singlet state, in the triplet state, the Gibbs barrier for the attack to the [
235 UV photoproducts of tryptophan yield excited triplet-state organic matters during sunlight irradiatio
236 oupled cluster [DLPNO-CCSD(T)] theory reveal triplet-state wavefunction spatial distributions consist
237 gy separation between the lowest singlet and triplet states (Delta E(S(1)-T(1)) = 500 cm(-1)) and an
239 rgies of charge transfer and locally excited triplet states influence the performance of the deep-blu
240 lexes, zeta-carotene does not quench excited triplet states of BChl a, likely due to elevation of the
241 eactive intermediates (RIs), such as excited triplet states of dissolved organic matter ((3)DOM*), si
244 d computational studies usually characterize triplet streaming either during alternations or during b
245 ations about the upcoming label based on the triplet structure and were surprised when it happened to
246 etic fluctuations are argued to lead to spin-triplet superconductivity from pairing between opposite
250 ses, the distinguishability of the molecular triplets-that is, the extent of orbital overlap-determin
251 (5) C loss leads to ribosome stalling at UUG triplets, the only codon translated by an m(5) C34-modif
252 ohort D) or 1.8 mg/kg (cohort E); and in the triplet therapy group fixed nivolumab 3 mg/kg and ipilim
253 in the nivolumab group, and 11 (50%) in the triplet therapy group including: eight (13%) of 64 patie
254 roup), nivolumab (nivolumab group), or both (triplet therapy group) using a 3 + 3 dose escalation des
255 the nivolumab group, and 82% (60-95) in the triplet therapy group, and the complete response rate wa
256 olumab group, and 1.7 years (1.6-1.9) in the triplet therapy group, median progression-free survival
260 , brentuximab vedotin with nivolumab and the triplet therapy, are being compared in a randomised phas
262 the reverse intersystem crossing (RISC) from triplet to singlet exciplex diminishes, a pronounced iso
264 iplets to gain oscillator strength, enabling triplets to be directly generated on molecules via photo
265 om the ground-state singlet to excited-state triplets to gain oscillator strength, enabling triplets
266 to-photoluminescence studies reveal that the triplet-to-singlet conversion in exciplexes involves an
267 The results of our work indicate successful triplet-to-singlet energy transfer and a sizable increas
268 o Cy in their triplet excited state and then triplet-to-singlet intersystem crossing in the nascent g
269 e molecular motor pillars confirms efficient triplet-to-triplet energy transfer between the porphyrin
271 y unfavourable and spectroscopy shows direct triplet transfer from nanocrystals to naphthalene; nonet
272 tracene is energetically favoured, and hence triplet transfer proceeds via a charge separated state.
273 e range [Formula: see text] = 3-9 D with the triplet transitions consistently showing shorter charge
274 latory activity in the beta band (~20 Hz) at triplet transitions that indexes learning: it emerges wi
275 ized that hypophosphorylation of Cx43 serine-triplet triggers pathological Cx43 redistribution to the
278 iplet excited states, enhancing the yield of triplet-triplet annihilation and promoting radiative dec
279 an intermediate in both singlet fission and triplet-triplet annihilation and that this is true for b
280 ile delayed fluorescence results mainly from triplet-triplet annihilation at lower temperatures in TH
283 stinct (1)(TT) emission arises directly from triplet-triplet annihilation in high-quality pentacene s
284 o triplet excitons, the limiting step is the triplet-triplet annihilation pathway, where the kinetics
291 f excited-state lifetime extension utilizing triplet-triplet excited-state equilibria is detailed.
293 dressable defect sites, we designed the spin-triplet, V(3+) complex, (C(6)F(5))(3)trenVCN(t)Bu (1).
294 ges associate with two centriole microtubule triplets via an elaborate filamentous base and that they
295 ed knockin mdx mice in which the Cx43 serine-triplet was replaced with either phospho-mimicking gluta