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1 onds due to the localized nature of their 4f valence electrons.
2 entral element essentially retains its eight valence electrons.
3 s domain wall is compensated by the unbonded valence electrons.
4 etals, which enforced alignment of the other valence electrons.
5 ation of w-phase due to the higher number of valence electrons.
6 re controlled by the configurations of their valence electrons.
7 the target ions, not readily screened by the valence electrons.
8 olecule: any attempt results in two unpaired valence electrons.
9  topological change of the Fermi surface for valence electrons.
10 ht-matter interactions and for properties of valence electrons.
11 g from the unique character of their outer-d valence electrons.
12 rge gap despite not having a magic number of valence electrons.
13 lectronically saturated and not deficient in valence electrons.
14 sed consistently on ground-state energies of valence electrons.
15 bly begins with very tight binding of the 34-valence electron 2Fe complex to the apo-[4Fe-4S] enzyme,
16 nate octet-defying species with formally six valence electrons(3).
17                          For example, the 18-valence electron ABX family of compounds features exampl
18  of Ir-trimers with a different number of 5d valence electrons already exists at room temperature.
19 ation of the 4f(1) configuration with ligand valence electrons, analogous to transition metals.
20 eV range, which is high enough to displace a valence electron and often also inner shell electrons fr
21 iew highlights synergistic effects involving valence electrons and atomic-level and nanoscale inhomog
22 our (no IVCT) because of localization of the valence electrons and poor spatial overlap between metal
23 e interaction between the ionic core and the valence electrons and the exchange energy between the su
24 such techniques are only weakly sensitive to valence electrons and yield superpositions of signals fr
25  provide a way to quantify the population of valence electrons, and point to possible applications of
26 including size, electronegativity, number of valence electrons, and position on the periodic table (g
27 ed effect of the nucleus, core electrons and valence electrons, and separating their contributions is
28  of main-group elements with more than eight valence electrons, and the concept of hypervalency is co
29 on-rich three-center bonding in triatomic 22-valence electron anions.
30  molecule drives the parent molecule and non-valence electron apart, thereby inhibiting geminate reco
31 compounds assuming open structures where the valence electrons are localized in interstitial voids, r
32 h-transition-temperature superconductors the valence electrons are localized--one per copper site--by
33 and bonding that reflect the extent to which valence electrons are shared between the endohedral atom
34 pped octahedral clusters with 25 metal-based valence electrons are shown to provide versatile buildin
35                               Monomeric five-valence-electron bis(boryl) complexes of gallium, indium
36                                 The first 16 valence electron [bis(NHC)](silylene)Ni(0) complex 1, [(
37 connection between real space, namely atoms, valence electrons, bonds, and orbitals, and reciprocal s
38 ngth of the effective interactions among the valence electrons but also on their type.
39 (dicoordinate carbon compounds with only six valence electrons), can undergo one-electron oxidation,
40 , positive BE shift due to O bonds), because valence electron charge density moves toward electronega
41 izes of the cations and anions and the total valence electron concentration (governed by the stoichio
42 stances and crystal structures themselves on valence electron concentration (T is a mixture of Ga and
43                                          The valence electron concentration (VEC) of the thallium lay
44  of the Mackay icosahedra and that a further valence electron concentration (VEC) optimization is ach
45 cture of cubic-B1 HECs correlates with their valence electron concentration (VEC).
46 relation between bonding state depletion and valence electron concentration across the compositional
47 ), the phases with 1 < or = x < or = 2.2 and valence electron concentration of 28.8-30 e-/formula ado
48 )(x)() phases with 0 < or = x < or = 0.6 and valence electron concentration of 30.4-31 e(-)/formula c
49 f constituent elements, as a function of the valence electron concentration, n, obtained from the int
50 onfigurational entropy and a decrease in the valence electron concentration, providing parameters for
51 xperimental validation, suggest that average valence electron concentration, the difference in atomic
52 nyl) sandwich complex, with the ground-state valence electron configuration of uranium(II) revealed b
53 (6) share the same crystal structure, atomic valence electron configuration, and phonon modes, they e
54 eemed particularly well adapted to the 3d(8) valence electron configuration.
55 it and crystal-field influences on the 5f(1) valence electron configuration.
56 obalt(III) can adopt identical low-spin d(6) valence electron configurations due to their close chemi
57 ometallic compounds with the 4d(6) and 5d(6) valence electron configurations have outstanding photoph
58 erties of materials are mainly determined by valence electron configurations, where different valence
59 rate information on elemental properties and valence electron configurations.
60 ver, due to blurring by the probe shape, the valence electron contribution forms a nearly featureless
61  more uniform relationship between the total valence electron count and the structure and bonding pat
62                        Here we show that the valence electron count dependence of the superconducting
63                     Furthermore, we identify valence electron count domains for alloy ductility and b
64 n by a sequential 2-electron boosting of the valence electron count of Au nanoparticles.
65  with well-defined structures related to the valence electron count of the involved metals.
66 al shells can be placed on a ladder of total valence electron count that ranges between 4n+2 (closo d
67 b (Ln = La-Nd, Sm) compounds that, with a 19 valence electron count, has one extra electron compared
68 ron affinities usually requires changing the valence electron count.
69 ogical isomers whose stability may depend on valence electron count.
70  such complexes has prevented application of valence electron counting and other tools for understand
71                        Typical examples show valence electron counts (vec) between 12 and 16 for the
72 of the Fe 3d orbitals regulated the observed valence electron counts between 220 and 228 electrons/fo
73 ns, respectively, clusters with all possible valence electron counts from 11 to 46 are studied to pro
74 ansion of the octet to 10, 12 or even higher valence electron counts.
75 -resolved X-ray imaging of chemically active valence electron densities extremely challenging.
76   Time-resolved imaging of chemically active valence electron densities is a long-sought goal, as the
77 cattered photons, to image chemically active valence electron densities.
78         Here, we selected ScS to measure the valence electron density and orbital population of Sc(2+
79 n(II) atom is surrounded by a torus of xenon valence electron density comprised of the three valence
80 er characterized by a periodic modulation of valence electron density coupled with lattice distortion
81 ffects of both the inter-atomic distance and valence electron density in MGs, and result in the obser
82 kalis or expanded alkalis, ones in which the valence electron density is pulled out to a greater exte
83 otubes in water with K(2)Ir(Cl)(6) reveals a valence electron density of 0.2-0.4 e(-)/100 carbon atom
84 nimum feature size ultimately depends on the valence electron density, which is sufficiently high and
85 ly just those underestimated energies of non-valence electrons determined Hofmeister effects.
86  to the confined spatial distribution of the valence electrons directly involved in the conical inter
87  these low-energy excitations is provided by valence electron energy loss spectroscopy and near-field
88                 We further use monochromated valence electron energy-loss spectroscopy to obtain spat
89 tion of transmission electron microscopy and valence electron energy-loss spectroscopy, we detect wat
90 e endohedral metal has relatively accessible valence electrons (from the d or f shells), it can also
91 o molecular entities with the same number of valence electrons have similar chemistries'.
92 ectrons, has single spin-[Formula: see text] valence electron in its p- or d-orbital, respectively.
93 electronic configurations when they have 100 valence electrons in 50 orbitals or 114 valence electron
94  100 valence electrons in 50 orbitals or 114 valence electrons in 57 orbitals.
95 tures stemming from f-orbital occupations of valence electrons in actinide elements.
96 n Fe-S proteins is the redistribution of the valence electrons in the manifold of thermally populated
97 8) through the chemical bonding of all eight valence electrons in Xe and, thereby, fulfilling the oct
98 ium (three valence electrons) with tin (four valence electrons) in the series In(1-x)Sn(x)Pd(2), whic
99  at pressures where core electrons (not only valence electrons) influence the structure and bonding o
100 crease exposure of atoms involved in n/sp(2) valence electron interactions.
101 asma fluctuations and crystallization of the valence electrons into an exciton condensate.
102  Li cores start to overlap and thereby expel valence electrons into quasi-two-dimensional layers char
103 f the Na(+) ionic diameter, and squeezes the valence electrons into the interstitial voids suggesting
104 on state as well as DFT-calculated number of valence electrons is obtained; measured energy shifts ar
105 fluoride (BF) is a diatomic molecule with 10 valence electrons, isoelectronic to carbon monoxide (CO)
106 owever, the halogen atoms in these cases are valence electron lone pair donors, and the sigma*Xe-O or
107 ence electron density comprised of the three valence electron lone pairs.
108 ng is always dominated by the core and inert valence electrons, making time-resolved X-ray imaging of
109                           Reaction of the 18-valence-electron manganese dihydrogen hydride complex [M
110   This is interpreted as a redistribution of valence electrons near the Fermi level.
111  adding one oxygen atom with a full octet of valence electrons (O(2-)) to stoichiometric cationic zir
112 etermine the vertical ionization energies of valence electrons of both the solvent and the solute mol
113 induction force implied that energies of non-valence electrons of ions/atoms at the interface might b
114  and is nowhere more apparent than in the 5f valence electrons of plutonium.
115 action between the two ground-state spin-1/2 valence electrons of two (88)Sr(+) ions, co-trapped in a
116 ened Coulomb repulsion and to the Born-Mayer valence electron overlap repulsion for various alloys.
117 tion is occupied by a sterically active free valence electron pair of chlorine.
118 by the presence of a sterically active, free valence electron pair on Xe.
119 sponsible for instabilities in seven to nine valence electron per atom (e(-)/a) bcc systems and five
120 1:1) ABX family of ternary materials with 18 valence electrons per formula unit.
121 stances while maintaining the same number of valence electrons per unit cell and close atomic coordin
122 yclometalation and ultimately affords the 14 valence-electron Pt(II) complex [Pt(kappa(2) PC -P(t) Bu
123 iguous 13+ forms via a complex redox-induced valence electron rearrangement whereby the one-electron
124 tent high-spin ground states under which the valence electrons remain coupled.
125 ve Dirac fermions can be realized when their valence electrons represent an SSH chain close to the to
126 on (Ph(3)C(+)) (ref. (2)) with seven and six valence electrons, respectively, and carbenes (R(2)C:)-t
127 idering that Al and Mg possess three and two valence electrons, respectively, clusters with all possi
128  ranging from +2 to -2, and following the 18-valence electron rule.
129 essure, some materials form electrides, with valence electrons separated from all atoms and occupying
130 ate a local magnetic field by modulating the valence electron shell motion relative to the nuclear/el
131 demonstrates the high potential of this four valence electron species in C-H bond activation reaction
132         Focusing instead on the family of 18 valence electron ternary ABX compounds that consist of e
133                                              Valence electron to carbon ratio and length of conjugate
134                     Band-bending enables the valence electron to tunnel into the surface states at re
135 ion of a large (10% or more) fraction of the valence electrons to the conduction band.
136 ributions of both the core electrons and the valence electrons to the derived electron charge density
137 e d or f shells), it can also contribute its valence electrons to the total electron count of the clu
138 l hydride cation, a rare five-coordinate, 16-valence electron transition metal alkyl hydride species
139 nar Mobius aromatic complexes with 16 and 18 valence electron transition metals.
140 re, allowing a stabilizing redistribution of valence electrons upon heating.
141 ed by a natural orbital decomposition of the valence electron wavepackets.
142 ong predicted as a means to launch and probe valence-electron wavepackets and as a building block for
143 he plasmon energies of the pi and pi + sigma valence electrons were measured using electron energy-lo
144  group on the population of the sigma and pi valence electrons, were constructed on the basis of natu
145 strates that the triflate salts tend to have valence electrons with higher s-character, and solid-sta
146 eved for a system containing 256 atoms (1024 valence electrons) with a negligibly small numerical err
147 is achieved by substitution of indium (three valence electrons) with tin (four valence electrons) in
148 oximate energy and relative proximity of two valence electrons within the same alkaline-earth atom, t
149 heoretically predict that a cluster with 107 valence electrons would uniquely combine high stability

 
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