ライフサイエンスコーパス: valence state

1 rom the Fe(+III)/O(-II) to the Fe(+II)/O(-I) valence state.

2 wo different life stages that share the same valence state.

3 with fluctuations of the plutonium 5f mixed-valence state.

4 laromatic portion of the bridge, and a mixed-valence state.

5 u(CO) IR band shape coalescence in the mixed valence state.

6 reoxidized by molecular oxygen to the mixed-valence state.

7 eal an approximate 10 ns lifetime for bright valence states.

8 on-like process due to the metal ions' multi-valence states.

9 harged states with carrier ions of different valence states.

10 gnetic metal (FM-M), owing to their multiple valence states.

11 middle and top) to represent three possible valence states.

12 vidence of valence trapping within the mixed-valence states.

13 ckel hydrocorphinate in its Ni(II) and Ni(I) valence states.

14 ion metals coordinated with N and/or at high valence states.

15 sition occurs between neutral and negatively valenced states.

16 potentials of Mn oxides are determined by Mn valence states (2+, 3+, 4+).

17 ) H(6) )Mo(CO)(3) regarding the metal-center valence state and electronic population of the planar-cy

18 ic transport of the uncommon Au(2+/3+) mixed-valence state and the characteristics of the elusive Au(

19 tersections between the excited zwitterionic valence state and the ground-state surface, similar to t

20 ogrammable functionalities by modulating the valence states and local coordination of constituents.

21 iconducting oxides with cations of different valence states and materials of distinct crystallographi

22 tice oxygen enables reversible changes in Mn valence states and Mn-O bond covalency during redox cycl

23 No redistribution of the manganese valence states and only minor perturbation of the exchan

24 o, Ni, Zn, Tc, Cd, Hg (affected by choice of valence state), and Gd.

25 the relationship among coordination number, valence state, and catalytic performance and achieves hi

26 ets to precisely determine the distribution, valence state, and structure of selenium in biofilms sam

27 JT ions disproportionate to higher and lower valence states as a means of avoiding their JT tendency,

28 state persistence, and preference for mixed-valence states as determined by electrochemical compropo

29 The latter makes Zn a low-valence state, as deduced from X-ray photoelectron spect

30 to a chemosensory cue that triggers the same valence state at different life stages, revealing an une

31 m settles into a magnetically ordered single valence state at low temperatures.

32 th growing tendency to form Cs (III) and (V) valence states at fluorine-rich conditions.

33 cycle, recycling sulfur in its most reduced valence state back to more oxidized forms usable as elec

34 These cannot be unambiguously assigned to a valence state based solely on the knowledge of bulk matt

35 wering the pH resulted in not only a trapped valence state, but also a dramatically increased reducti

36 Vacancy-engineered mixed-valence-state cerium oxide nanoparticles (nanoceria part

37 gy change of the absorption peak and thus no valence state change in the bulk.

38 her grain boundary density and the higher Cu valence state compared to CuO.

39 lable growth approach that enables a precise valence state control.

40 nalysis of manganese mineral occurrences and valence states demonstrate oxidation of Earth's crust th

41 social task were associated with changes in valence states during the PVT, while attention showed no

42 ytochrome c peroxidases that require a mixed valence state for activity.

43 is was used to track the evolution of the Se valence state for both crystalline and noncrystalline ph

44 te, and the Ni center has to be in its Ni(I) valence state for the enzyme to be active.

45 ogs is complicated by the possibility of two valence states for cerium and possible presence of magne

46 allographically characterized, higher nickel valence states have not been identified.

47 upation approaches the Cu(2+) limit, a mixed valence state in CaCu(3)Rh(4)O(12) and heavy fermion sta

48 cal/mol), indicating relatively stable mixed-valence state in the dichloromethane, whereas in the ace

49 Non-valence states in neutral molecules (Rydberg states) hav

50 tes that like iron, oxygen may have multiple valence states in our planet's interior.

51 iderably less is known about the role of non-valence states in photo-induced processes in anions.

52 fect through the electronic structure of the valence states in these strong-coupling conditions.

53 in contains two copper ions bound in a mixed-valence state, indicating that the CuA site in cytochrom

54 eous population of bridge-oxidized and mixed-valence states is likely related to a number of factors,

55 n excites a core electron into an unoccupied valence state, is an essential process in many standard

56 This temperature-dependent valence state isomerization has been observed for other

57 vity gradient across the wafer, a continuous valence state library is established to directly identif

58 utional paramagnetic Mn dopant ions in mixed valence states (Mn(2+) and Mn(3+)) was confirmed and qua

59 eactions, and its performance depends on the valence state, morphology and dispersion of Ag species.

60 n that many anionic chromophores have bright valence states near the detachment threshold.

61 electron oxidation, corresponding to a mixed-valence state, occurs at a significantly lower potential

62 efficiency is achieved at an average silver valence state of +1.08 in AgP(2) NCs.

63 The mixed valence state of Eu observed in the high-pressure (HP) f

64 redox-sensitive and retains a memory of the valence state of Fe in primary arc basalts and their man

65 demonstrated that both concentration and the valence state of inorganic arsenic (arsenite, As(III) vs

66 with the suggestions that cuprous ion is the valence state of intracellular copper.

67 r concentrations, 6-OHDA readily altered the valence state of iron [Fe(III)] to Fe(II), which would a

68 ccurately predict the composition of the mix valence state of Mn.

69 e over-oxidation of urea brought by the high valence state of Ni, tremendous efforts are devoted to o

70 ich has a unique bilayer structure and mixed valence state of nickel.

71 The valence state of precursor tobacco is not a controlling

72 Copper cations maintained the low-valence state of Rh.

73 identifies the previously indistinguishable valence state of silver atoms on the nanocrystal surface

74 er of the oxygen evolving complex in a mixed valence state of the form MnIIMnIIIMnIIIMnIII,MnIIMnIIIM

75 n d are strongly dependent on the ligand and valence state of the heme iron.

76 ates Cr(VI) was reduced to Cr(III) while the valence state of the iron core is unchanged.

77 licity and electrophilicity by switching the valence state of the palladium centre (Pd(0) and Pd(II),

78 sition between delocalized and trapped mixed valence states of an engineered CuA center in azurin has

79 ion near edge structure (XANES) to determine valence states of As from the tobacco plant to the cruci

80 The MoM-THA exhibited different valence states of chromium- and cobalt-containing debris

81 applied to study the fully reduced and mixed valence states of cytochrome ba(3) from Thermus thermoph

82 The mixed-valence states of DS are unstable at temperatures above

83 Soft X-ray reveals directly the valence states of Fe 3d electrons in the vicinity of Fer

84 oelectron spectroscopy results show that the valence states of Mn and Fe in Fe3O4@OMS-2@CTS changed d

85 operly, an accurate decomposition of the mix valence states of Mn remains non-trivial.

86 Approaches via phase change, strain, and valence states of redox species have been developed to c

87 The different valence states of tetrahedral metal ions were suggested

88 terial potential, and ratio of Ce(3+):Ce(4+) valence states of the cerium oxide nanoparticles.

89 tomers and supports His-Met ligation in both valence states of the iron.

90 for which the lowest conduction and highest valence states of the low-lying pair are shifted away fr

91 re to Li ions enables access to the multiple valence states of the metal cation.

92 l methods under ambient conditions since low-valence states of uranium are typically oxidized to U(VI

93 From the modeling of spectra and maps of the valence state over large regions of the cathodes, it was

94 ng ligand can effectively stabilize the high-valence-state Pd species (Pd(delta+)) resulted from the

95 matrix renormalization group plus n-electron valence state perturbation theory (DMRG+NEVPT2) and coup

96 isotopic labeling and high-level N-electron valence state perturbation theory and coupled-cluster co

97 re presents a clear dispersion upon crossing valence states, providing direct evidence of f-d hybridi

98 otential energy surface corrugation, lowered valence states reducing surface adsorbates, and forbidde

99 passivated solid electrolyte interphase and valence state reduction of the hard-to-dissolve metal co

100 be cycled with Mo atoms below a formally +4 valence state, resulting in an acceptable voltage regime

101 piration for tackling metals exhibiting high valence states such as in the lanthanide and actinide se

102 ansition metal ions (TM ions) are in a lower valence state than in the bulk, and the O K-edge prepeak

103 m isomer are more destabilizing in the mixed-valence state than in the diferrous state.

104 ates Y2Ru2O7-delta electrocatalyst had a low valence state that favors the high OER activity.

105 Cu...Cu distance of 2.4724(4) A in the mixed-valence state that is virtually identical to the Cu...Cu

106 spectra and quantitatively determined the 3d valence states that are completely redistributed through

107 ergy loss spectroscopy confirms a uniform Mn valence state throughout the SLs.

108 excellent control over the transition metal valence state to avoid performance deterioration, which

109 nduces a counterintuitive shift of the O(2p) valence state to lower binding energy of up to 243 meV w

110 on magnetite through precipitation of mixed-valence state U(V)/U(VI) solids.

111 The role of ionic radius and metal valence state was explored by conducting similar removal

112 Because of its high instability, the mixed-valence state was generated electrochemically in the pro

113 d bioavailability of Se is controlled by its valence states, we aimed to define Se speciation in coal

114 ases are formed that bear Cr in intermediate valence states, which convert to different species other

115 ized framework was found to exist in a mixed-valence state with thermally-activated semiconducting be

116 ading to the generation of a temporary mixed-valence state within the rigid and robust homo[2]catenan

117 lting from an enhanced synergy between mixed-valence states within the framework.

118 n anion exchange membrane fuel cells, the Mn valence state, within spinel Mn(3)O(4)/C, increases to a