ライフサイエンスコーパス: MeOH

1 MeOH and THF permeance increased when MOFs were embedded

2 MeOH displayed excellent chromatographic performance (se

3 d bound DMF molecules for methanol to give 1-MeOH, complete desolvation of the framework at 180 degre

4 aration (5min separation using acidified 10% MeOH isocratic flow in a CORTECS C18 column) to allow un

5 creasing organic modifier concentration (10% MeOH: K1 = 1590 M-1, K2 = 1130 M-1, alpha = 1.41.10% ACN

6 In 10% MeOH/H(2)O at pH 1 or 11 or in pure MeOH, assembly is dr

7 In 10% MeOH/H(2)O, the tetraphenylporphyrin (TPP) and 1,4,5,8-n

8 l3, benzene) and even in the presence of 10% MeOH.

9 ween these two groups than both 50% and 100% MeOH.

10 of some of the norbornene, but even in 100% MeOH, the norbornyl chloride products of ion pair return

11 r 1000W, extraction time 20min, solvent 100% MeOH, and solvent-to-sample ratio 10:1.

12 ed in MeOH/H2O ratios ranging from 0 to 100% MeOH and analyzed with untargeted reversed phase LC-MS s

13 ile, reacts in a similar fashion (e.g., 16 + MeOH --> 43).

14 theoretical predictions, and by employing 2% MeOH/toluene as solvent, the Heck-Matsuda reaction provi

15 stalline solid solutions (M,M')(NPBA)2(NO3)2(MeOH)2 (M, M' = Co2+, Ni2+, or Zn2+, 13-16), where mixtu

16 Molecule Magnet (SMM) [MnIII6O2(sao)6(O2CH)2(MeOH) 4] (1) (where sao2- is the dianion of salicylaldox

17 HCO2- in the molecule [MnIII6O2(sao)6(O2CH)2(MeOH)4] (1), with Et-sao2- (Et-saoH2 = 2-hydroxypropioph

18 Ester hydrolysis with Ba(OH)(2)/MeOH gave the target prodrug 2a which is a substrate for

19 (THF = tetrahydrofuran) solvent mixtures, 2-MeOH is characterized by a LMCT band at lambda(max) = 51

20 pon addition of HO(2) to 1 and converts to 2-MeOH at a rate of 65(1) s(-1), which is consistent with

21 ing above -50 degrees C, 3 is converted to 2-MeOH.

22 The solvent isotope effect of 1.29 (MeOH/MeOD) for acetyl chloride is similar to that for p-

23 (2a) and (Li-OPO)PdMe(L) (L = pyridine (2b); MeOH (2d); 4-(5-nonyl)pyridine) (py', 3)).

24 organic framework (MOF), [Bi(BTC)(H2O)].2H2O.MeOH denoted CAU-17, was synthesized and found to have a

25 Direct ammonolysis (NH(3)/MeOH) of such intermediates or benzylation of the imidaz

26 (5), CF3COCHCOCF3(-) (6), and solvent = 0.5 MeOH (4), 2 CH2Cl2 (5).

27 M Tris, pH 8, sheath liquid containing 50/50 MeOH/10 mM HCO(2)NH(4) delivered at 5 microL/min, spray

28 used reconstitution solvent mixture of 50/50 MeOH/H2O, our results indicate that the small fraction o

29 PSPEP sorbent and elution with 100muL of 50% MeOH) were combined with a fast UHPLC separation (5min s

30 bsequently, the adducts were eluted with 50% MeOH and the sample was reduced in volume in an evacuate

31 The phenolic profile of 80% MeOH extracts of the stinging nettle (Urtica dioica L.)

32 ggregate to give ((Na(5)O) subset [Ni(L)](9)(MeOH)(3))(BF(4))(2).OH.CH(3)OH, 7.

33 All peptides were more structured in 90% MeOH than in aqueous buffers.

34 by a nucleophilic attack on the nitrogen, a MeOH-assisted [1,3]-proton transfer, and subsequent loss

35 -H of the dihydropyridyl ring and the O of a MeOH and also via an N...H-O interaction between the N c

36 Mechanistic investigations of a MeOH-induced kinetic epoxide-opening spirocyclization of

37 uit samples were extracted with an acidified MeOH mixture assisted by ultrasound.

38 The epsilon in acidified MeOH and buffer pH 1 ranged between ~16,000-30,000 and ~

39 ical extract, using 80% organic solvent (ACN:MeOH:H2O 2:2:1).

40 In addition, MeOH-based nanoLC-MS/MS yielded superior results for the

41 Although MeOH also affects the magnitude of the reaction rates an

42 ves the fitting for TFE, MeCN/H(2)O 2:1, and MeOH but at the expense of that for tertiary alkanols.

43 In TFE, MeCN/H(2)O 2:1, and MeOH, the measured k(H) values were lower than expected

44 In the solvents investigated (CH(2)Cl(2) and MeOH), the most favorable mechanism is addition of perox

45 seful as food additives, such as MeOH-2, and MeOH-3, completely devoid of hepatotoxic components.

46 ea-mediated tetramer dissociation (pH 7) and MeOH-facilitated fibril formation similar to those of WT

47 nd thiophenes in combination with amines and MeOH as a C1 source.

48 strating why the presence of excess base and MeOH or H2O is required for efficient and enantioselecti

49 ed pyrrolidines using 4 N HCl in dioxane and MeOH gave the corresponding enantiomers of 2-substituted

50 The EtOAc and MeOH extracts of P. guajava showed 56.4% (COX-2) and 44.

51 Furan and MeOH could also be employed as external nucleophiles in

52 Finally, interaction of 1+ with H2O and MeOH and 2-Me+ with H2O was also examined.

53 equently used solvent systems, ACN/H(2)O and MeOH/H(2)O, revealed that the antimony(III)-tartrate dia

54 in the solution of 10 in deuterium oxide and MeOH-d4.

55 ICl) in CH(2)Cl(2), CH(2)Cl(2)/pyridine, and MeOH are described.

56 Starting with Wat1 removed and MeOH hydrogen bonded to Asp-297-CO(2)(-), we find that M

57 the Umemoto reagent as the CF(3) source and MeOH as the reductant is disclosed.

58 d k(D)/k(T) values, is the same in water and MeOH/water mixtures, implicating similar trajectories fo

59 0 degrees C methylation procedure (anhydrous MeOH/acetyl chloride, 25:4, v/v) was performed.

60 tion species react with nucleophiles such as MeOH by clean second-order kinetics with rate constants

61 pon the addition of a proton source, such as MeOH, or by running the reaction under a hydrogen atmosp

62 extracts, useful as food additives, such as MeOH-2, and MeOH-3, completely devoid of hepatotoxic com

63 For cpn10, both MeOH and TFE additions govern initial unfolding; however

64 e than the 6-fluoropurine compound with both MeOH/DBU/MeCN and iPentSH/DBU/MeCN and was more reactive

65 d significantly with 1 and BrCl in MeOH, but MeOH had little affect on the other reactions.

66 Likewise, complex 2 can replace acetone by MeOH and H2O to form [Fe(bpp)(H2L)](ClO4)2.1.25MeOH.0.5H

67 axane and its dumbbell precursor in a CH2Cl2/MeOH (3:2) mixed solvent and liquified by adding the oxi

68 rphine (FeTPP) and PhIO (in anhydrous CH2Cl2/MeOH).

69 own that both in DMPC vesicles and in CHCl3: MeOH the protein adopts a highly helical secondary struc

70 d transmission FTIR spectra of EmrE in CHCl3:MeOH, DMPC vesicles, and Escherichia coli lipid vesicles

71 itration followed by reduction (Fe, NH(4)Cl, MeOH-H(2)O) gave a methyl 2-amino-4,5-dialkoxybenzoate.

72 te constant for reaction of the Cp2Ti(III)Cl-MeOH at ambient temperature was 7.5 x 10(4) M(-1) s(-1).

73 high yields (53-99%) under mild conditions (MeOH as the solvent, 80-100 degrees C, 1-24 h).

74 MeOH vapor affords [Au(im(CH(2)py)(2))(2)(Cu(MeOH))(2)](PF(6))(3) (2), which produces green luminesce

75 times of about 4.7 min for (1)H spins in [D4]MeOH are seen in this system.

76 adoxical previous observation that decreased MeOH concentration leads to increased competing intermol

77 DMF, followed by recrystallization from DMF/MeOH, yields (Et(4)N)(5)[Mo(2)(CN)(11)] x 2DMF x 2MeOH (

78 m of methylcobalamin (Me-Cbl) in a mixed DMF/MeOH solvent in 0.2 M tetrabutylammonium fluoroborate el

79 l/mol in the 40:60 and 50:50 mixtures of DMF/MeOH, respectively.

80 om 0 to -80 degrees C in 40:60 and 50:50 DMF:MeOH ratios.

81 dicated that weaker donors (THF, MeCN, DMSO, MeOH, and even H2O) likewise promote this pathway, at ra

82 ylamines (e.g., H(2)NOMe and MeHNOMe) in dry MeOH at room temperature give three different types of p

83 lly investigate the effects of simple (i.e., MeOH and EtOH) and fluorinated (i.e., trifluoroethanol,

84 ometrically rigidified by H-bonding to eight MeOH molecules and encapsulation of two benzene guests.

85 ontains a sacrificial electron donor, either MeOH or triethanolamine (TEOA), and titanium dioxide (Ti

86 re dissolved in MeOH and diluted with either MeOH (0.1% HCl) or buffers to obtain final concentration

87 HPCCC separation under use of heptane-EtOAc-MeOH-H2O mixtures in normal-phase and reverse phase mode

88 nt systems viz. toluene/EtOAC/MeOH and EtOAC/MeOH, respectively were used for optimum separation and

89 ent systems viz.toluene/EtOAC/MeOH and EtOAC/MeOH, respectively were used for optimum separation and

90 s and two solvent systems viz. toluene/EtOAC/MeOH and EtOAC/MeOH, respectively were used for optimum

91 es and two solvent systems viz.toluene/EtOAC/MeOH and EtOAC/MeOH, respectively were used for optimum

92 roactive probe, 1,1'-ferrocenedimethanol (Fc(MeOH)2), is described, and a comparison of the physical

93 roactive probe, 1,1'-ferrocenedimethanol, Fc(MeOH)2, were prepared.

94 Similar diffusion coefficients for Fc(MeOH)2 in NIPA-AA gels are obtained by either electroana

95 reliable diffusion coefficient values for Fc(MeOH)2.

96 e transition, changes of concentration of Fc(MeOH)2 are detected in a copolymeric collapsed phase.

97 Transport of Fc(MeOH)2 in both swollen and collapsed gels was studied us

98 The diffusion coefficient of Fc(MeOH)2 in collapsed gels was approximately 2 orders of m

99 d to measure the diffusion coefficient of Fc(MeOH)2 in gels under a wide range of experimental condit

100 t for 3.0% NIPA gel, the concentration of Fc(MeOH)2 in the collapsed phase was approximately 6 times

101 The uncertainty in the Fc(MeOH)2 concentration in the gels, resulting from the dis

102 utoff of less than 232 and 295 g.mol(-1) for MeOH and THF, respectively) in all membranes.

103 d from 1.7 to 11.1 L.m(-2).h(-1).bar(-1) for MeOH/PS and THF/PS, respectively.

104 cs (QM/MM) calculations, the free energy for MeOH reduction of o-PQQ when MeOH is hydrogen bonded to

105 In addition, we found MeOH/ACN/Acetone (1:1:1, v/v/v) as extraction cocktail c

106 Hydrogen-bonding from MeOH is critical for the hyponitrite complex formation a

107 te constant (kH) were measured on going from MeOH and TFE to isooctane (kH(isooctane)/kH(MeOH) = 5-12

108 echanism that invokes a proton transfer from MeOH and benzoic acid to perepoxide (2) and zwitterion (

109 Full MeOH reforming is achieved through the corresponding ste

110 DFT studies (B3LYP-D3/6-311++G**/MeOH) on cyclization mechanisms involving the 2-hydroxya

111 Use of a proton source (e.g., MeOH) is not required; accordingly, synthetically versat

112 micarceplex in polar, protic solvents (e.g., MeOH).

113 SDS samples (via direct dilution with GnHCl/MeOH solution) is necessary to ensure accurate quantitat

114 olvent, e.g., hexane > toluene > DCM > THF > MeOH > H2O, an effect also noted by emission variation i

115 ydroxide by hydrolysis of water: Me2+aq --> [MeOH]+aq + H+aq.

116 SA, in tert-butylbenzene (t-BuPh) and in H2O/MeOH afforded, with CF3COOH, k(d) 28-fold larger in H2O/

117 ed, with CF3COOH, k(d) 28-fold larger in H2O/MeOH than in t-BuPh, whereas it was only 4-fold larger w

118 ty, we developed HPLC and UHPLC methods (H2O/MeOH/MeCN/HCOOH) which we applied and validated by analy

119 se curve for caffeine, using 200-microL (H2O/MeOH) injection volumes, showed less than 5% RSD for rep

120 haracterized with low O/C < 0.5; and hexane, MeOH, ACN, and H2O solvents increase the number and type

121 where A(-) = H2PO4(-) and CF3CO2(-) and HX = MeOH, PhOH, and Me2NOH or Et2NOH) are examined by photoe

122 (MeOH/NaOH) and methanol/ammonium hydroxide (MeOH/NH4OH)].

123 traction methods [methanol/sodium hydroxide (MeOH/NaOH) and methanol/ammonium hydroxide (MeOH/NH4OH)]

124 In MeOH, lysophosphatidic acid (LPA), a biomarker for sever

125 In MeOH/MeCN, up to 28% of exo-2-norbornyl methyl ether for

126 Upon reaction of 1 with KO(2) in MeOH at -90 degrees C, an intermediate (3) is formed, wh

127 oxidation of PhSH to PhSSPh with H(2)O(2) in MeOH.

128 ct with calcium hypochlorite (Ca(OCl)(2)) in MeOH to give respectively dimer-type ketals 2-(2',4',6'-

129 When using 3 in MeOH, a change in the product formation is observed, the

130 deprotection conditions [0.05 M K(2)CO(3) in MeOH, room temperature, 24 h and MeNH(2) (approximately

131 Fragmentations of 5 and 6 in MeOH afford chlorides 3g and 4g as well as the correspon

132 eoside and its reaction with an arylamine in MeOH in the absence of added metal catalyst.

133 r increased significantly with 1 and BrCl in MeOH, but MeOH had little affect on the other reactions.

134 le beta-formyl ester 21, whereas cleavage in MeOH followed by reduction with thiourea led to hemiacet

135 Ph2P-(C6H4) (2-F) with a binding constant in MeOH exceeding that of 1-Mes2B-4-MePh2P-(C6H4) ([1]+) by

136 Pigments were dissolved in MeOH and diluted with either MeOH (0.1% HCl) or buffers

137 peared better in samples reduced with DTT in MeOH.

138 he crude diacids were directly esterified in MeOH-HCl to afford the diesters.

139 W), time (5-15min), solvent (10-90% EtOAc in MeOH) and solvent-to-sample ratio (10:1 to 20:1).

140 meters such as solvent composition (EtOAc in MeOH), extraction temperature, pressure, flushing, stati

141 thyl derivatives by treatment with NH(4)F in MeOH.

142 ng D-aldopentoses by reaction with NH3(g) in MeOH solvent, isolated in solid form, and characterized

143 wing the Ugi reaction, treatment with HCl in MeOH achieves deprotection of the isopropylidene group a

144 Treatment of compound 34 with HCl in MeOH effected spiro-lactal formation and provided (+/-)-

145 of NEM compared with samples homogenized in MeOH containing NEM.

146 Thermal isomerization of the latter in MeOH occurred via a four-centered activated complex, and

147 guanidine to a 6-methylhexahydroindenone in MeOH at 85 degrees C afforded 7-epineoptilocaulin.

148 ubsequent dihydroxylation, using OsO4/NMO in MeOH conditions, resulted in an exceedingly diastereo- a

149 ced dioxetane concentrations are observed in MeOH and in nonprotic solvents with acid.

150 techol moieties, and inverse second order in MeOH concentration.

151 s undergo cyclization to 2-oxazolidinones in MeOH.

152 In the first step, anodic oxidation in MeOH using a repurposed power source provides a convenie

153 SO2, CF3SO2) react with hydrogen peroxide in MeOH, THF, MeCN or AcOH to form the corresponding C-N co

154 c) = 1.9 h, rt), and with a moderate rate in MeOH (t1/2(rac) = 30.5 h, rt).

155 sogeny Broth medium samples reconstituted in MeOH/H2O ratios ranging from 0 to 100% MeOH and analyzed

156 NPs suspended in MeOH under constant illumination produce valence-band ho

157 Toward 3,6-diphenyl-s-tetrazine in MeOH at 25 degrees C, the strained derivative is 160 tim

158 Toward 3,6-dipyridyl-s-tetrazine in MeOH at 25 degrees C, the strained derivative is 19 and

159 f M(2+), TPyA, H(2)DBQ, and triethylamine in MeOH solution.

160 4)(2).6H2O, TPyA, H2CA, and triethylamine in MeOH solution.

161 asic than a-PhobPH by about 2 pK(a) units in MeOH.

162 malononitriles 13 in 84-92% yields, while in MeOH the (Z)-2-[2-phenyl-4-(arylimino)-1H-imidazol-5(4H)

163 nding thiophenes 6 in good to high yields in MeOH as the solvent at 50-100 degrees C in the presence

164 MeOH and TFE to isooctane (kH(isooctane)/kH(MeOH) = 5-12; kH(isooctane)/kH(TFE) > 80).

165 iables quantity of sample (g), volume of KOH/MeOH (mL) and ultrasound time (s) were investigated in t

166 xime or 2-hydroxybenzaldeyhyde oxime and L = MeOH, EtOH) via the use of derivatized oxime ligands and

167 icities of [Rh2(micro-O2CCH3)2(eta1-O2CCH3)L(MeOH)]+ (L=dppz, 7; L=dppn, 8) relative to [Rh2(micro-O2

168 l sites of Ni(II) to give the complex [Ni(L)(MeOH)(2)] in which a Ni(II) center is bound in an octahe

169 n be achieved using weak proton sources like MeOH and PhOH, the facile heterolytic cleavage of the C-

170 Reaction of 1 with either liquid MeOH or MeOH vapor affords [Au(im(CH(2)py)(2))(2)(Cu(MeO

171 Maximum yield was obtained at ca.0.2 M MeOH.

172 sensitivity and shorter gradient times make MeOH an excellent organic modifier for the use in nanoLC

173 Deacetylation of 4b and 4e with MeONa/MeOH gave beta-glucuronides 5b and 5e.

174 phenolic compounds with O/C > 0.5; methanol (MeOH) has higher selectivity toward compounds characteri

175 ir spectral behaviors in acidified methanol (MeOH) and buffers pH 1-9.

176 TBP), in buffer solvent with added methanol (MeOH), 2-propanol (2-PrOH), and dimethyl sulfoxide (DMSO

177 reductively couples NO(g) at RT in methanol (MeOH), giving a structurally characterized hyponitrito-d

178 tion was evaluated on the basis of methanol (MeOH) and tetrahydrofuran (THF) permeances and rejection

179 rt, we demonstrate that the use of methanol (MeOH) as the organic modifier improves the detection lim

180 obile phases, aqueous solutions of methanol (MeOH/H(2)O = 40/60 and 30/70, v/v) and aqueous solutions

181 Mg/MeOH is significantly more reactive than Me(2)S or PPh(3

182 nyl, UO2Ac(H2O)n(MeOH)m(+), and UO2Ac2(H2O)n(MeOH)(m)H(+) (n = 1, 2, 3,...; m = 1, 2, 3,...).

183 : inorganic (nonligated) uranyl, UO2Ac(H2O)n(MeOH)m(+), and UO2Ac2(H2O)n(MeOH)(m)H(+) (n = 1, 2, 3,..

184 ion, and a unique ester reduction with NaBH4-MeOH catalyzed by NaB(OAc)3H that not only achieves exce

185 o form 100% of the 9-cation, then with NaOMe-MeOH, provided 29% of re-formed substrate (configuration

186 cycloadducts has been demonstrated by an NBS-MeOH mediated stereospecific efficient access to fully s

187 3 via a Dimroth rearrangement in either neat MeOH or in DCM with DBU.

188 its porfiromycin activation and nucleophile (MeOH, DNA) adduction.

189 itation with an appropriate solvent (Et(2)O, MeOH, or EtOAc), followed by filtration through a SPE pr

190 2-electron transfer and extrusion of H(2)O, MeOH, or MeOMe to give [Os(II)-N(2)].

191 ic acid-base titrations carried out in H(2)O/MeOH (9:1 vol.) afford pK(R+) values of 7.3(+/-0.07) for

192 ion, fluoride titration experiments in H(2)O/MeOH (9:1 vol.) show that the fluoride binding constants

193 )(2) reacted in DMF, followed by addition of MeOH and H(2)O, respectively.

194 pathway depends on the alcohol: addition of MeOH induces a transition to a superhelical structure th

195 ing in peak area response by the addition of MeOH to H2O, 5%, is outweighed by the fraction of compou

196 ta-sulfido carbonyl compounds by addition of MeOH.

197 ial unfolding; however, further additions of MeOH result in the formation of a non-native beta-struct

198 s pulled such that the overall conversion of MeOH to CH(2)(OH)(2) is exothermic.

199 ulting 2-arylchromen-2-ols in a cosolvent of MeOH and THF at rt for 1 h.

200 a clear impact on the metabolome coverage of MeOH extracted biological samples, highlighting the impo

201 lato)diboron [B(2)(pin)(2)] and 1.1 equiv of MeOH at -50 to -15 degrees C in 3-24 h.

202 data is proposed in which one equivalent of MeOH activates the epoxide electrophile via a hydrogen b

203 a hydrogen bond while a second equivalent of MeOH chelates the side-chain nucleophile and glycal ring

204 ratios as a function of the mole fraction of MeOH in dichloroethane showed that the homoadamantyl chl

205 f 2 to atmosphere produces a partial loss of MeOH accompanied by a luminescence color change to yello

206 The uptake and loss of MeOH vapor is rapid and reversible.

207 sure of 2 to vacuum affords complete loss of MeOH, and the luminescence changes to yellow-orange (lam

208 roduce, in combined high yield, a mixture of MeOH, C2H6, and MeOOH along with water-soluble n-Pr4N[(d

209 In a mixture of MeOH/CHCl3, the domino cyclization of 1 further affords

210 compound, with a relative nucleophilicity of MeOH to H2O of 11.

211 PEC nature and are due to photooxidation of MeOH by the NPs at the electrode surface.

212 We use photooxidation of MeOH by TiO2 NPs as a model system of photocatalysis in

213 ally demanding achiral NHCs, the presence of MeOH is required for high efficiency.

214 ethylbenzene) with SmI(2) in the presence of MeOH or TFE was studied.

215 yclic carbene (NHC) complex; the presence of MeOH promotes in situ protonation of the C-Cu bond and l

216 by reaction of 2 with KF in the presence of MeOH.

217 gate the topic of the ruthenium promotion of MeOH electro-oxidation over nanoscale platinum catalysts

218 of the benzoyl group (using 10 vol % NH(4)OH/MeOH) provided the N(alpha)-Fmoc-N-(hydroxy)-L-leucinami

219 zation reaction is second-order dependent on MeOH, and the glycal ring oxygen is required for second-

220 de reaction is only first-order dependent on MeOH.

221 Previous work from our laboratory optimized MeOH-inducible expression of the P. falciparum malarial

222 in disulfides suspended in NaPO(4) buffer or MeOH was assessed, and no differences in total normalize

223 Reaction of 1 with either liquid MeOH or MeOH vapor affords [Au(im(CH(2)py)(2))(2)(Cu(MeOH))(2)](

224 conventional techniques (e.g., using TMS or MeOH/benzene dual referencing) is demonstrated to be imp

225 cal ring oxygen is required for second-order MeOH catalysis.

226 n the electrode is able to decompose/oxidize MeOH to form (adsorbed) methoxy groups that can further

227 tion produce valence-band holes that oxidize MeOH.

228 from a C18 column by a binary mobile phase (MeOH:H2O = 1:1, v/v).

229 n be converted into 5 with CuBr(2) in i-PrOH/MeOH/H(2)O.

230 In 10% MeOH/H(2)O at pH 1 or 11 or in pure MeOH, assembly is driven exclusively by the TPP ring, le

231 The retention order of PY-MeOH, PY-BuOH, and PY in CEC is determined by their inte

232 ibution of pyrene (PY), 1-pyrenemethanol (PY-MeOH), and 1-pyrenebutanol (PY-BuOH) into the C18 statio

233 e related reduced iron complex, [Fe(II)(PY5)(MeOH)](2+).

234 (2) and the ferrous end-product [Fe(II)(PY5)(MeOH)](OTf)(2) estimates the strength of the O-H bond in

235 )O}(n) (1-SS) and {[Co(II)((R,R)-iPr-Pybox) (MeOH)](3)[W(V)(CN)(8)](2).5.5MeOH.0.5H(2)O}(n) (1-RR).

236 no-bridged chains, {[Co(II)((S,S)-iPr-Pybox)(MeOH)](3)[W(V)(CN)(8)](2).5.5MeOH.0.5H(2)O}(n) (1-SS) an

237 Br and Cl), R = CNH+ (with X = Cl), and R = MeOH+ (with X = Br), the corresponding beta-aryl-alpha-h

238 , Zn2+, Mn2+, Cu2+, Ag+; A = NO3-, OAc-; S = MeOH, H2O; a = 0, 1, 2; b = 0, 1, 2, 4; and c = 0, 2.

239 The (PPN){[Mn(III)(salphen)(MeOH)]2[Co(III)(CN)6]}.7MeOH (Mn2Co.7MeOH) analogue with

240 and the mixed Co/Os (PPN){[Mn(III)(salphen)(MeOH)]2[Co(III)0.92Os(III)0.08(CN)6]}.7MeOH (Mn2Co/Os.7M

241 metal Co/Os analogue (PPN){[Mn(III)(salphen)(MeOH)]2[Co(III)0.92Os(III)0.08(CN)6]}.7MeOH were underta

242 r new complex salts, (PPN){[Mn(III)(salphen)(MeOH)]2[M(III)(CN)6]}.7MeOH (Mn2M.7MeOH) (M = Fe, Ru, Os

243 The pristine (PPN){[Mn(salphen)(MeOH)]2[Os(CN)6]}.7MeOH (Mn2Os.7MeOH) behaves as an SMM

244 r of a pyridine ring and the H-O of a second MeOH molecule.

245 sily removed by treatment with MeMgBr or TFA/MeOH, which affords the NH-aziridines in good yield.

246 gen bonded to Asp-297-CO(2)(-), we find that MeOH returns to be hydrogen bonded to Glu-171-CO(2)(-) a

247 However, dopants became unnecessary for the MeOH mobile phase when the Ar lamp was used.

248 We further integrated the MeOH/ACN/Acetone extraction with the HILIC-FTMS method f

249 erall identified 33% fewer proteins than the MeOH-based procedure.

250 While the MeOH/NaOH solvent yielded more efficient recovery rates

251 nd quaternary ammonium was improved with the MeOH/NaOH based method.

252 CN to solution and solid-phase esters in THF/MeOH/50% aqueous NH2OH increases the efficiency of their

253 Kinetic measurements in 9:1 THF:MeOH at 25 degrees C indicate that 3 is formed near the

254 D) showed that the ZnCar framework adapts to MeOH and H2 O guests because of the torsional flexibilit

255 ounterion, produces the free NHC H-bonded to MeOH with a weakly associated CO2.

256 ders of magnitude on going from isooctane to MeOH.

257 ts with different polarities (i.e., toluene, MeOH, DMF, and DMSO).

258 basis of unpublished trapping studies using MeOH.

259 imated to be approximately 10(13) in 60% v/v MeOH/water at 0.1 M ionic strength.

260 The calculated DeltaG++ when MeOH is hydrogen bonded to Asp-297-CO(2)(-) is >50 kcal/

261 free energy for MeOH reduction of o-PQQ when MeOH is hydrogen bonded to Glu-171-CO(2)(-) and the crys

262 ts did enhance Kr lamp APPI sensitivity when MeOH was used as the mobile phase.

263 20 and 21 resulting from trapping of 13 with MeOH.

264 Reaction of 6 with MeOH yielded 9,9'-digerma-9,9'-bifluorene (7).

265 f a few hundred attomoles were achieved with MeOH; those levels could not be achieved with ACN.

266 and for acceptorless coupling of amines with MeOH and EtOH affording formamides and acetamides.

267 an octahedral coordination environment with MeOH ligands occupying the axial sites.

268 ion of 1 in solution, although exchange with MeOH was shown to be slow by an EXSY study.

269 NH2/MeCN), F > Cl approximately Br > I (with MeOH/1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)/MeCN), and

270 success rate of protein identification with MeOH-based nanoLC-ESI-MS/MS was 100%, with multiple prot

271 D+ catalyzed by CD38 increases linearly with MeOH concentration.

272 shown that all aldoxime ethers reacted with MeOH by clean second-order kinetics with rate constants

273 possible for chromatographic separation with MeOH versus ACN.

274 e (12) by selective transesterification with MeOH saturated with dry HCl gas.

275 s spectrometry, and 13 has been trapped with MeOH to afford methyl 1,3-cyclopentadiene-1- and -2-carb

276 ed and reused multiple times by washing with MeOH.