ライフサイエンスコーパス: gas phase

1 ured human lung A549 cells directly from the gas phase.

2 nt for delivering membrane proteins into the gas phase.

3 stinct from the underlying bulk or overlying gas phase.

4 reactions that ultimately yield HOMs in the gas phase.

5 g peptide containing up to five units in the gas phase.

6 s are energetically nearly degenerate in the gas phase.

7 ions released from the target protein in the gas phase.

8 iranium ion 5 and cycloalkenes occurs in the gas phase.

9 arged negative ions are seldom stable in the gas phase.

10 order of magnitude lower in MeCN than in the gas phase.

11 m from solution studies, but a few also from gas phase.

12 ional chemicals either in solution or in the gas phase.

13 cts directly with water to form H2SO3 in the gas phase.

14 in the solid state, in solution, and in the gas phase.

15 hat McjD in complex with MccJ25 survives the gas phase.

16 about the shape of an ionic molecule in the gas phase.

17 how this alters with increasing time in the gas phase.

18 presence of heterometallic fragments in the gas phase.

19 ntaining a tetraazamacrocyclic ligand in the gas phase.

20 occur upon charge reduction reactions in the gas phase.

21 ich are detected as single conformers in the gas phase.

22 s carefully transferred from solution to the gas phase.

23 d with octadecyldimethylmethoxysilane in the gas phase.

24 lopentamerization to form naphthalene in the gas phase.

25 l adsorption of heavy isotopologues from the gas phase.

26 to the pentameric self-assembly, even in the gas phase.

27 d for the detection of hydrazine even in the gas phase.

28 sistent loss or accumulation of (222)Rn in a gas phase.

29 zed diamondoids is shown to fluoresce in the gas phase.

30 in trap adducts with alpha-pinene CIs in the gas phase.

31 o oligomeric species both in solution and in gas phase.

32 gas-phase analogs or not even stable in the gas phase.

33 onse when compared to water molecules in the gas phase.

34 fter transfer from the solution phase to the gas phase?

35 complexes are collisionally activated in the gas phase, a larger proportion of the product ions produ

36 e that enables the separation of ions in the gas phase according to their charge, shape and size.

37 Herein, the gas phase acidities have been measured and calculated fo

38 We find correlations between the gas phase acidity and selectivity in two Umpolung reacti

39 Emission factors for these gas-phase acids varied from 0.3-8.4 mg kg(-1) fuel.

40 tion structures are largely preserved in the gas phase, although the lipids do not maintain regular b

41 either higher in energy than the most stable gas-phase analogs or not even stable in the gas phase.

42 Gas phase analyses revealed that two were complete denit

43 e gas phase and, in some cases, trapping the gas-phase analytes into sorbents or containers.

44 latile ring-opened species are formed in the gas phase and assist particle formation through condensa

45 ynamics (BOMD) simulation shows that, in the gas phase and at a temperature of 300 K, the dominant in

46 ed species are in quasi-equilibrium with the gas phase and can be used in an approximate manner to pr

47 takes place through a concerted mechanism in gas phase and in apolar solvents but a stepwise mechanis

48 ociation of proton-bound dimers, both in the gas phase and in dichloromethane solution, showing that

49 Computational analysis performed in the gas phase and in MeCN solution shows that the free energ

50 end of predominance of Phax conformer in the gas phase and of Pheq in solution.

51 S=O and O=C=N-S=O, has been generated in the gas phase and subsequently characterized in cryogenic ma

52 ducts with alpha-pinene CIs also form in the gas phase and that they are stable enough to be detected

53 raction of a SO2 with water molecules in the gas phase and with the surface of various sized water na

54 lies only on noninvasive measurements of the gas phase and, given its simplicity, indicates the poten

55 g the samples to release the analytes to the gas phase and, in some cases, trapping the gas-phase ana

56 s at the surface of fuel droplet, liquid and gas phases and then show how experimental observations f

57 4.0, a photochemical box model that couples gas-phase and aqueous-phase aerosol chemistry, along wit

58 chanistic point of view, with the support of gas-phase and computational studies.

59 and reaction intermediates were observed by gas-phase and electrospray ionization mass spectrometry,

60 rplay among electrolyte, solid catalyst, and gas-phase and liquid-phase reactants and products.

61 EID allowed for the comparison of the gas-phase and the solution-phase structural stability an

62 ism for multidomain protein unfolding in the gas phase, and highlights key similarities and differenc

63 ge states of denatured ubiquitin ions in the gas phase, and ion mobility to probe their structures.

64 gh-valent compound could be generated in the gas phase, and its reactivity against olefins, sulfides,

65 the pH, the concentration of mercury in the gas phase, and the enhancement of mercury in the slurry

66 oping analytical methods for both liquid and gas phases, and integrating different units to quantitat

67 s regarding the unfolding of albumins in the gas phase, as well as more general inferences regarding

68 pectroscopic evidence for H-tunneling in the gas phase at temperatures around 320-350 K observed in t

69 ) as well as mustard (HD) in both liquid and gas phases at ambient temperature and in the absence of

70 ere formed by the CPA oxidation by OH in the gas-phase, at the air-water interface as well as in the

71 0) surface, including studies of the role of gas-phase atomic hydrogen, surface hydrogen, and subsurf

72 Gas-phase autoxidation-regenerative peroxy radical forma

73 rometry (IM-MS), which separates ions in the gas phase based on their size, charge and shape, offers

74 structures that is supported by experimental gas-phase basicities.

75 aper presents an analysis of the exceptional gas-phase basicity, mostly in terms of experimental data

76 However, they are rarely stable in the gas phase because of strong electrostatic repulsion betw

77 Further, the relationship between gas-phase behavior, lipid composition, and instrumental

78 eties of FBDSA and basic sites to facilitate gas-phase bioconjugation and to reduce charge sequestrat

79 In the gas phase, both the CH...O and OH...O hydrogen bonds are

80 ine changes in both individual molecules and gas-phase bulk properties of oxidation products as a fun

81 lifetimes at near-ambient temperature in the gas phase but that gas-phase dynamics should be consider

82 treated with reactive metal reagents in the gas phase by ALD to form an outer metal ion bridging gro

83 ain interface protect the native fold in the gas phase by mediating contacts between the mobile prote

84 stable GTP analogue) were transferred to the gas phase by nano-electrospray ionization and characteri

85 single-crystal X-ray diffraction, and in the gas phase by quantum-chemical calculations.

86 relevant Criegee intermediates (CIs) in the gas phase by stabilization with spin traps and analysis

87 hat govern complex formation in solution and gas phases by comparing nonselective lipid binding with

88 Investigations of proteins in the gas phase can be used to selectively decouple factors af

89 Gas-phase carboxylic acids are ubiquitous in ambient air

90 To fill this gap, we measured gas-phase carboxylic acids in real-time inside and outsi

91 This is well known in heterogeneous gas-phase catalysis but much less discussed for electroc

92 the basis of the empirical difference in the gas-phase CCS and a CCS-based resolving power definition

93 which involved the use of ethanol as a polar gas-phase chemical modifier.

94 high-NOx conditions was caused by changes in gas-phase chemistry that led to the formation of organon

95 sed in higher-scale models, which only treat gas-phase chemistry.

96 ion catalyst achieved using high-temperature gas-phase chlorine and hydrogen treatments.

97 th approximately 20% of its mass detected as gas-phase CO2, CO, and H2O.

98 somer identification by measurement of their gas phase collision cross sections (CCSs).

99 h ion assemblies that have undergone minimal gas-phase collisional "clean-up" to retain native-like s

100 This is done thanks to a "gas-phase collisional purification" inside an ion trap m

101 f water, solar wind-surface interactions and gas-phase collisions.

102 tical standard free energies of formation in gas phase combined with quantum chemical estimates of He

103 these sensing materials for broad classes of gas-phase compounds such as condensable vapors and non-c

104 An estimation of the OPE gas phase concentration and gross absorption fluxes by u

105 pace, has thus far only been observed at low gas phase concentrations or in inert gas matrices.

106 es but are also observed to have substantial gas-phase concentrations contrary to many models that tr

107 wing frequency response performed at varying gas-phase concentrations gives diffusion coefficients th

108 This is the first gas-phase confirmation that the markedly elongated C-C b

109 Here the gas phase conformational space of drug and drug-like mol

110 play quite different physical properties and gas-phase conformations from lipids, which could lead to

111 llowing electrospray into kinetically stable gas-phase conformations).

112 n inert vaporization surface speeding up the gas-phase conversion of large molecules while lessening

113 etics steps and an activation energy for the gas-phase cycloaddition of two hexafluoropropene molecul

114 to assign each unfolded form observed in our gas-phase data set to the disruption of specific domains

115 vity over lyophilized enzyme powders for the gas-phase dehalogenation of 1-bromopropane.

116 supports the idea that interactions between gas-phase DEHP and soiled surfaces have been reduced to

117 nd Ag9 Pt3 clusters are size-selected in the gas phase, deposited on an ultrathin amorphous alumina s

118 a C horizontal lineC in FAs and a subsequent gas-phase detagging via tandem (neutral loss scan) mass

119 ize the significance of packing effects; the gas-phase dimer structure at the same level shows a 1.63

120 uridine-specific chemical derivatization and gas phase dissociation of RNA during liquid chromatograp

121 ric fragment ions, in turn shedding light on gas-phase dissociation mechanisms of glycosidic linkages

122 The complex mass spectra that result from gas-phase dissociation were assigned using a Bayesian de

123 ons generated by electrospray ionization and gas-phase dissociation.

124 Here we show that gas phase DMS concentrations (DMSgas) increased by an or

125 significant influence over structures in the gas phase due to strong Coulombic and hydrogen-bonding i

126 mbient temperature in the gas phase but that gas-phase dynamics should be considered when interpretin

127 A nanowire bonding process referred to as gas-phase electrodeposition is reported to form nanobrid

128 ding single-crystal X-ray diffraction (XRD), gas-phase electron diffraction (GED), a combined GED/mic

129 A historical challenge: Gas-phase electron diffraction and single-crystal X-ray

130 The gas-phase electron diffraction parameters are in good ag

131 Si(Ph,X) (X = F (3), Cl (4)) were studied by gas-phase electron diffraction, low-temperature NMR spec

132 IMS is a gas-phase electrophoretic technique that enables the sep

133 onsiderable uncertainty in how anthropogenic gas phase emissions alter the oxidative aging of organic

134 ors and the detailed chemical composition of gas phase emissions from a broad variety of cooking styl

135 organic aerosol production potential of the gas-phase emissions was determined by smog chamber aging

136 The interaction of gas phase endohedral fullerene Ho3N@C80 with intense (0.

137 ology, medicine, nutrition, and in industry, gas phase enthalpies of formation of many long chain sat

138 ering and Raman spectroscopy in a controlled gas-phase environment.

139 The fast release of the gas-phase extract gives rise to a high signal recorded b

140 d to liberate the sampled materials into the gas phase for atmospheric pressure chemical ionization a

141 es of approximately 95% were measured in the gas phase for oxygen evolution in alkaline media at an I

142 ovitamin A, vitamin E, and vitamin K1 in the gas phase for the first time.

143 entified 27 different reaction routes in the gas phase, forming a complex interlinked reaction networ

144 sine or cysteine residues, identification of gas-phase fragmentation patterns of endogenous dityrosin

145 The potential of copper(II) to induce gas-phase fragmentation reactions in macrotetrolides, a

146 anomeric configuration is retained following gas-phase glycosidic bond fragmentation during tandem ma

147 In studies of gas-phase H atoms impinging on a CO-adsorbed Ni(110) sur

148 beyond the atomic limit of the corresponding gas-phase harmonics measured under similar conditions.

149 nic acid (HMSA) in particle formation in the gas phase has been extensively studied, the details of t

150 ry (bimolecular) polyatomic reactions in the gas-phase have occurred.

151 states of matter (for instance solid/liquid/gas phases) have different symmetries, the phase transit

152 ion has shown potential to contribute to the gas-phase HONO levels during the morning, which accounts

153 C, and these species are useful for various gas-phase hydrocarbon reactions, including the selective

154 terestingly, the particle formation from the gas-phase hydrogen-bonded complexes of HMSA with (R1)(R2

155 n proof-of-principle experiments, the use of gas-phase hydrogen/deuterium exchange (HDX) combined wit

156 ety of protonated carbohydrate structures by gas-phase hydrogen/deuterium exchange (HDX) to discover

157 Propylene oxide is detected in the gas phase in a cold, extended molecular shell around the

158 ulfinylnitrene CF3S(O)N was generated in the gas phase in its singlet ground state and was characteri

159 unds (ELVOCs) that have been detected in the gas phase in previous studies and linked to SOA particle

160 ides by analyzing the N-H stretching mode in gas phase infrared (IR) spectroscopy, and then observing

161 Other powerful techniques such as gas-phase infrared (IR) spectroscopy have been limited t

162 ture and purity of which were verified using gas-phase infrared spectroscopy coupled to mass spectrom

163 mobility spectrometry-mass spectrometry and gas-phase infrared spectroscopy.

164 ing, we illustrate the capacity of selective gas-phase interactions using neutral gas vapors to yield

165 how that the unfolding of the protein in the gas phase involves the disruption of inter-domain contac

166 s vapors to yield an additional dimension of gas-phase ion mobility separation.

167 ional selectivity provided by a postsampling gas-phase ion mobility separation.

168 report an approach for spatial and temporal gas-phase ion population manipulation, wherein we collap

169 pectroscopy coupled to mass spectrometry and gas-phase ion-mobility measurements.

170 Gas-phase ion/ion reactions of (13)C-TrEnDi-modified pho

171 zation (ESI) allows the production of intact gas-phase ions from proteins in solution.

172 V spectroscopy of cold ( approximately 10 K) gas-phase ions, we probe the inherent conformational pre

173 w-in contrast-several advantages compared to gas phase IRMS.

174 ructural characterization of proteins in the gas phase is becoming increasingly popular, highlighting

175 drug molecules and their metabolites in the gas phase is poorly understood.

176 rpentinization environments where a separate gas phase is present may be more favorable for abiotic s

177 n isolated and cold molecular complex in the gas-phase is a fundamental measure of the strength of th

178 using a multicollector magnetic sector field gas-phase isotope ratio mass spectrometer.

179 and (La0.8 Sr0.2 )0.95 MnO3+/-delta , using gas-phase isotope-exchange with a 1:1 (16) O2 :(18) O2 r

180 spectrometry provides ion separation in the gas phase mainly based on differing ion-neutral collisio

181 Comparison of solution and gas phase measurements on a doubly tagged tripeptide sho

182 Despite the growing application of gas-phase measurements in structural biology and drug di

183 we use ab initio methods to investigate the gas-phase mechanisms governing the reactions of amines,

184 ferent dependence from the well-known one in gas-phase media is observed.

185 nd unique control of the emission, absent in gas-phase media.

186 xidative intramolecular electron transfer in gas-phase metal complexes.

187 are synthesized as films on substrates using gas-phase methods at high temperatures.

188 This implies that gas-phase methods such as polarization gating for attose

189 ayers with respect to the composition of the gas-phase mixtures: a kinetic effect dominant during the

190 on of ultrafast 2D terahertz spectroscopy of gas-phase molecular rotors at room temperature.

191 o otherwise identical enantiomers of a large gas-phase molecule using resonant microwave fields are h

192 te combustion (associated with less oxidized gas-phase molecules) correlated to higher primary organi

193 In the gas phase, most of the so-called push-pull nitrogen base

194 n NMR data and help in the assignment of the gas-phase MW data to individual diastereomers.

195 Moreover, a strong correlation between the gas-phase NHC-CO2 bond distance and the Gibbs free energ

196 Molecular interactions of gas-phase nonylphenols (NPs) with the surfaces of two co

197 e form of nanoparticles should be related to gas-phase nucleation procedure.

198 incorporated a substantial fraction (70%) of gas-phase O2 More oxygenated products were formed than t

199 We evaluated how gas-phase O3 interacts with residual petroleum hydrocarb

200 etailed reaction mechanisms and kinetics for gas-phase O3, NO3, and OH when they impinge on organic s

201 Purification in gas phase of PLA mixtures was established based on SY cu

202 of high harmonic generation in the solid and gas phases of argon and krypton.

203 s grow past it by direct condensation of the gas phase on their surface, driving liquid evaporation,

204 In the gas phase only three (3) and two (4) stable conformers d

205 In the gas phase, only 10% of the reactive trajectories undergo

206 This is one of the few basepairs whose gas-phase-optimized isolated geometry is inconsistent wi

207 been spectroscopically characterized in the gas phase or in matrices at very low temperatures.

208 o underestimates of both organic aerosol and gas-phase organic acids.

209 Exploring, exposing, and exploiting gas-phase organic chemistry at temperatures of 1000 degr

210 is formed from the atmospheric oxidation of gas-phase organic compounds leading to the formation of

211 ming an evaluation of a comprehensive set of gas-phase organic compounds present in gasoline motor ve

212 They emit complex mixtures of gas-phase organic compounds that vary in volatility and

213 Partitioning of gas-phase organic compounds to the walls of Teflon envir

214 nic radicals have played a central role in a gas-phase organosynthesis.

215 The selective gas-phase oxidation of disulfide bonds to their thiosulf

216 b) occur on similar time scales as analogous gas-phase oxidation reactions.

217 scopy to quantify SOx and NOx emissions from gas-phase oxy-combustion systems.

218 istry, the surface reaction of squalene with gas-phase ozone has been investigated.

219 ation of mainly secondary CI, in contrast to gas-phase ozonolysis mechanisms.

220 egee intermediates (CIs), mainly formed from gas-phase ozonolysis of alkenes, are considered as atmos

221 action products and kinetics differ from the gas-phase ozonolysis of alpha-terpineol.

222 Gas phase particle formation mechanisms and the effect o

223 have been shown to function as an effective gas-phase photocatalyst for the reduction of CO2 to CO v

224 Ozonolysis of the gas phase photochemical products in the dark or under co

225 of forming methylcyanoacetylene and MeC5N by gas-phase photolysis was evaluated from relevant acetyle

226 A one-step, gas-phase photothermocatalytic process for the synthesis

227 erry juice was subjected to cold atmospheric gas phase plasma and changes in hydroxycinnamic acids, f

228 m of the study was to evaluate the effect of gas phase plasma on phenolic compounds in pomegranate ju

229 re is no statistical difference of regulated gas-phase pollutant emissions between PFIs and GDIs.

230 tyrene (BTEXS) because of their toxicity and gas-phase prevalence, where exposure is typically by inh

231 that self-quenching is a sensitive and fast gas-phase probe of biomolecular structure that can be di

232 um interfacial phenomena and the equilibrium gas phase processes, respectively.

233 ex in either the electrospray droplet or the gas phase produced c-type fragment ions.

234 O2, a mixture of CO and H2 was produced as a gas-phase product (syngas).

235 The relative molar ratio of the produced gas-phase product was controllable by the reduction temp

236 We have investigated the gas-phase production of isoquinoline by performing colli

237 produces a very fast burst of low-volatility gas-phase products, which are competitively taken up by

238 rometry (DART-MS), and transmission FTIR for gas-phase products.

239 e strength of dispersive interactions in the gas phase properly, the importance of inter- and intramo

240 ltaneous detection of these molecules in the gas phase provides direct evidence for their gas-to-part

241 tionalisation with two different approaches, gas phase radical grafting and liquid phase reductive gr

242 polycyclic aromatic hydrocarbons (PAHs) via gas phase radical mediated aromatization reactions.

243 ion activation technology that exploits the gas-phase reaction between mass-selected ions and ozone

244 ry base) is known to drive the reaction, the gas-phase reaction follows the "mobile proton model" to

245 he complex [Ru(tpy)(bpy)(O2)](2+), formed by gas-phase reaction of [Ru(tpy)(bpy)](2+) with molecular

246 H2 )Si) isomers, was initially formed in the gas-phase reaction of ground-state atomic silicon (Si) w

247 for the very first time via the bimolecular gas-phase reaction of ground-state carbon atoms with 1,3

248 The rate coefficients for gas-phase reaction of trifluoroacetic acid (TFA) with tw

249 phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(*)).

250 Gas phase reactions between PtHn (-) cluster anions and

251 of predictions derived from computations on gas-phase reactivity of carbocations.

252 In this paper, the gas-phase reactivity of HFC-1447fz with OH radicals is p

253 Gas-phase reactivity of protonated model compounds with

254 the solution state or post-ionization in the gas phase, respectively.

255 tein oligomers ejected from nanodiscs in the gas phase retain large numbers of lipid interactions.

256 ty of defected indium oxide surfaces for the gas-phase reverse water gas shift reaction, CO2 + H2 + h

257 Partitioning into the gas phase seems to be determined by an octanol-air parti

258 Ion mobility spectrometry (IMS) is a gas phase separation technique, which relies on differen

259 dissociation, we demonstrate rapid baseline gas-phase separation and identification of tails involvi

260 With this combined gas-phase separation and subsequent fragmentation, we co

261 Ion mobility (IM) is a gas-phase separation technique that is used to determine

262 ltrasound (US), undergo an ensuing liquid-to-gas phase shift and transiently deposit 20-30mum large b

263 Gas-phase single-conformation spectroscopy is used to st

264 rier were determined computationally for the gas-phase SN2 reaction between the acetaldehyde enolate

265 onversion of the dominant interaction in the gas phase (SO2)S...O(H2O) to the dominant interaction on

266 tives to be promising precursors for further gas-phase spectroscopic studies of phosphinidenes; in pa

267 the utility of this technique for analytical gas phase spectroscopy.

268 Cr(H2O)4Cl2](+), difficult to be observed by gas-phase spectroscopy, are detected easily with carbon

269 The known gas-phase spectrum, including its vibronic structure, is

270 ht mass spectrometer was used to examine the gas-phase structures of a set of glycopeptides resulting

271 Their solid-state and gas-phase structures were studied using a multitechnique

272 These observations, however, are made on gas-phase structures.

273 The solid-state and gas-phase studies of the icosahedral Sb@M12@Sb20(n-/n+)

274 study reports a modified hydrogen-assisted, gas-phase synthesis for facile, scalable production of s

275 Our approach provides a clean gas-phase synthesis of this hitherto elusive cyclic radi

276 ly on collision with a third molecule in the gas-phase systems of combustion and planetary atmosphere

277 es high-temperature thermal reactions in the gas phase that are generally difficult to achieve in sol

278 Both in the solid state and the gas phase the central C-C bond is of similar length for

279 Compared with the gas phase, the enzyme lowers the Diels-Alder barrier sig

280 olecular oxygen under mild conditions in the gas phase, the process is either stoichiometric (and the

281 When compared to the gas phase, the trans to cis isomerization of glyoxal at

282 adium, PtC3 and PdC3 , were generated in the gas phase through laser vaporization of a metal target i

283 ne cross-section at this wavelength based on gas phase titration (GPT) measurements.

284 ination with limited charge reduction in the gas phase to obtain meaningful information on noncovalen

285 gen bond dissociation free energy from 99.5 (gas phase) to an experimentally measured value of 45.8 k

286 sities, heliotropic COD growth, solid-liquid-gas phase transformations, strong longitudinal phonon co

287 opposed to the distinct transitions through gas-phase unfolding intermediates observed of K6-, K11-,

288 have elucidated the reaction pathways in the gas phase using tandem mass spectrometry.

289 inker that can be selectively cleaved in the gas phase using two differential tandem mass-spectrometr

290 cm(-1) red-shifted with respect to unbiased gas-phase values.

291 The stability of the XB capsules in the gas phase was confirmed by electrospray ionization mass

292 vidin, transthyretin, and hemoglobin) in the gas phase was undertaken by 193 nm ultraviolet photodiss

293 zwitterionic pairs are rarely stable in the gas phase, we now demonstrate that charge-separated stat

294 methyl-benzene (m-C8H8I2) produces m-C8H8 in gas phase; we used photoelectron spectroscopy to probe t

295 hich are highly reactive with O((3)P) in the gas phase, were not previously investigated.

296 eby increasing the intrinsic basicity in the gas phase, while the bulk prevents efficient cation solv

297 es and dynamics of these biomolecules in the gas phase with beta-carotene as a particularly interesti

298 ore compact molecules were discovered in the gas phase with thus far unknown structures.

299 N, SCN, BO) trianions is demonstrated in the gas phase, with BeB11 (CN)12(3-) exhibiting colossal sta

300 ions of nanoscale vent holes on each chip by gas-phase Xenon difluoride etching.